EP0126984B1 - Isolateur électrique présentant une insensibilité à la pollution - Google Patents
Isolateur électrique présentant une insensibilité à la pollution Download PDFInfo
- Publication number
- EP0126984B1 EP0126984B1 EP84104677A EP84104677A EP0126984B1 EP 0126984 B1 EP0126984 B1 EP 0126984B1 EP 84104677 A EP84104677 A EP 84104677A EP 84104677 A EP84104677 A EP 84104677A EP 0126984 B1 EP0126984 B1 EP 0126984B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- zinc oxide
- insulator
- pollution
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000615 nonconductor Substances 0.000 title claims abstract description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 239000011787 zinc oxide Substances 0.000 claims abstract description 18
- 239000004065 semiconductor Substances 0.000 claims abstract description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 8
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 8
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 6
- 239000011521 glass Substances 0.000 claims abstract description 5
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 3
- 239000003989 dielectric material Substances 0.000 claims abstract description 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052797 bismuth Inorganic materials 0.000 claims abstract 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052804 chromium Inorganic materials 0.000 claims abstract 2
- 239000011651 chromium Substances 0.000 claims abstract 2
- 229910017052 cobalt Inorganic materials 0.000 claims abstract 2
- 239000010941 cobalt Substances 0.000 claims abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract 2
- 239000012212 insulator Substances 0.000 claims description 23
- 239000000919 ceramic Substances 0.000 claims 2
- 230000035945 sensitivity Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 11
- 210000003298 dental enamel Anatomy 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003570 air Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B17/00—Insulators or insulating bodies characterised by their form
- H01B17/50—Insulators or insulating bodies characterised by their form with surfaces specially treated for preserving insulating properties, e.g. for protection against moisture, dirt, or the like
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B19/00—Apparatus or processes specially adapted for manufacturing insulators or insulating bodies
- H01B19/04—Treating the surfaces, e.g. applying coatings
Definitions
- the invention relates to electrical insulators having improved insensitivity to pollution and more particularly those whose dielectrics are made of glass or porcelain.
- the semiconductor layer plays practically no role, because it is the polluted layer which fixes the distribution of potential, irregularly.
- the present invention as defined by claim 1 overcomes these drawbacks.
- composition of the coating according to the invention is known per se and in use for certain electronic components called varistors - see for example document EP-A-0 000 864.
- varistors see for example document EP-A-0 000 864.
- a pollution problem surface and current distribution between a polluted layer and the underlying varistor does not arise for such components.
- a variation in the current density of the order of 10 6 corresponds to a variation in the voltage gradient close to 2.
- the coefficients k and ⁇ are characteristic of the material and geometric dimensions (in particular the insulator's creepage distance, coating thickness).
- the zinc oxide content in the coating is advantageously greater than 90%.
- Said metal oxide is advantageously chosen from the group formed by bismuth oxide, manganese oxide, cobalt oxide, chromium oxide, antimony oxide.
- the particular characteristic of the coating based on zinc oxide used in the context of the present invention is that it prevents the local formation of arcs in the dry areas.
- the distribution of the electric field on the surface of the insulator is improved and this prevents the bypass arc.
- the voltage can be stabilized below the threshold. bypass in the air.
- FIG. 1 there is shown a section 1 of an insulator constituted by an assembly of insulating elements such as 2.
- Each element 2 substantially comprises a dielectric 3 made of glass or porcelain for example, provided with a metal cover 4 and a metal connecting rod 5.
- the dielectric 3 is coated externally with a thin layer 6 based on zinc oxide doped with at least one other metal oxide.
- the layer 6 can have a thickness of between 0.05 and 0.5 mm.
- this mixture is sintered at 1250 ° C. and then, for 10 grams of product, 0.5 mole of Bi 2 0 3 (0.2691 g of Bi 2 0 3 ) is added.
- composition and thickness of the coating layer are adjusted according to the electrical characteristics desired for said layer.
- the shape of the insulator also comes into play.
- the establishment of the coating based on zinc oxide can be carried out according to various procedures.
- an insulator comprising a porcelain dielectric
- the powder is shaped, for example, by spraying or by vacuum deposition, in the form of a layer on the external surface of the dielectric.
- the thickness of the layer is chosen to be sufficient to be compatible with the overheating it will have to undergo during the operation of the insulator and according to the desired electrical characteristics.
- the deposition of the zinc oxide-based layer can be carried out in particular by vacuum deposition and spray deposition techniques.
- the measurements were made at 25 ° C.
- the curve (A) relates to a material corresponding to the composition of the first example mentioned above and the curve (B) to a semiconductor enamel used according to the prior art for coating a insulator.
- the intensity of the current which crosses the zinc oxide is very important, higher than 1000 amperes and being able to reach 30000 amperes, whereas in the insulator according to the invention, the intensity is between the milliamp and the amp.
- the action of the zinc oxide-based layer is local and manifests itself in several places at fairly short time intervals without causing the service to be interrupted.
- the action is instantaneous; it concerns the entire arrester, which is passed through entirely, and causes the service to stop by opening the line protection circuit breakers.
Landscapes
- Inorganic Insulating Materials (AREA)
- Organic Insulating Materials (AREA)
- Thermistors And Varistors (AREA)
- Insulators (AREA)
- Insulated Conductors (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Spark Plugs (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT84104677T ATE28533T1 (de) | 1983-04-29 | 1984-04-26 | Verschmutzungsunempfindlicher elektrischer isolator. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8307100 | 1983-04-29 | ||
FR8307100A FR2545259B1 (fr) | 1983-04-29 | 1983-04-29 | Isolateur electrique presentant une insensibilite amelioree a la pollution |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0126984A1 EP0126984A1 (fr) | 1984-12-05 |
EP0126984B1 true EP0126984B1 (fr) | 1987-07-22 |
Family
ID=9288375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84104677A Expired EP0126984B1 (fr) | 1983-04-29 | 1984-04-26 | Isolateur électrique présentant une insensibilité à la pollution |
Country Status (14)
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4803100A (en) * | 1987-10-21 | 1989-02-07 | International Business Machines Corporation | Suspension and use thereof |
US4835341A (en) * | 1988-03-08 | 1989-05-30 | Maxwell Laboratories, Inc. | Electrical insulator for use in plasma environment |
US5548089A (en) * | 1994-01-13 | 1996-08-20 | Cooper Industries, Inc. | Bushing for gas-insulated switchgear |
GB0103255D0 (en) * | 2001-02-09 | 2001-03-28 | Tyco Electronics Raychem Gmbh | Insulator arrangement |
KR100910417B1 (ko) | 2008-02-14 | 2009-08-04 | 삼광유리공업주식회사 | 내열 강화 유리 애자 및 그 제조방법 |
ES2787511T3 (es) * | 2010-05-28 | 2020-10-16 | Lapp Insulator Gmbh | Aislante compuesto |
FR3067164B1 (fr) | 2017-06-02 | 2019-08-02 | Sediver Sa | Procede de traitement d'un composant en verre ou porcelaine a revetement protecteur super-hydrophobe |
US12354766B2 (en) * | 2024-05-15 | 2025-07-08 | Chaohu University | Large-tonnage disc-shaped suspension ceramic insulator and prestressing assembling device and method for same |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB586064A (en) * | 1945-02-20 | 1947-03-05 | Taylor Tunnicliff And Company | An improved electrically-conductive ceramic coating or composition |
US2576723A (en) * | 1946-10-11 | 1951-11-27 | Bullers Ltd | Electric insulator having potential drop controlling means |
DE1003309B (de) * | 1954-05-17 | 1957-02-28 | Licentia Gmbh | Hochspannungsisolator, insbesondere der Verschmutzung ausgesetzter Freiluftisolator |
GB1112765A (en) * | 1965-06-01 | 1968-05-08 | Taylor Tunnicliff & Co Ltd | Improvements in or relating to semi-conducting ceramic glaze compositions |
GB1240854A (en) * | 1968-09-27 | 1971-07-28 | British Railways Board | Improvements relating to high voltage electrical insulators |
US3795499A (en) * | 1969-10-11 | 1974-03-05 | Ngk Insulators Ltd | Method of producing semi-conducting glaze compositions |
US3627905A (en) * | 1969-12-08 | 1971-12-14 | British Railways Board | High-voltage electrical insulator having a predetermined surface conductance |
DE2361204C3 (de) * | 1973-12-06 | 1978-11-23 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Elektrische Hochspannungseinrichtung mit Isolierkörpern |
US4031498A (en) * | 1974-10-26 | 1977-06-21 | Kabushiki Kaisha Meidensha | Non-linear voltage-dependent resistor |
CH601135A5 (enrdf_load_stackoverflow) * | 1976-07-01 | 1978-06-30 | Bbc Brown Boveri & Cie | |
DE2735484C2 (de) * | 1977-08-05 | 1984-06-07 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur Herstellung von Dickfilm-Varistoren mit Zinkoxid als Hauptkomponente |
-
1983
- 1983-04-29 FR FR8307100A patent/FR2545259B1/fr not_active Expired
-
1984
- 1984-04-23 US US06/602,676 patent/US4563544A/en not_active Expired - Fee Related
- 1984-04-26 NO NO841647A patent/NO164389C/no unknown
- 1984-04-26 JP JP59085067A patent/JPS59207515A/ja active Granted
- 1984-04-26 AT AT84104677T patent/ATE28533T1/de not_active IP Right Cessation
- 1984-04-26 DE DE8484104677T patent/DE3464983D1/de not_active Expired
- 1984-04-26 CA CA000452824A patent/CA1250916A/fr not_active Expired
- 1984-04-26 EP EP84104677A patent/EP0126984B1/fr not_active Expired
- 1984-04-27 NZ NZ207972A patent/NZ207972A/en unknown
- 1984-04-27 ZA ZA843160A patent/ZA843160B/xx unknown
- 1984-04-27 ES ES1984287936U patent/ES287936Y/es not_active Expired
- 1984-04-27 AU AU27441/84A patent/AU564892B2/en not_active Ceased
- 1984-04-27 MX MX201180A patent/MX158055A/es unknown
- 1984-04-27 BR BR8401989A patent/BR8401989A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0126984A1 (fr) | 1984-12-05 |
AU564892B2 (en) | 1987-08-27 |
NO164389B (no) | 1990-06-18 |
BR8401989A (pt) | 1984-12-04 |
NZ207972A (en) | 1986-07-11 |
JPH0247808B2 (enrdf_load_stackoverflow) | 1990-10-23 |
US4563544A (en) | 1986-01-07 |
DE3464983D1 (en) | 1987-08-27 |
FR2545259B1 (fr) | 1985-12-27 |
NO841647L (no) | 1984-10-30 |
FR2545259A1 (fr) | 1984-11-02 |
ES287936U (es) | 1985-11-16 |
AU2744184A (en) | 1984-11-01 |
JPS59207515A (ja) | 1984-11-24 |
MX158055A (es) | 1988-12-29 |
CA1250916A (fr) | 1989-03-07 |
NO164389C (no) | 1990-09-26 |
ZA843160B (en) | 1985-07-31 |
ATE28533T1 (de) | 1987-08-15 |
ES287936Y (es) | 1986-06-16 |
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