IN2014CN04289A - - Google Patents

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Publication number
IN2014CN04289A
IN2014CN04289A IN4289CHN2014A IN2014CN04289A IN 2014CN04289 A IN2014CN04289 A IN 2014CN04289A IN 4289CHN2014 A IN4289CHN2014 A IN 4289CHN2014A IN 2014CN04289 A IN2014CN04289 A IN 2014CN04289A
Authority
IN
India
Prior art keywords
fuel
liquid
converted
evaporator unit
hydro
Prior art date
Application number
Inventor
Hassan Modarresi
Nielsen Thomas Rostrup
Original Assignee
Topsøe Fuel Cell As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Topsøe Fuel Cell As filed Critical Topsøe Fuel Cell As
Publication of IN2014CN04289A publication Critical patent/IN2014CN04289A/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0675Removal of sulfur
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631Reactor construction specially adapted for combination reactor/fuel cell
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1247Higher hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258Pre-treatment of the feed
    • C01B2203/1264Catalytic pre-treatment of the feed
    • C01B2203/127Catalytic desulfurisation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

A method for desulphurization of a liquid fossil fuel to be used in connection with a fuel cell is performed in a system comprising an evaporator unit (1) wherein the liquid fuel is first evaporated a fixed bed reactor (2) in the form of a gas phase hydro desulphurizer where the fuel is treated with hydrogen at atmospheric pressure over a highly active hydro cracking (HAHT) catalyst whereby sulphur species are converted to H2S an adsorber (3) where the produced hydrogen sulphide can be adsorbed on a catalytic bed and a fuel reformer (4) in which the fuel product is converted to syngas to be fed to an SOFC system (6). The evaporator unit (1) comprises a liquid spraying device preferably in the form of a piezoelectric spray nozzle.
IN4289CHN2014 2011-12-15 2012-11-21 IN2014CN04289A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201100974 2011-12-15
PCT/EP2012/073171 WO2013087378A2 (en) 2011-12-15 2012-11-21 Method and system for liquid fuel desulphurization for fuel cell application

Publications (1)

Publication Number Publication Date
IN2014CN04289A true IN2014CN04289A (en) 2015-09-04

Family

ID=47278784

Family Applications (1)

Application Number Title Priority Date Filing Date
IN4289CHN2014 IN2014CN04289A (en) 2011-12-15 2012-11-21

Country Status (10)

Country Link
US (1) US20140363749A1 (en)
EP (1) EP2791050A2 (en)
JP (1) JP2015507319A (en)
KR (1) KR20140104476A (en)
CN (1) CN104039690A (en)
AU (1) AU2012350999B2 (en)
CA (1) CA2859186A1 (en)
EA (1) EA201491166A1 (en)
IN (1) IN2014CN04289A (en)
WO (1) WO2013087378A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013226327A1 (en) * 2013-12-17 2015-06-18 Thyssenkrupp Marine Systems Gmbh Gas cycle for a solid oxide fuel cell system and solid oxide fuel cell system
CN108643882B (en) * 2018-05-04 2023-03-28 西安凯尔文石化助剂制造有限公司 H in crude oil 2 Method for eliminating S

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB263381A (en) * 1926-04-27 1926-12-30 Charles Delamare Maze Process and apparatus for the purification and hydrogenation of liquid hydrocarbons
US3476535A (en) * 1967-09-26 1969-11-04 United Aircraft Corp Hydrogen generator including desulfurization with diffused hydrogen feedback
IN189391B (en) * 1995-12-27 2003-02-15 Amalesh Sarkar
JP4313464B2 (en) * 1999-04-30 2009-08-12 本田技研工業株式会社 Fuel reformer
US6967063B2 (en) * 2001-05-18 2005-11-22 The University Of Chicago Autothermal hydrodesulfurizing reforming method and catalyst
AUPS014702A0 (en) * 2002-01-25 2002-02-14 Ceramic Fuel Cells Limited Desulfurisation of fuel
US7318845B2 (en) 2002-07-10 2008-01-15 Applied Research Associates, Inc. Compact distillates fuel processor with effective sulfur removal process
WO2004057176A1 (en) * 2002-12-20 2004-07-08 Volkswagen Mechatronic Gmbh & Co. Kg Pump-nozzle unit
US20040159584A1 (en) * 2003-02-18 2004-08-19 Ke Liu Mini-CPO providing hydrogen for hydrogen desulfurization of hydrocarbon feeds
US7422810B2 (en) * 2004-01-22 2008-09-09 Bloom Energy Corporation High temperature fuel cell system and method of operating same
DK1768207T3 (en) * 2005-09-27 2010-12-13 Haldor Topsoe As Process for the production of liquid fuel containing ethanol and for generating electricity
KR100853393B1 (en) * 2006-03-10 2008-08-21 한국과학기술원 Fuel reformer comprising sprayind device, sprayer used in the fuel reformer and fuel reforming method
US20090212127A1 (en) * 2007-12-14 2009-08-27 Weidlinger Associates, Inc. Fuel injector with single crystal piezoelectric actuator stack
KR101077929B1 (en) 2008-10-27 2011-10-31 한국과학기술원 Fuel Processing Method for Solid Oxide Fuel Cell System
US8211375B2 (en) * 2009-10-07 2012-07-03 Chevron U.S.A. Inc. Flow distribution device for downflow catalytic reactors
EP2783413B1 (en) * 2011-11-21 2018-10-17 Saudi Arabian Oil Company Method and a system for combined hydrogen and electricity production using petroleum fuels

Also Published As

Publication number Publication date
WO2013087378A3 (en) 2013-08-08
EA201491166A1 (en) 2014-12-30
CA2859186A1 (en) 2013-06-20
EP2791050A2 (en) 2014-10-22
AU2012350999A1 (en) 2014-07-03
CN104039690A (en) 2014-09-10
KR20140104476A (en) 2014-08-28
US20140363749A1 (en) 2014-12-11
WO2013087378A2 (en) 2013-06-20
AU2012350999B2 (en) 2016-04-14
JP2015507319A (en) 2015-03-05

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