EA200700950A1 - Способ получения циклогексанола и циклогексанона - Google Patents

Способ получения циклогексанола и циклогексанона

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Publication number
EA200700950A1
EA200700950A1 EA200700950A EA200700950A EA200700950A1 EA 200700950 A1 EA200700950 A1 EA 200700950A1 EA 200700950 A EA200700950 A EA 200700950A EA 200700950 A EA200700950 A EA 200700950A EA 200700950 A1 EA200700950 A1 EA 200700950A1
Authority
EA
Eurasian Patent Office
Prior art keywords
cyclohexanone
cyclohexanol
stage
mixture containing
mixture
Prior art date
Application number
EA200700950A
Other languages
English (en)
Other versions
EA011769B1 (ru
Inventor
Энки Кройуэльс
Хендрик Эверинг
Original Assignee
ДСМ АйПи АССЕТС Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ДСМ АйПи АССЕТС Б.В. filed Critical ДСМ АйПи АССЕТС Б.В.
Publication of EA200700950A1 publication Critical patent/EA200700950A1/ru
Publication of EA011769B1 publication Critical patent/EA011769B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Изобретение относится к способу получения циклогексанола и циклогексанона из бензола, причём способ включает следующие стадии:а) стадия частичного гидрирования, где бензол в присутствии металлического катализатора частично гидрируется, давая смесь, содержащую циклогексен и непрореагировавший бензол,b) стадия, где смесь, получаемую на стадии а, гидратируют, получая смесь, содержащую циклогексанол, и/или окисляют в присутствии металлического катализатора, получая смесь, содержащую циклогексанон, или смесь, содержащую циклогексанол и циклогексанон,с) стадия, где циклогексанол и/или циклогексанон выделяют из смеси, полученной на стадии b, содержащей непрореагировавший бензол, циклогексанол и/или циклогексанон,d) стадия гидрирования, где смесь, содержащую непрореагировавший бензол, получаемую на стадии с, гидрируют в присутствии металлического катализатора до циклогексана ие) стадия окисления, где смесь, полученную на стадии d, содержащую циклогексан, окисляют, получая смесь, содержащую циклогексанол и циклогексанон.
EA200700950A 2004-10-27 2005-09-30 Способ получения циклогексанола и циклогексанона EA011769B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04077966 2004-10-27
PCT/NL2005/000711 WO2006046852A1 (en) 2004-10-27 2005-09-30 Process for the preparation of cyclohexanol and cyclohexanone

Publications (2)

Publication Number Publication Date
EA200700950A1 true EA200700950A1 (ru) 2007-10-26
EA011769B1 EA011769B1 (ru) 2009-06-30

Family

ID=34928613

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200700950A EA011769B1 (ru) 2004-10-27 2005-09-30 Способ получения циклогексанола и циклогексанона

Country Status (7)

Country Link
EP (1) EP1805125A1 (ru)
JP (1) JP2008518001A (ru)
CN (1) CN101048358B (ru)
EA (1) EA011769B1 (ru)
TW (1) TW200626535A (ru)
UA (1) UA95064C2 (ru)
WO (1) WO2006046852A1 (ru)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006001482A1 (de) * 2006-01-11 2007-07-12 Sumitomo Chemical Co., Ltd. Katalysator und Verfahren zur Herstellung eines Ketons unter Verwendung desselben
US20080076946A1 (en) * 2006-09-22 2008-03-27 Sumitomo Chemical Company, Limited Process for producing cycloalkanol and/or cycloalkanone
JP5136017B2 (ja) * 2007-11-21 2013-02-06 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
CN102389839B (zh) * 2011-08-11 2012-11-14 河北美邦工程科技有限公司 一种环己酮生产过程中环己烯水合反应催化剂分离膜再生工艺
EA027382B1 (ru) * 2011-12-07 2017-07-31 Кап Iii Б.В. Способ получения смеси, содержащей циклогексанол и циклогексанон
WO2015163221A1 (ja) * 2014-04-22 2015-10-29 宇部興産株式会社 水素化触媒及びその製造方法、並びにそれを用いたシクロヘキサノン又はその誘導体の製造方法
CN110872208B (zh) * 2019-02-18 2023-10-27 南京匹亚化工有限公司 一种耦合环己烷混合物脱氢技术的环己醇制备方法
CN111153831B (zh) * 2020-02-19 2022-11-01 湘潭大学 一种环己酮肟的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7802125A (nl) * 1978-02-25 1979-08-28 Stamicarbon Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen.
NL7905781A (nl) * 1979-07-26 1981-01-28 Stamicarbon Werkwijze voor het bereiden van cyclohexanol.
NL8801036A (nl) * 1988-04-21 1989-11-16 Stamicarbon Werkwijze voor de bereiding van cyclohexanol en/of cyclohexanon.
NL9201269A (nl) * 1992-07-15 1994-02-01 Dsm Nv Werkwijze voor de bereiding van cyclohexylhydroperoxide.
JPH11322661A (ja) * 1998-05-11 1999-11-24 Mitsubishi Chemical Corp シクロヘキサノンの製造方法及びε−カプロラクタムの製造方法

Also Published As

Publication number Publication date
JP2008518001A (ja) 2008-05-29
WO2006046852A1 (en) 2006-05-04
CN101048358B (zh) 2010-05-05
CN101048358A (zh) 2007-10-03
EA011769B1 (ru) 2009-06-30
UA95064C2 (en) 2011-07-11
TW200626535A (en) 2006-08-01
EP1805125A1 (en) 2007-07-11

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): BY RU