DK2672819T3 - Pesticide sammensætninger og fremgangsmåder relateret dertil - Google Patents

Pesticide sammensætninger og fremgangsmåder relateret dertil Download PDF

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DK2672819T3
DK2672819T3 DK12745254.8T DK12745254T DK2672819T3 DK 2672819 T3 DK2672819 T3 DK 2672819T3 DK 12745254 T DK12745254 T DK 12745254T DK 2672819 T3 DK2672819 T3 DK 2672819T3
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alkyl
haloalkyl
cycloalkyl
alkenyl
phenyl
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Gary D Crouse
Thomas C Sparks
William Hunter Dent
Casandra Lee Mcleod
Lawrence C Creemer
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Dow Agrosciences Llc
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Claims (16)

1. Molekyle ifølge formel 1,2 eller 3
hvor: (a) Ar! er (1) furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, thienyl eller (2) substitueret furanyl, substitueret phenyl, substitueret pyridazinyl, substitueret pyridyl, substitueret pyrimidinyl eller substitueret thienyl, hvor substitueret furanyl, substitueret phenyl, substitueret pyridazinyl, substitueret pyridyl, substitueret pyrimidinyl og substitueret thienyl har en eller flere substituenter, der uafhængigt er valgt blandt H, F, Cl, Br, I, CN, N02, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, C!-C6-alkoxy, C!-C6-haloalkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(Ci-C6-alkyl), S(=0)n(Cr Ce-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)NRxRy, (CrC6-alkyl) NRxRy, C(=0)(Ci-C6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(Cr C6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrC6-alkyl)0(Ci-C6-alkyl), (CrC6-alkyl)S(Ci-C6-alkyl), C(=0)(Ci-C6-alkyl)C(=0)0(CrC6-alkyl), phenyl, phenoxy, substitueret phenyl og substitueret phenoxy, hvor sådan substitueret phenyl og substitueret phenoxy har en eller flere substituenter, der uafhængigt er valgt blandt H, F, Cl, Br, I, CN, N02, Cr C6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrCe-haloalkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(Ci-C6-alkyl), S(=0)n(Ci-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(Ci-C6-haloalkyl), C(=0)NRxRy, (Ci-C6-alkyl)NRxRy, C(=0)(Ci-C6-alkyl), C(=0)0(Ci-C6-alkyl), C(=0)(Ci-C6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci-C6-alkyl)0(Ci-C6-alkyl), (Ci-C6-alkyl)S(CrC6-alkyl), C(=0)(CrC6-alkyl)C(=0)0(CrC6-alkyl), phenyl og phenoxy; (b) Het er en 5- eller 6-leddet, mættet eller umættet heterocyklisk ring, der indeholder et eller flere heteroatomer, som uafhængigt er valgt blandt nitrogen, svovl eller oxygen, og hvor An og Ar2 er ikke orto til hinanden (men kan være meta eller para, således for en femleddet ring er de 1,3 og for en 6-leddet ring er de enten 1,3 eller 1,4), og hvor den heterocykliske ring kan også være substitueret med en eller flere substituenter, der uafhængigt er valgt blandt H, F, Cl, Br, I, CN, N02, oxo, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(CrC6-alkyl), S (=0)n(CrC6-haloalkyl), 0S02(C1-C6-alkyl), OS02(CrC6-haloalkyl), C(=0)NRxRy, (CrC6-alkyl)NRxRy, C(=0)(CrC6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(CrC6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-Ce-alkenyl), (CrCe-alkyipiCrCe-alkyl), (CrC6-alkyl)S(CrC6-alkyl), C(=0)(C1-C6-alkyl) C(=0)0(C1-C6-alkyl), phenyl, phenoxy, substitueret phenyl og substitueret phenoxy, hvor sådan substitueret phenyl og substitueret phenoxy har en eller flere substituenter, der uafhængigt er valgt blandt H, F, Cl, Br, I, CN, N02, Cr C6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrC6-haloalkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(CrC6-alkyl), S(=0)n(Ci-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)NRxRy, (Cr Ce-alkyl) NRxRy, C(=0)(CrC6-alkyl), C(=0)0(C1-C6-alkyl)J C(=0)(Ci-C6-haloalkyl), C(=0)0(C1-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci-C6-alkyl)0(Ci-C6-alkyl), (Ci-C6-alkyl)S(Ci-C6-alkyl), C(=0)(Ci-C6-alkyl)C(=0)0(CrC6-alkyl), phenyl og phenoxy; (c) Ar2 er (1) furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, thienyl eller (2) substitueret furanyl, substitueret phenyl, substitueret pyridazinyl, substitueret pyridyl, substitueret pyrimidinyl eller substitueret thienyl, hvor substitueret furanyl, substitueret phenyl, substitueret pyridazinyl, substitueret pyridyl, substitueret pyrimidinyl og substitueret thienyl har en eller flere substituenter, der uafhængigt er valgt blandt H, F, Cl, Br, I, CN, N02, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, haloalkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(C1-C6-alkyl), S (=0)n(CrC6-haloalkyl), OSO^C!-C6-alkyl), OS02(CrC6-haloalkyl), C(=0)NRxRy, (CrCe-alkyl) NRxRy, C(=0)(CrC6-alkyi), C(=0)0(Ci-C6-alkyl), C(=0)(Ci-C6-haloalkyl), C(=0)0(CrC6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyi), C(=0)0(C2-C6-alkenyl), (CrC6-alkyl)0(CrC6-alkyl), (CrCe-alkyl^CrCe-alkyl), C(=0)(C1-C6-alkyi) C(=0)0(CrC6-alkyl), phenyl, phenoxy, substitueret phenyl og substitueret phenoxy, hvor sådan substitueret phenyl og substitueret phenoxy har en eller flere substituenter, der uafhængigt er valgt blandt H, F, Cl, Br, I, CN, N02, Cr C6-alkyl, Ci-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrC6-haloalkoxy, C2-Ce-alkenyl, C2-C6-alkynyl, S(=0)n(Ci-C6-alkyl), S(=0)n(Ci-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)NRxRy, (CrC6- alkyl)NRxRy, C(=0)(Ci-C6-alkyl), C(=0)0(Ci-C6-alkyl), C(=0)(Ci-C6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(CrC6-haloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci-C6-alkyl)0(Ci -C6-alkyl), (Ci -C6-al kyl)S(C! -C6-alkyl), C(=0)(Ci-C6-alkyl)C(=0)0(CrC6-alkyl), phenyl og phenoxy; (d) R1 er valgt blandt H, CN, F, Cl, Br, I, C^Cg-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkoxy, CrC6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(Ci-C6-alkyl), 0S02(Ci-C6-alkyl), C(=0)NRxRy, (CrC6-alkyl) NRxRy, C(=0)(CrC6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrCg-alkyipiCrCg-alkyl), (CrCg-alkyl^CrCg-alkyl), C(=0)(Ci-C6-alkyl) C(=0)0(Ci-C6-alkyl, phenyl eller phenoxy, hvor hver -alkyl, cycloalkyl, cycloalkoxy, alkoxy, alkenyl, alkynyl, phenyl og phenoxy eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, I, CN, N02, oxo, CrCg-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrC6-haloalkoxy, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(CrC6-alkyl), S (=0)n(Ci-C6-haloalkyl), 0S02(Ci-C6-alkyl), OS02(CrC6-haloalkyl), C(=0)NRxRy, (CrC6-alkyl) NRxRy, C(=0)(Ci-C6-alkyl), C(=0)0(C1-C6-alkyl), C(=0)(Ci-C6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrC6-alkyl)O(Ci-Ce-alkyl), (CrC6-alkyl)S(Ci-C6-alkyl), C(=0)(CrC6-alkyl) C(=0)0(Ci-C6-alkyl), phenyl og phenoxy; (e) R2 er H, CrCg-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C(=0)H, C(=0)(CrC6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-Cg-alkenyl), (C-i-Cg-alkyl)0(Ci-C6-alkyl), (C-|-Cg-alkyl)S(Ci-Cg-alkyl), C(=0)(CrC6-alkyl) C(=0)0(Ci-C6-alkyl), phenyl, Ci-C6-alkylphenyl, Cr Cg-alkyl-O-phenyl, C(=0)Flet-1, Het-1, CrCg-alkyl-Flet-1 eller CrC6-alkyl-O-Het-1, hvor hver alkyl, cycloalkyl, alkenyl, alkynyl, phenyl og Het-1 eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, I, CN, N02, NRxRy, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, Ci-C6-alkoxy, Ci-C6-haloalkoxy, C2-C6-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(C1-C6-alkyl), S(=0)n(C1-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)NRxRy, (Cr Ce-alkyl) NRxRy, C(=0)(CrC6-alkyl), C(=0)0(C1-C6-alkyl), C(=0)(CrC6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci-C6-alkyl)0(CrC6-alkyl), (Ci-C6-alkyl)S(Ci-C6-alkyl), C(=0)(C1-C6-alkyl) C(=0)0(CrC6-alkyl), phenyl, phenoxyog Het-1; (f) R3 er Ci-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C(=0)H, C(=0)(CrC6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrCg-alkyipiCrCg-alkyl), (CrCg-alkylJSiCrCg-alkyl), C(=0)(Ci-C6-alkyl) C(=0)0(Ci-C6-alkyl), phenyl, CrC6-alkylphenyl, Cr Ce-alkyl-O-phenyl, C(=0)Het-1, Het-1, Ci-C6-alkyl-Het-1, Ci-C6-alkyl-0-C(—0)C-i-Cg-al kyl-Ο-Ci-Cg-al kyl, Ci-Cg-al kyl-0-C(—0)Ci-Cg-alkyl-0-Ci-Cø-alkyl-0-CrC6-alkyl, Ci-Cg-alkyl-0-C(—0)Ci-Cg-alkyl-O-C-i-Cg-haloalkyl, C1-C6-alkyl-0-C(=0)C1-C6-alkyl-N(Rx)C(=0)-0-phenyl, CrC6-alkyl-0-C(=0)Ci-C6-alkyl-N (Rx)C(=0)-0-CrC6-alkylphenyl, CrC6-alkyl-C(=0)N(Rx)CrC6-alkyl, CrC6-alkyl-C(=0)N(Rx)CrC6-alkyl-Het-1-C(=0)-O-C1-Cg-alkyl, Ci-C6-alkyl-C(=0)N(Rx)CrC6-alkyl-Het-1, CrC6-alkyl-C(=0)-Het-1, Ci-C6-alkyl-C(=0)N(Rx)C1-C6-alkyl-(N(Rx)(Ry))(C(=0)0H), Ci-Cg-alkyl-C(=0)N(Rx)Ci-Cg-alkyl-N(Rx)(Ry), CrC6-alkyl-C(=0)N(Rx)Cr C6-alkyl-N(Rx)C(=0)-0-CrC6-alkyl, CrCg-alkyl-Ci^JNiR,) CrC6-alkyl (N (Rx) C(=0)-0-Ci-C6-alkyl) (C(=0)0H), CrC6-alkyl-C(=0) Het-1C(=0)-O-C1 -Cg-alkyl, Ci -C6-alkyl-0-C(=0)-0-Ci -C6-alkyl, Ci-C6-alkyl-0-C(=0) Ci-C6-alkyl, CrC6-alkyl-0-C(=0) C3-C6-cycloalkyl, CrC6-alkyl-0-C(=0)Het-1, CrC6-alkyl-0-C(=0) CrC6-alkyl-N (Rx) C(=0)-0-C1-C6-alkyl, Ci-C6-alkyl-NRxRy, eller CrCg-alkyl-O-Het-1, hvor hver alkyl, cycloalkyl, alkenyl, alkynyl, phenyl og Het-1 eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, I, CN, N02, NRxRy, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, Ci-C6-alkoxy, Ci-C6-haloalkoxy, C2-C6-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(C1-C6-alkyl), S(=0)n(C1-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)0H, C(=0)NRxRy, (CrC6-alkyl)NRxRy, C(=0)(C1-C6-alkyl), C(=0)0(C1-C6-alkyl), C(=0)(CrC6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrCe-alkyipiCrCe-alkyl), (Ci-C6-alkyl)S(CrC6-alkyl), C(=0)(C1-C6-alkyl)C(=0)0(C1-C6-alkyl), phenyl, phenoxy, SKCrCe-alkyl)3, S(=0)nNRxRy, og Het-1; (g) R4 er H, Ci-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C(=0)H, C(=0)(CrC6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-Ce-alkenyl), (Ci-C6-alkyl)0(CrC6-alkyl), (CrC6-alkyl)S(CrC6-alkyl), C(=0)(CrC6-alkyl) C(=0)0(Ci-C6-alkyl), phenyl, Ci-C6-alkylphenyl, Cr Ce-alkyl-O-phenyl, C(=0)Het-1, Het-1, CrC6-alkyl-Het-1 eller CrC6-alkyl-O-Het-1, hvor hver alkyl, cycloalkyl, alkenyl, alkynyl, phenyl og Het-1 eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, I, CN, N02, NRxRy, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrC6-haloalkoxy, C2-C6-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(CrC6-alkyl), S(=0)n(CrC6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)NRxRy, (Cr Ce-alkyl) NRxRy, C(=0)(CrC6-alkyl), C(=0)0(Ci-C6-alkyl), C(=0)(Ci-C6-haloalkyl), C(=0)0(CrC6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci -C6-aIkyI)0(Ci-C6-aIkyI), (Ci-C6-alkyl)S(Ci-C6-alkyl), C(=0)(CrC6-alkyl) C(=0)0(CrC6-alkyl), phenyl, phenoxy og Het-1; (h) R5 er en 2- til 4-leddet mættet eller umættet hydrocarbylbinding, hvor nævnte binding også kan være substitueret med F, Cl, Br, I, CN, N02, oxo, NRxRy, CrCe-alkyl, CrCe-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, Ci-C6-haloalkoxy, C2-C6-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(Ci-C6-alkyl), S(=0)n(CrC6-haloalkyl), 0S02(CrC6-alkyl), OS02(Ci-C6-haloalkyl), C(=0)H, C(=0)0H, C(=0)NRxRy, (CrC6-alkyl) NRxRy, C(=0)(C1-C6-alkyi), C(=0)0(CrC6-alkyl), C(=0)(CrC6-haloalkyl), C(=0)0(Ci-C6-haloalkyi), C(=0)(C3-C6-cycloalkyi), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci-C6-alkyOOiCrCe-alkyl), (CrCe-alky^S^-Ce-alkyl), C(=0)(Ci-C6-alkyi) C(=0)0(C1-C6-alkyl), phenyl, phenoxy og Het-1, hvor hver alkyl, cycloalkyl, cycloalkoxy, alkoxy, alkenyl, alkynyl, phenyl, phenoxy og Het-1 eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, I, CN, Ν02, oxo, NRxRy, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrCe-haloalkoxy, C2-C6-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(C1 -C6-alkyl), S(=0)n(Ci-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)0H, C(=0)NRxRy, (CrC6-alkyl)NRxRy, C(=0)(CrC6-alkyl), C(=0)0(Ci-C6-alkyl), C(=0)(CrC6-haloalkyl), C(=0)0(CrC6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrC6-alkyl)0(CrC6-alkyl), (Ci-C6-alkyl)S(Ci-C6-alkyl), C(=0)(Ci-C6-alkyl) C(=0)0(CrC6-alkyl), phenyl,-halophenyl, phenoxy og Het-1; (i) n = O, 1 eller 2; (j) Rx og Ry er uafhængigt valgt blandt H, Ci-C6-alkyl, Ci-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, S(=0)n(C1-C6-alkyl), S(=0)n(CrC6-haloalkyl), 0S02(Ci-C6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)(Ci-C6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(CrC6-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6- cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-Cg-alkenyl), (Ci-C6-alkyl)0(Ci-C6-alkyl), (Ci-C6-alkyl)S(CrC6-alkyl), C(=0)(CrC6-alkyl) C(=0)0(Ci-C6-alkyl) og phenyl, hvor hver alkyl, cycloalkyl, cycloalkoxy, alkoxy, alkenyl, alkynyl, phenyl, phenoxy og Het-1 eventuelt er substitueret med en eller flere substituenter uafhængigt valgt blandt F, Cl, Br, I, CN, N02, oxo, CrC6-alkyl, CrC6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrC6-alkoxy, CrC6-haloalkoxy, C2-Ce-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(CrC6-alkyl), S (=0)n(Ci-C6-haloalkyl), 0S02(Ci-C6-alkyl), OS02(CrC6-haloalkyl), C(=0)H, C(=0)OH, C(=0) (CrC6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(Cr Ce-haloalkyl), C(=0)0(Ci-C6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (Ci-C6-alkyl)0(^ -C6-al kyl), (Ci-C6-alkyl)S(Ci-C6-alkyl), C(=0)(C1 -C6-alkyl) C(=0)0(CrC6-alkyl), phenyl, halogenphenyl, phenoxy og Het-1, eller Rx og Ry sammen kan eventuelt danne en 5- til 7-leddet mættet eller umættet cyklisk gruppe, der kan indeholde et eller flere heteroatomer valgt blandt nitrogen, svovl og oxygen, og hvor den cykliske gruppe kan indeholde >C=0 eller >C=S og hvor den nævnte cykliske gruppe kan være substitueret med F, Cl, Br, I, CN, CrCs-alkyl, Ci-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkoxy, C3-C6-halocycloalkoxy, CrCe-alkoxy, CrCø-haloalkoxy, C2-C6-alkenyl, C3-C6-cycloalkenyl, C2-C6-alkynyl, S(=0)n(C1-C6-alkyl), S(=0)n(C1-C6-haloalkyl), 0S02(CrC6-alkyl), OS02(CrC6-haloalkyl), C(=0)(Ci-C6-alkyl), C(=0)0(CrC6-alkyl), C(=0)(Ci-C6-haloalkyl), C(=0)0(CrC6-haloalkyl), C(=0)(C3-C6-cycloalkyl), C(=0)0(C3-C6-cycloalkyl), C(=0)(C2-C6-alkenyl), C(=0)0(C2-C6-alkenyl), (CrCe-alkyipiCrCe-alkyl), (CrC6-alkyl)S(CrC6-alkyl), C(=0)(CrC6-alkyl) C(=0)0(CrC6-alkyl), phenyl, substitueret phenyl, phenoxy og Het-1; og (k) Het-1 er en 5- eller 6-leddet, mættet eller umættet heterocyklisk ring, der indeholder et eller flere heteroatomer uafhængigt valgt blandt nitrogen, svovl eller oxygen.
2. Molekylet ifølge krav 1, hvor Αη er en substitueret phenyl, hvor den substituerede phenyl har en eller flere substituenter, der uafhængigt er valgt blandt Ci-C6-haloalkyl og Ci-C6-halogenalkoxy, fortrinsvis uafhængigt valgt fra CF3, OCF3, og OCF2CF3.
3. Molekylet ifølge krav 1, hvor Αη er en substitueret phenyl, hvor den substituerede phenyl haren eller flere Cr C6-halogenalkoxy; Flet er en triazolyl; Ar2 er en phenyl; R1 erH; R2 er H; R3 er C1 -C6-alkylHet-1, hvori-alkyl og Het-1 eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, Ci-C6-alkyl, Ci-C6-haloalkyl, CrCe-haloalkoxy, S(=0)n(CrC6-alkyl), C(=0)0H, C(=0)0(C1-C6-alkyl), phenyl, Si(Ci-C6-alkyl)3, og S(=0)nNRxRy; R4 er phenyl, hvor phenylen eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, NRxRy, CrC6-alkyl eller Cr C6-alkoxy; og n = 0, 1 eller 2; Rx og Ry er uafhængigt valgt blandt Fl og phenyl, hvor phenylen eventuelt kan være substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F og Cl; og hvor Het-1 er en 5- eller 6-leddet, mættet eller umættet heterocyklisk ring, der indeholder et eller flere heteroatomer uafhængigt valgt blandt nitrogen, svovl eller oxygen.
4. Molekylet ifølge krav 1, hvor - Ar2 er en phenyl, - R2 er H, - R3 er CrC6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, CrCø-alkylphenyl, Cr C6-alkylHet-1, C1-C6alkyl-0-C(=0)C1-C6-alkyl-0-C1-C6-alkyl, CrC6-alkyl- 0-C(=0)C1-C6-alkyl-0-C1-C6-alkyl-0-C1-C6-alkyl, C-|-Cø-alkyl-0-C(—0)C-|-Ce-alkyl-O-CrCe-haloalkyl, Ci-C6-alkyl-0-C(=0)Ci-C6-alkyl-N(Rx) C(=0)-O-phenyl, Ci-C6-alkyl-0-C(=0)Ci-C6-alkyl-N(Rx) C(=0)-0-CrC6-alkylphenyl, C1-C6-alkyl-C(=0)N(Rx)C1-C6-alkylJ C1-C6-alkyl-C(=0)N(Rx) C1-C6-alkyl-Het-1C(=0)-0-C1-C6-alkyl> C1-C6alkyl-C(=0)N(Rx)C1-C6-alkyl-Het-1, CrC6-alkyl-C(=0)Het-1, C1-C6-alkyl-C(=0)N(Rx)C1-C6-alkyl (N(Rx)(Ry))(C(=0)0H), Ci-C6-alkyl-C(=0)N(Rx)Ci-C6-alkyl-N(Rx)(Ry), Cr C6-alkyl-C(=0)N(Rx)Ci-C6-alkyl-N(Rx)C(=0)-0-CrC6-alkyl> CrC6-alkyl-C(=0)N(Rx)C1-C6-alkyl-(N(Rx)C(=0)-0-C1-C6-alkyl)(C(=0)0H)> CrC6-alkyl-C(=0)Het-1-C(=0)-0-C1-C6-alkyl> C1-C6-alkyl-0-C(=0)-0-C1-C6-alkyl, C-|-Cø-alkyl-0-C(—0)G-i-Gø-alkyl, C-|-Cø-alkyl-0-C(—0)C3-Cø-cycloalkyl, CrC6-alkyl-0-C(=0)Het-1 eller Ci-Cø-alkyl-0-C(=0)CrCø-alkyl-N(Rx)C(=0)-0-Ci-C6-alkyl hvor hver -alkyl, -alkenyl, -alkynyl, phenyl og Het-1 eventuelt er substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F, Cl, Br, Ci-C6-alkyl, CrC6-haloalkyl, Ci-C6-haloalkoxy, S(=0)n(Ci-Cø-alkyl), C(=0)0H, C(=0)0(Ci-C6-alkyl), phenyl, Si(Ci-C6-alkyl)3, og S(=0)nNRxRy, - R4 er phenyl, Ci-C6-alkylphenyl eller CrC6-alkyl-0-phenyl, hvor hver-alkyl og phenyl eventuelt er substitueret med en eller flere substituenter uafhængigt valgt blandt F, Cl, NRxRy, C^Cø-alkyl eller CrCø-alkoxy, - R5 er substitueret med oxo, C(=0)0FI, phenyl og Het-1, hvor hver phenyl og Het-1 eventuelt kan være substitueret med en eller flere substituenter, der uafhængigt er valgt blandt oxo, Ci-C6-haloalkyl, Ci-C6-haloalkoxy, C(=0)0FI og -halophenyl, eller - Rx og Ry er uafhængigt valgt blandt Fl og phenyl, hvor nævnte phenyl eventuelt kan være substitueret med en eller flere substituenter, der uafhængigt er valgt blandt F og Cl.
5. Molekylet ifølge krav 1, hvor R1 er H eller CrCe-alkyl, fortrinsvis H eller CH3.
6. Molekylet ifølge krav 1, hvor Het er valgt blandt benzofuranyl, benzoisothiazolyl, benzoisoxazolyl, benzoxazolyl, benzothienyl, benzothiazolyl, cinnolinyl, furanyl, indazolyl, indolyl, imidazolyl, isoindolyl, isoquinolinyl, isothiazolyl, isoxazolyl, oxadiazolyl, oxazolinyl, oxazolyl, phthalazinyl, pyrazinyl, pyrazolinyl, pyrazolyl, pyridazinyl, pyridyl, pyrimidinyl, pyrrolyl, quinazolinyl, quinolinyl, quinoxalinyl, tetrazolyl, thiazolinyl, thiazolyl, thienyl, triazinyl, triazolyl, piperazinyl, piperidinyl, morpholinyl, pyrrolidinyl, tetrahydrofuranyl, tetrahydropyranyl, 1,2,3,4-tetrahydroquinolinyl, 4,5-dihydro-oxazolyl, 4,5-dihydro-1H-pyrazolyl, 4,5-dihydro-isoxazolyl og 2,3-dihydro-[1,3,4]-oxadiazolyl, fortrinsvis fra triazolyl, imidazolyl eller pyrazolyl, der kan være substitueret eller usubstitueret, hvor mere
fortrinsvis Het er en 1,2,4-triazolyl, en 1,4-imidazolyl
en 1,3-pyrazolyl
endnu mere foretrukket en substitueret 1,3-pyrazolyl, eller en 1,4-pyrazolyl
eller hvor Het-1 er valgt blandt benzofuranyl, benzoisothiazolyl, benzoisoxazolyl, benzoxazolyl, benzothienyl, benzothiazolyl, benzothiadizolyl, cinnolinyl, furanyl, indazolyl, indolyl, imidazolyl, isoindolyl, isoquinolinyl, isothiazolyl, isoxazolyl, oxadiazolyl, oxazolinyl, oxazolyl, phthalazinyl, pyrazinyl, pyrazolinyl, pyrazolyl, pyridazinyl, pyridyl, pyrimidinyl, pyrrolyl, quinazolinyl, quinolinyl, quinoxalinyl, tetrazolyl, thiazolinyl, thiazolyl, thienyl, thienylpyrazolyl, triazinyl, triazolyl, piperazinyl, piperidinyl, morpholinyl, pyrrolidinyl, tetrahydrofuranyl, tetrahydropyranyl, 1,2,3,4-tetrahydroquinolinyl, 4,5-dihydro-oxazolyl, 4,5-dihydro-1H-pyrazolyl, 4,5-dihydro-isoxazolyl og 2,3-dihydro-[1,3,4]-oxadiazolyl, fortrinsvis fra benzofuranyl, benzoisothiazolyl, benzoisoxazolyl, benzoxazolyl, benzothienyl, benzothiazolyl, cinnolinyl, furanyl, indazolyl, indolyl, imidazolyl, isoindolyl, isoquinolinyl, isothiazolyl, isoxazolyl, oxadiazolyl, oxazolinyl, oxazolyl, phthalazinyl, pyrazinyl, pyrazolinyl, pyrazolyl, pyridazinyl, pyridyl, pyrimidinyl, pyrrolyl, quinazolinyl, quinolinyl, quinoxalinyl, tetrazolyl, thiazolinyl, thiazolyl, thienyl, triazinyl, triazolyl, piperazinyl, piperidinyl, morpholinyl, pyrrolidinyl, tetrahydrofuranyl, tetrahydropyranyl, 1,2,3,4-tetrahydroquinolinyl, 4,5-dihydro-oxazolyl, 4,5-dihydro-1H-pyrazolyl, 4,5-dihydro-isoxazolyl og 2,3-dihydro-[1,3,4]-oxadiazolyl og mere fortrinsvis fra benzothiadizolyl, furanyl, oxazolyl og thienylpyrazolyl.
7. Molekylet ifølge krav 1, hvor molekylet er valgt blandt
8. Sammensætning der omfatter et molekyle ifølge krav 1.
9. Ikke-terapeutisk fremgangsmåde til anvendelse af en sammensætning ifølge krav 8, hvilken fremgangsmåde omfatter at påføre en sammensætning ifølge krav 8 til et areal til bekæmpelse af et skadedyr i en mængde, der er tilstrækkelig til at kontrollere et sådant skadedyr.
10. Ikke-terapeutisk fremgangsmåde ifølge krav 9, hvor molekylet er valgt blandt
og skadedyret er bedehærorm (BAW), majskolbeorm (CEW) eller grøn ferskenbladlus (GPA).
11. Ikke-terapeutisk fremgangsmåde ifølge krav 9, hvor området er et område hvor æbler, majs, bomuld, sojabønner, rasp, hvede, ris, sorghum, byg, havre, kartofler, appelsiner, lucerne, salat, jordbær, tomater, peberfrugter, korsfrugter, pærer, tobak, mandler, sukkerroer eller bønner vokser, eller frøene deraf vil blive plantet.
12. Sammensætningen ifølge krav 8 der omfatter et pesticid-acceptabelt syreadditionssalt, et salt, et solvat eller et polymorf af et molekyle ifølge krav 1 eller et molekyle ifølge krav 1, hvor mindst en H er 2H eller mindst en C er 14C.
13. Sammensætningen ifølge krav 8, der yderligere omfatter mindst en anden forbindelse valgt fra insecticid-gruppen, acaricid-gruppen, nematicid-gruppen, fungicid-gruppen, herbicid-gruppen, Al-gruppen eller synergist-gruppen eller mindst en forbindelse, der har en virkningsmåde, der er valgt blandt acetylcholinesteraseinhibitor, natriumkanalmodulator, chitinbiosynteseinhibitor, GABA-styret chloridkanal-antagonist, GABA- og glutamat-styret chloridkanal-agonist, acetylcholinreceptor-agonist, METI-inhibitor, Mg-stimuleret ATPase-hæmmer, nikotinacetylcholin-receptor, Midgut-membran-disruptor, oxidativ phosphoryleringsdisrupterog ryanodin-receptor (RyRs).
14. Sammensætningen ifølge krav 8, der yderligere omfatter et frø; hvilket frø fortrinsvis er genetisk modificeret til at udtrykke et eller flere specialtræk.
15. Fremgangsmåden der omfatter anvendelse afen sammensætning ifølge krav 8 på en genetisk modificeret plante, der er blevet genetisk modificeret til at udtrykke et eller flere specialtræk.
16. Molekylet ifølge krav 1 eller en sammensætning ifølge krav 8 til anvendelse ved bekæmpelse af endoparasitter, ektoparasitter eller begge i et ikke-humant dyr ved oral administration, dermal applikation eller parenteral administration.
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