DK2671912T3 - Fremgangsmåde til stabilisering af polymerer indeholdende estergrupper - Google Patents

Fremgangsmåde til stabilisering af polymerer indeholdende estergrupper Download PDF

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Publication number
DK2671912T3
DK2671912T3 DK12170771.5T DK12170771T DK2671912T3 DK 2671912 T3 DK2671912 T3 DK 2671912T3 DK 12170771 T DK12170771 T DK 12170771T DK 2671912 T3 DK2671912 T3 DK 2671912T3
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DK
Denmark
Prior art keywords
liquid
carbodiimides
process according
ester groups
containing ester
Prior art date
Application number
DK12170771.5T
Other languages
English (en)
Inventor
Wilhelm Laufer
Armin Eckert
Original Assignee
Rhein Chemie Rheinau Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhein Chemie Rheinau Gmbh filed Critical Rhein Chemie Rheinau Gmbh
Application granted granted Critical
Publication of DK2671912T3 publication Critical patent/DK2671912T3/da

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/29Compounds containing one or more carbon-to-nitrogen double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/82Post-polymerisation treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyethers (AREA)

Claims (5)

1. Fremgangsmåde til stabilisering af polymerer indeholdende estergrupper, kendetegnet ved, at carbodiimider med formel (I)
(I), idet R1, R2, R4 og R6 uafhængigt af hinanden er C3-C6-alkyl, og R3 og R5 uafhængigt af hinanden svarer til Ci-C3-alkyl, i flydende form (væskedoseret) i kontinuerlige eller diskontinuerlige processer tilsættes til fremstilling og/eller forarbejdning heraf.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at grupperne R1 til R6 inde i molekylet er ens.
3. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at grupperne R1 til R6 er isopropyl.
4. Fremgangsmåde ifølge et eller flere af kravene 1 til 3, kendetegnet ved, at tilsætningen af den flydende carbodiimid sker ved temperaturer på 10 - 35 °C.
5. Fremgangsmåde ifølge et eller flere af kravene 1 til 4, kendetegnet ved, at det i forbindelse med polymererne drejer sig om polyethylenterephthalat (PET), polybutylenterephthalat (PBT), polytrimethylenterephthalat (PTT), termoplastiske polyurethaner (TPU), copolyestere, termoplastiske elastomerer baseret på polyester (TPE-E), polymælkesyre (PLA) og/eller PLA-derivater, polyhydroxyalkanoater (PHA), stivelsesbaserede kunststoffer og/eller polyamider (PA) eller blends heraf.
DK12170771.5T 2012-06-05 2012-06-05 Fremgangsmåde til stabilisering af polymerer indeholdende estergrupper DK2671912T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12170771.5A EP2671912B1 (de) 2012-06-05 2012-06-05 Verfahren zur Stabilisierung von Estergruppen-enthaltenden Polymeren

Publications (1)

Publication Number Publication Date
DK2671912T3 true DK2671912T3 (da) 2015-07-27

Family

ID=47915278

Family Applications (1)

Application Number Title Priority Date Filing Date
DK12170771.5T DK2671912T3 (da) 2012-06-05 2012-06-05 Fremgangsmåde til stabilisering af polymerer indeholdende estergrupper

Country Status (16)

Country Link
US (1) US20150175776A1 (da)
EP (1) EP2671912B1 (da)
JP (1) JP6174688B2 (da)
KR (1) KR102019532B1 (da)
CN (1) CN104364306A (da)
BR (1) BR112014030444B1 (da)
CA (1) CA2875157C (da)
DK (1) DK2671912T3 (da)
ES (1) ES2541410T3 (da)
HU (1) HUE026635T2 (da)
IN (1) IN2014DN10258A (da)
MX (1) MX2014014974A (da)
PL (1) PL2671912T3 (da)
PT (1) PT2671912E (da)
RU (1) RU2624299C2 (da)
WO (1) WO2013182330A1 (da)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LT6658B (lt) * 2017-12-08 2019-09-25 Douglas Craig Pet apdorojimo būdas
CN108912014A (zh) * 2018-06-22 2018-11-30 上海朗亿功能材料有限公司 一种液体型碳化二亚胺化合物制备方法与应用
EP3686239A1 (de) * 2019-01-23 2020-07-29 LANXESS Deutschland GmbH Hydrolysestabilisierte polyethylenterephthalat (pet) - haltige zusammensetzungen
EP4361209A1 (de) * 2022-10-27 2024-05-01 LANXESS Deutschland GmbH Hydrolysestabilisierte polyester-haltige zusammensetzungen

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1130594B (de) 1956-07-30 1962-05-30 Du Pont Verfahren zur Herstellung von gegebenenfalls modifizierten Polykondensationsprodukten mití¬N?C?N-Brueckengliedern
NL273087A (da) * 1960-12-31
US3798198A (en) * 1969-12-19 1974-03-19 Shoe & Allied Trades Res Ass Hydrolytically stabilized polyurethanes
US3711439A (en) * 1970-11-27 1973-01-16 Inmont Corp Stabilized polyurethane compositions
DE3930845A1 (de) * 1989-09-15 1991-03-28 Hoechst Ag Mit carbodiimiden modifizierte polyesterfasern und verfahren zu ihrer herstellung
DE4238046A1 (de) * 1992-11-11 1994-05-19 Basf Ag Neue Bis-(4-substituierte-2,6-diisopropyl-phenyl)-carbodiimide, ein Verfahren zu ihrer Herstellung und ihre Verwendung sowie die zu ihrer Herstellung verwendbaren 4-substituierten 2,6-Diisopropyl-phenylisocyanate
US6013340A (en) * 1995-06-07 2000-01-11 Nike, Inc. Membranes of polyurethane based materials including polyester polyols
DE19920276A1 (de) * 1999-05-04 2000-11-09 Basf Ag Thermoplastische Formmassen
DE10161863A1 (de) 2001-12-14 2003-07-03 Basf Ag Stabilisatorzusammensetzung II
JP3894846B2 (ja) * 2002-06-19 2007-03-22 平岡織染株式会社 難燃メッシュシート
KR20050004379A (ko) * 2003-07-02 2005-01-12 삼성전자주식회사 원자층 증착용 가스 공급 장치
US8247156B2 (en) * 2010-09-09 2012-08-21 Xerox Corporation Processes for producing polyester latexes with improved hydrolytic stability
CN102816087A (zh) * 2011-06-10 2012-12-12 上海朗亿功能材料有限公司 一种胶黏剂用水解稳定剂的制备方法

Also Published As

Publication number Publication date
US20150175776A1 (en) 2015-06-25
CA2875157C (en) 2020-07-14
HUE026635T2 (en) 2016-07-28
RU2624299C2 (ru) 2017-07-03
EP2671912A1 (de) 2013-12-11
JP2015518911A (ja) 2015-07-06
BR112014030444A2 (pt) 2017-06-27
IN2014DN10258A (da) 2015-08-07
PL2671912T3 (pl) 2015-10-30
KR20150024868A (ko) 2015-03-09
PT2671912E (pt) 2015-08-21
RU2014153978A (ru) 2016-07-27
MX2014014974A (es) 2015-03-13
ES2541410T3 (es) 2015-07-20
EP2671912B1 (de) 2015-04-22
CA2875157A1 (en) 2013-12-12
WO2013182330A1 (de) 2013-12-12
CN104364306A (zh) 2015-02-18
JP6174688B2 (ja) 2017-08-02
BR112014030444B1 (pt) 2021-02-17
KR102019532B1 (ko) 2019-09-06

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