EP0040369B1

EP0040369B1 - Apparatus for the surface treatment of an object

Info

Publication number: EP0040369B1
Application number: EP19810103487
Authority: EP
Inventors: Yoshinobu Takahashi; Yasuo Tokushima; Kentaro Ogata; Mamoru Suzuki; Jyoji Ito; Kenji Fukuta
Original assignee: Toyota Motor Corp
Current assignee: Toyota Motor Corp
Priority date: 1980-05-12
Filing date: 1981-05-07
Publication date: 1984-02-15
Also published as: EP0040369A1; DE3162243D1

Description

This invention relates to an apparatus for surface treatment effectively applicable for treating or finishing the surface of metal articles or objects when chemical coating, plating, etching, etc., is carried out.
Various methods have conventionally been known for treating or finishing the surface of metal articles, such as chemical coating, plating, etching, etc. Above all chemical conversion treatment for forming some kinds of corrosion resistant films on the surface of steel plates or steel bars by means of chemical reaction or electro-chemical reaction is known, and more particularly phosphating, wherein zinc phosphate, manganese phosphate, ferrous phosphate, etc., are employed, is widely known. And it is widely practiced as a method of surface preparation when steel members are coated in the field of, for example, car assemblying, bridge building, or manufacturing of household electrical appliances.
When practicing such a surface treatment objects-to-be-treated must be in general contacted with the treating liquid, and either of two ways, a spraying method in which the liquid is sprayed over the surface of the objects-to-be-treated and a dipping method in which the objects are dipped in the liquid, is selected for contacting the objects with the liquid. The former spraying method is unsuitable for treating objects of complicated shape, for example car bodies which have portions difficult to be uniformly treated by spraying such as a fender, a door, or a constructed part into a box-like shape. The liquid is liable not to sufficiently reach the inside surface of complicated corner, leaving sometimes untreated portions or sometimes unsatisfactorily treated portions. The latter dipping method is much better than the former in respect of the liquid reaching to many quarters of the objects-to-be-treated, but it still leaves something to be desired because the sludge produced in the period of dipping of the objects-to-be-treated into the liquid is deposited on the bottom of a treating vessel so as to cause some troubles in a continuous surface treatment.
In the course of chemical reaction taking place between a steel plate as an object-to-be-treated and a treating liquid containing phosphate by-products called sludge are produced. This chemical conversion sludge created in the course of a side reaction did not give rise to so serious problematical trouble in the conventional spray method wherein phosphate conversion coating was made on the surface of the object by means of the spraying, because the forced pressure of the spraying naturally prevented sticking of the sludge onto the coated surface of the object. The sludge has however recently become a serious factor for deteriorating the quality of the articles since the surface treatment had been gradually changed to the full dipping treatment method, wherein the object is completely dipped in the treating liquid. In this full dipping method the sludge is liable to be floated in suspension in the treating liquid. This kind of chemical conversion sludge is not only floated in a treating vessel containing the liquid but also flung up from the bottom of the vessel on which it has once been deposited due to the movement of the object-to-be-treated W₃ in the vessel. The sludge possibly stuck to the crystal' coating or contained in the formed coating deteriorates the corrosion resistance of the coating or adversely affects the forthcoming electrodepositing process. It is therefore highly desirable to advantageously discharge or exhaust such harmful problem-arising sludge out of the vessel.
Conventionally leading the liquid out of the system or vessel, by recycling the same outside and inside the vessel, was practiced for removing the sludge. A sludge removing apparatus disposed outside the vessel is apt to occupy an innegligible space and impose an innegligible cost. It is naturally accompanied by some other problems such as complicacy of piping for recycling, increasing of the recycled amount of the liquid, etc., and a still unsolved problem is flinging up of the deposited sludge on the vessel bottom.
It is an object of this invention, which was made against such a background, to provide an apparatus for the surface treatment, being substantially relieved of the conventional disadvantages, capable of continuously removing the sludge produced in the full dipping method from the bottom of the treating vessel.
The apparatus for performing the above- mentioned surface treatment in accordance with this invention is provided, as an essential feature, at the bottom portion of the treating vessel with one or more hoppers, which function to collect the deposited sludge. for exhausting the same through the lower portion of the hopper outside the treating vessel wherein a plurality of slant plates disposed above the bottom of the treating vessel are provided containing the treating liquid for performing an aimed surface treatment by dipping an object-to-be-treated in a treating liquid such as chemical conversion solution like phosphate; the slant plates are disposed, being inclined in the same direction, with a predetermined inter- distance among them. The sludge produced in the treating liquid is gradually precipitated, while being floated therein, on the bottom of the vessel through the gap or clearance between the slant plates, which are not contacted with the vessel bottom. This disposition of the slant plates facilitates the sludge produced in the vessel to be gradually precipitated or deposited down on the bottom thereof, by well functioning as protecting walls, almost not being affected by the flowing of the liquid and the movement of the objects-to-be-treated. In such an apparatus the deposited sludge can not be flung up into the liquid again by virtue of the slant plates, but can be easily taken away out of the vessel.
A few concrete examples will be described hereunder with reference to the appended drawings, in which:

Figures 1 and 2 are respectively a schematic transverse sectional view of two different embodiments of an apparatus for surface treatment in accordance with this invention.

An apparatus shown in Figure 1 relates to, for example, zinc phosphating process as a preliminary treatment on an object-to-be-treated W₃ such as a car body when it is applied with coating. As a first step for applying the zinc phosphate treatment the object W₃ is degreased with a trichloroethylene or alkaline solution, followed by water cleaning and contact with titanium phosphate solution as a second step. In this way nuclei of phosphate coating crystals are formed on the surface of the object W₃. An object W₃ which has been applied with such surface preparation is conveyed, being suspended from a hanging conveyor 27 as shown in Figure 1, from right to left for being dipped into treating liquid of a treating vessel 20.
The object W₃ which has been dipped into the treating liquid 4 at the initial stage of the process, is gradually conveyed toward the final stage on the left side end for being completely covered in the meantime by the continuously grown zinc phosphate crystals all over the surface thereof. The time required for this process is within the range of 60-300 seconds.
In this surface treatment process of the objects sludge consisting of ferrous phosphate and others is produced, and four hoppers 22 (generally several in number) of funnel shape are formed as extensions from the bottom portion of the vessel 20 for depositing or precipitating the sludge on the bottom of the hopper 22.
The four hoppers 22 are horizontally arranged in series in parallel to a conveying direction Y of the objects-to-be-treated W₃. Within those hoppers 22 a multiplicity of slant plates 24 inclined by an angle (a) of 45-90° against the conveying direction of the objects W₃ are arranged parallelly with each other, keeping away from a wall surface 23 of the hopper 22 with a predetermined distance, viz., being not in contact therewith. Those slant plates 24 function as protector walls for preventing the deposited sludge from being stirred by the flowing movement of the treating liquid. Besides, each hopper 22 is provided at the lower end thereof with a one-way valve 26.
The treating vessel 20 is further provided with undermentioned several devices: a slant gush-spraying pipe 28 and a horizontal gush-spraying pipe 30 disposed on the rightward end portion, in Figure 1, of the vessel 20 for gush-spraying the treating liquid to the objects W₃ which are moved by a inclined conveyor 27 into the liquid in the vessel 20; a gushing nozzle 34 disposed, above a horizontal bottom portion 32 of the vessel 20 on the rightward side away from the hoppers 22, in communication with the slant gush-spraying pipe 28, for gushing the liquid toward the hoppers-arranged direction; and a recovering tank 36 for reservoiring the liquid overflowed out of the treating vessel 20.
In this embodiment of such a structure the objects W₃ are transported in suspended state from the conveyor 27 in the direction designated with the arrow Y for being dipped into the liquid, while a part of the liquid reservoired in the recovering tank 36 is led, via conduits 38, 40, to the slant gush-spraying pipe 28 and via conduits 38, 42 to the horizontal gush-spraying pipe 30 by the action of a pump P₄, for being gush-sprayed onto the just incoming objects W₃. The rest of the liquid in the recovering tank 36 is led, by the action of pumps P₅, P₆. via conduits 38, 44 back into the vessel 20 for being recycled, while making a counterflow in the direction designated by an arrow X against the movement of the objects W₃ in the liquid, to the recovering tank 36.
In the initial stage of the dipping of the objects W₃, from the beginning of dipping to the start of leftward movement in Figure 1 after the complete dipping, strong or vehement chemical reaction progresses between the object W₃ and the treating liquid while producing large amount of sludge. The sludge is however precipitated by the action of gravity in each of the hoppers 22 extended from the lower portion of the vessel 20 and on the horizontal portion 32 is collected into the hopper 22 by virture of the gush-spraying of the liquid from the gushing nozzle 34 disposed on the conduit 40. The sludge precipitated into the hoppers 22 comes first onto each of the parallelly arranged slant plates 24 and then drops through the gap therebetween as far as the wall surface of the individual hoppers 22, for finally being collected along the wall surface in the lower portion 46 of the respective hopper 22. The sludge collected there in this way is intermittently delivered to a separater 50, by the action of a pump P₇, via the one-way valve 26 and the conduit 48. The liquid containing the thus collected sludge is separated at the separater 50, which is located out of the recycling circuit, for being returned to the recovering tank 36 or to a gush-spraying device disposed on the final stage side of the vessel 20.
As the slant plates 24 arranged horizontally with each other in the lower portion of the vessel 20, and particularly in this case within the hoppers 22, are inclined against the flowing direction X of the liquid, i.e., the same direction to the object conveyance, stirring of the sludge collected in the lower portion 46 by the liquid flowed into between the slant plate 24 can not occur. And the conveyance operation of the objects as well as the gush-spraying of the liquid from the slant gush-spraying pipe 28 and the horizontal gush-spraying pipe 30 can not cause stirring or flinging uo of the sludge, either, because the slant plates 24 well prevent the phenomenon by functioning as protector walls. In other words, the above described structure effectively protects the objects-to-be-treated W₃ from being deteriorated in quality by sticking of the sludge in floatation or flung up from the lower portion 46 of the hopper 22 in the course of the surface treatment. As described earlier the sludge deposited on the horizontal portion 32 is also removed therefrom into the lower portion 46 of the hopper 22 by the gushing of the liquid from the gushing nozzle 34, which means complete relief of the sludge from the bottom portion of the vessel 20.. This invention can be said to have succeeded, through remarkable decrease of the floating and depositing sludge, in improving the quality of the surface treatment, particularly the anti-corrosion coating quality, of the objects-to-be-treated W₃.
In the description of the above embodiment all of the hoppers 22 arranged in series are of the same size, but a modified type wherein the nearest hopper 22 to the object incoming side end is made the largest in capacity and others are made gradually smaller toward the leftward end is preferably recommended, because the sludge producing rate is largest at the initial stage of contact between the object W₃ and the liquid.
Still another embodiment will be described with reference to Figure 2, wherein an object W₄ suspended by a conveyor 62 is, after it has been completely dipped in zinc phosphating solution contained in a treating vessel 60, moved therein for being given chemical conversion treatment in the meantime just like in the previous embodiment. The only difference lies in the structure of the bottom portion of the vessel 60. In this embodiment only one hopper 64 of funnel shape is formed at the leftward end of the bottom portion, and the rest of the bottom portion is left as a flat portion 66. Above the flat portion 66 a multiplicity of slant plates 68 inclined at an angle (f3) of 45-90° are arranged, parallelly to each other with a predetermined interdistance, in the horizontal direction and along the conveyance direction Y of the objects-to-be-treated W₄. They are not in contact with the flat portion 66, just like slant plates 70 which are similarly arranged in the hopper 64 parallelly with each other and kept away from a wall surface 72 of the hopper 64 by a predetermined distance.
On the flat portion 66 a suitable number of gushing nozzles 74 are arranged parallelly thereto for gushing the liquid toward the hopper 64 so as to wash away the deposited sludge thereon.
When an object W₄ suspended from a conveyor 62 is transported in the direction designated with an arrow Y to be dipped into the liquid in an apparatus of such a structure, producing of the sludge is begun by the chemical conversion treatment. And the sludge thus produced is precipitated through the clearance(s) between the slant plates 68 onto the flat portion 66 of the vessel 60 and also to the lower portion of the hopper 64 along the slant plates 70 while passing the clearance(s) therebetween. The liquid in a recovering tank 76 is via conduits 78, 80 by the action of a pump P₈ led to each of the gushing nozzles 74 for being gushed therefrom respectively. The sludge deposited on the flat portion 66 is therefore collected to the hopper 64 passing through the clearance formed between the slant plates 68 and the flat portion 66. The sludge collected in the hopper 64 is led via a one-way valve 82 and a conduit 84 by the action of a pump P_. to a separater 86 which is located outside the recycle circuit of the liquid. The separated liquid in the separater 86 is returned to a recovering tank 76 or to a gush-spraying device 15, disposed on the final stage side of the vessel 60. The remaining liquid in the recovering tank 76 is led via conduits 78, 88 by the action of pumps P₁₀ and P11 to the vessel 60 for being flowed in the direction designated with an arrow X so as to be re-utilized to the chemical conversion treatment of the objects W₄.
As the slant plates 68, 70 are, just like in the previous embodiment, inclined in the reversed direction X of that of the flowing of the liquid, they not only prevent the liquid from flowing therebetween but also prevent the deposited sludge from being flung up when the objects W₄ are moved in the liquid by functioning as protective walls.
This embodiment is particularly featured in eliminating disposition of many hoppers and consequently simplifying the structure of the bottom portion of the vessel, and besides in uni- formalizing the shape of, as well as reducing the size of, the slant plates.
In the foregoing embodiments the slant plates 24, 68, 70 are all inclined with an angle (a, A) of 45-90° in the conveying direction of the objects W, the direction marked the arrow Y, that is reversed against the flowing direction of the liquid marked the arrow X. And it is true that the inclined direction of the slant plates is in the same way as the direction of conveyance of the objects W for the better effect of the slant plates as the protective walls, but this invention is not limited to this way of arrangement. A multiplicity of slant plates inclined in the inverted direction to the above embodiments are also allowable. As to the angle of inclination (α, β) of the slant plates 24, 68, 70, in this instance, the preferable range lies within 45-90°, as an angle larger than 45° is favorable for smoothly sliding down the sludge without staying on the plate, an angle less than 45° being contrary undesirable because of easy piling up of the sludge on the plate. This tendency of arresting the sludge of smoothly falling down from the surface of the plate, which consequently obliges the plate to be curtailed its length according to the extent of turbulence of the treating liquid.
Summarising the above described details of this invention, structure of the bottom portion of the treating vessel used for the surface treatment has been improved, accompanied by disposition of a multiplicity of slant plates functioning as the protective walls, with a remarkable result of preventing the sludge from being flung up in the course of the treatment for being smoothly removed out of the treating vessel. This effect of having enhanced the quality of treatment by preventing the once deposited sludge from being stirred up into the treating liquid and the recycling efficiency of the treating liquid by effectively removing the sludge therefrom is very significant from the standpoint of industrial efficiency.

Claims

1. An apparatus for applying a predetermined surface treatment on an object-to-be-treated by means of dipping said object in a treating liquid contained in a treating vessel, said apparatus comprising one or more hoppers (18, 22, 64) of funnel shape which are disposed at the bottom portion of said treating vessel (3, 20, 60) for collecting precipitated sludge into said hoppers (18, 22, 64), said collected sludge being removed out of said treating vessel (3, 20, 60) from the lower portion of said hoppers (18, 22, 64), characterized in that a multiplicity of slant plates (24, 68, 70) inclined in the same direction are disposed, above the bottom portion of said treating vessel (3, 20, 60) with a predetermined inter-distance so that floating sludge in said liquid may be precipitated through the clearance between said slant plates (24, 68, 70) onto the bottom portion of said treating vessel (3, 20, 60).

2. The apparatus in accordance with claim 1, characterized in that said slant plates (24, 70) are arranged in said hoppers (22, 64).

3. The apparatus in accordance with claim 1 or claim 2, characterized in that the multiplicity of slant plates (24, 68, 70) inclined in the same direction are disposed in a horizontal arrangement above flat portion (32, 66) of the bottom portions of said treating vessel (20, 60) where said hopper (22, 64) is not disposed, and at least one gushing nozzle (34, 74) is disposed above said flat portion (32, 66) for washing away the sludge precipitated on said flat portion (32, 66) with the gushing liquid into said hoppers (22, 64).

4. The apparatus in accordance with claim 3, characterized in that the angle (a, A) formed between said slant plates (24, 68, 70) and the direction of conveyance of the object-to-be-treated (W) is within the range of 45-90°.