EP2134814A4 - Method of scavenging mercaptans from hydrocarbons - Google Patents

Method of scavenging mercaptans from hydrocarbons

Info

Publication number
EP2134814A4
EP2134814A4 EP08731506.5A EP08731506A EP2134814A4 EP 2134814 A4 EP2134814 A4 EP 2134814A4 EP 08731506 A EP08731506 A EP 08731506A EP 2134814 A4 EP2134814 A4 EP 2134814A4
Authority
EP
European Patent Office
Prior art keywords
hydrocarbons
mercaptans
scavenging
scavenging mercaptans
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08731506.5A
Other languages
German (de)
French (fr)
Other versions
EP2134814A1 (en
Inventor
Timothy J O'brien
Jerry J Weers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baker Hughes Holdings LLC
Original Assignee
Baker Hughes Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baker Hughes Inc filed Critical Baker Hughes Inc
Priority to EP14164453.4A priority Critical patent/EP2759587B1/en
Publication of EP2134814A1 publication Critical patent/EP2134814A1/en
Publication of EP2134814A4 publication Critical patent/EP2134814A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1033—Oil well production fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
EP08731506.5A 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons Withdrawn EP2134814A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP14164453.4A EP2759587B1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US89562507P 2007-03-19 2007-03-19
US12/042,536 US20080230445A1 (en) 2007-03-19 2008-03-05 Method of scavenging mercaptans from hydrocarbons
PCT/US2008/056006 WO2008115704A1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP14164453.4A Division EP2759587B1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Publications (2)

Publication Number Publication Date
EP2134814A1 EP2134814A1 (en) 2009-12-23
EP2134814A4 true EP2134814A4 (en) 2013-04-24

Family

ID=39766340

Family Applications (2)

Application Number Title Priority Date Filing Date
EP14164453.4A Active EP2759587B1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons
EP08731506.5A Withdrawn EP2134814A4 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP14164453.4A Active EP2759587B1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Country Status (4)

Country Link
US (1) US20080230445A1 (en)
EP (2) EP2759587B1 (en)
EA (1) EA016758B1 (en)
WO (1) WO2008115704A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7918905B2 (en) * 2007-05-17 2011-04-05 Baker Hughes Incorporated Method for improving biodiesel fuel
GB2547364B8 (en) * 2010-10-05 2017-11-29 The Queen's Univ Of Belfast Process for removing metals from hydrocarbons
US9296956B2 (en) 2010-10-28 2016-03-29 Chevron U.S.A. Inc. Method for reducing mercaptans in hydrocarbons
US20140084206A1 (en) * 2012-09-27 2014-03-27 Baker Hughes Incorporated Treating Additives for the Deactivation of Sulfur Species Within a Stream
CN103768913B (en) * 2012-10-22 2016-04-27 中国石油化工股份有限公司 A kind of method removing hydrogen sulfide and mercaptan in gas
RU2532019C1 (en) * 2013-07-30 2014-10-27 Ахматфаиль Магсумович Фахриев Agent for neutralising hydrogen sulphide and inhibiting growth of sulphate-reducing bacteria
WO2019202598A2 (en) 2018-04-18 2019-10-24 Clairion Ltd. A process for separation of heavy metals and/or sulfur species from ionic liquids

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4127474A (en) * 1977-01-03 1978-11-28 Uop Inc. Treating a petroleum distillate with an alkanolamine hydroxide and a supported oxidation catalyst impregnated with polynuclear aromatic sulfonic acid
US4923596A (en) * 1989-05-22 1990-05-08 Uop Use of quaternary ammonium compounds in a liquid/liquid process for sweetening a sour hydrocarbon fraction
US5232887A (en) * 1992-04-02 1993-08-03 Uop Catalyst for sweetening a sour hydrocarbon fraction
US5413704A (en) * 1993-11-15 1995-05-09 Uop Process for sweetening a sour hydrocarbon fraction using a mixture of a supported metal chelate and a solid base
US5840177A (en) * 1994-03-03 1998-11-24 Baker Hughes Incorporated Quaternary ammonium hydroxides as mercaptan scavengers

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928211A (en) * 1970-10-21 1975-12-23 Milchem Inc Process for scavenging hydrogen sulfide in aqueous drilling fluids and method of preventing metallic corrosion of subterranean well drilling apparatuses
US4033860A (en) * 1975-09-10 1977-07-05 Uop Inc. Mercaptan conversion process
US4778617A (en) * 1984-11-27 1988-10-18 The Drackett Company Acid cleaner composition
US4594147A (en) 1985-12-16 1986-06-10 Nalco Chemical Company Choline as a fuel sweetener and sulfur antagonist
US4867865A (en) 1988-07-11 1989-09-19 Pony Industries, Inc. Controlling H2 S in fuel oils
US4929340A (en) * 1989-07-31 1990-05-29 Uop Catalyst and process for sweetening a sour hydrocarbon fraction using dipolar compounds
US5183560A (en) 1991-09-09 1993-02-02 Baker Hughes Incorporated Treatment of oils using choline base
US5430160A (en) * 1991-09-23 1995-07-04 Florida State University Preparation of substituted isoserine esters using β-lactams and metal or ammonium alkoxides
AU2714192A (en) 1991-10-21 1993-04-22 Baker Hughes Incorporated Treatment of oils using epoxylated tertiary amines
US5744024A (en) * 1995-10-12 1998-04-28 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4127474A (en) * 1977-01-03 1978-11-28 Uop Inc. Treating a petroleum distillate with an alkanolamine hydroxide and a supported oxidation catalyst impregnated with polynuclear aromatic sulfonic acid
US4923596A (en) * 1989-05-22 1990-05-08 Uop Use of quaternary ammonium compounds in a liquid/liquid process for sweetening a sour hydrocarbon fraction
US5232887A (en) * 1992-04-02 1993-08-03 Uop Catalyst for sweetening a sour hydrocarbon fraction
US5413704A (en) * 1993-11-15 1995-05-09 Uop Process for sweetening a sour hydrocarbon fraction using a mixture of a supported metal chelate and a solid base
US5840177A (en) * 1994-03-03 1998-11-24 Baker Hughes Incorporated Quaternary ammonium hydroxides as mercaptan scavengers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BASU B ET AL: "MEROX AND RELATED METAL PHTHALOCYANINE CATALYZED OXIDATION PROCESSES", CATALYSIS REVIEWS: SCIENCE AND ENGINEERING, MARCEL DEKKER INC. NEW YORK, US, vol. 35, no. 4, 1 December 1993 (1993-12-01), pages 571 - 609, XP000408832, ISSN: 0161-4940 *
See also references of WO2008115704A1 *

Also Published As

Publication number Publication date
EP2759587A1 (en) 2014-07-30
EP2134814A1 (en) 2009-12-23
EP2759587B1 (en) 2020-02-12
WO2008115704A1 (en) 2008-09-25
US20080230445A1 (en) 2008-09-25
EA200901177A1 (en) 2010-04-30
EA016758B1 (en) 2012-07-30

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