EP0000268B1 - Verfahren zum thermischen Härten von Glasscheiben insbesondere zur Anwendung als Seiten-und Heckscheiben für Motorfahrzeuge - Google Patents

Verfahren zum thermischen Härten von Glasscheiben insbesondere zur Anwendung als Seiten-und Heckscheiben für Motorfahrzeuge Download PDF

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Publication number
EP0000268B1
EP0000268B1 EP78300071A EP78300071A EP0000268B1 EP 0000268 B1 EP0000268 B1 EP 0000268B1 EP 78300071 A EP78300071 A EP 78300071A EP 78300071 A EP78300071 A EP 78300071A EP 0000268 B1 EP0000268 B1 EP 0000268B1
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EP
European Patent Office
Prior art keywords
glass sheet
gas
quenching
glass
flow
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Expired
Application number
EP78300071A
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English (en)
French (fr)
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EP0000268A1 (de
Inventor
Geoffrey Greenhalgh
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Pilkington Automotive Ltd
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Triplex Safety Glass Co
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Publication date
Application filed by Triplex Safety Glass Co filed Critical Triplex Safety Glass Co
Publication of EP0000268A1 publication Critical patent/EP0000268A1/de
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • C03B27/0404Nozzles, blow heads, blowing units or their arrangements, specially adapted for flat or bent glass sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • C03B27/0413Stresses, e.g. patterns, values or formulae for flat or bent glass sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2225/00Transporting hot glass sheets during their manufacture
    • C03B2225/02Means for positioning, aligning or orientating the sheets during their travel, e.g. stops
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31Surface property or characteristic of web, sheet or block
    • Y10T428/315Surface modified glass [e.g., tempered, strengthened, etc.]

Definitions

  • This invention relates to the toughening of glass sheets and in particular to the production of flat or curved sheets of thermally toughened glass to be used as motor vehicle side or rear windows.
  • the toughened glass sheets shall be fractured by localised impact at a defined position on the glass sheet, two particular positions being at the geometrical centre of the glass sheet and at a position adjacent the edge of the sheet. It is then required that areas of the fractured glass sheet should be selected where the particle count is a minimum and where the particle count is a maximum and limitations are placed on the minimum and maximum particle counts permissible in such areas.
  • the minimum particle count permissible determines the maximum size of particles resulting from fracture so as to limit the danger of laceration by larger particles subsequent to fracture of the glass sheet in an accident.
  • the maximum particle count permissible determines the minimum fineness of particles resulting from accidental fracture of the glass sheet so as to limit the danger of ingestion of fine glass particles.
  • At present motor vehicle side and rear windows are made from glass of about 4.0 mm to 6.0 mm thickness and can be uniformly toughened so as to meet official fracture requirements.
  • glass sheets of thickness 4 mm and above meet the proposed E.E.C. standard referred to below if uniformly toughened to have a central tensile stress in the range 55 MN/m 2 to 59 MN/m 2.
  • E.E.C. standard referred to below if uniformly toughened to have a central tensile stress in the range 55 MN/m 2 to 59 MN/m 2.
  • thinner glass in motor vehicles e.g. of about 3.0 mm thickness
  • glass of thickness in the range 2.5 mm to 3.5 mm being of particular interest.
  • the proposed E.E.C. standard also has the requirement that the fractured glass sheet shall not contain any elongated particles with jagged ends of more than 6 cm in length, such particles being referred to as "splines".
  • British Standard No. BS 5282 entitled "ROAD VEHICLE SAFETY GLASS" is less restrictive than the proposed E.E.C. standard in that it specifies for qlass less than 4 mm in thickness a minimum particle count of 40 in a 5 cm x 5 cm square may be permitted and the maximum permitted particle count in a 5 cm x 5 cm square may be 400.
  • the British Standard also basically prohibits the presence of splines of more than 6 cm in length in the fractured test glass. The British Standard also requires that no splines are to be present in the fractured glass sheet.
  • quenching was effected by directing quenching jets at the glass sheet, and imparting a vertical oscillation or a circular oscillation to the quenching jets to produce the required distribution of regions of the glass sheet quenched at a maximum rate.
  • the quenching could also be effected by directing stationary quenching jets at the glass sheet to produce the required distribution of regions of the glass sheet quenched at a maximum rate.
  • a method of toughening a glass sheet in which the glass sheet is advanced into and relative to a flow of quenching gas directed towards at least one surface of the glass sheet from individual spaced gas outlets to induce overall toughening stresses therein, characterised in that advance of the sheet relative to the flow of quenching gas is terminated for a predetermined time, whereby localised gas flows are applied to at least said one surface of the glass sheet from said individual gas outlets during said predetermined time to produce in the glass as the toughening stresses develop a distribution of regions of more highly toughened glass interspersed with regions of lesser toughened glass in which distribution there are areas in which the principal stresses acting in the plane of the glass sheet are unequal, and in that the advance of the glass sheet relative to the flow of quenching gas is continued after said predetermined time.
  • the invention also comprehends a method in which the glass sheet is advanced between flows of quenching gas which are directed from individual gas outlets towards both surfaces of the glass sheet, characterised in that advance of the glass sheet relative to the flow of quenching gas operative on at least one surface of the glass sheet is terminated during said predetermined time.
  • advance of the glass sheet relative to the flows of quenching gas operative on both surfaces of the glass sheet may be terminated for said nredetermined time.
  • the glass sheet is advanced into the flow of quenching gas and is halted in the flow for said predetermined time.
  • the glass sheet is advanced into the flow of quenching gas and the individual gas outlets providing the flow of quenching gas are moved in the same direction and at the same speed as the glass sheet during said predetermined time.
  • the invention may be applied to a glass sheet which is being advanced horizontally on a roller conveyor through a quenching station wherein flows of, quenching gas are directed from individual gas outlets against at least one or both surfaces of the glass sheet.
  • the invention also includes a method comprising advancing the glass sheet horizontally on a gaseous support through a quenching station wherein at least the lower surface of the glass sheet is subjected to a flow of quenching gas directed from individual gas outlets against the lower surface of the sheet, said flow of quenching gas also providing the gaseous support for the sheet.
  • a flow of quenching gas may also be directed from individual gas outlets against the upper surface of the glass sheet.
  • the glass sheet may be subjected to additional localised gas flows constituted by an array of gas jets operative on at least part of one or both surfaces of the glass sheet in addition to the main flow of quenching gas during the predetermined time in which advance of the glass sheet relative to the main flow of quenching gas is terminated.
  • the array of gas jets may be spaced apart in rows transversely of the direction of advance of the glass sheet with the rows spaced apart in the direction of advance of the sheet.
  • the invention also comprehends a toughened glass sheet produced by the method of the invention and for use as a side or rear window for a motor vehicle.
  • Figure 1 illustrates the fracture pattern of a toughened glass sheet suitable for use as the side window or rear window of a motor vehicle produced by the method of the invention.
  • the glass sheet has a distribution, in rectangular array, of localised areas 1 of more highly toughened glass interspersed with areas 2 of lesser toughened glass. Areas 3 of the glass have a medium toughening stress and in each of the areas 3 the principal stresses are unequal with the major principal stress acting in the direction indicated by the arrows 4.
  • Areas 5 of the glass also have a medium toughening stress and have unequal principal stresses with the major principal stress 6 in each area 5 acting in a direction substantially perpendicular to the direction of the major principal stress 4 in each of the areas 3.
  • the medium toughening stresses produced in the areas 3 and 5 of the glass sheet are a combination of the normal toughening stresses of equal magnitude in all directions in the plane of the glass sheet, and additional area stresses produced in the areas 3 and 5 due to the different rates at which the adjacent areas 1 and 2 are cooled and contract. These area stresses are not of equal magnitude in all directions in the plane of the glass sheet.
  • the central tensile stress in the areas 3 and 5 of the glass sheet due to the combined effect of the normal toughening stresses and the area stresses can be resolved into unequal principal stresses in the plane of the glass sheet namely a major principal tensile stress and a minor principal tensile stress acting at right angles to the major principal tensile stress.
  • the major principal tensile stress 6 acts in a direction perpendicular to the direction of the major principal tensile stress 4 in the areas 3.
  • the size of the particles produced in a fractured glass sheet depends on the degree of toughening of the glass and in general the fineness of the particles increases with the degree of toughening. Hence 'the particles of relatively small size are produced in the more highly toughened areas 1, in the lesser toughened areas 2 larger particles are produced, and in the areas 3 and 5 having a medium toughening stress particles of medium size are produced. This distribution of small, larger and medium sized particles is produced over the whole surface of the fractured glass sheet.
  • the glass sheet is toughened to the degree described in DE-A-2709105 there are no splines in the fracture, and the requirements of the proposed E.E.C. standard and of British Standard No. BS 5282 with regard to minimum and maximum particle sizes are met.
  • Apparatus as shown in Figure 2 may be employed for transporting glass sheets on a gaseous support through a heating station to a quenching station.
  • Flat sheets of glass 7 which are cut to the required shape for use as a side or rear window of a vehicle are fed in sequence on to asbestos covered conveyor rollers 8 at the loading end of the apparatus.
  • the rollers 8 have collars 9 of slightly larger diameter than the major surfaces of the rollers and the glass sheets ride on the collars 9.
  • the rollers 8 are inclined at a slight angle to the horizontal, for example an angle of about 5°.
  • the sheets 7 are fed in sequence by the rollers 8 through an inlet 10 into a heating furnace comprising a tunnel structure including a roof 11 which has side walls 12.
  • the sheets 7 are conveyed through the first part of the heating furnace on further asbestos covered rollers 8 and are then conveyed through the remaining length of the furnace on a base bed structure which generates a gaseous support for the glass sheets while they are heated.
  • the bed structure comprises a base plate 13 which is a flat plate of heat-resistant stainless steel and which forms the roof of an exhaust chamber indicated at 14.
  • the plate 13 is uniformly apertured for the passage of hot gases from outlet apertures 15, Figure 3.
  • Each of the apertures 15 for the passage of hot gases upwardly through the base plate 13 is defined by the bore of a supply tube 16 which is fitted into a hole in the base plate.
  • the tops of the tubes 16 are flush with the top surface of the base plate 13 and the tubes 16 extend downwardly from the base plate 13 and are located at their lower ends in holes in a floor 17 of the exhaust chamber 14. Hot gases are supplied through ducts 18, Figure 2 to plenum chambers 19.
  • the floor 17 of the exhaust chamber 14 forms the roof of one of the plenum chambers 19.
  • the base plate 13 is also formed with equally interspersed exhaust openings 20 communicating with the exhaust chamber 14. Outlet apertures, not shown, in the walls of the exhaust chamber 14 allow gases to escape to atmosphere or for collection and recirculation.
  • the upper face of the base plate 13 is an accurately flat surface formed to receive in intimate engagement the lower face of a series of removable blocks 21 which are machined from heat-resistant stainless steel with their lower faces machined flat so that they can be slid into the apparatus from one side into gas- tight engagement with the upper surface of the base plate 13.
  • the blocks 21 each have gas escape apertures 22 communicating with the outlet apertures 15 and gas exhaust apertures 23 communicating with the exhaust openings 20. Hot gases supplied through the ducts 18 into the plenum chambers 19 proceed upwardly through the tubes 16 and the apertures 22 in the block 21 and escape and expand above the upper surface of the block 21 to create a gaseous support under the advancing glass sheets 7.
  • Gas is continually released from the apertures 22 into the gaseous support for each glass sheet and simultaneously gas escapes from the gaseous support through the exhaust apertures 23 into the exhaust chamber 14 and thence to the outlet apertures.
  • the upper surfaces of the blocks 21 are transversely tilted so as to lie at the same small angle to the horizontal, for example 5°, as the conveyor rollers 8.
  • the upper surfaces of the collars 9 on the conveyor rollers 8 are slightly higher than the level of the upper surface of the first block 21 so that as soon as each glass sheet 7 becomes completely and uniformly supported on the gaseous support it tends to slide down the transverse incline until it is in engagement with rotating discs 24 mounted alongside the blocks 21 on vertical spindles (not shown) which extend upwardly from drive motors (not shown) arranged outside the furnace which motors drive the discs at a controlled speed commensurate with the rate of advance of the glass sheets on to the gaseous support by the rollers 8.
  • the collars 9 may be arranged so that if the sheets are already touching the collars then they will be in a position to be driven by the edge discs 24 without any substantial movement of the sheets down the transversely sloping upper surface of the first block 21.
  • the glass sheets are, as shown in Figure 2, placed on the conveyor rollers end-to-end so that a succession of flat glass sheets 7 are advanced into the furnace by the driving action of the conveyor rollers.
  • the edge discs 24 maintain the registration of the glass sheets in the furnace and also provide drive to cause the forward movement of the sheets. However, some of the discs 24 may be free running and act as rotatable guides.
  • the advance of the hot glass sheets continues to a quenching station which is indicated generally at 27 in Figure 2 and is shown in more detail in Figure 3.
  • the glass sheets are supported on a gaseous support generated above a bed of identical construction to the bed in the furnace except that the bed is supplied with chilling air at ambient temperature.
  • the presence of each glass sheet advancing into the quenching station 27 from the furnace generates a gaseous cushion between the sheet and the upper surface of the bed which provides both the required support for the sheet and a flow of chilling air against the bottom surface of the glass sheet.
  • the advance of the glass sheet into the quenching station is by means of rotating discs, not shown.
  • the quenching section there is a generalised flow of quenching gas contacting the upper surface of the glass sheet which gas flow has a substantially identical chilling effect on the upper surface of the glass as the chilling effect of the lower surface by the gaseous support.
  • the gas flows on the upper surface are generated from an upper gas supply and exhaust equipment of identical construction to the base bed supplying gas to and exhausting gas from the gaseous support.
  • the upper part of the quenching station comprises a plate 28 of asbestos-based, heat-resistant material which has gas supply apertures 29 and gas exhaust apertures 30.
  • the plate 28 is fixed to an apertured base plate 31 of a gas exhaust chamber 32.
  • the matching surfaces of the plates 28 and 31 are machined flat so as to be gas tight.
  • the roof of the exhaust chamber 32 is a plate 33 which also forms the base of a plenum chamber 34 to which chilling air at ambient temperature is supplied.
  • the chilling air passes through apertures in the plate 33 and is conducted down tubes 35 extending through the exhaust chamber 32 the lower ends of which tubes are fixed in the base plate 31 of the exhaust chamber and communicate with the gas supply apertures 29 in the plate 28.
  • the gas exhaust apertures 30 in the plate 28 are aligned with exhaust apertures 36 in the plate 31 so that gas can escape from above the glass sheet into the exhaust chamber 32 whose walls have apertures so that the exhaust gases can be exhausted to atmosphere or collected and recirculated:
  • the hot glass sheet is subjected to generalised quenching gas flows at the quenching station as it is advanced into the quenching station.
  • generalised quenching gas flows at the quenching station As illustrated in Figure 3 the gas supply apertures 22 in the plate 21 and the gas supply apertures 29 in the plate 28 are slightly inclined to the direction of advance of the glass so as to avoid the production of a striped toughening pattern in the glass sheet.
  • the advance of the glass sheet is halted when the whole of the glass sheet is within the quenching station by means of a plunger 53 ( Figure 3) which is operated by a solenoid 54.
  • the plunger extends downwardly through a hole 56 in the plate 28.
  • a proximity sensor such as a thermocouple 55 extends downwardly through the plate 28 in front of the plunger 53 in the direction of advance of the glass sheet.
  • the solenoid 54 is de- energised to cause withdrawal of the plunger 53 and the advance of the glass sheet continues through the quenching station.
  • the resultant toughened glass sheet emerges from the quenching station on rollers 51.
  • the glass sheet is subjected to additional localised gas flows so as to intensify the differential toughening effect produced by the localised gas flows 40 from the gas supply apertures 22 and 29 in the plates 21 and 28.
  • This is achieved by also subjecting the upper surface of the glass sheet when stationary in the quenching station to a rectangular array of gas jets which are spaced apart in rows transversely of the direction of advance of the glass with rows spaced apart in the direction of advance.
  • the array of gas jets is provided by an array of gas supply nozzles 37 which are connected in rows to ducts 38 located in the exhaust chamber 32.
  • the nozzles 37 extend downwardly through specially enlarged gas exhaust apertures 30 in the plate 28 as illustrated in Figure 6.
  • each of the ducts 38 is connected to an air supply manifold 39 located outside the exhaust chamber 32 alongside the quenching station.
  • An air supply to the manifold 39 is switched on when the glass sheet is stationary in the quenching station, and the manifold 39 is connected through a pressure regulator to a solenoid operated spool valve of conventional design.
  • the solenoid 54 is energised to extend the plunger 53 into the path of the glass sheet this also actuates a pressure switch which operates the spool valve to supply compressed air to the nozzles 37.
  • the additional localised gas flows emerging from the nozzles 37 as illustrated by the arrows 41 in Figure 5, act to intensify the production of the distribution of regions of more highly toughened glass interspersed with regions of lesser toughened glass in the part of the glass sheet which lies below the nozzles 37.
  • the plunger 53 is raised, the supply of compressed air to the nozzles 37 is cut off and the advance of the glass sheet continues through the quenching station.
  • This embodiment of the invention has particular application for intensification of the differential toughening pattern over a localised area of the glass sheet in order to modify the fracture pattern in such an area which may be necessary in order to meet official fracture requirements.
  • the array of nozzles 37 may extend over the whole of the quenching station so that the whole of the glass sheet is subjected to localised gas flows from the nozzles 37 if it is required to intensify the production of the distribution of differentially toughened areas of glass over the whole of the glass sheet.
  • the compressed air supply switched to manifold 39 is at 690 KPa.
  • the diameter of the bore of each of the nozzles 37 is 48 mm and the nozzle spacing is at 38 mm square pitch.
  • the spacing of the ends of the nozzles from the upper surface of the glass supported on the gas cushion at the quenching station is 6 mm to 12 mm.
  • Figure 8 illustrates another method of operating the invention.
  • the glass sheet floats on a gaseous support which is generated above an apertured base plate 21 of greater length than that of the glass sheet and quenching gas flows are applied to the glass sheet both from the plate 21 through gas supply apertures 22 and through gas supply apertures 29 in the plate 28 of the upper part of the quenching station in the manner described with reference to Figures 4 and 5.
  • the upper part of the quenching station comprising the plate 28 with the gas exhaust chamber 32 and the plenum chamber 34 is mounted on wheels 62 which run on a trackway 63 extending above and parallel to the lower apertured plate 21 of the quenching station.
  • a pinion 64 mounted on the upper part of the quenching station engages with a fixed rack 65 extending alongside the trackway 63. When the pinion 64 is driven by a motor (not shown) this drives the upper part of the quenching station along the trackway 63 over the full length of the lower plate 21.
  • the upper part of the quenching station is initially stationary and as shown in Figure 8 is located above the left hand end of the lower apertured plate 21 adjacent to the furnace.
  • a hot glass sheet is advanced from the furnace onto the plate 21 beneath the upper part of the quenching station and is subjected to the generalised gas flows at the quenching station as it moves into this position.
  • a proximity detector 66 in the upper part of the quenching station which generates a signal initiating operation of the drive motor for the pinion 64 which drives the upper part of the quenching station along the trackway 63.
  • the upper part of the quenching station is driven at a controlled speed equal to the speed of advance of the glass sheet along the lower apertured plate 21. While the upper part of the quenching station is being driven along the trackway 63 to follow the movement of the glass sheet the gas flows 40 from the gas supply apertures 29 in the plate 28 of the upper part of the quenching station act on localised areas of the upper face of the glass sheet so as to produce the required distribution of regions of more highly toughened glass interspersed with regions of lesser toughened glass in the glass sheet. When the upper part of the quenching station reaches a position above the right hand end of the lower apertured plate 21 it is stopped and is then returned to the left hand end of the plate 21 along the trackway 63 for quenching a succeeding glass sheet.
  • the upper part of the quenching station may also include nozzles 37 as in the arrangement of Figures 5 and 6 subjecting the upper face of the glass sheet to additional localised gas flows so as to intensify the differential toughening effect produced by the localised gas flows from the gas supply apertures 29 in the plate 28 of the upper part of the quenching station.
  • the lower part of the quenching station including the base plate 21 is mounted to be moved in correspondence with the upper part of the quenching station.
  • a hot glass sheet is moved from the furnace onto the base plate 21.
  • the glass sheet floats above the base plate 21 on the gaseous support and is carried forward by forward movement of the base plate 21 in correspondence with the movement of the upper part of the quenching station.
  • the base plate 21 need only be the same length as that of the upper part of the quenching station.
  • each glass sheet advances on to a transitional blook whose thickness along its longitudinal centre line is the same as the thickness .of the two blocks 21 but whose upper face is machined as a series of flats of gradually increasing angle which result in the upper surface of the block having the desired final curved form of the glass sheets.
  • the glass advances on to this transitional block and is heated to a temperature such that it can sag downwardly to conform to the shape of the block.
  • the block is apertured to provide a gaseous support created beneath the hot deformable glass as it slides over the block.
  • This downward sagging increases progressively as the glass sheet advances and the glass which is still hot and deformable moves from the block onto a final part of the bed whose cross section conforms to the now curved shape of the glass sheet.
  • the glass sheet advances over this curved section of the bed to the quenching station the upper and lower part of which are also suitable curved with a curved distribution of the nozzles 37 when provided in order to enhance the differential toughening effect.
  • Figure 9 illustrates the toughening of glass sheet 7 which is being advanced on a roller conveyor comprising a series of horizontal rollers 57.
  • the conveyor carries the glass sheet through a heating furnace to a quenching station where the rollers carry the glass sheet between upper and lower blowing boxes 58 and 59.
  • the box 58 has an array of blowing nozzles 60 which point downwardly towards the roller conveyor so as to direct quenching gas flows on to the upper surface of the glass sheet 7.
  • the nozzles 60 are arranged at a slight angle to the direction of advance of the glass sheet in the same way as the supply and exhaust apertures in Figure 4.
  • the lower blowing box 59 has upwardly projecting blowing nozzles 61 which are directed through the gaps between the rollers 57 and are also arranged at a slight angle to the direction of advance of the glass sheet.
  • the plunger 53 is mounted beneath the upper blowing box 58 and operates to arrest the advance of the sheet 7 when it is wholly within the quenching station. Gas flows from the nozzles 60 and 61 then act as localised gas flows applied to the upper and lower faces of the glass sheet, and are applied for a time sufficient to ensure that the glass sheet emerging from the quenching station on the roller conveyor has the required distribution of regions of more highly toughened glass interspersed with regions of lesser toughened glass.
  • the arrangement of Figure 9 may also include additional nozzles 37 as in the arrangement of Figures 5 and 6. Compressed air is switched to the nozzles 37 when the glass sheet is stationary between the upper and lower blowing boxes and localised air jets from the nozzles are directed against the faces of the glass sheet to intensify the differential toughening effect produced by the gas flows from the blowing box nozzles 60 and 61.
  • either one or both of the blowing boxes may be mounted as in the arrangement of Figure 8 to be driven forward at the same speed of the glass sheet once the glass sheet has entered between the blowing boxes.

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)

Claims (10)

1. Verfahren zum Vorspannen einer Glasbahn (7), bei dem die Glasbahn (7) in einen und relativ zu einem Abschreckgasstrom vorgerückt wird, der von gesonderten beabstandeten Gasauslässen (22, 29) auf wenigstens eine Oberfläche der Glasbahn gerichtet wird, um Gesamtvorspannungsbeanspruchungen darin zu erzeugen, dadurch gekennzeichnet, daß man das Vorrücken der Bahn (7) relativ zum Abschreckgasstrom für eine bestimmte Zeit beendet, wodurch örtlich begrenzte Gasströme auf wenigstens die eine Oberfläche der Glasbahn (7) von den gesonderten Gasauslässen (22, 29) während der vorbestimmten Zeit einwirken, um im Glas während der Entwicklung der Vorspannungsbeanspruchungen eine Verteilung von Zonen stärker vorgespannten Glases (1), in denen Zonen geringer vorgespannten Glases (2) eingesprengt sind, zu erzeugen, in welcher Verteilung es Bereiche (3, 5) gibt, in denen die in der Ebene der Glasbahn (7) wirkenden Spannungen (6) ungleich sind, und daß man das Vorrücken der Glasbahn (7) relativ zum Abschreckgasstrom nach der vorbestimmten Zeit fortsetzt.
2. Verfahren nach Anspruch 1, bei dem die Glasbahn zwischen Abschreckgasstromen vorgerückt wird, die von gesonderten Gasauslässen auf beide Oberflächen der Glasbahn gerichtet werden, dadurch gekennzeichnet, daß man das Vorrücken der Glasbahn relativ zum Abschreckgasstrom, der auf wenigstens eine Oberfläche der Glasbahn einwirkt, während der vorbestimmten Zeit beendet.
3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß man das Vorrücken der Glasbahn relativ zum Abschreckgasstrom, der auf beide Oberflächen der Glasbahn einwirkt, für die vorbestimmte Zeit beendet.
4. Verfahren nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die Glasbahn, die in den oder die Abschreckgasströme vorgerückt wird, in dem oder den Strömen für die vorbestimmte Zeit aufgehalten wird.
5. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die gesonderten Gasauslässe, die den oder die Abschreckgasströme liefern, in den oder die die Glasbahn vorrückt, in der gleichen Richtung und mit der gleichen Geschwindigkeit wie die Glasbahn während der vorbestimmten Zeit bewegt werden.
6. Verfahren nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die Glasbahn horizontal auf einem Rollenförderer durch eine Abschreckstation vorgerückt wird und daß Abschreckgasströme von gesonderten Gasauslässen gegen wenigstens eine oder beide Oberflächen der Glasbahn gerichtet werden.
7. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Glasbahn horizontal auf einem gasförmigen Träger durch eine Abschreckstation vorgerückt wird und wenigstens die Unterseite der Glasbahn einem von gesonderten Gasauslässen gegen die Unterseite gerichteten Abschreckgasstrom ausgesetzt wird, der gleichzeitig den gasförmigen Träger für die Bahn bildet.
8. Verfahren nach Anspruch 7, dadurch gekennzeichnet, daß auch ein Abschreckgasstrom von gesonderten Gasauslässen gegen die Oberseite der Glasbahn gerichtet wird.
9. Verfahren nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die Glasbahn zusätzlichen örtlich begrenzten Gasströmen, die aus einer Gruppe von auf wenigstens einen Teil einer oder beider Oberflächen der Glasbahn einwirkenden Gasstrahlen gebildet werden, zusätzlich zu dem Hauptabschreckgasstrom während der vorbestimmten Zeit ausgesetzt wird, in der das Vorrücken der Glasbahn relativ zum Hauptabschreckgasstrom beendet wird.
10. Verfahren nach Anspruch 9, dadurch gekennzeichnet, daß die Gasstrahlen der Gruppe Abstände in Reihen quer zur Vorrückrichtung der Glasbahn aufweisen, wobei die Reihen unter Abstand in der Vorrückrichtung der Bahn angeordnet sind.
EP78300071A 1977-06-23 1978-06-23 Verfahren zum thermischen Härten von Glasscheiben insbesondere zur Anwendung als Seiten-und Heckscheiben für Motorfahrzeuge Expired EP0000268B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB2636077 1977-06-23
GB2636077 1977-06-23

Publications (2)

Publication Number Publication Date
EP0000268A1 EP0000268A1 (de) 1979-01-10
EP0000268B1 true EP0000268B1 (de) 1981-05-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP78300071A Expired EP0000268B1 (de) 1977-06-23 1978-06-23 Verfahren zum thermischen Härten von Glasscheiben insbesondere zur Anwendung als Seiten-und Heckscheiben für Motorfahrzeuge

Country Status (6)

Country Link
US (1) US4178414A (de)
EP (1) EP0000268B1 (de)
JP (1) JPS5433515A (de)
DE (1) DE2860735D1 (de)
IE (1) IE47501B1 (de)
IT (1) IT1159745B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5515911A (en) * 1978-07-14 1980-02-04 Nippon Sheet Glass Co Ltd Glass plate cooling method
FR2525206B1 (fr) * 1982-04-16 1986-02-21 Saint Gobain Vitrage Procede pour la trempe differenciee de vitrages, notamment de pare-brise d'automobiles
US4946491A (en) * 1988-11-21 1990-08-07 Glasstech, Inc. Method and apparatus for glass tempering
JP2653708B2 (ja) * 1990-01-31 1997-09-17 セントラル硝子株式会社 強化ガラス板の製造方法
FI90046C (fi) * 1992-02-12 1993-12-27 Tamglass Eng Oy Munstycksarrangemang foer en haerdningsugn foer planglas
JPH09183626A (ja) * 1995-12-28 1997-07-15 Central Glass Co Ltd 薄板強化ガラス
US6180237B1 (en) * 1997-06-13 2001-01-30 Asahi Glass Company Ltd. Tempered glass
FR2768142B1 (fr) * 1997-09-11 1999-11-05 Saint Gobain Vitrage Dispositif de refroidissement de feuilles de verre bombees
FI104422B (fi) * 1998-06-30 2000-01-31 Tamglass Ltd Oy Menetelmä ja laite lasilevyjen karkaisemiseksi
JP2001026434A (ja) * 1999-07-13 2001-01-30 Nippon Sheet Glass Co Ltd ガラス急冷装置
FI126760B (fi) 2010-01-11 2017-05-15 Glaston Services Ltd Oy Menetelmä ja laite lasilevyjen kannattamiseksi ja kuumentamiseksi kuumalla kaasutyynyllä
FI20105257A (fi) * 2010-03-15 2011-09-16 Glaston Services Ltd Oy Laite lasilevyjen lämmittämiseksi karkaisua varten
EP2604582A1 (de) * 2011-12-17 2013-06-19 Cristales Automotrices de Jalisco, S.A. Verfahren und Vorrichtung zum dreidimensionalen Verformen von Platten, insbesondere Glasplatten
JP6702027B2 (ja) * 2015-07-24 2020-05-27 Agc株式会社 強化ガラス板
EP3246295B1 (de) * 2016-05-17 2021-07-07 Glaston Finland Oy Verfahren zur wärmebehandlung von glasscheiben

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1960222A (en) * 1930-10-22 1934-05-22 Saint Gobain Manufacture of tempered glass
US2042610A (en) * 1933-06-17 1936-06-02 Corning Glass Works Method and apparatus for tempering glass
US2078541A (en) * 1934-01-16 1937-04-27 Assurex Le Roi Des Verres De S Process for tempering glass
US2244715A (en) * 1934-12-22 1941-06-10 American Securit Co Tempered glass and process for manufacture of the same
FR803643A (fr) * 1935-06-21 1936-10-05 Saint Gobain Procédé et dispositifs pour la trempe du verre et autres matières
US3293015A (en) * 1961-09-22 1966-12-20 Pittsburgh Plate Glass Co Method and apparatus for tempering glass sheets on a gas support bed
NL293175A (de) * 1962-05-26
GB1095284A (en) * 1963-06-11 1967-12-13 Triplex Safety Glass Co Improvements in or relating to methods of and apparatus for toughening sheets of glass
GB1107265A (en) * 1963-10-02 1968-03-27 Triplex Safety Glass Co Improvements in or relating to apparatus for and methods of toughening glass articles
DE6604585U (de) * 1965-12-28 1970-01-29 Ford Werke Ag Getempertes sicherheitsglas
US3497340A (en) * 1968-07-29 1970-02-24 Ppg Industries Inc Method of tempering and reshaping glass sheets
US3873295A (en) * 1974-02-05 1975-03-25 Selas Corp Of America Quench apparatus for glass tempering
FR2316197A1 (fr) * 1975-07-02 1977-01-28 Saint Gobain Procede et dispositif pour le bombage et la trempe annexe eventuelle des feuilles de verre
GB1512163A (en) * 1976-03-05 1978-05-24 Triplex Safety Glass Co Toughened glass sheets

Also Published As

Publication number Publication date
EP0000268A1 (de) 1979-01-10
IE781228L (en) 1978-12-23
IE47501B1 (en) 1984-04-04
JPS5433515A (en) 1979-03-12
IT1159745B (it) 1987-03-04
DE2860735D1 (en) 1981-09-03
IT7868471A0 (it) 1978-06-22
US4178414A (en) 1979-12-11
JPS6138132B2 (de) 1986-08-27

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