EA201992624A1 - Способ парового риформинга оксигенатов и катализаторы для использования в указанном способе - Google Patents

Способ парового риформинга оксигенатов и катализаторы для использования в указанном способе

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Publication number
EA201992624A1
EA201992624A1 EA201992624A EA201992624A EA201992624A1 EA 201992624 A1 EA201992624 A1 EA 201992624A1 EA 201992624 A EA201992624 A EA 201992624A EA 201992624 A EA201992624 A EA 201992624A EA 201992624 A1 EA201992624 A1 EA 201992624A1
Authority
EA
Eurasian Patent Office
Prior art keywords
oxygenates
steam reforming
catalysts
converted
carbide
Prior art date
Application number
EA201992624A
Other languages
English (en)
Inventor
Поль Эрик Хойлунд Нильсен
Браен Кьергаард Ользен
Ливед Ё. Лемус-Егрес
Original Assignee
Хальдор Топсёэ А/С
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Хальдор Топсёэ А/С filed Critical Хальдор Топсёэ А/С
Publication of EA201992624A1 publication Critical patent/EA201992624A1/ru

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/22Carbides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/061Methanol production
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/068Ammonia synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • C01B2203/1058Nickel catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217Alcohols
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217Alcohols
    • C01B2203/1229Ethanol
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

В способе парового риформинга оксигенатов, в частности риформинга при низких соотношениях пар/углерод (П/У), осуществляют конверсию исходного газа, содержащего оксигенаты, такие как этанол, в синтез-газ над катализатором на основе тройного карбида. Затем газа, прошедший риформинг, либо преобразуют в целевые химические вещества, либо смешивают с исходным потоком, поступающим в риформер в установке, например в установке для производства аммиака или метанола. Предпочтительным тройным карбидом является никель-цинковый карбид.
EA201992624A 2017-05-10 2018-05-03 Способ парового риформинга оксигенатов и катализаторы для использования в указанном способе EA201992624A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201700294 2017-05-10
PCT/EP2018/061269 WO2018206376A1 (en) 2017-05-10 2018-05-03 Process for steam reforming of oxygenates and catalysts for use in the process

Publications (1)

Publication Number Publication Date
EA201992624A1 true EA201992624A1 (ru) 2020-04-20

Family

ID=62152528

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201992624A EA201992624A1 (ru) 2017-05-10 2018-05-03 Способ парового риформинга оксигенатов и катализаторы для использования в указанном способе

Country Status (5)

Country Link
US (2) US11505461B2 (ru)
EP (1) EP3621918A1 (ru)
CN (1) CN110636988A (ru)
EA (1) EA201992624A1 (ru)
WO (1) WO2018206376A1 (ru)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11505461B2 (en) 2017-05-10 2022-11-22 Haldor Topsøe A/S Process for steam reforming of oxygenates and catalysts for use in the process
CN114939426B (zh) * 2022-05-09 2024-02-13 烟台大学 一种双金属碳化物M3ZnCx粉体材料及制备方法及应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7335346B2 (en) 1999-08-17 2008-02-26 Battelle Memorial Institute Catalyst and method of steam reforming
US6461539B1 (en) 1999-10-18 2002-10-08 Conoco Inc. Metal carbide catalysts and process for producing synthesis gas
US7323497B2 (en) 2003-05-02 2008-01-29 Johnson Matthey Plc Production of hydrocarbons by steam reforming and Fischer-Tropsch reaction
AU2012308049A1 (en) 2011-05-06 2013-11-28 Trojan Technologies Anti-fouling surface. And radiation source assembly and fluid treatment system comprising same
WO2012154042A1 (en) 2011-05-10 2012-11-15 Biomethanol Chemie Nederland B.V. A process for catalytic steam reforming of a feedstock comprising an oxygenated hydrocarbon and a hydrocarbon
US9302250B2 (en) 2012-11-15 2016-04-05 Phillips 66 Company Catalysts for renewable hydrogen production from oxygenated feedstocks
EP2964569A4 (en) 2012-11-15 2017-01-04 Phillips 66 Company Process scheme for catalytic production of renewable hydrogen from oxygenate feedstocks
EP3209607B1 (en) 2014-10-20 2020-01-15 Haldor Topsøe A/S Process for the catalytic preparation of hydrogen cyanide from methane and ammonia
US11505461B2 (en) 2017-05-10 2022-11-22 Haldor Topsøe A/S Process for steam reforming of oxygenates and catalysts for use in the process

Also Published As

Publication number Publication date
WO2018206376A1 (en) 2018-11-15
US11999617B2 (en) 2024-06-04
CN110636988A (zh) 2019-12-31
BR112019022764A2 (pt) 2020-05-19
US20200239305A1 (en) 2020-07-30
EP3621918A1 (en) 2020-03-18
US20230047360A1 (en) 2023-02-16
US11505461B2 (en) 2022-11-22

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