EA021535B9 - Способ получения этанола и высших спиртов - Google Patents

Способ получения этанола и высших спиртов

Info

Publication number
EA021535B9
EA021535B9 EA201390065A EA201390065A EA021535B9 EA 021535 B9 EA021535 B9 EA 021535B9 EA 201390065 A EA201390065 A EA 201390065A EA 201390065 A EA201390065 A EA 201390065A EA 021535 B9 EA021535 B9 EA 021535B9
Authority
EA
Eurasian Patent Office
Prior art keywords
synthesis gas
higher alcohols
ethanol
product
preparation
Prior art date
Application number
EA201390065A
Other languages
English (en)
Other versions
EA201390065A1 (ru
EA021535B1 (ru
Inventor
Поль Эрик Хойлунд Нильсен
Бурчин Темель
Пабло Беато
Original Assignee
Хальдор Топсеэ А/С
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Хальдор Топсеэ А/С filed Critical Хальдор Топсеэ А/С
Publication of EA201390065A1 publication Critical patent/EA201390065A1/ru
Publication of EA021535B1 publication Critical patent/EA021535B1/ru
Publication of EA021535B9 publication Critical patent/EA021535B9/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Способ получения этанола и/или высших спиртов, включающий следующие этапы: (а) предоставление синтез-газа спирта, содержащего моноксид углерода и водород в молярном соотношении более 0,5; (b) добавление количества метанола и/или высших спиртов к синтез-газу для получения смеси синтез-газа; (c) преобразование смеси синтез-газа из этапа (b) в присутствии одного или более катализаторов, катализирующих преобразование смеси синтез-газа в этанол и/или высшие спирты, содержащие продукт; и (d) извлечение продукта из этапа (c), на котором синтез-газ очищают посредством удаления соединений карбонила металла до или после добавления метанола и/или высших спиртов в синтез-газ, при этом соединения карбонила металла удаляют из синтез-газа посредством взаимодействии газа с сорбенотом, содержащим медь-алюминиевую шпинель, модифицированную путём восстановления в восстановительной среде при температуре от 250 до 500°C перед взаимодействием с синтез-газом и при необходимости (e) охлаждение извлечённого продукта на этапе (d); и (f) взаимодействие охлаждённого продукта с гидрогенизирующим катализатором.
EA201390065A 2010-07-05 2011-05-17 Способ получения этанола и высших спиртов EA021535B9 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201000595 2010-07-05
PCT/EP2011/002447 WO2012003901A1 (en) 2010-07-05 2011-05-17 Process for the preparation of ethanol and higher alcohols

Publications (3)

Publication Number Publication Date
EA201390065A1 EA201390065A1 (ru) 2013-06-28
EA021535B1 EA021535B1 (ru) 2015-07-30
EA021535B9 true EA021535B9 (ru) 2016-05-31

Family

ID=44169173

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201390065A EA021535B9 (ru) 2010-07-05 2011-05-17 Способ получения этанола и высших спиртов

Country Status (11)

Country Link
US (1) US8637580B2 (ru)
EP (1) EP2590922B1 (ru)
CN (1) CN103119012B (ru)
AU (1) AU2011276182B2 (ru)
BR (1) BR112013000301B1 (ru)
CA (1) CA2803946C (ru)
CO (1) CO6620029A2 (ru)
EA (1) EA021535B9 (ru)
MX (1) MX2012014765A (ru)
WO (1) WO2012003901A1 (ru)
ZA (1) ZA201300097B (ru)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013000268A2 (pt) * 2010-07-05 2016-05-24 Haldor Topsoe As método de remover carbonilas de metal de correntes gasosas e absorvente de carbonila de metal
WO2013072228A1 (en) * 2011-11-18 2013-05-23 Haldor Topsøe A/S Process for the preparation of higher alcohols
US9988330B2 (en) * 2012-12-20 2018-06-05 Haldor Topsoe A/S Process and apparatus for the production of higher alcohols
CN104892360A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备乙醇的新方法
DE102016006707A1 (de) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
DE102016006713A1 (de) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
DE102016006710A1 (de) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
DE102016006712A1 (de) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
DE102016006709A1 (de) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
DE102016006729A1 (de) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Verfahren und Anlage zur parallelen Herstellung von Butadien und Synthesegas
EP3388408A1 (de) 2017-04-11 2018-10-17 Linde Aktiengesellschaft Verfahren und anlage zur herstellung von butadien aus ethanol
DE102017003840A1 (de) 2017-04-20 2018-10-25 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
DE102018003343A1 (de) 2018-04-24 2019-10-24 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Ethanol
FR3133196A1 (fr) 2022-03-07 2023-09-08 Totalenergies One Tech Procede de fabrication d’un carbureacteur a partir de charges d’origine renouvelable
FR3135265A1 (fr) 2022-05-06 2023-11-10 Totalenergies Onetech Procédé d’obtention d’hydrocarbures, et installation associée
FR3135264A1 (fr) 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés
FR3135263A1 (fr) 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés
FR3135986A1 (fr) 2022-05-30 2023-12-01 Totalenergies Onetech Procede de fabrication de fluides hydrocarbones a partir de charges d’origine renouvelable
FR3138444A1 (fr) 2022-07-27 2024-02-02 Totalenergies Onetech Composition renouvelable de carburéacteur à teneur élevée en composés naphténiques et procédé de préparation associé
FR3138443A1 (fr) 2022-07-27 2024-02-02 Totalenergies Onetech Composition renouvelable de carburéacteur à teneur élevée en composés naphténiques

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4825013A (en) * 1984-11-05 1989-04-25 The Dow Chemical Company Preparation of ethanol and higher alcohols from lower carbon number alcohols
EP0499095A1 (de) * 1991-02-12 1992-08-19 Bayer Ag Katalysatoren zur Entfernung von Schwefelverbindungen aus technischen Gasen, Verfahren zu deren Herstellung sowie deren Verwendung
US20090018371A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing alcohols from syngas

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2468510A (en) * 1945-12-14 1949-04-26 Standard Oil Dev Co Pretreatment of gases for the synthesis of hydrocarbons
CA2693680A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing syngas

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4825013A (en) * 1984-11-05 1989-04-25 The Dow Chemical Company Preparation of ethanol and higher alcohols from lower carbon number alcohols
EP0499095A1 (de) * 1991-02-12 1992-08-19 Bayer Ag Katalysatoren zur Entfernung von Schwefelverbindungen aus technischen Gasen, Verfahren zu deren Herstellung sowie deren Verwendung
US20090018371A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing alcohols from syngas

Also Published As

Publication number Publication date
CA2803946A1 (en) 2012-01-12
ZA201300097B (en) 2014-03-26
CN103119012A (zh) 2013-05-22
CO6620029A2 (es) 2013-02-15
EP2590922A1 (en) 2013-05-15
EP2590922B1 (en) 2014-12-03
AU2011276182A1 (en) 2013-01-24
BR112013000301B1 (pt) 2018-06-26
AU2011276182B2 (en) 2014-03-27
CA2803946C (en) 2017-05-16
BR112013000301A2 (pt) 2016-05-31
US20130123377A1 (en) 2013-05-16
EA201390065A1 (ru) 2013-06-28
US8637580B2 (en) 2014-01-28
CN103119012B (zh) 2016-03-02
EA021535B1 (ru) 2015-07-30
WO2012003901A1 (en) 2012-01-12
MX2012014765A (es) 2013-01-29

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Legal Events

Date Code Title Description
TH4A Publication of the corrected specification to eurasian patent
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): TM RU