EP0069056B1 - Verfahren zur Aromatisierung von Tabakrauch, Zigarettenendstück zur Durchführung des Verfahrens und Verwendung des Verfahrens - Google Patents
Verfahren zur Aromatisierung von Tabakrauch, Zigarettenendstück zur Durchführung des Verfahrens und Verwendung des Verfahrens Download PDFInfo
- Publication number
- EP0069056B1 EP0069056B1 EP82810238A EP82810238A EP0069056B1 EP 0069056 B1 EP0069056 B1 EP 0069056B1 EP 82810238 A EP82810238 A EP 82810238A EP 82810238 A EP82810238 A EP 82810238A EP 0069056 B1 EP0069056 B1 EP 0069056B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silica gel
- cigarette
- process according
- weight
- propylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 32
- 239000000779 smoke Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000741 silica gel Substances 0.000 claims abstract description 42
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 42
- 239000000126 substance Substances 0.000 claims description 19
- 241000208125 Nicotiana Species 0.000 claims description 13
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 13
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 3
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 abstract description 26
- 229940011037 anethole Drugs 0.000 abstract description 13
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 abstract description 13
- 238000003860 storage Methods 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 230000000391 smoking effect Effects 0.000 description 4
- 235000013355 food flavoring agent Nutrition 0.000 description 3
- 239000011232 storage material Substances 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
Definitions
- the invention relates to a method for aromatizing tobacco smoke extracted from a cigarette by means of a silica gel arranged in the mouthpiece of the cigarette and loaded with flavorings, a cigarette end piece, in particular cigarette filter, for carrying out the method, and a use of this method.
- silica gel as a flavoring substance carrier has the disadvantage that for a really good flavoring of tobacco smoke extracted from a cigarette, on the one hand a great deal of the mostly very expensive flavoring material is required because of the high adsorption capacity of the silica gel, and on the other hand the storage capacity is unsatisfactory given the high aroma loads required for this As an important point in practice, the aroma delivery to the warm and humid flue gas stream flowing past the silica gel loaded with the aroma substance is too uneven over the smoking time of the cigarette.
- the object of the present invention is to provide a method for aromatizing tobacco smoke sucked from a cigarette, when used on the one hand during storage of the cigarettes or. of the silica gel loaded according to the invention, practically no aroma substance is undesirably released into the environment, so that only a minimal amount of the usually very expensive aroma substance is required, and on the other hand, during the smoking of such a flavored cigarette, this aroma substance is very evenly and practically completely passed on to the entire period of smoking flowing wet and flue gas flow is released.
- This object is achieved according to the invention in a method of the type mentioned at the outset by adjusting the adsorbability of the highly porous silica gel to a desired value with the aid of propylene glycol which acts as a deactivating agent.
- the aroma carrier thus loaded with aroma substances is in a warm and moist flue gas stream of a cigarette, then with each pull of the smoker on such a cigarette, as desired, a certain relatively uniform amount of aroma substance is released to the flowing warm and humid flue gas stream.
- a synthetic tobacco aroma a natural or synthetic tobacco extract, a natural or synthetic tobacco smoke extract or a phenol ether, for example anethole or anisole, is used as the aroma substance.
- silica gel which, at an equilibrium of 20 ° C. and 50% relative atmospheric humidity, based on the dry substance of the silica gel, contains 5 to 18% by weight, preferably about 8% by weight, of water.
- the weight of the dry silica gel is determined by exposing the moisture-laden silica gel to a temperature of 160 ° C. until the weight of the silica gel remains constant and then determining its dry weight.
- the silica gel laden with flavorings is arranged in at least part of a cigarette filter. It is advantageous if the silica gel loaded with flavorings and propylene glycol is incorporated into at least part of the filter material intended for a cigarette filter, for example a double filter.
- the present invention also relates to a cigarette end piece, in particular a cigarette filter, for carrying out the method according to the invention, which is characterized in that it has a chamber containing at least the granular silica gel loaded with flavorings and propylene glycol.
- the present invention also relates to a use of the method according to the invention for the anetholization of tobacco smoke.
- the chamber filters were provided under standard conditions when smoking with a highly porous, containing 10 wt .-% anethole and 20 wt .-% propylene glycol wt .-% (each based on the weight of the unloaded carrier material) Cigarettes in nine puffs of smoke in the particulate phase determined the presence of anethole, shortly after loading the silica gel used and again after about three months, both times with an amount of anethole (in particulate phase) of 0.44 mg / cigarette.
- the silica gel loaded with a flavoring agent and propylene glycol in the manufacture of a cigarette filter by means of an adhesive between the fibers of the filter material strand.
- the carrier material loaded with flavorings and propylene glycol would preferably be arranged in the tobacco part of the filter cigarette next to the plug of the filter.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Silicon Compounds (AREA)
- Manufacture Of Tobacco Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82810238T ATE19462T1 (de) | 1981-06-10 | 1982-06-01 | Verfahren zur aromatisierung von tabakrauch, zigarettenendstueck zur durchfuehrung des verfahrens und verwendung des verfahrens. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH3787/81 | 1981-06-10 | ||
CH378781 | 1981-06-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0069056A1 EP0069056A1 (de) | 1983-01-05 |
EP0069056B1 true EP0069056B1 (de) | 1986-04-30 |
Family
ID=4263466
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82810238A Expired EP0069056B1 (de) | 1981-06-10 | 1982-06-01 | Verfahren zur Aromatisierung von Tabakrauch, Zigarettenendstück zur Durchführung des Verfahrens und Verwendung des Verfahrens |
Country Status (5)
Country | Link |
---|---|
US (1) | US4466451A (ru) |
EP (1) | EP0069056B1 (ru) |
JP (1) | JPS57208979A (ru) |
AT (1) | ATE19462T1 (ru) |
DE (1) | DE3270841D1 (ru) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4941486A (en) * | 1986-02-10 | 1990-07-17 | Dube Michael F | Cigarette having sidestream aroma |
US4862905A (en) * | 1987-06-15 | 1989-09-05 | R. J. Reynolds Tobacco Company | Rods containing pelletized material |
US4966171A (en) * | 1988-07-22 | 1990-10-30 | Philip Morris Incorporated | Smoking article |
US5345951A (en) * | 1988-07-22 | 1994-09-13 | Philip Morris Incorporated | Smoking article |
US4991606A (en) * | 1988-07-22 | 1991-02-12 | Philip Morris Incorporated | Smoking article |
US5188130A (en) * | 1989-11-29 | 1993-02-23 | Philip Morris, Incorporated | Chemical heat source comprising metal nitride, metal oxide and carbon |
US5105834A (en) * | 1989-12-18 | 1992-04-21 | R.J. Reynolds Tobacco Company | Cigarette and cigarette filter element therefor |
US5076294A (en) * | 1990-03-29 | 1991-12-31 | R. J. Reynolds Tobacco Company | Filter cigarette |
US5269329A (en) * | 1990-07-09 | 1993-12-14 | Kimberly-Clark Corporation | Method of producing tobacco flavored cigarette filter |
GB9018131D0 (en) * | 1990-08-17 | 1990-10-03 | Rothmans International Ltd | Smoking article |
US5246017A (en) * | 1990-11-06 | 1993-09-21 | R. J. Reynolds Tobacco Company | Cigarette and cigarette filter element therefor |
FR2680952B1 (fr) * | 1991-09-05 | 1994-05-20 | Exploitation Indle Tabacs Allume | Procede destine a modifier ou a aromatiser la fumee primaire ou secondaire des produits a fumer. |
US6053175A (en) * | 1998-03-03 | 2000-04-25 | D'angelo; Carmen A. | Method for treating smoking article |
US6209547B1 (en) | 1998-10-29 | 2001-04-03 | Philip Morris Incorporated | Cigarette filter |
US6911189B1 (en) | 1999-10-29 | 2005-06-28 | Philip Morris Usa Inc. | Filter for selective removal of a gaseous component |
JP4883706B2 (ja) * | 2007-08-10 | 2012-02-22 | Necトーキン株式会社 | 線輪部品 |
US9845259B2 (en) * | 2009-01-03 | 2017-12-19 | General Ecology, Inc. | Apparatus for filtering and/or conditioning and/or purifying a fluid such as water |
CN110876487B (zh) * | 2019-12-14 | 2022-03-01 | 江西中烟工业有限责任公司 | 一种颗粒型加热不燃烧卷烟的发烟段的制备方法 |
EP3912485A1 (en) | 2020-05-18 | 2021-11-24 | Del-Vis Sp. z o.o. | Cigarette product and a method for manufacturing the product |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE549413C (de) * | 1927-05-26 | 1932-04-27 | Josef Paeffgen | Verfahren zum Abscheiden der giftigen Anteile aus dem Tabakrauch |
US2063014A (en) * | 1932-12-22 | 1936-12-08 | Raymond P Allen | Tobacco |
CH464764A (de) * | 1964-03-20 | 1968-10-31 | Erlenmeyer Hans Dr Prof | Verfahren zur Herstellung von Nikotin aus Tabakrauch spezifisch absorbierendem Kieselgel |
US3390686A (en) * | 1965-12-21 | 1968-07-02 | American Tobacco Co | Tobacco smoke filter element |
FR1589807A (ru) * | 1967-10-24 | 1970-04-06 | ||
US3972335A (en) * | 1972-09-20 | 1976-08-03 | Calgon Corporation | Mentholated cigarette filter |
CH643443A5 (de) * | 1979-06-14 | 1984-06-15 | Baumgartner Papiers Sa | Zigarettenendstueck. |
-
1982
- 1982-06-01 DE DE8282810238T patent/DE3270841D1/de not_active Expired
- 1982-06-01 AT AT82810238T patent/ATE19462T1/de not_active IP Right Cessation
- 1982-06-01 EP EP82810238A patent/EP0069056B1/de not_active Expired
- 1982-06-04 US US06/384,944 patent/US4466451A/en not_active Expired - Lifetime
- 1982-06-10 JP JP57099925A patent/JPS57208979A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
EP0069056A1 (de) | 1983-01-05 |
JPH0473993B2 (ru) | 1992-11-25 |
ATE19462T1 (de) | 1986-05-15 |
JPS57208979A (en) | 1982-12-22 |
DE3270841D1 (en) | 1986-06-05 |
US4466451A (en) | 1984-08-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0069056B1 (de) | Verfahren zur Aromatisierung von Tabakrauch, Zigarettenendstück zur Durchführung des Verfahrens und Verwendung des Verfahrens | |
EP0756461B1 (de) | Tabakerzeugnisse oder tabakerzeugnissen ähnliche waren mit antioxidativ wirkenden naturstoffen und verfahren zur herstellung derselben | |
US3144024A (en) | Impregnated filter means for tobacco articles | |
DE2939965C2 (ru) | ||
DE3686237T2 (de) | Einschliessung in eine matrize von aroma fuer rauchartikel. | |
DE2715469C2 (de) | Verfahren zur Herstellung stabiler, aromatisierter cellulosehaltiger Produkte und die danach erhaltenen cellulosehaltigen Produkte | |
DE1517242A1 (de) | Filterelement | |
DE69221635T2 (de) | Neue tabakersatzstoffe | |
DE3417586A1 (de) | Filter zur verminderung der toxischen wirkungen von zigarettentabak-rauch | |
DE2223691A1 (de) | Rauchartikel | |
DE69112928T2 (de) | Mit Tabak aromatisierter Filter für Rauchprodukte sowie Verfahren zu Herstellung desselben. | |
JPS55102385A (en) | Tobacco product with filter impregnated by solid flavor | |
DE3021668C2 (de) | Verwendung von porösem Magnesiumsilikat und/oder Magnesiumsilikathydrat im Mundstück von Zigaretten | |
DE4332019C2 (de) | Ventilierte Filtercigarette | |
DE60308877T2 (de) | Biologisch abbaubare filterzigarette mit zwei dichten | |
DE3837930C1 (ru) | ||
DE69030471T2 (de) | Rauchartikel | |
DE2341685C3 (de) | Zigarettenfilter aus Celluloseacetatfasern und Verfahren zu seiner Herstellung | |
JPH08505051A (ja) | フィルタシガレット | |
DE3715842A1 (de) | Rauchbarer artikel | |
DE1767024C3 (de) | Verwendung eines porösen Magnesiumsilikathydrates als Filtermittel für Tabakrauch | |
DE2738930A1 (de) | Rauchgegenstand | |
DE69224458T2 (de) | Neuartige Zigarettenvorrichtung zum Rauchen in mehreren Malen | |
CH287549A (de) | Mit Filter verschenes Rauchzeug. | |
CH662042A5 (en) | Cigarette endpiece |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19830224 |
|
ITF | It: translation for a ep patent filed | ||
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
REF | Corresponds to: |
Ref document number: 19462 Country of ref document: AT Date of ref document: 19860515 Kind code of ref document: T |
|
REF | Corresponds to: |
Ref document number: 3270841 Country of ref document: DE Date of ref document: 19860605 |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
ITTA | It: last paid annual fee | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19940328 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19940524 Year of fee payment: 13 Ref country code: GB Payment date: 19940524 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 19940531 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 19940614 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19940630 Year of fee payment: 13 |
|
EPTA | Lu: last paid annual fee | ||
EAL | Se: european patent in force in sweden |
Ref document number: 82810238.4 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19950601 Ref country code: GB Effective date: 19950601 Ref country code: AT Effective date: 19950601 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19950602 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Effective date: 19950630 |
|
BERE | Be: lapsed |
Owner name: BAUMGARTNER PAPIERS S.A. Effective date: 19950630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Effective date: 19960101 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 19950601 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 19960101 |
|
EUG | Se: european patent has lapsed |
Ref document number: 82810238.4 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20010430 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20010511 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20010726 Year of fee payment: 20 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020531 Ref country code: CH Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020531 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |