EP0157583A2 - Compositions lubrifiantes à base d'huile - Google Patents

Compositions lubrifiantes à base d'huile Download PDF

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Publication number
EP0157583A2
EP0157583A2 EP85302112A EP85302112A EP0157583A2 EP 0157583 A2 EP0157583 A2 EP 0157583A2 EP 85302112 A EP85302112 A EP 85302112A EP 85302112 A EP85302112 A EP 85302112A EP 0157583 A2 EP0157583 A2 EP 0157583A2
Authority
EP
European Patent Office
Prior art keywords
linear
trimellitate
ester
composition according
branched chain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85302112A
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German (de)
English (en)
Other versions
EP0157583A3 (fr
Inventor
Andrew Christopher Currie
Alan Stuart Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of EP0157583A2 publication Critical patent/EP0157583A2/fr
Publication of EP0157583A3 publication Critical patent/EP0157583A3/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/68—Esters
    • C10M129/72—Esters of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02—Petroleum fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C10M105/36—Esters of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/08—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
    • C10M2203/1045—Aromatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C10M2203/1065—Naphthenic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
    • C10M2203/1085—Residual fractions, e.g. bright stocks used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/003—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C10M2205/0265—Butene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/284—Esters of aromatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/285—Esters of aromatic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/285—Esters of aromatic polycarboxylic acids
    • C10M2207/2855—Esters of aromatic polycarboxylic acids used as base material

Definitions

  • the present invention relates to oil-based lubricant compositions comprising esters of aromatic polycarboxylic acids.
  • Oil-based lubricants conventionally contain a mineral oil, a hydrocarbon polymer e.g. a polybutene and an organic ester as the main components.
  • the esters are added to the lubricants to improve their performance in specific applications.
  • the choice of ester used is limited by several factors such as viscosity index, compatibility with hydrocarbon base oil components (e.g. polybutenes), volatility and oxidative stability.
  • One type of ester which meets most of these criteria is that derived from trimellitic acid and linear primary alcohols.
  • a specific example is an ester derived from trimellitic acid and a mixture of linear Cg and C 10 primary alcohols.
  • trimellitates of linear primary alcohols suffer from some disadvantages under low temperature conditions. For instance, such trimellitates have unacceptable low temperature compatibility with the hydrocarbon base oil components in the lubricant. More importantly, lubricants containing trimellitates of linear primary alcohols solidify on standing at low temperatures, e.g. around -10°C. These disadvantages are significant if the lubricants are to be used in cold environments especially if used as crank case lubricants in automotive engines.
  • the present invention is a lubricant composition
  • a lubricant composition comprising a mineral oil, a hydrocarbon base oil component and a trimellitate ester component characterised in that the ester component is either a mixture of a trimellitate ester of a branched chain alcohol and a trimellitate ester of a linear alcohol, or a trimellitate ester derived from a mixture of linear and branched chain alcohols.
  • the hydrocarbon base oil component referred to herein is preferably a hydrocarbon polymer, most preferably a polybutene.
  • the weight average molecular weight of the polybutene used is suitably from 200 to 6000, preferably from 1000 to 3000.
  • trimellitate esters are suitably those of linear and branched chain primary alcohols and are preferably derived by reacting trimellitic acid or the anhydride thereof with one or more of the appropriate primary alcohols having 8 to 10 carbon atoms.
  • trimellitate ester component is more preferably derived by the reaction of trimellitic anhydride with a mixture of the relevant linear and branched primary alcohols. Trimellitate esters which are derived from mixtures of isodecanol and C S -C 10 linear alcohols are particularly preferred.
  • the relative amounts of the trimellitate esters derived from linear and branched chain primary alcohols will depend upon the intended use of the lubricant composition. However, for lubricants usable in low temperature environments, the relative proportions of linear trimellitate esters to branched chain trimellitate esters is suitably from 4:1 to 1:4, preferably from 2:1 to 1:2 by weight.
  • the lubricant composition may contain other conventional additives such as antioxidants, detergents, stabilizers and the like.
  • trimellitate esters were prepared from trimellitic anhydride and the respective alcohol using a round-bottom two litre flask fitted with anchor stirrer, thermometer pocket, nitrogen sparge and Dean and Stark head/condenser. All products were prepared using conventional stannous oxalate catalysts, at a maximum reaction temperature of 210°C using conventional techniques.
  • the alkyl group composition of esters prepared is detailed in Table 1.
  • the mixed trimellitate of linear C 8 /C 10 alcohol and isodecanol was found to offer both a much reduced viscosity ratio compared to a mixed tri(isodecyl/tridecyl) trimellitate and an acceptable low temperature hydrocarbon compatability.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Fertilizers (AREA)
  • Lubricants (AREA)
EP85302112A 1984-03-28 1985-03-26 Compositions lubrifiantes à base d'huile Withdrawn EP0157583A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8408017 1984-03-28
GB848408017A GB8408017D0 (en) 1984-03-28 1984-03-28 Oil-based lubricant compositions

Publications (2)

Publication Number Publication Date
EP0157583A2 true EP0157583A2 (fr) 1985-10-09
EP0157583A3 EP0157583A3 (fr) 1987-08-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP85302112A Withdrawn EP0157583A3 (fr) 1984-03-28 1985-03-26 Compositions lubrifiantes à base d'huile

Country Status (2)

Country Link
EP (1) EP0157583A3 (fr)
GB (1) GB8408017D0 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0264842A2 (fr) * 1986-10-18 1988-04-27 BASF Aktiengesellschaft Utilisation d'esters d'acides carboxyliques dans des lubrifiants complètement ou partiellement synthétiques ainsi que des lubrifiants contenant lesdits esters
EP0288620A1 (fr) * 1987-04-27 1988-11-02 Kao Corporation Procédé de traitement de fibres et composition utilisée à cet effet
EP0325860A1 (fr) * 1987-12-29 1989-08-02 Exxon Research And Engineering Company Huile lubrifiante pour le travail des métaux
WO1989010345A1 (fr) * 1988-04-18 1989-11-02 The Lubrizol Corporation Composition fluide synthetique stable a la chaleur et a l'oxydation
US5164122A (en) * 1988-04-18 1992-11-17 The Lubrizol Corporation Thermal oxidatively stable synthetic fluid composition
WO1999011599A1 (fr) * 1997-08-29 1999-03-11 RWE-DEA Aktiengesellschaft für Mineraloel und Chemie Esters d'acides polycarboxyliques aromatiques avec des 2-alkylalcan-1-ols
US6465400B1 (en) 1998-12-25 2002-10-15 Idemitsu Kosan Co., Ltd. Lubricating oil composition for high-temperature use
DE102011102540A1 (de) * 2011-05-26 2012-11-29 KLüBER LUBRICATION MüNCHEN KG Hochtemperaturöl
WO2016096074A3 (fr) * 2014-12-17 2016-09-01 Klüber Lubrication München Se & Co. Kg Lubrifiants haute température
WO2016096075A3 (fr) * 2014-12-17 2016-09-01 Klüber Lubrication München Se & Co. Kg Lubrifiant haute température pour les industries alimentaires
EP3147317A1 (fr) * 2015-09-28 2017-03-29 Evonik Degussa GmbH Ester de tripentyle de l'acide trimellitique
CN111187649A (zh) * 2020-02-05 2020-05-22 新疆工程学院 一种基于嵌段聚酯化学改性的偏苯三甲酸酯润滑油基础油及其制备方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113248383A (zh) * 2021-05-19 2021-08-13 山东信发瑞捷新材料科技有限公司 高粘度指数偏苯三酸酯的合成方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2102272A1 (fr) * 1970-08-14 1972-04-07 Ciba Geigy Composition de base pour lubrifiants synthetiques ou fluides fonctionnels
US3833618A (en) * 1970-09-16 1974-09-03 Standard Oil Co 4-(high molecular weight alkyl-substituted carbophenoxy)phthalic anhydride and analogous diacid
US3954812A (en) * 1973-05-10 1976-05-04 Standard Oil Company Polybutene composition containing halogen-containing additives and use thereof
GB1481270A (en) * 1975-12-31 1977-07-27 Hercules Inc Synthetic oil lubricant
GB1499316A (en) * 1974-10-04 1978-02-01 Bp Chem Int Ltd Polybutene compositions

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2102272A1 (fr) * 1970-08-14 1972-04-07 Ciba Geigy Composition de base pour lubrifiants synthetiques ou fluides fonctionnels
US3833618A (en) * 1970-09-16 1974-09-03 Standard Oil Co 4-(high molecular weight alkyl-substituted carbophenoxy)phthalic anhydride and analogous diacid
US3954812A (en) * 1973-05-10 1976-05-04 Standard Oil Company Polybutene composition containing halogen-containing additives and use thereof
GB1499316A (en) * 1974-10-04 1978-02-01 Bp Chem Int Ltd Polybutene compositions
GB1481270A (en) * 1975-12-31 1977-07-27 Hercules Inc Synthetic oil lubricant

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0264842A2 (fr) * 1986-10-18 1988-04-27 BASF Aktiengesellschaft Utilisation d'esters d'acides carboxyliques dans des lubrifiants complètement ou partiellement synthétiques ainsi que des lubrifiants contenant lesdits esters
EP0264842A3 (en) * 1986-10-18 1989-03-22 Basf Aktiengesellschaft Use of carboxylic-acid esters in completely or partially synthetic lubricants, and lubricants containing them
EP0288620A1 (fr) * 1987-04-27 1988-11-02 Kao Corporation Procédé de traitement de fibres et composition utilisée à cet effet
US4789381A (en) * 1987-04-27 1988-12-06 Kao Corporation Fiber treating process and composition used therefor
AU612218B2 (en) * 1987-12-28 1991-07-04 Exxon Research And Engineering Company Metalworking lubricating oil
EP0325860A1 (fr) * 1987-12-29 1989-08-02 Exxon Research And Engineering Company Huile lubrifiante pour le travail des métaux
US5068049A (en) * 1987-12-29 1991-11-26 Exxon Research & Engineering Company Method of cold rolling a metal
WO1989010345A1 (fr) * 1988-04-18 1989-11-02 The Lubrizol Corporation Composition fluide synthetique stable a la chaleur et a l'oxydation
US5164122A (en) * 1988-04-18 1992-11-17 The Lubrizol Corporation Thermal oxidatively stable synthetic fluid composition
WO1999011599A1 (fr) * 1997-08-29 1999-03-11 RWE-DEA Aktiengesellschaft für Mineraloel und Chemie Esters d'acides polycarboxyliques aromatiques avec des 2-alkylalcan-1-ols
US6310234B1 (en) 1997-08-29 2001-10-30 Rwe-Dea Aktiengesellschaft Fuer Mineraloel Und Chemie Esters of aromatic polycarboxylic acids with 2-alkylalkan-1-ols
US6465400B1 (en) 1998-12-25 2002-10-15 Idemitsu Kosan Co., Ltd. Lubricating oil composition for high-temperature use
USRE39382E1 (en) * 1998-12-25 2006-11-07 Idemitsu Kosan Co., Ltd. Lubricating oil composition for high-temperature use
WO2012159738A1 (fr) * 2011-05-26 2012-11-29 Klüber Lubrication München Se & Co. Kg Huile haute température
EA026445B1 (ru) * 2011-05-26 2017-04-28 Клюбер Лубрикацион Мюнхен Се Унд Ко. Кг Высокотемпературное масло и его применение
DE102011102540B4 (de) * 2011-05-26 2013-12-12 KLüBER LUBRICATION MüNCHEN KG Hochtemperaturöl
AU2012261221B2 (en) * 2011-05-26 2016-05-12 KLUBER LUBRICATION MUNCHEN SE & Co. KG High temperature oil
DE102011102540A1 (de) * 2011-05-26 2012-11-29 KLüBER LUBRICATION MüNCHEN KG Hochtemperaturöl
JP2017538838A (ja) * 2014-12-17 2017-12-28 クリューバー リュブリケーション ミュンヘン ソシエタス ヨーロピア ウント コンパニー コマンディートゲゼルシャフトＫｌｕｅｂｅｒ Ｌｕｂｒｉｃａｔｉｏｎ Ｍｕｅｎｃｈｅｎ ＳＥ ＆ Ｃｏ．ＫＧ 高温用潤滑剤
WO2016096075A3 (fr) * 2014-12-17 2016-09-01 Klüber Lubrication München Se & Co. Kg Lubrifiant haute température pour les industries alimentaires
WO2016096074A3 (fr) * 2014-12-17 2016-09-01 Klüber Lubrication München Se & Co. Kg Lubrifiants haute température
JP2017538840A (ja) * 2014-12-17 2017-12-28 クリューバー リュブリケーション ミュンヘン ソシエタス ヨーロピア ウント コンパニー コマンディートゲゼルシャフトＫｌｕｅｂｅｒ Ｌｕｂｒｉｃａｔｉｏｎ Ｍｕｅｎｃｈｅｎ ＳＥ ＆ Ｃｏ．ＫＧ 食品産業のための高温用潤滑剤
EP3372660A1 (fr) * 2014-12-17 2018-09-12 Klüber Lubrication München SE & Co. KG Lubrifiants haute température
EP3372659A1 (fr) * 2014-12-17 2018-09-12 Klüber Lubrication München SE & Co. KG Lubrifiants haute température
EP3375850A1 (fr) * 2014-12-17 2018-09-19 Klüber Lubrication München SE & Co. KG Lubrifiant haute température pour l'industrie alimentaire
EP3375851A1 (fr) * 2014-12-17 2018-09-19 Klüber Lubrication München SE & Co. KG Lubrifiant haute température pour l'industrie alimentaire
EP3147317A1 (fr) * 2015-09-28 2017-03-29 Evonik Degussa GmbH Ester de tripentyle de l'acide trimellitique
EP3147318A1 (fr) * 2015-09-28 2017-03-29 Evonik Degussa GmbH Ester de triphényle de l'acide triméllitique
CN111187649A (zh) * 2020-02-05 2020-05-22 新疆工程学院 一种基于嵌段聚酯化学改性的偏苯三甲酸酯润滑油基础油及其制备方法
CN111187649B (zh) * 2020-02-05 2022-01-28 新疆工程学院 一种基于嵌段聚酯化学改性的偏苯三甲酸酯润滑油基础油及其制备方法

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GB8408017D0 (en) 1984-05-10
EP0157583A3 (fr) 1987-08-05

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