ECSP12012133A - Proceso para la acetilación de elementos de madera - Google Patents

Proceso para la acetilación de elementos de madera

Info

Publication number
ECSP12012133A
ECSP12012133A ECSP12012133A ECSP12012133A EC SP12012133 A ECSP12012133 A EC SP12012133A EC SP12012133 A ECSP12012133 A EC SP12012133A EC SP12012133 A ECSP12012133 A EC SP12012133A
Authority
EC
Ecuador
Prior art keywords
wooden elements
acetilation
elements
acetylation
thawed
Prior art date
Application number
Other languages
English (en)
Spanish (es)
Inventor
Michel Maes
Beno Pol
Original Assignee
Titan Wood Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB1001750.7A external-priority patent/GB201001750D0/en
Priority claimed from GBGB1022090.3A external-priority patent/GB201022090D0/en
Application filed by Titan Wood Ltd filed Critical Titan Wood Ltd
Publication of ECSP12012133A publication Critical patent/ECSP12012133A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0466—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas
    • B05D3/0473—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas for heating, e.g. vapour heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27M—WORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M1/00—Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
    • B27M1/08—Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6492—Lignin containing materials; Wood resins; Wood tars; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00—Macromolecular compounds derived from lignocellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J165/00—Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
    • C09J165/02—Polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31975—Of cellulosic next to another carbohydrate
    • Y10T428/31978—Cellulosic next to another cellulosic
    • Y10T428/31986—Regenerated or modified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31989—Of wood
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/4935—Impregnated naturally solid product [e.g., leather, stone, etc.]
    • Y10T428/662—Wood timber product [e.g., piling, post, veneer, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Forests & Forestry (AREA)
  • Biochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
ECSP12012133 2010-02-04 2012-08-31 Proceso para la acetilación de elementos de madera ECSP12012133A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1001750.7A GB201001750D0 (en) 2010-02-04 2010-02-04 Composite and process thereof
GBGB1022090.3A GB201022090D0 (en) 2010-12-30 2010-12-30 Manufacturing process

Publications (1)

Publication Number Publication Date
ECSP12012133A true ECSP12012133A (es) 2012-12-28

Family

ID=43901358

Family Applications (1)

Application Number Title Priority Date Filing Date
ECSP12012133 ECSP12012133A (es) 2010-02-04 2012-08-31 Proceso para la acetilación de elementos de madera

Country Status (19)

Country Link
US (1) US8865318B2 (https=)
EP (1) EP2531561A1 (https=)
JP (2) JP2013518743A (https=)
KR (1) KR101921340B1 (https=)
CN (1) CN102822282B (https=)
AU (1) AU2011212184B2 (https=)
BR (1) BR112012019630B1 (https=)
CA (1) CA2788597C (https=)
CL (1) CL2012002179A1 (https=)
CO (1) CO6571904A2 (https=)
CR (1) CR20120441A (https=)
EC (1) ECSP12012133A (https=)
MX (1) MX336534B (https=)
NZ (1) NZ601675A (https=)
PE (1) PE20130617A1 (https=)
RU (1) RU2569536C2 (https=)
SG (1) SG183181A1 (https=)
UA (1) UA118832C2 (https=)
WO (1) WO2011095824A1 (https=)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2718351T3 (pl) 2011-06-10 2020-03-31 Titan Wood Limited Acetylacja włókna drzewnego
MX353017B (es) * 2011-09-28 2017-12-18 Titan Wood Ltd Paneles de fibras de densidad media.
EP2623281A1 (en) * 2012-01-31 2013-08-07 Titan Wood Limited Acetylated wood
CN104284905B (zh) * 2012-02-07 2017-06-09 泰坦木业有限公司 木材乙酰化的方法和乙酰化木材
BR112014029241B1 (pt) 2012-05-22 2021-01-05 Titan Wood Limited sistema de reator e processo para a acetilação de materiais lignocelulósicos e uso de um sistema de reator para conduzir um processo para a acetilação de materiais lignocelulósicos
US20140065340A1 (en) * 2012-08-29 2014-03-06 Eastman Chemical Company Moisturized acetylated wood and methods for making the same
GB2511120B (en) * 2013-02-26 2017-06-21 Medite Europe Ltd Acetylated wood fibre
GB2511121B (en) * 2013-02-26 2017-10-04 Medite Europe Ltd Process for manufacturing products from acetylated wood fibre
EP3004217A1 (en) * 2013-06-03 2016-04-13 Chemconserve B.V. Modified wood fibres for manufacture in composites
WO2015177242A1 (en) * 2014-05-21 2015-11-26 Titan Wood Limited Process for acetylation of wood in the presence of an acetylation catalyst
BR112017022023B1 (pt) * 2015-04-13 2022-07-05 Tricoya Technologies Ltd Método para a acetilação de madeira
US11338468B2 (en) 2015-04-13 2022-05-24 Tricoya Technologies Ltd. Method for continuous acetylation of wood elements
UY36621A (es) * 2015-04-13 2016-11-30 Tricoya Technologies Ltd Método para la acetilación continua de elementos de madera
ES2660426T3 (es) * 2015-11-18 2018-03-22 SWISS KRONO Tec AG Tablero de material derivado de la madera OSB (oriented strand board) con propiedades mejoradas y procedimiento para su producción
EP3178622B1 (de) * 2015-12-07 2018-07-04 SWISS KRONO Tec AG Verfahren zur herstellung einer holzwerkstoffplatte mit reduzierter emission an flüchtigen organischen verbindungen (vocs)
CN106042110B (zh) * 2016-06-01 2017-10-27 江苏科技大学 一种阻燃木板的生产工艺
MY201561A (en) 2016-06-23 2024-02-28 Tricoya Tech Ltd Cooling acetylated wood elements
DK201800137A1 (en) * 2018-03-28 2019-10-02 Danish Wood Technology A/S Treatment of wood
EP3774241B1 (en) 2018-04-13 2023-05-31 Tricoya Technologies Ltd Acetylated wood and method of making same
US12377574B2 (en) 2019-02-01 2025-08-05 Tricoya Technologies Ltd Boards from acetylated rubberwood
ES3040747T3 (en) 2019-05-22 2025-11-04 Basf Se Fibre mouldings
CN111251400B (zh) * 2020-01-16 2022-04-26 北京市飞宇商贸有限公司 一种红木家具的制作方法
WO2021216803A1 (en) * 2020-04-22 2021-10-28 University Of Maryland, College Park Moldable and molded cellulose-based structural materials, and systems and methods for forming and use thereof
US20230271912A1 (en) 2020-07-28 2023-08-31 Titan Wood Limited Purification of wood acetylation fluid
US20220371219A1 (en) * 2021-05-20 2022-11-24 Washington State University Thermally modified composite wood-strand products for construction and other applications
WO2024100210A1 (en) 2022-11-09 2024-05-16 Tricoya Technologies Ltd Purification of acetic acid by heteroazeotropic distillation with water
WO2024200869A1 (en) 2023-03-31 2024-10-03 Titan Wood Limited Production of acetic acid anhydride
WO2025026976A1 (en) 2023-07-28 2025-02-06 Titan Wood Limited Acetic acid corrosivity reduction
AU2024317084A1 (en) 2023-07-28 2026-02-19 Titan Wood Limited Acetylated wood colouring process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388378A (en) * 1980-12-05 1983-06-14 United States Gypsum Company Thermoplastic hardboard from acetylated mat
GB9403509D0 (en) * 1994-02-24 1994-04-13 Bp Chem Int Ltd Acetylation of lignocellulosic materials
JP3090067B2 (ja) * 1996-10-30 2000-09-18 ヤマハ株式会社 木質パネル及びその製造方法
JP2001096511A (ja) * 1999-09-30 2001-04-10 Yamaha Corp 木質エレメントの改質方法
CN103481342B (zh) * 2008-02-01 2018-09-07 泰坦木业有限公司 乙酰化的木材

Also Published As

Publication number Publication date
CA2788597A1 (en) 2011-08-11
WO2011095824A1 (en) 2011-08-11
CR20120441A (es) 2013-01-24
EP2531561A1 (en) 2012-12-12
MX336534B (es) 2016-01-21
UA118832C2 (uk) 2019-03-25
CA2788597C (en) 2018-09-18
US20130209822A1 (en) 2013-08-15
RU2569536C2 (ru) 2015-11-27
CN102822282A (zh) 2012-12-12
BR112012019630A2 (pt) 2016-05-03
US8865318B2 (en) 2014-10-21
MX2012009021A (es) 2012-11-29
BR112012019630B1 (pt) 2020-10-20
RU2012137514A (ru) 2014-03-10
AU2011212184B2 (en) 2014-12-04
KR101921340B1 (ko) 2018-11-22
KR20130009759A (ko) 2013-01-23
CO6571904A2 (es) 2012-11-30
JP2013518743A (ja) 2013-05-23
JP2016027958A (ja) 2016-02-25
PE20130617A1 (es) 2013-06-23
SG183181A1 (en) 2012-09-27
JP6262180B2 (ja) 2018-01-17
AU2011212184A1 (en) 2012-08-30
NZ601675A (en) 2014-02-28
CN102822282B (zh) 2016-03-02
CL2012002179A1 (es) 2013-01-11

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