DK2812111T3 - Fremgangsmåde til reformering af kulbrinter i forbindelse med en hexaaluminatholdig katalysator - Google Patents

Fremgangsmåde til reformering af kulbrinter i forbindelse med en hexaaluminatholdig katalysator

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Publication number
DK2812111T3
DK2812111T3 DK13747145.4T DK13747145T DK2812111T3 DK 2812111 T3 DK2812111 T3 DK 2812111T3 DK 13747145 T DK13747145 T DK 13747145T DK 2812111 T3 DK2812111 T3 DK 2812111T3
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DK
Denmark
Prior art keywords
hexaaluminate
connection
containing catalyst
reforming hydrocarbons
reforming
Prior art date
Application number
DK13747145.4T
Other languages
Danish (da)
English (en)
Inventor
Stephan Schunk
Andrian Milanov
Andreas Strasser
Guido Wasserschaff
Thomas Roussière
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Application granted granted Critical
Publication of DK2812111T3 publication Critical patent/DK2812111T3/da

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/737Hexaaluminate-type AB12O19
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/40Carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DK13747145.4T 2012-02-10 2013-02-07 Fremgangsmåde til reformering af kulbrinter i forbindelse med en hexaaluminatholdig katalysator DK2812111T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12154901 2012-02-10
PCT/IB2013/051024 WO2013118078A1 (de) 2012-02-10 2013-02-07 Hexaaluminathaltiger katalysator zur reformierung von kohlenwasserstoffen sowie ein verfahren zur reformierung

Publications (1)

Publication Number Publication Date
DK2812111T3 true DK2812111T3 (da) 2025-11-24

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ID=48946966

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DK13747145.4T DK2812111T3 (da) 2012-02-10 2013-02-07 Fremgangsmåde til reformering af kulbrinter i forbindelse med en hexaaluminatholdig katalysator

Country Status (9)

Country Link
EP (1) EP2812111B1 (enExample)
JP (1) JP6238909B2 (enExample)
KR (1) KR20140126366A (enExample)
CN (1) CN104080530B (enExample)
CA (1) CA2864063C (enExample)
DK (1) DK2812111T3 (enExample)
RU (1) RU2631497C2 (enExample)
WO (1) WO2013118078A1 (enExample)
ZA (1) ZA201406561B (enExample)

Families Citing this family (19)

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Publication number Priority date Publication date Assignee Title
EP2886514A1 (de) 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
JP6167911B2 (ja) * 2014-01-16 2017-07-26 株式会社村田製作所 触媒およびそれを用いて実施される改質方法
DE102014011213A1 (de) 2014-07-29 2016-02-04 Linde Aktiengesellschaft Verfahren zur Synthesegasherstellung
RU2017117872A (ru) * 2014-10-24 2018-11-26 Басф Се Высокотемпературный синтез алюминатов посредством пламенного аэрозольного пиролиза
CN107847860A (zh) * 2015-07-09 2018-03-27 优美科股份公司及两合公司 具有nh3‑scr活性、氨氧化活性和对挥发性钒和钨化合物的吸附能力的三效催化剂
US10577243B2 (en) * 2015-11-18 2020-03-03 Exxonmobil Research And Engineering Company Reforming catalyst
CN108262046A (zh) * 2016-12-30 2018-07-10 中国石油天然气股份有限公司 掺杂六铝酸盐氧化物催化剂、其制备方法及其应用
WO2018219992A1 (de) 2017-06-02 2018-12-06 Basf Se Verfahren zur kohlenstoffdioxid-hydrierung in gegenwart eines nickel- und magnesiumspinellhaltigen katalysators
EP3574994A1 (en) * 2018-05-30 2019-12-04 Basf Se Method for producing catalyst monoliths for the reforming of hydrocarbons
CN113329815B (zh) * 2019-01-31 2024-06-11 巴斯夫欧洲公司 包含包含氧、镧、铝和钴的混合氧化物的模制品
CN109939683B (zh) * 2019-04-09 2022-03-04 江苏新沃催化剂有限公司 一种催化燃烧VOCs的三元复合氧化物型催化剂及其制备方法
JP2023514815A (ja) 2020-01-31 2023-04-11 ビーエーエスエフ ソシエタス・ヨーロピア 成形物を調製する方法、成形物、及びメタン改質触媒としてのその使用
US20230311108A1 (en) 2020-07-29 2023-10-05 Basf Se Solid shaped body and use of the solid shaped body
KR20230043860A (ko) 2020-07-29 2023-03-31 바스프 에스이 솔리드 성형체 및 상기 솔리드 성형체의 용도
CN117480011A (zh) 2021-06-15 2024-01-30 巴斯夫欧洲公司 用于制备合成气的方法
WO2022263012A1 (de) 2021-06-15 2022-12-22 Linde Gmbh Verfahren zur aktivierung eines katalysators
EP4448441A1 (en) 2021-12-15 2024-10-23 Basf Se High pressure nh3-reforming and combined reforming of nh3 as co-feed for hydrocarbon/co2-reforming
WO2024003354A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt-based catalyst for the conversion of hydrocarbons to synthesis gas
WO2024003347A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt- and strontium-based catalyst for the conversion of hydrocarbons to synthesis gas

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JP2559718B2 (ja) * 1986-12-03 1996-12-04 東洋シ−シ−アイ株式会社 触媒燃焼反応用耐熱性触媒とその製造方法
FR2721837B1 (fr) * 1994-07-01 1996-08-30 Inst Francais Du Petrole Catalyseur d'oxydation resistant a des temperatures elevees, son procede de preparation et procede de combustion utilisant un tel catalyseur
US6413489B1 (en) * 1997-04-15 2002-07-02 Massachusetts Institute Of Technology Synthesis of nanometer-sized particles by reverse micelle mediated techniques
JP4163292B2 (ja) * 1998-07-28 2008-10-08 千代田化工建設株式会社 炭化水素の改質用触媒及び改質方法
JP4355047B2 (ja) * 1999-04-05 2009-10-28 石油資源開発株式会社 リホーミング用触媒およびこれを用いた合成ガスの製法
GB0115850D0 (en) * 2001-06-28 2001-08-22 Isis Innovations Ltd Catalyst
US7442669B2 (en) * 2002-03-05 2008-10-28 Tda Research, Inc. Oxidation catalysts comprising metal exchanged hexaaluminate wherein the metal is Sr, Pd, La, and/or Mn
GB0214383D0 (en) * 2002-06-21 2002-07-31 Isis Innovation Catalyst
JP4414951B2 (ja) * 2005-09-08 2010-02-17 日揮株式会社 炭化水素の接触部分酸化用の触媒及び合成ガスの製造方法
US20070111884A1 (en) * 2005-11-14 2007-05-17 Laiyuan Chen Catalyst support, supported catalyst, and methods of making and using the same
CN101306361A (zh) * 2007-05-15 2008-11-19 北京石油化工学院 反相微乳液法制备六铝酸盐催化剂的方法
WO2009104386A1 (ja) * 2008-02-21 2009-08-27 株式会社エフ・シー・シー 触媒担体の製造方法及び触媒担体
EP2119671A1 (en) * 2008-05-14 2009-11-18 Erik Elm Svensson Preparation of hexaaluminate
JP2010180096A (ja) * 2009-02-05 2010-08-19 Nagoya Institute Of Technology セラミック多孔性材料とその製造方法
CN101927160A (zh) * 2009-06-26 2010-12-29 中国科学院大连化学物理研究所 一种催化剂及其制备和应用

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Publication number Publication date
CN104080530A (zh) 2014-10-01
EP2812111A4 (de) 2015-11-18
CA2864063C (en) 2021-06-01
RU2014136535A (ru) 2016-04-10
WO2013118078A1 (de) 2013-08-15
EP2812111B1 (de) 2025-09-03
JP6238909B2 (ja) 2017-11-29
RU2631497C2 (ru) 2017-09-25
ZA201406561B (en) 2016-08-31
CN104080530B (zh) 2018-08-07
EP2812111A1 (de) 2014-12-17
KR20140126366A (ko) 2014-10-30
CA2864063A1 (en) 2013-08-15
JP2015511209A (ja) 2015-04-16

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