EP0033714B1 - Schienenanordnung für Elektrolysezellen - Google Patents
Schienenanordnung für Elektrolysezellen Download PDFInfo
- Publication number
- EP0033714B1 EP0033714B1 EP81810016A EP81810016A EP0033714B1 EP 0033714 B1 EP0033714 B1 EP 0033714B1 EP 81810016 A EP81810016 A EP 81810016A EP 81810016 A EP81810016 A EP 81810016A EP 0033714 B1 EP0033714 B1 EP 0033714B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- busbars
- cell
- arrangement according
- busbar arrangement
- cells
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 239000004411 aluminium Substances 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 63
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/16—Electric current supply devices, e.g. bus bars
Definitions
- the present invention relates to a rail arrangement for guiding the direct electrical current from the cathode bar ends of a longitudinal electrolysis cell, in particular for the production of aluminum, to the anodes of the subsequent cell.
- the electrolysis cell In normal operation, the electrolysis cell is usually operated periodically, even if there is no anode effect by breaking in the crust and adding alumina.
- the cathode bars are embedded in the carbon base of the electrolysis cell, the ends of which penetrate the electrolysis tank on both long sides. These iron bars collect the electrolysis current, which flows via the busbars arranged outside the cell, the risers, the anode bars or trusses and the anode rods to the carbon anodes of the subsequent cell.
- the ohmic resistance from the cathode bars to the anodes of the subsequent cells causes energy losses which are in the order of up to 1 kWh / kg of aluminum produced. Attempts have therefore repeatedly been made to optimize the arrangement of the busbars with respect to the ohmic resistance.
- the vertical components of magnetic induction formed must also be taken into account, which - together with the horizontal current density components - generate a force field in the liquid metal obtained through the reduction process.
- the current is conducted from cell to cell as follows:
- the direct electrical current emerges from cathode bars arranged in the carbon bottom of the cell.
- the ends of the cathode bars are connected to the busbars via flexible bands, which run parallel to the row of electrolytic cells. From these busbars running along the long sides of the cells, the current is led, via other flexible belts and via risers, to the two ends of the traverse of the subsequent cell.
- the current distribution between the nearer and the far end of the traverse based on the general current direction of the cell row, varies from 100-0% to 50-50%.
- the vertical anode rods which carry the carbon anodes and feed with electrical current, are attached to the crossbar by means of locks.
- the electrical direct current must travel a relatively long way from a cathode bar end of a cell to an anode of the subsequent cell.
- part of the electrical current has to be conducted via the busbars to the downstream end of the crossbar, then it flows backwards over the crossbar.
- the electrical current is raised from the level of the cathode bar to the height of the traverse and then flows down to the anodes. This returning and returning the current in two directions means an additional consumption of metal during the manufacture of the furnace series and an additional consumption of energy due to the Joule effect.
- the inventor has therefore set itself the task of creating a rail arrangement for guiding the direct current from the cathode bar ends of a longitudinal electrolysis cell to the anodes of the subsequent cell, in which less metallic rail material has to be used, smaller losses of electrical energy occur and also the harmful magnetic energy Effects are reduced.
- the flexible current strips arranged close to one another which conduct the current from the cathode bar ends to the busbars leading to the subsequent cell or the current from the busbars which are connected to the cathode bar ends of the preceding electrolysis cell, lead to the anodes, have the effect that the third type of the flow components mentioned above, which rotates in the four quadrants, is eliminated.
- This so-called symmetrical solution in which the busbars are equidistant from the two long sides of the cells, may prevent the magnetic influence partially but not completely.
- the aim is therefore to limit or eliminate the magnetic influence of the neighboring cells Q ihe.
- This is achieved by an asymmetrical arrangement of the busbars, in that the distance of the busbars from the long sides of the electrolysis cell is shorter on the side facing the row of neighboring cells and longer on the other side.
- the resulting asymmetry has the effect that the magnetic influence of the neighboring cell row is eliminated and the first flow component discussed above along the inner circumference of the cell is also prevented.
- the flexible current bands which connect the cathode bar ends to the busbars are more or less curved.
- these flexible current strips are strongly bent, but when the busbars are at a large distance from the long sides of the cell, they are almost stretched. This does not change the electrical resistance, but only the influence of the magnetic field.
- the busbars facing away from and facing the neighboring cell row are preferably arranged in such a way that the difference in their distance from the corresponding long sides of the cells makes up approximately 50-80 cm.
- the cross section of the first and second busbars is designed such that the electrical resistance of all busbars is approximately the same.
- the short busbars can have a smaller cross section than the longer ones.
- the busbars can also be made of metals of different electrical resistance, the shortest busbars having the greatest, the longest busbars the smallest specific electrical resistance.
- the asymmetry can also be generated by connecting a different number of cathode bar ends to first busbars opposite one another with respect to the cell longitudinal axis.
- the electrolysis cells 10 and 12 shown in FIG. 1 are picked out from a row of cells in an aluminum smelter.
- the general direction of the direct electrical current is designated I.
- the adjacent row of electrolytic cells, which exerts a magnetic influence on the electrolytic cells 10 and 12, is located on the left in relation to the general current direction I.
- the cathode bars arranged in the carbon bottom of cells 10 and 12 are only hinted at.
- Flexible current strips 14, 16 are arranged at both ends of the cathode bars, which, as shown in Fig., At a short distance between the busbars 18, 20, 22 and 24 strongly bent, on the other hand, the busbars opposite with respect to the longitudinal axis of the cell are almost stretched with a large distance.
- the busbars 18, 20, 22 and 24 are briefly closed at 26.
- Three busbars 28, 30 and 32 arranged along the sequence cell 12 are conductively connected to the equipotential connection 26.
- Flexible current bands 34 branch off from each of these current rails, one band each being connected to an anode carrier (not shown).
- the busbar 28 leads the current to the nearest anodes 36, the busbar 30 to the middle anodes 36 and the busbar 32 to the anodes 36 of the follower cell 12 which are furthest away in the direction of current I.
- all the busbars have the same electrical resistance, the bars 24 and 28 therefore have the smallest cross-section, if all the rails are made of the same material, and the rails 18 and 32 have the largest.
- electrolysis cell 10 is also equipped with anodes 36 and the corresponding power supply lines, these have been omitted because of a better overview.
- an electrolysis cell has 32 cathode bar ends, but has only 30 anodes. If a regular current distribution is to be ensured, an equipotential connection 26 must be present if the number of cathode bar ends and anodes is not the same.
- Fig. 2 38 means the steel tub, 40 the thermal insulation, 42 the carbon bottom and 44 the cathode bar ends; a the large distance between the busbars 18, b the small one.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Control Of Motors That Do Not Use Commutators (AREA)
- Optical Measuring Cells (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81810016T ATE4917T1 (de) | 1980-02-01 | 1981-01-23 | Schienenanordnung fuer elektrolysezellen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH812/80 | 1980-02-01 | ||
CH81280 | 1980-02-01 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0033714A2 EP0033714A2 (de) | 1981-08-12 |
EP0033714A3 EP0033714A3 (en) | 1981-08-26 |
EP0033714B1 true EP0033714B1 (de) | 1983-10-05 |
Family
ID=4195757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81810016A Expired EP0033714B1 (de) | 1980-02-01 | 1981-01-23 | Schienenanordnung für Elektrolysezellen |
Country Status (12)
Country | Link |
---|---|
US (1) | US4359377A (is) |
EP (1) | EP0033714B1 (is) |
AR (1) | AR225488A1 (is) |
AT (1) | ATE4917T1 (is) |
AU (1) | AU6660581A (is) |
BR (1) | BR8100590A (is) |
CA (1) | CA1156971A (is) |
DE (2) | DE3009158A1 (is) |
IS (1) | IS1144B6 (is) |
NO (1) | NO154925C (is) |
YU (1) | YU25681A (is) |
ZA (1) | ZA81288B (is) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2576920B1 (fr) * | 1985-02-07 | 1987-05-15 | Pechiney Aluminium | Cuve d'electrolyse hall-heroult a barres cathodiques et a calorifugeage dissymetriques |
US5981719A (en) * | 1993-03-09 | 1999-11-09 | Epic Therapeutics, Inc. | Macromolecular microparticles and methods of production and use |
US6090925A (en) * | 1993-03-09 | 2000-07-18 | Epic Therapeutics, Inc. | Macromolecular microparticles and methods of production and use |
US10128486B2 (en) | 2015-03-13 | 2018-11-13 | Purdue Research Foundation | Current interrupt devices, methods thereof, and battery assemblies manufactured therewith |
WO2018019888A1 (en) | 2016-07-26 | 2018-02-01 | Sgl Cfl Ce Gmbh | Cathode current collector/connector for a hall-heroult cell |
CN109845039B (zh) * | 2016-07-29 | 2021-05-25 | 哈奇有限公司 | 用于电解池的柔性电气连接器 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1185548A (fr) * | 1957-10-29 | 1959-07-31 | Elektrokemisk As | Dispositif pour l'amenée de courant aux fours pour la production d'aluminium par fusion électrolytique |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA887250A (en) * | 1971-11-30 | Vsesojuzny Nauchno-Issledovatelsky I Proektny Institut Aljuminievoi, Mag Nievoi I Elektrodnoi Promyshlennosti | Bus bar system for aluminum reduction cells | |
US3650941A (en) * | 1968-09-23 | 1972-03-21 | Kaiser Aluminium Chem Corp | Electrolytic reduction cell |
CH544812A (de) * | 1970-09-01 | 1973-11-30 | Alusuisse | Zelle für die Gewinnung von Aluminium durch Elektrolyse von Aluminiumoxid im Schmelzfluss |
US3821101A (en) * | 1972-09-08 | 1974-06-28 | V Nikiforov | Wiring system of electrolyzers for producing aluminum |
FR2378107A1 (fr) * | 1977-01-19 | 1978-08-18 | Pechiney Aluminium | Procede pour ameliorer l'alimentation en courant de cuves d'electrolyse alignees en long |
FR2423554A1 (fr) * | 1978-02-08 | 1979-11-16 | Pechiney Aluminium | Procede de reduction des perturbations magnetiques dans les series de cuves d'electrolyse a haute intensite |
CH649317A5 (de) * | 1978-08-04 | 1985-05-15 | Alusuisse | Elektrolysezelle mit kompensierten magnetfeldkomponenten. |
-
1980
- 1980-03-10 DE DE19803009158 patent/DE3009158A1/de not_active Withdrawn
-
1981
- 1981-01-16 ZA ZA00810288A patent/ZA81288B/xx unknown
- 1981-01-19 US US06/226,062 patent/US4359377A/en not_active Expired - Fee Related
- 1981-01-23 AT AT81810016T patent/ATE4917T1/de not_active IP Right Cessation
- 1981-01-23 AU AU66605/81A patent/AU6660581A/en not_active Abandoned
- 1981-01-23 EP EP81810016A patent/EP0033714B1/de not_active Expired
- 1981-01-23 DE DE8181810016T patent/DE3161057D1/de not_active Expired
- 1981-01-28 CA CA000369486A patent/CA1156971A/en not_active Expired
- 1981-01-30 NO NO810327A patent/NO154925C/no unknown
- 1981-01-30 YU YU00256/81A patent/YU25681A/xx unknown
- 1981-01-30 IS IS2610A patent/IS1144B6/is unknown
- 1981-02-02 BR BR8100590A patent/BR8100590A/pt unknown
- 1981-02-02 AR AR284177A patent/AR225488A1/es active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1185548A (fr) * | 1957-10-29 | 1959-07-31 | Elektrokemisk As | Dispositif pour l'amenée de courant aux fours pour la production d'aluminium par fusion électrolytique |
Also Published As
Publication number | Publication date |
---|---|
YU25681A (en) | 1983-06-30 |
EP0033714A2 (de) | 1981-08-12 |
NO810327L (no) | 1981-08-03 |
ZA81288B (en) | 1982-02-24 |
IS1144B6 (is) | 1984-03-05 |
AU6660581A (en) | 1981-09-10 |
IS2610A7 (is) | 1981-07-02 |
DE3009158A1 (de) | 1981-08-06 |
US4359377A (en) | 1982-11-16 |
BR8100590A (pt) | 1981-08-18 |
ATE4917T1 (de) | 1983-10-15 |
NO154925C (no) | 1987-01-14 |
CA1156971A (en) | 1983-11-15 |
DE3161057D1 (en) | 1983-11-10 |
EP0033714A3 (en) | 1981-08-26 |
NO154925B (no) | 1986-10-06 |
AR225488A1 (es) | 1982-03-31 |
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