EA200901177A1 - Способ очистки углеводородов от меркаптанов - Google Patents
Способ очистки углеводородов от меркаптановInfo
- Publication number
- EA200901177A1 EA200901177A1 EA200901177A EA200901177A EA200901177A1 EA 200901177 A1 EA200901177 A1 EA 200901177A1 EA 200901177 A EA200901177 A EA 200901177A EA 200901177 A EA200901177 A EA 200901177A EA 200901177 A1 EA200901177 A1 EA 200901177A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- mercaptans
- hydrocarbons
- mercaptan
- quaternary ammonium
- metal
- Prior art date
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000004140 cleaning Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/06—Metal salts, or metal salts deposited on a carrier
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1033—Oil well production fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
Abstract
Предлагается способ очистки углеводородов, газообразных смесей углеводородов и т.п. от сероводорода и меркаптанов, который заключается в добавлении в указанные среды состава очистителя от меркаптана, содержащего алкоксид или гидроксид четвертичного аммония в присутствии металла в высокой степени окисления, такого как кобальт, железо, хром и/или никель. Металл в высокой степени окисления является окислителем и его можно использовать в качестве катализатора в присутствии этоксида или гидроксида четвертичного аммония, при этом повышается эффективность очистки среды от меркаптана.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89562507P | 2007-03-19 | 2007-03-19 | |
| US12/042,536 US20080230445A1 (en) | 2007-03-19 | 2008-03-05 | Method of scavenging mercaptans from hydrocarbons |
| PCT/US2008/056006 WO2008115704A1 (en) | 2007-03-19 | 2008-03-06 | Method of scavenging mercaptans from hydrocarbons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200901177A1 true EA200901177A1 (ru) | 2010-04-30 |
| EA016758B1 EA016758B1 (ru) | 2012-07-30 |
Family
ID=39766340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200901177A EA016758B1 (ru) | 2007-03-19 | 2008-03-06 | Способ очистки углеводородов от меркаптанов |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20080230445A1 (ru) |
| EP (2) | EP2759587B1 (ru) |
| EA (1) | EA016758B1 (ru) |
| WO (1) | WO2008115704A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7918905B2 (en) * | 2007-05-17 | 2011-04-05 | Baker Hughes Incorporated | Method for improving biodiesel fuel |
| GB2547364B8 (en) * | 2010-10-05 | 2017-11-29 | The Queen's Univ Of Belfast | Process for removing metals from hydrocarbons |
| US9296956B2 (en) | 2010-10-28 | 2016-03-29 | Chevron U.S.A. Inc. | Method for reducing mercaptans in hydrocarbons |
| US20140084206A1 (en) * | 2012-09-27 | 2014-03-27 | Baker Hughes Incorporated | Treating Additives for the Deactivation of Sulfur Species Within a Stream |
| CN103768913B (zh) * | 2012-10-22 | 2016-04-27 | 中国石油化工股份有限公司 | 一种脱除气体中硫化氢和硫醇的方法 |
| RU2532019C1 (ru) * | 2013-07-30 | 2014-10-27 | Ахматфаиль Магсумович Фахриев | Реагент для нейтрализации сероводорода и подавления роста сульфатвосстанавливающих бактерий |
| CN112312994A (zh) | 2018-04-18 | 2021-02-02 | 克莱恩有限公司 | 用于从离子液体中分离重金属和/或硫种类的方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928211A (en) * | 1970-10-21 | 1975-12-23 | Milchem Inc | Process for scavenging hydrogen sulfide in aqueous drilling fluids and method of preventing metallic corrosion of subterranean well drilling apparatuses |
| US4033860A (en) * | 1975-09-10 | 1977-07-05 | Uop Inc. | Mercaptan conversion process |
| US4124531A (en) * | 1977-01-03 | 1978-11-07 | Uop Inc. | Catalytic composite for the treatment of sour petroleum distillates |
| US4778617A (en) * | 1984-11-27 | 1988-10-18 | The Drackett Company | Acid cleaner composition |
| US4594147A (en) | 1985-12-16 | 1986-06-10 | Nalco Chemical Company | Choline as a fuel sweetener and sulfur antagonist |
| US4867865A (en) | 1988-07-11 | 1989-09-19 | Pony Industries, Inc. | Controlling H2 S in fuel oils |
| US4923596A (en) * | 1989-05-22 | 1990-05-08 | Uop | Use of quaternary ammonium compounds in a liquid/liquid process for sweetening a sour hydrocarbon fraction |
| US4929340A (en) * | 1989-07-31 | 1990-05-29 | Uop | Catalyst and process for sweetening a sour hydrocarbon fraction using dipolar compounds |
| US5183560A (en) | 1991-09-09 | 1993-02-02 | Baker Hughes Incorporated | Treatment of oils using choline base |
| US5430160A (en) * | 1991-09-23 | 1995-07-04 | Florida State University | Preparation of substituted isoserine esters using β-lactams and metal or ammonium alkoxides |
| AU2714192A (en) * | 1991-10-21 | 1993-04-22 | Baker Hughes Incorporated | Treatment of oils using epoxylated tertiary amines |
| US5232887A (en) * | 1992-04-02 | 1993-08-03 | Uop | Catalyst for sweetening a sour hydrocarbon fraction |
| US5413704A (en) * | 1993-11-15 | 1995-05-09 | Uop | Process for sweetening a sour hydrocarbon fraction using a mixture of a supported metal chelate and a solid base |
| CA2133270C (en) * | 1994-03-03 | 1999-07-20 | Jerry J. Weers | Quaternary ammonium hydroxides as mercaptan scavengers |
| US5744024A (en) * | 1995-10-12 | 1998-04-28 | Nalco/Exxon Energy Chemicals, L.P. | Method of treating sour gas and liquid hydrocarbon |
-
2008
- 2008-03-05 US US12/042,536 patent/US20080230445A1/en not_active Abandoned
- 2008-03-06 EP EP14164453.4A patent/EP2759587B1/en active Active
- 2008-03-06 EA EA200901177A patent/EA016758B1/ru not_active IP Right Cessation
- 2008-03-06 EP EP08731506.5A patent/EP2134814A4/en not_active Withdrawn
- 2008-03-06 WO PCT/US2008/056006 patent/WO2008115704A1/en active Search and Examination
Also Published As
| Publication number | Publication date |
|---|---|
| EP2759587B1 (en) | 2020-02-12 |
| US20080230445A1 (en) | 2008-09-25 |
| WO2008115704A1 (en) | 2008-09-25 |
| EP2134814A4 (en) | 2013-04-24 |
| EP2134814A1 (en) | 2009-12-23 |
| EP2759587A1 (en) | 2014-07-30 |
| EA016758B1 (ru) | 2012-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EA200901177A1 (ru) | Способ очистки углеводородов от меркаптанов | |
| Yentekakis et al. | Biogas management: advanced utilization for production of renewable energy and added-value chemicals | |
| EA201391134A1 (ru) | Способ очистки газа | |
| NO20083522L (no) | Fremgangsmate for rensing av gassblandinger inneholdende merkaptaner og andre sure gasser | |
| US8623308B2 (en) | Process for removing mercaptans from a gas stream comprising natural gas on an inert gas | |
| NZ598538A (en) | Desulphurisation process | |
| DK1542944T3 (da) | Katalytisk fremgangsmåde til fremstilling af alkylmermercaptaner ved tilsætning af hydrogensulfid til en olefin | |
| WO2010012883A3 (fr) | Solution absorbante a base de n, n, n',n' -tetramethylhexane-1, 6-diamine et d'une amine comportant des fonctions amine primaire ou secondaire et procede d 'elimination de composes acides d 'un effluent gazeux | |
| EA201171402A1 (ru) | Абсорбент для избирательного удаления сероводорода из потоков текучей среды | |
| UA91821C2 (ru) | способ очистки газов, полученных из установки газификации | |
| EA201290015A1 (ru) | Композиция для очистки углекислых газов | |
| MY144111A (en) | Removal of mercury from fluids by supported metal oxides | |
| EA201300285A1 (ru) | Композиция абсорбента для удаления загрязняющих веществ, в основном соединений серы, содержащихся в жидких и газообразных потоках, способ получения разработанной композиции абсорбента, способ удаления примесей, в основном соединений серы, включая сероводород, содержащихся в жидких или газообразных потоках, и применение композиции абсорбента | |
| EA201290005A1 (ru) | Промывочная композиция для очистки от кислотных газов | |
| WO2008008639A3 (en) | Reforming sulfur-containing hydrocarbons using a sulfur resistant catalyst | |
| JP2010047469A (ja) | ガス流からの不純物減少のための方法及びシステム | |
| MY149964A (en) | Catalyst for producing hydrocarbon from synthetic gas, method for producing catalyst, method for regenerating catalyst, and method for producing hydrocarbon from synthetic gas | |
| Li et al. | Rotten eggs revaluated: Ionic liquids and deep eutectic solvents for removal and utilization of hydrogen sulfide | |
| Zhang et al. | Mechanism of elemental mercury oxidation over copper-based oxide catalysts: Kinetics and transient reaction studies | |
| CA3043787A1 (en) | A process for the removal of hydrogen chloride and sulfur oxides from a gas stream by absorption | |
| EA202193305A1 (ru) | Катализатор для каталитического окислительного крекинга сероводорода с одновременным получением водорода | |
| MY176953A (en) | Method for purifying gas mixtures containing mercaptans and other acid gases | |
| MX2010004860A (es) | Proceso y reactivo para eliminacion de oxigeno de corrientes de hidrocarburo. | |
| EA200700093A1 (ru) | Способ комплексного использования составляющих оливина | |
| MX2012003737A (es) | Proceso para la remocion de azufre de gases despedidos de refineria. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
|
| QB4A | Registration of a licence in a contracting state |