EP0123461A2 - Überschichtete lichtempfindliche Einheiten - Google Patents

Überschichtete lichtempfindliche Einheiten Download PDF

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Publication number
EP0123461A2
EP0123461A2 EP84302259A EP84302259A EP0123461A2 EP 0123461 A2 EP0123461 A2 EP 0123461A2 EP 84302259 A EP84302259 A EP 84302259A EP 84302259 A EP84302259 A EP 84302259A EP 0123461 A2 EP0123461 A2 EP 0123461A2
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EP
European Patent Office
Prior art keywords
layer
percent
weight
selenium
photoresponsive device
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Granted
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EP84302259A
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English (en)
French (fr)
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EP0123461A3 (en
EP0123461B1 (de
Inventor
Andrew R. Melnyk
Clifford H. Griffiths
Paul J. Brach
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Xerox Corp
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Xerox Corp
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Publication of EP0123461A2 publication Critical patent/EP0123461A2/de
Publication of EP0123461A3 publication Critical patent/EP0123461A3/en
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Publication of EP0123461B1 publication Critical patent/EP0123461B1/de
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/14—Inert intermediate or cover layers for charge-receiving layers

Definitions

  • This invention is generally directed to a layered photoresponsive device, and more specifically, the present invention is directed to such a device of the kind comprising, in the order stated, a substrate; a hole transport layer comprising an arylamine dispersed in a resinous binder composition; a charge carrier photogenerating layer; and a protective overcoating layer.
  • Photoresponsive devices including layered photoresponsive devices containing charge transport layers, and charge generating layers of selenium, selenium alloys, phthalocyanines, and the like are known.
  • photoreceptor materials comprised of inorganic or organic compositions wherein the charge carrier generation and charge carrier transport functions are accomplished by discrete contiguous layers are disclosed in the prior art.
  • photoreceptor materials are disclosed in the prior art which include an overcoating layer of an electrically insulating polymeric material, and in conjunction with this overcoated type photoreceptor, there have been proposed a number of imaging methods.
  • the surface of the transparent plastic is electrostatically charged to a desired polarity, followed by exposing the device to activating radiation, which generates a hole electron pair in the photoconductive layer, causing electrons to move to the plastic layer and neutralize the positive charges contained on the free surface of the plastic layer, thus creating an electrostatic image.
  • the diamine transport molecules contained in the transport layer can be adversely affected, and degraded by ultraviotet light, and corona exposures, rendering such devices substantially useless for obtaining continuous high quality images. This is particularly a problem with regard to devices containing a top photogenerating layer, which is charged positively.
  • the diamines contained in the transport layer are converted to a cationic radical by ultraviolet light, this radical causing the positive charges contained on the surface of the layered imaging member to be undesirably eliminated.
  • the overcoating layer of the photoresponsive device of the present invention is comprised of materials that will absorb damaging short wavelength light, while transmitting the longer wavelengths to the photogeneration layer. Since the damaging light radiation extends into the visible, that is wavelength of 450 nanometers the photosensitivity is reduced in the blue by a purely absorptive layer. The photosensitivity at these blue wavelengths can however be restored by using as an overcoat layer materials that are photosensitive to the the short wavelengths they absorb.
  • the improved layered photoresponsive device of the present invention accomplishes this important objective.
  • the present invention provides a photoresponsive device of the kind specified which is characterised in that the overcoating layer comprises an ultraviolet light absorbing composition.
  • a layered photoresponsive imaging device wherein the aryldiamine molecules that escape from the hole transport layer are prevented from degradation by the protective overcoating layer.
  • the overcoating layer functions as an ultraviolet light absorbant substance, while simultaneously functioning as a visible light photogeneration layer, and as a physical protectant layer for the other layers contained in the device.
  • the improved photoresponsive devices of the present invention can be prepared by a number of known methods, the process parameters and the order of coating the layers being dependent on the device desired.
  • the improved photoresponsive device of the present invention can be prepared by providing a conductive substrate, and applying thereto by solvent coating processes, laminating processes, solvent spraying processes, or other methods, a hole transport layer, a photogenerating layer, and a protective overcoating.
  • the improved photoresponsive device of the present invention can be prepared by depositing the hole transport layer and photogenerating layers by a solvent spraying process, followed by application of the protective overcoating layer by vacuum deposition.
  • the hole transport, and photogenerating layers are generally deposited at room temperature, while the overcoating layer is applied at higher temperatures, with the thickness of the layers being controlled for example by the proportions of solvent to hole transport layer or photogenerating layer utilized, and by repeating the coating process as appropriate.
  • solvents that may be selected in the solvent spraying process include methylene chloride, ethylene chloride, and mixtures thereof.
  • the improved layered photoresponsive device of the present invention can be selected for use in various imaging systems, and more importantly, can function in imaging and/or printing systems utilizing visible light and/or infrared light
  • the improved photoresponsive devices of the present invention can be selected for use in imaging devices where the device is positively charged and wherein the arylamine materials selected for use in the transport layer are not degraded by ultraviolet light.
  • the imaging method of the present invention involves positively charging the photoresponsive device described herein, subjecting the device to imagewise charging for the purpose of forming an electrostatic latent image thereon, developing the latent image with a developer composition comprised of toner particles and carrier particles, followed by transferring the image to a suitable substrate such as paper, and permanently affixing the image thereto.
  • the photoresponsive device can be selected for use in printing systems, that is in those apparatuses wherein a iaser, such as a gallium arsenide laser, or image bars are used for generating the image to be developed.
  • a iaser such as a gallium arsenide laser
  • image bars are used for generating the image to be developed.
  • Illustrated in Figure 1 is the improved photoresponsive device of the present invention, generally designated 1, and comprising a substrate 3, a hole or charge transport layer 5, containing a hole transporting composition dispersed in an inert resinous binder 6, a charge carrier photogenerating layer 7, containing a photogenerating pigment optionally dispersed in an inert resinous binder 8, and a protective overcoating layer 9.
  • the substrate layer 3 may be opaque or substantially transparent, and may comprise suitable materials having the appropriate mechanical properties.
  • the substrate is comprised of an insulating material, such as an organic or inorganic polymeric material, a layer of an organic or inorganic material having a semiconductive surface layer arranged thereon, or a conductive material such as for example, aluminum, chromium, nickel, indium, tin oxide, brass, or the like.
  • insulating layers that can be selected as the substrate include various resinous materials, such as polycarbonates, polyesters, and the like, however, the substrate fs preferably comprised of a material commercially available as aluminized Mylar.
  • the substrate may be flexible or rigid, and may have a number of different configurations, including a plate, cylindrical drum, a scroll, an endless flexible belt, and the like.
  • the substrate is in the form of an endless flexible belt, or a rigid cylindrical drum.
  • this layer may be of substantial thickness, for example, over 10 millimeters, or of minimum thickness, providing there are no adverse effects with the resulting device. In one preferred embodiment, the thickness of this layer ranges from about 3 millimeters to about 10 millimeters.
  • the hole transport layer 5 can be comprised of a number of suitable materials which are capable of transporting holes, this layer generally having a thickness in the range of from about 5 to about 50 micrometers, and preferably this layer is of a thickness of from about 20 to about 40 micrometers.
  • Transport layer 5 thus comprises an arylamine electron donor dispersed in an inert resinous binder material 6.
  • electron donor molecules include those as described in U.S. Patent 4,265,990
  • the inert highly insulating resinous binder 6, which has a resistivity of at least 10 12 ohm-cm to prevent undue dark decay, is a material which is not necessarily capable of supporting the injection of holes from the photogenerator layer, and is not capable of allowing the transport of these holes through the material.
  • the resin becomes electrically active when it contains from about 10 to 75 weight percent of the substituted N,N,N',N'-tetraphenyl-[1,1'-biphenyl]4,4'-diamines.
  • diamines include, N,N'-diphenyl-N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine wherein alkyl is selected from the group consisting of methyl, such as 2-methyl, 3-methyl, and 4-methyl, ethyl, propyl, butyl, hexyl, and the like.
  • the amine is N,N'-diphenyl-N,N'- bis(halophenyl)-[1,1'-biphenyl]-4,4'-diamine wherein halo is 2-chloro, 3-chloro, or 4-chloro.
  • electrically active donor compositions which can be dispersed in the electrically inactive resin to form a layer which will transport holes include the arylamines, triphenylamine, bis-(4-diethylamino-2-methylphenyl)phenylmethane; bis - (4-diethylaminophenyl)phenylmethane; 1 -phenyl-3-(4'-diethylaminostearyl)-5-(4"-diethylaminophenyl) pyrazoline; 4-diethylaminobenzaldehyde-1,1-diphenyl hydrazone; 2,5-bis-(4'diethylaminophenyl)-1,3,4-oxadiazole; and 1,4-bis-[bis(4'-(phenylmethyl)-amino-2'-methylphenyl)methyl] benzene.
  • a preferred hole transport layer in a thickness of from about 10 micrometers to about 20 micrometers, is comprised of 35 percent by weight of the diamine N,N'-diphenyl-N,N'-bis(3-methylphenyl)1,1'-biphenyl-4,4'-diamine, dispersed in 65 percent by weight of the polycarbonate resin commercially available as Makrolon.
  • Illustrative examples of insulating resinous binders 6 for the hole transport layer include in addition to polycarbonate resins commercially available as Makrolon, Merlon and Lexan, polysulfones polystyrene, and the like.
  • the diamine transport molecule is dispersed in the resinous binder, in an amount ranging from about 25 percent by weight to 70 percent by weight, and preferably in an amount of from about 30 percent by weight to about 50 percent by weight.
  • the photogenerating layer 7 includes for example, numerous photoconductive charge carrier generating materials providing they are electronically compatible with the charge carrier transport layer, that is, they can inject photoexcited charge carriers into the transport layer and charge carriers can travel in both directions across the interface between the two layers.
  • the photogenerating layer 7 can be comprised of inorganic photosensitive pigments such as trigonal selenium, mixtures of Groups IA and IIA elements, cadmium selenide, cadmiun sulfur selenide, copper and chlorine doped cadmium sulfide, and trigonal selenium doped with sodium carbonate reference U.S. Patents 4,232,102 and 4,233,283, and the like, optionally dispersed in various resinous binders.
  • the photogenerating layer can also contain organic charge carrier generating materials such as phthaiocyanines, including for example, metal phthalocyanines, metal free phthalocyanines, vanadyl phthalocyanines, squaraine pigments, such as methyl squarilium pigments, hydroxy squarilium pigments, and mixtures thereof, optionally dispersed in resinous binders.
  • organic charge carrier generating materials such as phthaiocyanines, including for example, metal phthalocyanines, metal free phthalocyanines, vanadyl phthalocyanines, squaraine pigments, such as methyl squarilium pigments, hydroxy squarilium pigments, and mixtures thereof, optionally dispersed in resinous binders.
  • photogenerating materials not disclosed herein can be selected for the photoresponsive device of the present invention including, for example, other phthalocyanines, such as copper phthalocyanine, zinc phthalocyanine, magnesium phthalocyanine, the x-form of metal free phthalocyanine, and the like.
  • other phthalocyanines such as copper phthalocyanine, zinc phthalocyanine, magnesium phthalocyanine, the x-form of metal free phthalocyanine, and the like.
  • the photogenerating pigments are usually dispersed in an inactive resinous binder, 8, illustrative examples of which include polyesters, polycarbonates, polystyrenes, polysulfones, phenoxy resins, epoxy resins, and the like, with polyesters being preferred.
  • the photogenerating pigment is contained in the resinous binder in an amount of from about 5 percent by weight to about 80 percent by weight, and preferably in an amount of from about 10 percent by weight to about 40 percent by weight.
  • the resinous binder is present in an amount of from about 95 percent by weight to about 20 percent by weight, and preferably in an amount of from about 90 percent by weight to about 60 percent by weight.
  • the thickness of the photogenerating layer depends on a number of factors including the thicknesses of the other layers, generally, however, this layer ranges in thickness of from about 0.01 micrometers to about 10 micrometers, and preferably is of a thickness of from about 0.1 micrometers to about 1.0 micrometers.
  • the maximum thickness of this layer is dependent primarily on factors such as mechanical considerations, while the minimum thickness of this layer is dependent on for example, the pigment particle size, optical density of the photogenerating pigment, and the like.
  • the overcoating layer 9 which generally ranges in thickness of from about 0.05 micrometers to about 10 micrometers, and preferably is of a thickness of from about 0.2 micrometers to about 5 micrometers, is comprised of materials that are capable of absorbing ultraviolet light so as to prevent the degradation of the electron donor arylamine materials contained in the transport layer 5, which materials diffuse to some extent into layer 7. Also, this layer can function as a protective layer for the photoresponsive device.
  • Illustrative examples of materials selected for layer 9 include selenium, alloys of selenium, such as arsenic selenium, containing 0.1 to 50 percent by weight of arsenic, and 99.9 to about 50 percent by weight selenium, arsenic selenium alloys containing halogens, such as chlorine or iodine, in an amount of from about 1 part per million to about 1 percent, as well as selenium tellurium alloys, arsenic selenium tellurium alloys, the above selenium alloys containing germanium, and the like.
  • selenium such as arsenic selenium, containing 0.1 to 50 percent by weight of arsenic, and 99.9 to about 50 percent by weight selenium
  • arsenic selenium alloys containing halogens, such as chlorine or iodine in an amount of from about 1 part per million to about 1 percent, as well as selenium tellurium alloys, arsenic selenium tellurium alloys,
  • overcoating materials not specifically disclosed herein may also be selected providing the objectives of the present invention are achieved including, for example, other inorganic and organic materials, such as vacuum deposited phthalocyanines, subject to the provision that these materials absorb ultraviolet light, and function as an electrically active charge generating layer.
  • solvent coated organic polymers may be used provided they absorb ultraviolet light, or contain ultraviolet absorbing additives, and further, providing that the coating process does not result in the diffusion of the arylamine transport molecule into the overcoating layer 9.
  • organic materials that may be selected for the overcoating layer 9 include various polymers containing therein organic and/or inorganic ultraviolet light absorbers.
  • Examples of these materials include polycarbonates, polyesters, silicon polymers, siloxanes, and the like, having dispersed therein ultraviolet light absorbers, such as zinc oxide, amorphous or crystalline particles of selenium, arsenic, or selenium tellurium alloys, phenidone, uvinul, and the like.
  • the ultraviolet light absorbers are present in the organic material in an amount ranging from about 5 percent by weight to about 40 percent by weight, and preferably in an amount of from about 10 percent by weight to about 20 percent by weight.
  • overcoating layer 9 prevents the degradation of the arylamines contained in the charge transport layer that have migrated or diffused into the photogenerating layer during, for example the solvent coating of this layer.
  • the overcoating layer is believed to prevent the penetration into the photoresponsive device of ultraviolet light, and ionized molecules resulting from corona eiposure.
  • the action of ultraviolet light and ionized molecules on the charge transport amine molecules is believed to result in the formation of cations. This causes the photoresponsive device to have unstable electricals due to the trapped cation radicals. These unstable electricals cause an increase residual voltage or loss in charge acceptance of the photoresponsive device due to charge sweepout, adversely affecting the device and resulting in images of very low quality.
  • the overcoating layer 9 can also act as a protectant, both physical and chemical, for the photoresponsive device, and further, this overcoating layer prevents ions generated by the corona charging device to reach the photogenerating layer. More specifically, as a protective layer, the overcoating layer prevents the mechanical abrasion and/or chemical damage relating to the developing, charging and cleaning processes selected for electrostatographic imaging methods.
  • this overcoating layer enables broad spectral response of the photoresponsive device in that it combines for example excellent blue and visible photoresponse of the selenium alloy, overcoating layer with excellent red and infrared photoresponse of the phthalocyanine generating layer.
  • the photoresponsive device of the present invention is useful primarily as an infrared imaging device, that can be selected for incorporation into various imaging systems, wherein light emitted by lasers are utilized. Such a device has sensitivity ranging from about 700 nanometers to about 900 nanomaters, and thus can be selected for use with solid state lasers, including heiium-neon lasers, and gallium arsenide lasers. However, as disclosed herein, the photoresponsive devices of the present invention are also sensitive to visible light, that is light having a wavelength of from about 400 nanometers to about 700 nanometers.
  • a preferred layered photoresponsive device of the present invention designated 10, and comprised of a substrate 15 of an aluminum drum in a thickness of 4 millimeters, a hole transport layer 17, containing 35 percent by weight of N,N'- diphenyl-N,N'-bis(3-methylphenyl)1,1'-biphenyl-4,4'-diamine dispersed in 18, 65 percent by weight of a polycarbonate commercially available as Merion, this layer having a thickness of from about 10 micrometers to about 25 micrometers, a photogenerating layer 19, comprised of 30 percent by weight of vanadyl phthalocyanine, dispersed in 20, 70 percent by weight of a polyester material, PE-100, commercially available from Goodyear Corporation, this layer having a thickness of 1 micrometer, and layer 21, the protective layer, comprised of an arsenic selenium alloy, containing 2 weight percent of arsenic, and 98 weight percent of selenium, this layer having a thickness of 1.0 micrometer
  • FIG. 3 Illustrated in Figure 3 is a another embodiment of the improved photoresponsive device of the present invention designated 25, this device being comprised of a substrate 30, of an electroformed nickel belt in a thickness of 100 micrometers, a charge transport layer 32, having a thickness of 16 micrometers, and containing 40 percent by weight of N,N'-diphenyl-N,N'-bis(3-methylphenyl)1,1'-biphenyl-4,4'. diamine, and 60 percent by weight of a polycarbonate, commercially available as Merlon, a photogenerating layer 34 containing 30 percent by weight of trigonal selenium, dispersed in 33, 70 percent by weight of a polyester material, PE-49,000, commercially available from E I.
  • a photogenerating layer 34 containing 30 percent by weight of trigonal selenium, dispersed in 33, 70 percent by weight of a polyester material, PE-49,000, commercially available from E I.
  • duPont Co. this layer having a thickness of 0.8 micrometers, and a protective layer 36, 0.5 micrometers in thickness containing a selenium arsenic alloy, containing 36 weight percent of arsenic, and 64 weight percent of selenium.
  • the processing steps were accomplished in a room containing red safe lights so as to not expose the materials, particularly the amine charge transport materials, to light of wavelengths less than 500 Angstroms, in order to prevent ultraviolet light degradation of such materials.
  • An overcoated photoreceptive device was prepared by applying, with spraying, with a Model No. 21 spray gun, commercially available from Binks, Inc., an amine charge transport layer onto a clean aluminum cylinder having a diameter of 83 millimeters.
  • the spraying was accomplished in a laminar air flow booth designed to process volatile solvents containing an entrance means and exhaust means.
  • This booth also contained a motor driven mandrel with the aluminum cylinder mounted thereon, which cylinder was rotated about the vertical axis of the mandrel at 290 revolutions per minute.
  • the Binks spray gun was located 20 centimeters from the aluminum cylinder, and the spray booth was maintained at a temperature of 20 degrees centigrade and a relative humidity of about 40 percent.
  • the aluminum cylinder Prior to spraying the aluminum cylinder was cleaned by dipping it into a solution containing 3 percent of sodium carbonate and 3 percent of sodium triphosphate, for 1 minute. Subsequently, the aluminum cylinder was removed from the solution, washed with water and immersed for 0.5 minutes in concentrated nitric acid, 67 weight percent. The cylinder was then removed from the nitric acid and rinsed thoroughly with deionized water.
  • the charge transport layer applied contained a 4 percent solid solution of a mixture of 65 percent by weight of the polycarbonate resin, Merlon M 39N, and 35 percent by weight of N,N'-diphenyl-N,N'- bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine.
  • This mixture was prepared by dissolving in a 0.5 liter amber bottle, the polycarbonate resin, Merlon M39N available commercially from Mobay Chemical, in a solution containing 60 percent by volume of methylene chloride and 40 percent by volume 1,1,2-trichloroethane.
  • the polycarbonate resin was dissolved by tumbling the solution mixture for one hour on a paint shaker, and after tumbling the resulting mixture was allowed to stand for about 24 hours at room temperature.
  • the photogenerating composition was prepared by mixing 30 percent by of weight vanadyl phthalocyanine, and 70 percent by weight of a polyester, commercially available from Goodyear as PE- 100 polyester. This mixture was placed in a 1 liter amber bottle, containing in a 60/40 volume ratio, a mixture of solvents of methylene chloride and 1,1,2-trichloroethylene. To the bottle was added steel shot, 3 millimeters in diameter. The contents of the bottle were then mixed on a paint shaker for 24 hours.
  • the resulfing device was dried at 100°C for 1.25 hours in a forced air oven, re sulting in a photogenerating layer having a dry thickness of 1 micrometer.
  • a top ultraviolet light absorbing over pating ayer was then applied to the above photogenerating layer by pacing th e aluminum cylinder, containing the charge transport layer, and the photogenerating layer in a vacuum chamber, and vacuum evaporating on the photogenerating layer, an alloy containing 98 percent by weight of selenium and 2 percent by weight of arseni
  • the vacuum chamber contained a horizontally rotating, motor driven shaft, a string of four crucibles, longer in length than the aluminum linder, these crucibles being of the size of 2 . 5 x 1 2. 5 cm, which cr ables were placed 30 cm in distance away from the cylinder.
  • an overcoating layer of an arsenic selenium alloy containing 2 percent by weight of arsenic and 98 percent by weight of selenium, which overcoating had a thickness of 1.5 micrometers.
  • photoresponsive device comprised in the order stated of (1) an aluminum substrate, (2) a diamine transport layer, (3) a photogenerating layer of vanadyl phthalocyanine, and (4) and overcoating layer containing a selenium arsenic alloy.
  • the above prepared device was then charged positively to 800 volts with a corotron and was found to be electrically stable, over 100,000 imaging cycles, in that the device retained a positive charge of 800 volts as measured with an electrostatic voltmeter, commercially available from Monroe Electronics Inc. of Rochester New York.
  • the photoresponsive device sensitivity ranged from 90 volts/erg/cm 2 at 400 nanometers to 60 volts/erg/cm 2 at 900 nanometers, as measured with an electrostatic voltmeter, commercially available from Monroe Electronics Inc. of Rochester New York, which indicates that images can be formed on this device over a wavelength ranging from 400 nanometers to 900 nanometers.
  • the above-prepared photoresponsive device was incorporated as a photoreceptor into a commercially available Xerox 3300 copying apparatus, containing exposure lamps generating visible light, corotrons, a developing station, a fixing station, a transfer station, and a fusing station. Subsequent to development with toner particles containing a styrene n-butylmethacrylate resin copolymer and carbon black there resulted for 2,000 imaging cycles high quality images with excellent solid area coverage and iow background, as determined by a visual observation of these images.
  • the above-prepared photoresponsivedevice was incorporated as a photoreceptor into a commercially available Xerox 2700 printing device.
  • a photoresponsive device was prepared by applying with a Bird applicator gap thickness of 125 micrometers an amine transport layer, onto a clean nickel sheet, having a thickness of 50 micrometers.
  • the nickel sheet was cleaned by repeating the process steps of Example I as they apply to the cleaning of the aluminum cyclinder.
  • the transport layer was then overcoated with a photogeneration layer as follows:
  • An overcoating layer of arsenic triselenide (As 2 Se 3 ) 39 percent by weight of arsenic, and 61 percent by weight of selenium was applied to the photogenerating layer in a vacuum chamber by vacuum deposition, by repeating the appropriate process steps of Example 1.
  • the device was maintained at room temperature while sufficient As2Se3 was evaporated to produce an overcoating layer thickness of 0.1 micrometers.
  • the above-prepared device was then charged positively to 800 volts with a corotron, and was found to be electrically stable, over 30,000 imaging cycles in that the device retained a positive charge of 800 volts as measured with an electrostatic voltmeter, commercially available from Monroe Electronics, Inc.
  • the photoresponsive device sensitivity ranged from 10 volts/erg/cm 2 , at 400 nanometers, to 30 volts/erg/cm 2 , at 900 nanometers, as measured with an electrostatic voltmeter, commercially available from Monroe Electronics, Inc., indicating that images could be formed on this device.
  • a photoresponsive device was prepared by repeating the procedure of Example I with the exception that the top overcoating layer of the selenium arsenic alloy was not applied to the photogenerating layer, thus resulting in a photoresponsive device comprised in the order stated-of (1) an aluminum substrate, (2) a diamine transport layer, and (3) a photogenerating layer of vanadyl phthalocyanine. This device was then incorporated as a photoreceptor into the Xerox 2700 printer, reference Example II, and after 1,000 imaging cycles substantially no images resulted since apparently the amine transport layer, some of the molecules of which diffused into the photogenerating layer, were adversely affected.
  • the overcoated photoresponsive device prepared in accordance with Example I was incorporated as a photoreceptor in the same Xerox 2700 printer and after 50,000 images were formed and developed, no image degradation was observed in that the images were of high resolution with good solid background. Further, the overcoated device after 50,000 imaging cycles and exposure to room fluorescent light, showed that the charge acceptance remained at 850 volts with no decrease, as measured by an electrostatic voltmeter, commercially available from Monroe Electronics, inc.
  • Two photoresponsive devices were prepared, by repeating the procedures of Examples land III, resulting in the photoresponsive device without a selenium alloy overcoating, and a photoresponsive device with a selenium alloy. Both photoresponsive devices were then exposed to light of a wavelength of 400 noanometers, at an intensity of 2 milliwatts/cm 2 , for 5 minutes.
  • the device with no selenium allpy overcoating accepted less than 100 volts, as measured with an electrostatic voltmeter, commercially available from Monroe Electronics, Inc., while the device containing the arsenic alloy overcoating, reference the device of Example I, was unaffected and accepted charge of 8D0 volts.
  • the photoresponsive devices as prepared in accordance with Examples I-IV were individually tested for ultraviolet light degradation by exposing these devices to unfiltered light from a 1 kilowatt Xenon lamp for a period of 30 seconds, for the purpose of determining whether the devices would accept charge since acceptance of charge indicates that these devices would form images and were not degraded by ultraviolet light. Measurements were accomplished with an electrostatic voltmeter, commercially available from Monroe Electronics, Inc. Those devices containing the arsenic alloy overcoating, reference the device as prepared in Example I, accepted 800 volts of charge, while those devices that did not contain a selenium alloy overcoating, accepted 0 volts, indicating substantial degradation of the materials in the device.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photoreceptors In Electrophotography (AREA)
EP84302259A 1983-04-25 1984-04-03 Überschichtete lichtempfindliche Einheiten Expired EP0123461B1 (de)

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US48793583A 1983-04-25 1983-04-25
US487935 1983-04-25

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EP0123461A2 true EP0123461A2 (de) 1984-10-31
EP0123461A3 EP0123461A3 (en) 1986-01-15
EP0123461B1 EP0123461B1 (de) 1989-08-23

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EP0189991A1 (de) * 1985-01-25 1986-08-06 Xerox Corporation Lichtempfindliche Abbildungselemente mit Polysilynenen in Lochtransportzusammensetzungen
US4869987A (en) * 1988-11-23 1989-09-26 Eastman Kodak Company Multiactive electrophotographic reusable element
US4869986A (en) * 1988-11-23 1989-09-26 Eastman Kodak Company Multiactive electrophotographic element
GB2258737A (en) * 1991-08-16 1993-02-17 Xerox Corp Photoreceptor.
US5213927A (en) * 1990-12-17 1993-05-25 Eastman Kodak Company Inverse multiactive electrophotographic element
KR101274904B1 (ko) * 2004-08-05 2013-06-14 사우디 베이식 인더스트리즈 코포레이션 알킬렌 옥시드의 선택적 수화를 위한 촉매계 방법 및 장치

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JPS62100766A (ja) * 1985-10-29 1987-05-11 Toyo Ink Mfg Co Ltd 電子写真感光体
US4874682A (en) * 1988-10-28 1989-10-17 International Business Machines Corporation Organic photoconductors with reduced fatigue
JP2014006350A (ja) * 2012-06-22 2014-01-16 Fuji Xerox Co Ltd 電子写真感光体、プロセスカートリッジ、画像形成装置、及び電子写真感光体の製造方法

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US4296191A (en) * 1980-06-16 1981-10-20 Minnesota Mining And Manufacturing Company Two-layered photoreceptor containing a selenium-tellurium layer and an arsenic-selenium over layer
US4420547A (en) * 1980-10-16 1983-12-13 Olympus Optical Company Ltd. Photosensitive member for electrophotography having ultraviolet absorption layer

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EP0189991A1 (de) * 1985-01-25 1986-08-06 Xerox Corporation Lichtempfindliche Abbildungselemente mit Polysilynenen in Lochtransportzusammensetzungen
US4869987A (en) * 1988-11-23 1989-09-26 Eastman Kodak Company Multiactive electrophotographic reusable element
US4869986A (en) * 1988-11-23 1989-09-26 Eastman Kodak Company Multiactive electrophotographic element
US5213927A (en) * 1990-12-17 1993-05-25 Eastman Kodak Company Inverse multiactive electrophotographic element
GB2258737A (en) * 1991-08-16 1993-02-17 Xerox Corp Photoreceptor.
KR101274904B1 (ko) * 2004-08-05 2013-06-14 사우디 베이식 인더스트리즈 코포레이션 알킬렌 옥시드의 선택적 수화를 위한 촉매계 방법 및 장치

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DE3479537D1 (en) 1989-09-28
JPS59208554A (ja) 1984-11-26
CA1250777A (en) 1989-03-07
EP0123461A3 (en) 1986-01-15
EP0123461B1 (de) 1989-08-23

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