EP0037815A1 - Combustible universel pour moteurs - Google Patents
Combustible universel pour moteursInfo
- Publication number
- EP0037815A1 EP0037815A1 EP80901839A EP80901839A EP0037815A1 EP 0037815 A1 EP0037815 A1 EP 0037815A1 EP 80901839 A EP80901839 A EP 80901839A EP 80901839 A EP80901839 A EP 80901839A EP 0037815 A1 EP0037815 A1 EP 0037815A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixtures
- volume
- fuel
- oil
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Definitions
- a further object of the invention is to provide a novel liquid fuel composed of known materials in specified amounts which burn well in engines without substantial polution problems and which is not based on fossil fuels.
- Applicant has succeeded in developing a novel universal liquid fuel which is composed of raw materials which are comparatively cheap and in abundance anywhere in the world.
- the raw materials are moreover inexhaustible, since they are based mainly on vegetable materials or residues derived therefrom.
- a _y wii-o The expression "universal fuel for piston engines of any type” denotes in this context a fuel which is suitable for conventional piston engines of any type, such as conventional internal combustion engines as used in passenger vehicles of any type, in lorries, tracked vehicles in civil engineering and military use, marine engines, Diesel engines, radial piston engines as used in propeller driven aircraft, including helicopters, as well as turbine engines, such as used in turboprop aircraft.
- the use of the universal fuel according to the invention does not appreciably alter the horse-power rating of the engines, nor does it affect the maximum velocity or the acceleration of the craft driven by the engines.
- the invention thus concerns a universal liquid fuel for all types of piston engines, said fuel consisting essentially of: a) 1% to 71% by volume of one or more primary, secondary and tertiary onohydric aliphatic alcohols containing 1 to 8 carbon atoms, benzyl alcohol or mixtures thereof; b) from 0.5% to 10% by volume of water; c) from 1% to 90% by volume of one or more vegetable oils, or mixtures thereof; and d) from 10% to 80% by volume of one or more
- O ethers having the formula ROR', wherein R and R * may be the same or different and either of them designates a C. to C- alkyl group, or mixtures thereof; with the proviso that the mixtures form clear solutions, which do not undergo a phase separation on standing for a protracted period.
- the invention concerns a universal liquid fuel for piston engines of any type as hereinbefore defined constituted of from 50% to 66% by volume of one or more primary, secondary or tertiary monohydric ali ⁇ phatic alcohols containing 1 to 8 carbon atoms, or benzyl alcohol, or mixtures thereof, from 2.6 to 9.2% by volume of water, from 4.4% to 14.7% by volume of vegetable oils or mixtures thereof and of 13% to 40% of ethers of the formula ROR' , wherein R and R' may be the same or different and either of them designates a C, to C_ alkyl group or mixtures thereof.
- the lower members of the series of alcohols defined above i.e. methyl alcohol, ethyl alcohol, and propyl or isopropyl alcohol are preferred, while optimal results are obtained by the use of methyl and ethyl alcohol or mixtures thereof.
- the preferred vegetable oil is sunflower oil
- the preferred alcohol is technical grade ethyl alcohol, whereby it has to be taken into account that such alcohol contains about 5% by volume of water, which has to be added to proportion of water defined above.
- the ether giving optimal results is diethyl ether.
- the C, to C-. alkyl ethers, suitable for use in the fuel, may be symmetrical or asymmetrical. Here again the lower members of the symmetrical ethers are preferred. Mixtures of these ethers are 5 also suitable. Diethyl ether, dimethyl ether, methyl ethyl ether, n-propyl ether and isopropyl ether are preferred. Diethyl ether is especially preferred. All the commercially available vegetable triglyceride oils are suitable for use in the 0 inventive fuels.
- oils examples include sun ⁇ flower oil, castor oil, soybean oil, cottonseed oil, olive oil and corn oil. Sunflower oil and corn oil are preferred. These vegetable oils are a known class and are to be distinguished from natural 5 resinous materials such as turpentine or hydrocarbons such as lubricating oils.
- the process for preparing the fuel according to the invention is simple and does not necessitate the use of a special plant or apparatus. 0 T e various components selected are mixed together in the proportions specified hereinafter. The mixture is stirred until a clear solution is obtained and then passed to storage. Appropriate precautions have to be taken to prevent explosions or fires, 5 since most of the raw materials and particularly the fuel obtained is highly flammable and even explosive.
- the fuel of this invention may also be mixed with gasoline or Diesel fuel.
- compositions are preferred for use in a Diesel engine as follows: a) about 22% to 36% by volume of one or more primary, secondary or tertiary monohydric aliphatic alcohols containing 1 to 8 carbon atoms, or benzyl alcohol, or mixtures thereof; b) from about 0.5% to 9% by volume of water; c) from about 20% to 60% by volume of one or more vegetable oils, or mixtures thereof; and d) from about 20% to 40% by volume of one or more ethers having the formula ROR' , wherein R and R' may be the same or different and either of them designates a C, to C. alkyl group, or mixtures thereof.
- a further quantity of 25 parts of ethyl alcohol (95%) is admixed with 2.63 parts of de- mineralized water.
- Example I The procedure of Example I is followed, but the ethyl alcohol is replaced by identical volumes of methyl alcohol.
- Example I The procedure of Example I is followed, but the ethyl alcohol is replaced by identical volumes of a mixture of equal parts of ethyl alcohol and methyl alcohol.
- Example XII The fuel obtained according to Example XII was also used in a heavy Mack-Diesel lorry. The results were excellent.
- the invention has been described herein with reference to certain preferred embodiments. However, as obvious variations thereon will become apparent to those skilled in the art, the invention is not considered to be limited thereto.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Un combustible universel pour des moteurs a combustion interne tels que des moteurs a piston, comprend: a) 1% a 71% en volume environ d'un alcool monohydrique aliphatique primaire, secondaire ou tertiaire contenant de 1 a 8 atomes de carbone, ou un alcool benzylique, ou des melanges de ceux-ci; b) 0,5% a 10% en volume environ d'eau; c) de 1% a90% en volume environ d'une ou plusieurs huiles vegetales, ou leur melange; et d) de 10% a 80% en volume environ d'un ou plusieurs ethers de formule ROR', ou R et R' peuvent etre identiques ou differents et R et R' representent un groupe alkyle de C1 a C3, ou leur melange.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL58206A IL58206A (en) | 1978-09-05 | 1979-09-10 | Process for preparing calcined gypsum and gypsum board |
IL7958257A IL58257A (en) | 1979-09-10 | 1979-09-18 | Universal liquid fuel for piston engines |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0037815A1 true EP0037815A1 (fr) | 1981-10-21 |
EP0037815A4 EP0037815A4 (fr) | 1982-02-16 |
Family
ID=26320794
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19800901839 Withdrawn EP0037815A4 (fr) | 1979-09-10 | 1981-03-23 | Combustible universel pour moteurs. |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0037815A4 (fr) |
WO (1) | WO1981000721A1 (fr) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3140382A1 (de) * | 1981-10-10 | 1983-04-21 | Veba Oel AG, 4660 Gelsenkirchen-Buer | Dieselkraftstoff |
IT1165778B (it) * | 1982-11-25 | 1987-04-29 | S M I A Soc Meccanica Ind Auto | Carburante liquido per motori a combustione interna ad accensione spontanea a ciclo diesel |
DE3307091A1 (de) * | 1983-03-01 | 1984-09-06 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | Treibstoff und eine verwendung desselben |
DE4333418C1 (de) * | 1993-09-30 | 1994-10-13 | Tessol Kraftstoffe Mineraloele | Treibstoffgemisch |
US6324827B1 (en) * | 1997-07-01 | 2001-12-04 | Bp Corporation North America Inc. | Method of generating power in a dry low NOx combustion system |
GB2384004B (en) * | 2002-01-15 | 2006-08-23 | Nicholas Charles Mcphee | Fuel mixture |
DE10241659A1 (de) * | 2002-09-05 | 2004-03-25 | Oliver Riess | Flüssiger Kraftstoff und Verfahren zu seiner Herstellung |
RU2387702C2 (ru) | 2003-06-24 | 2010-04-27 | Михил Арьян КАУСЕМАКЕР | Способ получения оксигената в качестве присадки к топливам, прежде всего дизельным топливам, бензинам и метиловому эфиру рапсового масла |
WO2008124800A1 (fr) * | 2007-04-09 | 2008-10-16 | Ethanol Eex, Llc | Mélanges de carburant |
EP2331658B1 (fr) | 2008-08-05 | 2019-06-26 | Spirit Of The 21st Century Group, LLC | Carburants modifiés |
DE102009015347A1 (de) | 2009-03-27 | 2010-09-30 | Man Nutzfahrzeuge Aktiengesellschaft | Dieselkraftstoff auf Ethanol-Basis |
US20130014432A1 (en) | 2010-03-31 | 2013-01-17 | Haldor Topsoe A/S | Method for the preparation of a compression ignition engine fuel |
EP3515899B1 (fr) | 2016-09-21 | 2021-09-01 | Cepsa S.A.U. | Étheres du solketal, leur procede de production et leur utilisations |
KR102525112B1 (ko) * | 2019-04-15 | 2023-04-21 | 요시노 셋고 가부시키가이샤 | 전처리용 혼합 교반기, 석고 슬러리 제조 장치, 건축용 면재 제조 장치, 전처리 소석고 제조 방법, 석고 슬러리 제조 방법, 건축용 면재 제조 방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1420622A (en) * | 1920-07-06 | 1922-06-27 | Edward A Charbonneaux | Gaseous fuel |
FR869828A (fr) * | 1940-10-18 | 1942-02-20 | Perfectionnements apportés aux combustibles, tels notamment que ceux à utiliser dans les moteurs à explosion et combustion interne, et à leurs procédés d'obtention | |
FR889873A (fr) * | 1944-01-21 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1398947A (en) * | 1918-06-25 | 1921-11-29 | Us Ind Alcohol Co | Motor-fuel for aeroplanes |
US1338982A (en) * | 1919-09-19 | 1920-05-04 | Arthur F Ray | Composite motor-fuel |
US1495094A (en) * | 1923-04-13 | 1924-05-20 | Morgan Benjamin Howell | Fuel for internal-combustion engines |
US1501383A (en) * | 1923-09-28 | 1924-07-15 | Daly O White | Motor fuel |
US1684686A (en) * | 1925-01-06 | 1928-09-18 | Elmer H Records | Aqueous liquid fuel |
US2117610A (en) * | 1936-05-27 | 1938-05-17 | James W Jean | Motor fuel |
US3902868A (en) * | 1972-11-06 | 1975-09-02 | Enercon Corp International | Fuel additive and method for improving combustion |
-
1980
- 1980-08-29 WO PCT/US1980/001119 patent/WO1981000721A1/fr not_active Application Discontinuation
-
1981
- 1981-03-23 EP EP19800901839 patent/EP0037815A4/fr not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR889873A (fr) * | 1944-01-21 | |||
US1420622A (en) * | 1920-07-06 | 1922-06-27 | Edward A Charbonneaux | Gaseous fuel |
FR869828A (fr) * | 1940-10-18 | 1942-02-20 | Perfectionnements apportés aux combustibles, tels notamment que ceux à utiliser dans les moteurs à explosion et combustion interne, et à leurs procédés d'obtention |
Non-Patent Citations (1)
Title |
---|
See also references of WO8100721A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP0037815A4 (fr) | 1982-02-16 |
WO1981000721A1 (fr) | 1981-03-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT CH DE FR GB LU NL SE |
|
17P | Request for examination filed |
Effective date: 19810921 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19830629 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: ESTRADA-CHAPETON, ROBERTO |