DK2864022T3 - Middel til oprensning af væsker, fremgangsmåde til fremstilling deraf og anvendelse deraf - Google Patents

Middel til oprensning af væsker, fremgangsmåde til fremstilling deraf og anvendelse deraf Download PDF

Info

Publication number
DK2864022T3
DK2864022T3 DK13730886.2T DK13730886T DK2864022T3 DK 2864022 T3 DK2864022 T3 DK 2864022T3 DK 13730886 T DK13730886 T DK 13730886T DK 2864022 T3 DK2864022 T3 DK 2864022T3
Authority
DK
Denmark
Prior art keywords
trass
modified
water
approx
mixture
Prior art date
Application number
DK13730886.2T
Other languages
English (en)
Inventor
Konrad Fichtel
Michael Fichtel
Roland Fichtel
Original Assignee
Ftu Gmbh Forschung Und Technische Entw Im Umweltschutz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ftu Gmbh Forschung Und Technische Entw Im Umweltschutz filed Critical Ftu Gmbh Forschung Und Technische Entw Im Umweltschutz
Application granted granted Critical
Publication of DK2864022T3 publication Critical patent/DK2864022T3/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/11—Clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/206—Organic halogen compounds
    • B01D2257/2064—Chlorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds

Claims (12)

1. Modificeret Trass, som har en aktiv overflade ifølge BET på s ca. 60 m2/g og kan opnås ved en fremgangsmåde, der omfatter følgende trin: (a) Trass bringes i kontakt med en blanding afvand og overfladeaktivt middel og/eller syrer for at opløse komponenter i Trass; og (b) de opløste komponenter fjernes fra Trass.
2. Modificeret Trass ifølge krav 1, hvor den Trass, der anvendes til fremstilling deraf, er afledt af Bavarian Trass eller Rheinischer Trass, Trass fra Schwarzwald (Tyskland) eller Trass fra Eifel (Frankrig).
3. Modificeret Trass ifølge krav 1 eller krav 2, hvor den modificerede Trass har en aktiv overflade på > ca. 80 m2/g, fortrinsvis > ca. 100 m2/g, mere foretrukket > ca. 120 m2/g, endnu mere foretrukket > ca. 140 m2/g.
4. Modificeret Trass ifølge et hvilket som helst af de foregående krav, som er imprægneret med en komponent, der er valgt fra gruppen omfattende sulfider, polysulfider, metalsalte eller en hvilken som helst kombination deraf, eller som er ladet med en komponent, der er valgt fra gruppen omfattende elementært svovl, vandglas eller en hvilken som helst kombination deraf.
5. Modificeret Trass ifølge krav 4, hvor henholdsvis metallerne eller metalsaltene omfatter vanadium, wolfram, titan, palladium, rhodium, platin, auer-metal, Raney-nikkel, manganoxid, vanadiumpentoxid, samarium(lll)-oxid og/eller Hopcalite eller en hvilken som helst kombination deraf.
6. Modificeret Trass ifølge et hvilket som helst af de foregående krav, som er blandet med koks, aktivkul og/eller alkaliske komponenter.
7. Fremgangsmåde til fremstilling af en modificeret Trass, som har en aktiv overflade ifølge BET på > ca. 60 m2/g, hvilken fremgangsmåde omfatter følgende trin: (a) Trass bringes i kontakt med en blanding afvand og overfladeaktivt middel og/eller syrer for at opløse komponenter i Trass; og (b) de opløste komponenter fjernes fra Trass.
8. Fremgangsmåde ifølge krav 7, hvor syren er saltsyre, salpetersyre eller svovlsyre eller en blanding deraf.
9. Fremgangsmåde ifølge et hvilket som helst af kravene 7 til 8, hvor kontakten mellem blandingen afvand og overfladeaktivt middel og/eller syrer og Trass udføres ved en temperatur, som går fra omgivelsestemperaturer op til 150°C.
10. Anvendelse af en modificeret Trass ifølge et hvilket som helst af kravene 1-6 til oprensning af væsker.
11. Anvendelse ifølge krav 10, hvor væsken er valgt blandt udstødningsgasser eller postevand.
12. Anvendelse ifølge krav 10 eller 11, hvor oprensningen omfatter fjernelse af konta-minanterfra væsken valgt blandt kviksølv, tungmetaller, kvælstofoxid, dioxin, klorerede furaner, klorerede kulbrinter, aromatiske kulbrinter, carbonmonoxid, saltsyre, svovldioxid, svovlhydrid, bakterier, svampe, biologisk affald eller en hvilken som helst kombination deraf.
DK13730886.2T 2012-06-21 2013-06-21 Middel til oprensning af væsker, fremgangsmåde til fremstilling deraf og anvendelse deraf DK2864022T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012012367.1A DE102012012367B4 (de) 2012-06-21 2012-06-21 Aktivierter trass,dessen herstellung und verwendung
PCT/EP2013/063079 WO2013190135A1 (en) 2012-06-21 2013-06-21 Means for purifying fluids, method of its preparation and its use

Publications (1)

Publication Number Publication Date
DK2864022T3 true DK2864022T3 (da) 2017-05-22

Family

ID=48672629

Family Applications (1)

Application Number Title Priority Date Filing Date
DK13730886.2T DK2864022T3 (da) 2012-06-21 2013-06-21 Middel til oprensning af væsker, fremgangsmåde til fremstilling deraf og anvendelse deraf

Country Status (11)

Country Link
US (1) US9597654B2 (da)
EP (1) EP2864022B1 (da)
JP (1) JP2015521539A (da)
KR (1) KR102136093B1 (da)
CN (1) CN104394960B (da)
DE (1) DE102012012367B4 (da)
DK (1) DK2864022T3 (da)
ES (1) ES2625059T3 (da)
HU (1) HUE033390T2 (da)
PL (1) PL2864022T3 (da)
WO (1) WO2013190135A1 (da)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014113620A1 (de) 2014-09-22 2016-03-24 Ftu Gmbh Puzzolane zur Abgasreinigung
CN106241903A (zh) * 2016-08-11 2016-12-21 李宝全 一种环保净水剂
CN108246259A (zh) * 2018-04-02 2018-07-06 鲁东大学 一种高效吸附挥发性有机物的生物质碳材料的制备方法
DE102018108934A1 (de) 2018-04-16 2019-10-17 I-Stone Gmbh Verwendung von mit Polythionaten beschichtetem Trass zur Abgasreinigung
CN115155513B (zh) * 2022-07-08 2024-01-26 两山生态科技(山东)有限公司 一种改性火山灰的制备方法及其应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4832079B1 (da) * 1968-04-16 1973-10-03
FR2529802A1 (fr) * 1982-07-06 1984-01-13 Pro Catalyse Masses d'absorption pour l'elimination du mercure
DE19745191A1 (de) * 1997-10-13 1999-04-15 Ftu Gmbh Forschung Und Tech En Mittel, Verfahren zur Herstellung der Mittel und Verwendung der Mittel zur Gasreinigung
DE19936930A1 (de) * 1999-08-19 2001-02-08 Ftu Gmbh Forschung Und Entwick Verfahren und Vorrichtung zur Abtrennung von Quecksilber aus heißen Pyrolysegasen
JP2006110517A (ja) * 2004-10-18 2006-04-27 Taiheiyo Cement Corp 硝酸性窒素汚染水の水質浄化方法
CN101175948A (zh) * 2005-03-17 2008-05-07 Noxⅱ国际有限公司 降低煤燃烧中的汞排放量
JP4332605B2 (ja) * 2005-03-31 2009-09-16 福井県 調湿材料およびその製造方法
EP2180933A4 (en) * 2007-08-03 2011-08-10 Errcive Inc POROUS BODIES AND METHODS
TWI404566B (zh) * 2008-01-18 2013-08-11 Rohm & Haas 用於水處理之吸附床
CN101327993B (zh) * 2008-08-04 2010-11-10 清华大学 一种利用粉末吸附剂去除地下水中有害离子的方法及装置
IT1394436B1 (it) * 2009-05-07 2012-06-15 Aero Sekur S P A Dispositivo di filtrazione di aggressivi nbc per il trattamento di grandi masse d aria.
CN101962188A (zh) * 2010-11-15 2011-02-02 西藏大为建筑环保工程有限责任公司 用火山灰制备超细高纯SiO2的方法
WO2012071206A1 (en) 2010-11-22 2012-05-31 Albemarle Corporation Brominated inorganic sorbents for reduction of mercury emissions
CN102976434B (zh) * 2012-12-11 2014-01-15 常州大学 一种含铅废水的处理方法

Also Published As

Publication number Publication date
ES2625059T3 (es) 2017-07-18
PL2864022T3 (pl) 2017-08-31
CN104394960A (zh) 2015-03-04
EP2864022B1 (en) 2017-02-15
DE102012012367B4 (de) 2014-03-27
KR102136093B1 (ko) 2020-07-22
KR20150020595A (ko) 2015-02-26
CN104394960B (zh) 2018-04-06
HUE033390T2 (en) 2017-12-28
US9597654B2 (en) 2017-03-21
DE102012012367A1 (de) 2013-12-24
US20150238928A1 (en) 2015-08-27
WO2013190135A1 (en) 2013-12-27
EP2864022A1 (en) 2015-04-29
JP2015521539A (ja) 2015-07-30

Similar Documents

Publication Publication Date Title
Yang et al. Removal of elemental mercury from flue gas using red mud impregnated by KBr and KI reagent
Yang et al. Mercury removal from flue gas by noncarbon sorbents
AU2003232091B2 (en) Sorbents and methods for the removal of mercury from combustion gases
US7572421B2 (en) Mercury sorbents and methods of manufacture and use
CA2557695C (en) Sorbent for removal of trace hazardous air pollutants from combustion flue gas and preparation method thereof
US20070092418A1 (en) Sorbents for Removal of Mercury from Flue Gas
DK2864022T3 (da) Middel til oprensning af væsker, fremgangsmåde til fremstilling deraf og anvendelse deraf
US20090145343A1 (en) Sorbents for Removal of Mercury From Flue Gas Cross Reference To Related Applications
WO2007149833A2 (en) Methods of manufacturing mercury sorbents and removing mercury from a gas stream
WO2013082157A1 (en) Multi-functional composition for rapid removal of mercury from a flue gas
Balasundaram et al. Technology for mercury removal from flue gas of coal based thermal power plants: A comprehensive review
CA2600876C (en) Adsorbents for mercury removal from flue gas
WO2015051363A1 (en) Method and system for removing gaseous mercury in flue gases
CN107159088B (zh) 具有持久吸附性能的纳汞材料
JP2007529305A (ja) 燃焼排ガス中の重金属を低減するための方法
CA2887676A1 (en) Gaseous mercury oxidation and capture
JP7032133B2 (ja) 流体精製方法
Zhang et al. Simultaneous removal of elemental mercury and arsine from a reducing atmosphere using chloride and cerium modified activated carbon
Uffalussy et al. Novel Capture Technologies: Non‐carbon Sorbents and Photochemical Oxidations
JP2006263587A (ja) 燃焼排ガス処理方法
Staszak et al. Energy industry
WANG et al. Removal of Hg0 from simulated coal-fired flue gas by using activated spent FCC catalysts
Xu et al. A Novel Furfural Residue Activated Carbon Powder for the Removal of Flue Gas Hg0
Huang et al. Novel sorbents and their sorptive properties for mercury emissions control of coal-fired flue gas
Fisher et al. Reactive carbon from life support wastes for incinerator flue gas cleanup-System Testing