EA199800098A1 - Эластомерный сополимер, эластомерная композиция, способ получения эластомерного сополимера, изделие - Google Patents

Эластомерный сополимер, эластомерная композиция, способ получения эластомерного сополимера, изделие

Info

Publication number
EA199800098A1
EA199800098A1 EA199800098A EA199800098A EA199800098A1 EA 199800098 A1 EA199800098 A1 EA 199800098A1 EA 199800098 A EA199800098 A EA 199800098A EA 199800098 A EA199800098 A EA 199800098A EA 199800098 A1 EA199800098 A1 EA 199800098A1
Authority
EA
Eurasian Patent Office
Prior art keywords
elastomeric
copolymer
elastomeric copolymer
product
obtaining
Prior art date
Application number
EA199800098A
Other languages
English (en)
Inventor
Якоб Ренкема
Бернардус Йоханна Мюскенс
Андреас Антониус Остерлакен
Original Assignee
Дсм Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL1000687A external-priority patent/NL1000687C2/xx
Application filed by Дсм Н.В. filed Critical Дсм Н.В.
Publication of EA199800098A1 publication Critical patent/EA199800098A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Изобретение относится к эластомерному сополимеру, содержащему 25-85 мас.% этилена, 15-75 мас.% альфа-олефина и, необязательно, до 20 мас.% диена. Он отличается тем, что сополимер имеет коэффициент однородной разветвленности (КОР), который удовлетворяет зависимости (а)Изобретение также относится к способу получения такого эластомерного сополимера. В этом способе используется катализатор, имеющий фактор реакционной способности RF менее 10.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199800098A 1995-06-29 1996-06-26 Эластомерный сополимер, эластомерная композиция, способ получения эластомерного сополимера, изделие EA199800098A1 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US64795P 1995-06-29 1995-06-29
NL1000687A NL1000687C2 (en) 1995-06-29 1995-06-29 Ethylene-~a-olefin(-diene) copolymer for prodn. of thermoplastic elastomers
EP96201116 1996-05-03
US1884996P 1996-05-30 1996-05-30
PCT/NL1996/000261 WO1997001586A1 (en) 1995-06-29 1996-06-26 Elastomeric copolymer

Publications (1)

Publication Number Publication Date
EA199800098A1 true EA199800098A1 (ru) 1998-08-27

Family

ID=56289698

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199800098A EA199800098A1 (ru) 1995-06-29 1996-06-26 Эластомерный сополимер, эластомерная композиция, способ получения эластомерного сополимера, изделие

Country Status (9)

Country Link
EP (1) EP0835271A1 (ru)
JP (1) JPH11509881A (ru)
KR (1) KR19990028655A (ru)
AU (1) AU6244596A (ru)
BR (1) BR9609483A (ru)
CA (1) CA2225742A1 (ru)
EA (1) EA199800098A1 (ru)
MX (1) MX9800210A (ru)
WO (1) WO1997001586A1 (ru)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE226232T1 (de) * 1997-04-29 2002-11-15 Dow Chemical Co Amorphe propylen-polyen copolymere und diese enthaltende zusammensetzungen
EP0981556A1 (en) * 1997-04-30 2000-03-01 The Dow Chemical Company Ethylene/alpha-olefin/diene interpolymers and their preparation
NL1006421C2 (nl) * 1997-06-27 1998-12-29 Dsm Nv Elastomeer copolymeer.
EA002450B1 (ru) * 1997-06-27 2002-04-25 Дсм Н.В. Эластомерный сополимер и способ его получения
DE69938061D1 (de) * 1998-12-21 2008-03-13 Exxonmobil Chem Patents Inc Verfahren zur herstellung von verzweigten ethylen-propylen copolymeren
EP1641847A2 (en) 2003-07-09 2006-04-05 DSM IP Assets B.V. Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
JP4777352B2 (ja) * 2005-08-10 2011-09-21 三井化学株式会社 共重合体ゴム、ゴム組成物、及びゴム成形体
US20100280206A1 (en) * 2007-11-09 2010-11-04 Borealis Technology Oy Polyethylene copolymer
KR101391693B1 (ko) * 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법
KR101585206B1 (ko) * 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR102659554B1 (ko) * 2018-11-26 2024-04-24 롯데케미칼 주식회사 인장신율과 복원력이 우수한 복합수지 조성물

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1327673C (en) * 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
EP0552946B1 (en) * 1992-01-23 1997-04-16 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin/7-methyl-1,6-octadiene copolymer rubber and composition of the same
KR100280253B1 (ko) * 1992-06-18 2001-02-01 간디 지오프레이 에이치. 에틸렌 중합체의 제조방법
CA2110654C (en) * 1992-12-17 2006-03-21 Albert Rossi Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems
US5472775A (en) * 1993-08-17 1995-12-05 The Dow Chemical Company Elastic materials and articles therefrom
NL9400758A (nl) * 1994-05-06 1995-12-01 Dsm Nv Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
US6300451B1 (en) * 1994-10-24 2001-10-09 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
NL9401893A (nl) * 1994-11-14 1996-06-03 Dsm Nv Katalysator voor het bereiden van een rubberachtig copolymeer.

Also Published As

Publication number Publication date
KR19990028655A (ko) 1999-04-15
EP0835271A1 (en) 1998-04-15
BR9609483A (pt) 1999-03-02
JPH11509881A (ja) 1999-08-31
AU6244596A (en) 1997-01-30
WO1997001586A1 (en) 1997-01-16
MX9800210A (es) 1998-04-30
CA2225742A1 (en) 1997-01-16

Similar Documents

Publication Publication Date Title
AR012812A1 (es) Interpolimeros de olefinas/polienos; proceso para preparar dichos interpolimeros; composiciones que comprenden dichos interpolimeros y articulosde manufactura obtenidos procesando dichos interpolimeros
EA199800098A1 (ru) Эластомерный сополимер, эластомерная композиция, способ получения эластомерного сополимера, изделие
GC0000321A (en) Olefin oligomerization
GR3032161T3 (en) Amido siladiyl bridged catalyst components, methods of making and using
AU589986B2 (en) Polymerisation of olefins using a ziegler-natta catalyst and two organometallic compounds
MY126510A (en) Magnesium dichloride- alcohol adducts, process for their preparation and catalyst components obtained therefrom
MY127059A (en) Process for the preparation of c5-/c6-olefins.
AR001081A1 (es) Un proceso para preparar ciertos aza ciclohexapeptidos y compuestos preparados mediante dicho proceso
EA200201160A1 (ru) Каталитические композиции для полимеризации и способы получения полимеров и бимодальных полимеров
MY105224A (en) Catalysts for the polymerization of olefins.
TW353080B (en) Catalyst composition, method for making and use of the same
MX9604374A (es) Polietilenos hidrofilicos modificados en polvo de peso molecular elevado y/o ultraelevado.
BG104423A (en) Process for the production of heterophasic polymer compositions, and compositions thus obtained
ES2135866T3 (es) Procedimiento de hidroformilacion.
ES2127349T3 (es) Aditivos polimeros mejoradores del flujo.
DE69014504D1 (de) Verfahren zur Herstellung von Ethylen/Propylen/Ethylidennorbornen-Kautschuke.
EA200301043A1 (ru) Металлоалюмофосфатное молекулярное сито с кубической морфологией кристаллов и способ превращения метанола в олефины с использованием этого сита
MY129127A (en) Process for separating linear internal olefins from branched internal olefins
EA199800977A1 (ru) СПОСОБ ПОЛУЧЕНИЯ СОПОЛИМЕРА ЭТИЛЕНА И α-ОЛЕФИНА
ES2147894T3 (es) Procedimiento de preparacion de polibutadieno con alto contenido en cis.
ES2177132T3 (es) Compuestos de complejo pi.
NO940090L (no) Blanding for makrodefekt-fri sement, samt fremgangsmåte for fremstilling av denne
EA199700235A1 (ru) Способ получения ингибитора протеазы вич из (2-s)-4-пиколил-2-пиперазин-трет-бутилкарбоксамида
ES2055220T3 (es) Copolimeros alternantes, procedimiento para su fabricacion, y su uso.
EA199800214A1 (ru) Каталитическая система для получения каучукоподобного сополимера