EP0037324A1 - Procédé de blocage des éléments alcalin et alcalino-terreux radioactifs - Google Patents

Procédé de blocage des éléments alcalin et alcalino-terreux radioactifs Download PDF

Info

Publication number
EP0037324A1
EP0037324A1 EP81400467A EP81400467A EP0037324A1 EP 0037324 A1 EP0037324 A1 EP 0037324A1 EP 81400467 A EP81400467 A EP 81400467A EP 81400467 A EP81400467 A EP 81400467A EP 0037324 A1 EP0037324 A1 EP 0037324A1
Authority
EP
European Patent Office
Prior art keywords
slag
waste
silico
fine
radioactive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP81400467A
Other languages
German (de)
English (en)
French (fr)
Inventor
Francis Gagneraud
Michel Gagneraud
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Entreprise Gagneraud Pere et Fils
Original Assignee
Entreprise Gagneraud Pere et Fils
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Entreprise Gagneraud Pere et Fils filed Critical Entreprise Gagneraud Pere et Fils
Publication of EP0037324A1 publication Critical patent/EP0037324A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/34—Disposal of solid waste
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing
    • G21F9/301—Processing by fixation in stable solid media
    • G21F9/302—Processing by fixation in stable solid media in an inorganic matrix

Definitions

  • the present invention relates to the field of protection against radioactivity of materials, materials, contaminated objects or waste of any kind in general.
  • the invention provides a solution to the problem of preserving waste containing Cesium 137, Strontium 90 and other long-lived elements by providing a means of packaging for solid residues or solutions previously solidified by an appropriate means described in the application. Patent No. 79.07246 of the Applicant.
  • the process of the invention essentially consists in blocking the waste, introduced into containers of concrete or other material, using metallurgical slag with a glassy structure and finely ground.
  • slag with a particle size less than 2 mm, preferably ground to less than 0.1 mm and having a specific surface greater than 1500 cm 2 / g (measured according to the Blaine method).
  • the waste When the waste is coated in a slag slurry, the latter prevents the diffusion of radioactive elements.
  • the hypotheses put forward concerning the zeolitic effect of the silico-aluminum slags there exist in the network of free sites in which the alkaline and alkaline-earth ions are preferably housed, but also other ions (chromate , manganate zincate, etc.) which are also insolubilized, and the release of insoluble, precipitated and adsorbed adsorbed ions is extremely low.
  • slag and sqories are suitable for carrying out the process of the invention.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
EP81400467A 1980-03-27 1981-03-25 Procédé de blocage des éléments alcalin et alcalino-terreux radioactifs Withdrawn EP0037324A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8006806 1980-03-27
FR8006806A FR2479541A1 (fr) 1980-03-27 1980-03-27 Procede de blocage des elements alcalins et alcalino-terreux radio-actifs

Publications (1)

Publication Number Publication Date
EP0037324A1 true EP0037324A1 (fr) 1981-10-07

Family

ID=9240171

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81400467A Withdrawn EP0037324A1 (fr) 1980-03-27 1981-03-25 Procédé de blocage des éléments alcalin et alcalino-terreux radioactifs

Country Status (4)

Country Link
EP (1) EP0037324A1 (xx)
JP (1) JPS56151399A (xx)
FR (1) FR2479541A1 (xx)
ZA (1) ZA811602B (xx)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2527376A1 (fr) * 1982-05-21 1983-11-25 Kernforschungsz Karlsruhe Procede pour ameliorer les proprietes de dechets solides radioactifs incorpores dans une matrice et solidifies
WO1984000841A1 (en) * 1982-08-16 1984-03-01 Litovitz Theodore A Fixation of anionic materials with a complexing agent
EP0297356A1 (de) * 1987-07-03 1989-01-04 Siemens Aktiengesellschaft Abfalldeponie, insbesondere Endlager für radioaktive Stoffe
US5198128A (en) * 1987-07-03 1993-03-30 Siemens Aktiengesellschaft Waste disposal site, in particular for the ultimate disposal of radioactive substances
EP0709859A1 (en) * 1994-10-27 1996-05-01 Jgc Corporation Solidifying material for radioactive wastes, process for solidifying radioactive wastes and solidified product
US5732363A (en) * 1994-10-27 1998-03-24 Jgc Corporation Solidifying material for radioactive wastes, process for solidifying radioactive wastes and solidified product
FR2844913A1 (fr) * 2002-09-20 2004-03-26 Univ Pasteur Procede de confinement du cesium et /ou du rubidium dans des matrices ceramiques frittees a base de perlite expansee, matrices mises en oeuvre et produits ainsi obtenus.

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61274299A (ja) * 1985-05-30 1986-12-04 三菱重工業株式会社 放射性廃棄物の固化方法
JP2002243892A (ja) * 2001-02-22 2002-08-28 Hitachi Ltd 放射性アルカリ廃液の固化処理方法
JP5661066B2 (ja) * 2012-05-28 2015-01-28 株式会社 フュー・テクノロジー 放射性物質を含有した焼却灰の処理方法及び処理固形物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2717656A1 (de) * 1977-04-21 1978-10-26 Nukem Gmbh Verfahren zur herstellung auslaugfester und salzlaugebestaendiger bloecke aus zement und radioaktiven abfaellen
FR2395573A1 (fr) * 1977-06-24 1979-01-19 Pechiney Ugine Kuhlmann Uran Procede de conditionnement des produits de fission provenant du retraitement des combustibles irradies par voie seche
FR2432752A1 (fr) * 1978-08-03 1980-02-29 Gagneraud Francis Procede d'enrobage de dechets radioactifs en vue d'assurer le transport et le stockage en toute securite

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2717656A1 (de) * 1977-04-21 1978-10-26 Nukem Gmbh Verfahren zur herstellung auslaugfester und salzlaugebestaendiger bloecke aus zement und radioaktiven abfaellen
FR2395573A1 (fr) * 1977-06-24 1979-01-19 Pechiney Ugine Kuhlmann Uran Procede de conditionnement des produits de fission provenant du retraitement des combustibles irradies par voie seche
FR2432752A1 (fr) * 1978-08-03 1980-02-29 Gagneraud Francis Procede d'enrobage de dechets radioactifs en vue d'assurer le transport et le stockage en toute securite

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2527376A1 (fr) * 1982-05-21 1983-11-25 Kernforschungsz Karlsruhe Procede pour ameliorer les proprietes de dechets solides radioactifs incorpores dans une matrice et solidifies
GB2124015A (en) * 1982-05-21 1984-02-08 Kernforschungsz Karlsruhe Method for improving the properties of solidified radioactive solid wastes
WO1984000841A1 (en) * 1982-08-16 1984-03-01 Litovitz Theodore A Fixation of anionic materials with a complexing agent
EP0297356A1 (de) * 1987-07-03 1989-01-04 Siemens Aktiengesellschaft Abfalldeponie, insbesondere Endlager für radioaktive Stoffe
US5198128A (en) * 1987-07-03 1993-03-30 Siemens Aktiengesellschaft Waste disposal site, in particular for the ultimate disposal of radioactive substances
EP0709859A1 (en) * 1994-10-27 1996-05-01 Jgc Corporation Solidifying material for radioactive wastes, process for solidifying radioactive wastes and solidified product
US5732363A (en) * 1994-10-27 1998-03-24 Jgc Corporation Solidifying material for radioactive wastes, process for solidifying radioactive wastes and solidified product
FR2844913A1 (fr) * 2002-09-20 2004-03-26 Univ Pasteur Procede de confinement du cesium et /ou du rubidium dans des matrices ceramiques frittees a base de perlite expansee, matrices mises en oeuvre et produits ainsi obtenus.
WO2004027783A2 (fr) * 2002-09-20 2004-04-01 Universite Louis Pasteur (Etablissement Public A Caractere Scientifique, Culturel Et Professionnel) Procede de confinement du cesium et/ou du rubidium dans des matrices ceramiques frittees a base de relite expansee
WO2004027783A3 (fr) * 2002-09-20 2004-05-13 Univ Louis Pasteur Etablisseme Procede de confinement du cesium et/ou du rubidium dans des matrices ceramiques frittees a base de relite expansee

Also Published As

Publication number Publication date
JPS56151399A (en) 1981-11-24
FR2479541A1 (fr) 1981-10-02
ZA811602B (en) 1982-03-31
FR2479541B3 (xx) 1983-06-10

Similar Documents

Publication Publication Date Title
EP0338060B1 (fr) Procede de stabilisation, de solidification et de stockage de dechets
EP0037324A1 (fr) Procédé de blocage des éléments alcalin et alcalino-terreux radioactifs
WO2007135067A1 (fr) Composition a base de ciment pour l'enrobage d'une solution aqueuse contenant du bore, procede d'enrobage et composition de coulis cimentaire
US20090012343A1 (en) Waste disposal method
EP3020692B1 (fr) Liant de géosynthèse comprenant un activateur alcalino-calcique et un composé silico-alumineux
US20080134943A1 (en) Encapsulation Medium
CA2214142A1 (en) Improved method for the treatment and stabilization of hazardous waste
US5489741A (en) Treatment and stabilization of hazardous waste
FR2525803A1 (fr) Procede pour ameliorer la retention des radionucleides par les dechets radioactifs solidifies
FR3031103A1 (fr) Coulis cimentaire pour remplissage d'un espace annulaire autour d'une alveole de stockage de dechets radioactifs creusee dans un milieu argileux
US7445591B2 (en) Treatment of waste products
RU2315380C1 (ru) Способ цементирования радиоактивных отходов в контейнере
EP0568430B1 (fr) Matériau de colmatage, procédé de fabrication de ce matériau de colmatage et procédé de mise en place de ce matériau sur un site de stockage de conteneurs
JP3282715B2 (ja) 水和反応遅延型セメント組成物及び該組成物を使用した多層構造型遮蔽体
SU1547699A3 (ru) Способ безвредного складировани отходов
US20060111603A1 (en) Storage of hazardous materials
EP0871598B1 (fr) Procede de valorisation de residus d'incineration de dechets menagers et de cendres resultant de l'incineration de boues de stations d'epuration d'eaux urbaines et melange obtenu par ce procede
JPS59116100A (ja) 人造岩石による放射性廃棄物の封じ込め方法
JP4096328B2 (ja) 放射性廃棄物埋設用充填材
JPH0631883B2 (ja) 放射性廃棄物の処分方法および充填材
JP3164131B2 (ja) 放射性廃棄物の処理構造物に用いられる骨材
JP2002307050A (ja) 重金属を含有する土壌の処理及び再利用方法、並びに重金属溶出低減材
FR2770839A1 (fr) Procede maac mortier actif anti corrosion procede de regeneration des betons hydrauliques armes degrades
JP2000281394A (ja) セメントクリンカー、セメント組成物及び多層構造型遮蔽体
JPS6094156A (ja) タンピング用材料

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE GB IT LU NL SE

17P Request for examination filed

Effective date: 19811024

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19830515

RIN1 Information on inventor provided before grant (corrected)

Inventor name: GAGNERAUD, FRANCIS

Inventor name: GAGNERAUD, MICHEL