EA033375B1 - Способ удаления сульфата, кальция и/или других растворимых металлов из сточных вод - Google Patents

Способ удаления сульфата, кальция и/или других растворимых металлов из сточных вод

Info

Publication number
EA033375B1
EA033375B1 EA201590361A EA201590361A EA033375B1 EA 033375 B1 EA033375 B1 EA 033375B1 EA 201590361 A EA201590361 A EA 201590361A EA 201590361 A EA201590361 A EA 201590361A EA 033375 B1 EA033375 B1 EA 033375B1
Authority
EA
Eurasian Patent Office
Prior art keywords
water
calcium
waste water
sulphate
soluble metals
Prior art date
Application number
EA201590361A
Other languages
English (en)
Other versions
EA201590361A1 (ru
Inventor
Laura Nevatalo
Der Meer Tuomas Van
Bernd Kerstiens
Original Assignee
Outotec Finland Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Outotec Finland Oy filed Critical Outotec Finland Oy
Publication of EA201590361A1 publication Critical patent/EA201590361A1/ru
Publication of EA033375B1 publication Critical patent/EA033375B1/ru

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • C02F1/004Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5209Regulation methods for flocculation or precipitation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/101Sulfur compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/005Processes using a programmable logic controller [PLC]
    • C02F2209/006Processes using a programmable logic controller [PLC] comprising a software program or a logic diagram
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Removal Of Specific Substances (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

Изобретение относится к способу и системе для удаления сульфата, кальция и/или растворимых металлов из сточных вод, при этом данный способ включает следующие стадии: а) стадию осаждения гипса, б) стадию осаждения эттрингита, в) первую стадию отделения, г) стадию нейтрализации и д) вторую стадию отделения, чтобы получить воду, имеющую пониженное содержание сульфата, кальция и/или растворимых металлов. Сточные воды представляют собой технологическую воду, частично очищенную сточную воду или содержащую сульфат воду, такую как рудничная вода, оборотную воду из концентратора или отработанную воду из концентратора.
EA201590361A 2012-08-27 2013-08-22 Способ удаления сульфата, кальция и/или других растворимых металлов из сточных вод EA033375B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20125884A FI126285B (en) 2012-08-27 2012-08-27 Process for removing sulfate, calcium and / or other soluble metals from wastewater
PCT/FI2013/050816 WO2014033361A1 (en) 2012-08-27 2013-08-22 Method for removing sulphate, calcium and/or other soluble metals from waste water

Publications (2)

Publication Number Publication Date
EA201590361A1 EA201590361A1 (ru) 2015-08-31
EA033375B1 true EA033375B1 (ru) 2019-10-31

Family

ID=50182576

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201590361A EA033375B1 (ru) 2012-08-27 2013-08-22 Способ удаления сульфата, кальция и/или других растворимых металлов из сточных вод

Country Status (14)

Country Link
EP (1) EP2888206B1 (ru)
CN (1) CN104603068A (ru)
AR (1) AR092239A1 (ru)
AU (1) AU2013308317B2 (ru)
BR (1) BR112015003530B8 (ru)
CA (2) CA2961057C (ru)
CL (1) CL2015000392A1 (ru)
EA (1) EA033375B1 (ru)
ES (1) ES2739654T3 (ru)
FI (1) FI126285B (ru)
IN (1) IN2015KN00435A (ru)
PT (1) PT2888206T (ru)
WO (1) WO2014033361A1 (ru)
ZA (1) ZA201501159B (ru)

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US9278875B2 (en) 2012-11-27 2016-03-08 Veolia Water Solutions & Technologies Support Process for reducing the sulfate concentration in a wastewater stream by employing regenerated gibbsite
AR094158A1 (es) * 2012-12-20 2015-07-15 Outotec Oyj Metodo para el tratamiento de agua industrial
FI127809B (en) * 2014-02-26 2019-03-15 Outotec Oyj Method for removing sulfate from waste water
FI126851B (fi) * 2014-04-02 2017-06-30 Suominen Lauri Hannunpoika Menetelmä sulfaatin poistamiseksi vesiliuoksesta
GB201407101D0 (en) 2014-04-22 2014-06-04 Paxton Richard G New process for the treatment of high sulphate waters
BR112017004200B1 (pt) * 2014-09-05 2022-04-19 Ecolab Usa Inc Método para reduzir uma concentração de um ou mais oxoânions, e, sistema de tratamento de oxoânions
US10071923B2 (en) 2014-09-05 2018-09-11 Ecolab Usa Inc. Addition of aluminum reagents to oxoanion-containing water streams
US9389209B2 (en) 2014-09-05 2016-07-12 Ecolab Usa Inc. Oxoanion concentration determination using aluminum reagents
PE20180805A1 (es) 2015-07-22 2018-05-09 Mintek PROCEDIMIENTO DE TRATAMIENTO DE EFLUENTE - REFINO DE pH PARA LA RETIRADA DE SULFATO
MX2018000859A (es) * 2015-07-22 2018-05-04 Mintek Proceso de tratamiento de efluentes mejorado para la eliminacion de sulfato.
CN106045121A (zh) * 2016-07-14 2016-10-26 山东科技大学 一种快速降低废水中六价铬浓度的预处理方法
CN106830432A (zh) * 2017-03-07 2017-06-13 中冶节能环保有限责任公司 一种高含铁高碱度矿井水处理工艺和系统
CN107117738B (zh) * 2017-04-24 2019-12-17 华中科技大学 一种锰矿区废水处理方法
US20200216337A1 (en) * 2017-08-14 2020-07-09 Siemens Energy, Inc. Sulfate removal of wet air oxidized spent caustic
CA3076461A1 (en) * 2017-09-20 2019-03-28 Smr Technologies Limited New process for the treatment of high sulphate waters
US20200247681A1 (en) 2017-09-20 2020-08-06 Smr Technologies Limited Suitable reagent for the treatment of high-sulphate waters
CN107673514A (zh) * 2017-11-14 2018-02-09 上海电力学院 硫酸根去除与污泥资源化利用的废水处理系统及处理方法
JP6986226B2 (ja) 2017-12-27 2021-12-22 三菱マテリアル株式会社 廃水の処理方法
JP6970917B2 (ja) 2017-12-27 2021-11-24 三菱マテリアル株式会社 廃水の処理方法
CN108203181A (zh) * 2018-01-11 2018-06-26 武汉天空蓝环保科技有限公司 电厂循环冷却水废水处理方法及系统
IT201900010095A1 (it) * 2019-06-26 2020-12-26 Agromatrici S R L Impianto e procedimento per la produzione di carbonato di calcio di defecazione.
WO2021028621A1 (en) 2019-08-15 2021-02-18 Teknologian Tutkimuskeskus Vtt Oy Use of secondary aluminium in precipitation of sulphate from waste water
CA3109965A1 (en) * 2020-02-23 2021-08-23 Kurita America Inc. Sulfate and trace metal precipitation methods and compositions
CN111453880A (zh) * 2020-04-09 2020-07-28 安徽浩悦环境科技有限责任公司 一种联合沉淀法去除多种类重金属废液的方法
SE545642C2 (en) 2020-07-16 2023-11-21 Axolot Solutions Holding Ab A method and a system for removal of sulfate from wastewater by electrocoagulation
CN114735723B (zh) * 2021-06-22 2024-05-31 华融化学股份有限公司 一种钾碱粗盐水精制工艺
US11939519B2 (en) 2022-08-29 2024-03-26 Saudi Arabian Oil Company Methods and systems to reduce scale formation
CN118047466A (zh) * 2024-04-16 2024-05-17 山东省水利科学研究院 一种水中硫酸根处理复合药剂及处理方法、应用
CN118221248B (zh) * 2024-05-24 2024-10-18 长春黄金研究院有限公司 去除酸性矿山废水中硫酸根的方法
CN118255497B (zh) * 2024-05-29 2024-09-03 长春黄金研究院有限公司 酸性矿山废水中有价物质分级回收的方法

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EP0250626A1 (de) * 1986-06-30 1988-01-07 Walhalla-Kalk Entwicklungs- und Vertriebsgesellschaft mbH Verfahren zur Abtrennung von Sulfationen aus Abwässern
US6280630B1 (en) * 1997-06-03 2001-08-28 Mintek Process for the treatment of effluent streams
WO2011163451A1 (en) * 2010-06-23 2011-12-29 Veolia Water Solutions & Technologies Support A process for reducing the sulfate concentration in a wastewater stream
US20120031850A1 (en) * 2010-08-05 2012-02-09 Kevin Smith Extraction of Sulfate from Water

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EP0250626A1 (de) * 1986-06-30 1988-01-07 Walhalla-Kalk Entwicklungs- und Vertriebsgesellschaft mbH Verfahren zur Abtrennung von Sulfationen aus Abwässern
US6280630B1 (en) * 1997-06-03 2001-08-28 Mintek Process for the treatment of effluent streams
WO2011163451A1 (en) * 2010-06-23 2011-12-29 Veolia Water Solutions & Technologies Support A process for reducing the sulfate concentration in a wastewater stream
US20120031850A1 (en) * 2010-08-05 2012-02-09 Kevin Smith Extraction of Sulfate from Water

Also Published As

Publication number Publication date
AU2013308317A1 (en) 2015-03-05
FI126285B (en) 2016-09-15
CA2881769A1 (en) 2014-03-06
AR092239A1 (es) 2015-04-08
EA201590361A1 (ru) 2015-08-31
CA2961057A1 (en) 2014-03-06
CL2015000392A1 (es) 2015-06-26
WO2014033361A1 (en) 2014-03-06
ZA201501159B (en) 2021-09-29
CN104603068A (zh) 2015-05-06
CA2961057C (en) 2020-06-30
FI20125884A (fi) 2014-04-03
CA2881769C (en) 2020-07-21
EP2888206A1 (en) 2015-07-01
ES2739654T3 (es) 2020-02-03
EP2888206B1 (en) 2019-05-22
BR112015003530A2 (pt) 2017-07-04
PT2888206T (pt) 2019-08-19
EP2888206A4 (en) 2016-10-19
IN2015KN00435A (ru) 2015-07-17
BR112015003530B8 (pt) 2023-02-07
AU2013308317B2 (en) 2016-12-22
BR112015003530B1 (pt) 2021-10-19

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Designated state(s): AM AZ BY KG TJ TM