EA200901177A1 - METHOD FOR CLEANING HYDROCARBONS FROM MERCAPTANS - Google Patents

METHOD FOR CLEANING HYDROCARBONS FROM MERCAPTANS

Info

Publication number
EA200901177A1
EA200901177A1 EA200901177A EA200901177A EA200901177A1 EA 200901177 A1 EA200901177 A1 EA 200901177A1 EA 200901177 A EA200901177 A EA 200901177A EA 200901177 A EA200901177 A EA 200901177A EA 200901177 A1 EA200901177 A1 EA 200901177A1
Authority
EA
Eurasian Patent Office
Prior art keywords
mercaptans
hydrocarbons
mercaptan
quaternary ammonium
metal
Prior art date
Application number
EA200901177A
Other languages
Russian (ru)
Other versions
EA016758B1 (en
Inventor
Тимоти Дж. О`брайен
Джерри Дж. Уирс
Original Assignee
Бейкер Хьюз Инкорпорейтед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бейкер Хьюз Инкорпорейтед filed Critical Бейкер Хьюз Инкорпорейтед
Publication of EA200901177A1 publication Critical patent/EA200901177A1/en
Publication of EA016758B1 publication Critical patent/EA016758B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1033—Oil well production fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives

Abstract

Предлагается способ очистки углеводородов, газообразных смесей углеводородов и т.п. от сероводорода и меркаптанов, который заключается в добавлении в указанные среды состава очистителя от меркаптана, содержащего алкоксид или гидроксид четвертичного аммония в присутствии металла в высокой степени окисления, такого как кобальт, железо, хром и/или никель. Металл в высокой степени окисления является окислителем и его можно использовать в качестве катализатора в присутствии этоксида или гидроксида четвертичного аммония, при этом повышается эффективность очистки среды от меркаптана.A method for purifying hydrocarbons, gaseous mixtures of hydrocarbons, and the like is proposed. from hydrogen sulfide and mercaptans, which consists in adding a mercaptan purifier containing alkoxide or quaternary ammonium hydroxide in the presence of a highly oxidized metal such as cobalt, iron, chromium and / or nickel to these media. The metal is highly oxidized and is an oxidizing agent and can be used as a catalyst in the presence of quaternary ammonium ethoxide or hydroxide, while the efficiency of purification of the environment from mercaptan is increased.

EA200901177A 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons EA016758B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US89562507P 2007-03-19 2007-03-19
US12/042,536 US20080230445A1 (en) 2007-03-19 2008-03-05 Method of scavenging mercaptans from hydrocarbons
PCT/US2008/056006 WO2008115704A1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Publications (2)

Publication Number Publication Date
EA200901177A1 true EA200901177A1 (en) 2010-04-30
EA016758B1 EA016758B1 (en) 2012-07-30

Family

ID=39766340

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200901177A EA016758B1 (en) 2007-03-19 2008-03-06 Method of scavenging mercaptans from hydrocarbons

Country Status (4)

Country Link
US (1) US20080230445A1 (en)
EP (2) EP2134814A4 (en)
EA (1) EA016758B1 (en)
WO (1) WO2008115704A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7918905B2 (en) * 2007-05-17 2011-04-05 Baker Hughes Incorporated Method for improving biodiesel fuel
GB2484301B8 (en) * 2010-10-05 2017-11-22 The Queen's Univ Of Belfast Process for removing metals from hydrocarbons
US9296956B2 (en) 2010-10-28 2016-03-29 Chevron U.S.A. Inc. Method for reducing mercaptans in hydrocarbons
US20140084206A1 (en) * 2012-09-27 2014-03-27 Baker Hughes Incorporated Treating Additives for the Deactivation of Sulfur Species Within a Stream
CN103768913B (en) * 2012-10-22 2016-04-27 中国石油化工股份有限公司 A kind of method removing hydrogen sulfide and mercaptan in gas
RU2532019C1 (en) * 2013-07-30 2014-10-27 Ахматфаиль Магсумович Фахриев Agent for neutralising hydrogen sulphide and inhibiting growth of sulphate-reducing bacteria
EP3781293A2 (en) 2018-04-18 2021-02-24 Clairion Ltd. A process for separation of heavy metals and/or sulfur species from ionic liquids

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928211A (en) * 1970-10-21 1975-12-23 Milchem Inc Process for scavenging hydrogen sulfide in aqueous drilling fluids and method of preventing metallic corrosion of subterranean well drilling apparatuses
US4033860A (en) * 1975-09-10 1977-07-05 Uop Inc. Mercaptan conversion process
US4124531A (en) * 1977-01-03 1978-11-07 Uop Inc. Catalytic composite for the treatment of sour petroleum distillates
US4778617A (en) * 1984-11-27 1988-10-18 The Drackett Company Acid cleaner composition
US4594147A (en) 1985-12-16 1986-06-10 Nalco Chemical Company Choline as a fuel sweetener and sulfur antagonist
US4867865A (en) 1988-07-11 1989-09-19 Pony Industries, Inc. Controlling H2 S in fuel oils
US4923596A (en) * 1989-05-22 1990-05-08 Uop Use of quaternary ammonium compounds in a liquid/liquid process for sweetening a sour hydrocarbon fraction
US4929340A (en) * 1989-07-31 1990-05-29 Uop Catalyst and process for sweetening a sour hydrocarbon fraction using dipolar compounds
US5183560A (en) 1991-09-09 1993-02-02 Baker Hughes Incorporated Treatment of oils using choline base
US5430160A (en) * 1991-09-23 1995-07-04 Florida State University Preparation of substituted isoserine esters using β-lactams and metal or ammonium alkoxides
AU2714192A (en) * 1991-10-21 1993-04-22 Baker Hughes Incorporated Treatment of oils using epoxylated tertiary amines
US5232887A (en) * 1992-04-02 1993-08-03 Uop Catalyst for sweetening a sour hydrocarbon fraction
US5413704A (en) * 1993-11-15 1995-05-09 Uop Process for sweetening a sour hydrocarbon fraction using a mixture of a supported metal chelate and a solid base
CA2133270C (en) * 1994-03-03 1999-07-20 Jerry J. Weers Quaternary ammonium hydroxides as mercaptan scavengers
US5744024A (en) * 1995-10-12 1998-04-28 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon

Also Published As

Publication number Publication date
EA016758B1 (en) 2012-07-30
EP2134814A4 (en) 2013-04-24
EP2134814A1 (en) 2009-12-23
EP2759587B1 (en) 2020-02-12
EP2759587A1 (en) 2014-07-30
WO2008115704A1 (en) 2008-09-25
US20080230445A1 (en) 2008-09-25

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

QB4A Registration of a licence in a contracting state