EA201491166A1 - Способ и система для десульфуризации жидкого топлива для применения топливного элемента - Google Patents

Способ и система для десульфуризации жидкого топлива для применения топливного элемента

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Publication number
EA201491166A1
EA201491166A1 EA201491166A EA201491166A EA201491166A1 EA 201491166 A1 EA201491166 A1 EA 201491166A1 EA 201491166 A EA201491166 A EA 201491166A EA 201491166 A EA201491166 A EA 201491166A EA 201491166 A1 EA201491166 A1 EA 201491166A1
Authority
EA
Eurasian Patent Office
Prior art keywords
fuel
liquid
unit
hydrogen
desulphurization
Prior art date
Application number
EA201491166A
Other languages
English (en)
Inventor
Хассан Модарреси
Томас Роструп-Нильсен
Original Assignee
Топсёэ Фуль Селл А/С
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Топсёэ Фуль Селл А/С filed Critical Топсёэ Фуль Селл А/С
Publication of EA201491166A1 publication Critical patent/EA201491166A1/ru

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0675—Removal of sulfur
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C01B2203/127—Catalytic desulfurisation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Способ десульфуризации жидкого ископаемого топлива для применения в топливных элементах, который осуществляют с использованием системы, содержащей испарительную установку (1), в которой жидкое топливо сначала испаряют, реактор (2) с неподвижным слоем в виде газофазной установки гидродесульфуризации, в котором топливо подвергают обработке водородом при атмосферном давлении в присутствии высокоактивного катализатора гидрокрекинга (ВАКГ), при этом происходит преобразование соединений серы в HS, поглотитель (3), в котором полученный сульфид водорода может адсорбироваться в каталитическом слое, и установку (4) риформинга топлива, в которой происходит преобразование топливного продукта в синтез-газ, который подают в систему (6) ТОТЭ. Испарительная установка (1) содержит устройство для разбрызгивания жидкости, предпочтительно в виде пьезоэлектрической распылительной форсунки.
EA201491166A 2011-12-15 2012-11-21 Способ и система для десульфуризации жидкого топлива для применения топливного элемента EA201491166A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201100974 2011-12-15
PCT/EP2012/073171 WO2013087378A2 (en) 2011-12-15 2012-11-21 Method and system for liquid fuel desulphurization for fuel cell application

Publications (1)

Publication Number Publication Date
EA201491166A1 true EA201491166A1 (ru) 2014-12-30

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ID=47278784

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201491166A EA201491166A1 (ru) 2011-12-15 2012-11-21 Способ и система для десульфуризации жидкого топлива для применения топливного элемента

Country Status (10)

Country Link
US (1) US20140363749A1 (ru)
EP (1) EP2791050A2 (ru)
JP (1) JP2015507319A (ru)
KR (1) KR20140104476A (ru)
CN (1) CN104039690A (ru)
AU (1) AU2012350999B2 (ru)
CA (1) CA2859186A1 (ru)
EA (1) EA201491166A1 (ru)
IN (1) IN2014CN04289A (ru)
WO (1) WO2013087378A2 (ru)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013226327A1 (de) * 2013-12-17 2015-06-18 Thyssenkrupp Marine Systems Gmbh Gaskreislauf für ein Festoxidbrennstoffzellen-System und Festoxidbrennstoffzellen-System
CN108643882B (zh) * 2018-05-04 2023-03-28 西安凯尔文石化助剂制造有限公司 一种原油中的h2s的消除方法

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GB263381A (en) * 1926-04-27 1926-12-30 Charles Delamare Maze Process and apparatus for the purification and hydrogenation of liquid hydrocarbons
US3476535A (en) * 1967-09-26 1969-11-04 United Aircraft Corp Hydrogen generator including desulfurization with diffused hydrogen feedback
IN189391B (ru) * 1995-12-27 2003-02-15 Amalesh Sarkar
JP4313464B2 (ja) * 1999-04-30 2009-08-12 本田技研工業株式会社 燃料改質装置
US6967063B2 (en) * 2001-05-18 2005-11-22 The University Of Chicago Autothermal hydrodesulfurizing reforming method and catalyst
AUPS014702A0 (en) 2002-01-25 2002-02-14 Ceramic Fuel Cells Limited Desulfurisation of fuel
US7318845B2 (en) 2002-07-10 2008-01-15 Applied Research Associates, Inc. Compact distillates fuel processor with effective sulfur removal process
WO2004057176A1 (de) * 2002-12-20 2004-07-08 Volkswagen Mechatronic Gmbh & Co. Kg Pumpe-düse-einheit
US20040159584A1 (en) * 2003-02-18 2004-08-19 Ke Liu Mini-CPO providing hydrogen for hydrogen desulfurization of hydrocarbon feeds
US7422810B2 (en) * 2004-01-22 2008-09-09 Bloom Energy Corporation High temperature fuel cell system and method of operating same
ATE478445T1 (de) * 2005-09-27 2010-09-15 Haldor Topsoe As Verfahren zur erzeugung von elektrizität mittels eines festelektrolytstapels und ethanol
KR100853393B1 (ko) * 2006-03-10 2008-08-21 한국과학기술원 분무장치를 포함하는 연료 개질기, 연료 개질기용 분무기및 연료 개질 방법
US20090212127A1 (en) * 2007-12-14 2009-08-27 Weidlinger Associates, Inc. Fuel injector with single crystal piezoelectric actuator stack
KR101077929B1 (ko) * 2008-10-27 2011-10-31 한국과학기술원 고체산화물 연료전지 시스템의 연료 개질 방법
US8211375B2 (en) * 2009-10-07 2012-07-03 Chevron U.S.A. Inc. Flow distribution device for downflow catalytic reactors
KR102080819B1 (ko) * 2011-11-21 2020-02-24 사우디 아라비안 오일 컴퍼니 석유 연료를 사용한 화합된 수소 및 전기 생산 방법 및 그 시스템

Also Published As

Publication number Publication date
AU2012350999A1 (en) 2014-07-03
CA2859186A1 (en) 2013-06-20
JP2015507319A (ja) 2015-03-05
AU2012350999B2 (en) 2016-04-14
KR20140104476A (ko) 2014-08-28
CN104039690A (zh) 2014-09-10
WO2013087378A2 (en) 2013-06-20
WO2013087378A3 (en) 2013-08-08
US20140363749A1 (en) 2014-12-11
IN2014CN04289A (ru) 2015-09-04
EP2791050A2 (en) 2014-10-22

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