DK2669007T3 - Fremgangsmåde til fremstilling af en katalysator under anvendelse af mindst ét trin til hurtigtørring, hvilken katalysator kan anvendes til Fischer-Tropsch-syntese - Google Patents

Fremgangsmåde til fremstilling af en katalysator under anvendelse af mindst ét trin til hurtigtørring, hvilken katalysator kan anvendes til Fischer-Tropsch-syntese Download PDF

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DK2669007T3
DK2669007T3 DK13305441.1T DK13305441T DK2669007T3 DK 2669007 T3 DK2669007 T3 DK 2669007T3 DK 13305441 T DK13305441 T DK 13305441T DK 2669007 T3 DK2669007 T3 DK 2669007T3
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temperature
oxide support
stage
catalyst
drying
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Sylvie Maury
Fabrice Diehl
Adrien Berliet
Joseph Lopez
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Ifp Energies Now
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)

Claims (7)

1. Fremgangsmåde til fremstilling af en katalysator omfattende en aktiv fase omfattende mindst ét metal fra gruppe VIII valgt blandt cobalt, nikkel, ruthenium og jern, alene eller i blanding, og en oxidbærer valgt blandt et alumina og et silica-alumina, hvilken fremgangsmåde omfatter: mindst ét trin til stabilisering af oxidbæreren for at danne en spinelstruktur mellem et metal valgt blandt cobalt, nikkel, magnesium, calcium og zink og oxidbæreren, hvilket stabiliseringstrin består i: et trin til imprægnering af oxidbæreren med en vandig opløsning af et eller flere salte af et metal valgt blandt cobalt, nikkel, magnesium, calcium og zink for at imprægnere et metalindhold på mellem 1 og 10 vægtprocent i forhold til den samlede vægt af den endelige katalysator, - et trin til tørring, hvor den imprægnerede oxidbærer drives frem ved hjælp af en gas, hvilken imprægnerede oxidbærer i nævnte trin udsættes for en temperaturstigningsrampe på mellem 250 og 600 °C/min, idet den imprægnerede oxidbærers opholdstid i tørringstrinet er på mellem 1 sekund og 1 minut, et trin til kalcinering af den imprægnerede og tørrede oxidbærer, hvilken kalcinering udføres i ét trin i luft ved en temperatur på mellem 700 og 1200 °C, i et tidsrum på mellem 1 h og 24 h, eller i to trin ved en temperatur på mellem 300 og 600 °C i luft, i et tidsrum på mellem %% h og 3 h, derefter ved en temperatur på mellem 700 og 1200 °C, i et tidsrum på mellem 1 h og 24 h. idet stabiliseringstrinet efterfølges af mindst ét gennemløb af følgende trin: - et trin til imprægnering af den stabiliserede oxidbærer, hvilket imprægneringstrin udføres med mindst én opløsning, der indeholder mindst én precursor for metallet fra gruppe VIII valgt blandt cobalt, nikkel, ruthenium og jern, - et trin til tørring af den stabiliserede og imprægnerede oxidbærer, hvilket trin gennemføres i fluidiseret leje i nærværelse af en gas, hvor bæreren udsættes for en temperaturstigningsrampe på mellem 0,5 og 5 °C/min for at opnå en temperatur på mellem 50 og 170 °C, idet bærerens opholdstid i tørringstrinet, efter opnåelse af tørringstemperaturen, er på mellem 20 og 180 min, et trin til kalcinering af den imprægnerede og tørrede stabiliserede oxidbærer, hvilket kalcineringstrin udføres ved en temperatur på mellem 320 og 460 °C og i et tidsrum på mellem 15 min og 15 h, for at opnå en katalysator i oxidform, hvor metallet fra gruppe VIII er homogent fordelt.
2. Fremgangsmåde ifølge krav 1, hvor den aktive fase omfatter cobalt.
3. Fremgangsmåde ifølge et hvilket som helst af kravene 1-2, hvor oxidbæreren består af silica-alumina.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1-3, hvor gassen, der anvendes i stabiliseringstrinets tørringstrin, er luft, alene eller i blanding med en inaktiv gas.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1-4, hvor gassens temperatur ved indgangen til stabiliseringstrinets tørringstrin er på mellem 300 og 800 °C.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1-5, hvor gennemløbet af imprægnerings-, tørrings- og kalcineringstrinene, i nævnte rækkefølge, udføres mindst to gange.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1-6, hvor trinet til kalcinering af den imprægnerede og tørrede stabiliserede oxidbærer udføres i fluidiseret leje i nærværelse af en gas, hvor den imprægnerede og tørrede stabiliserede oxidbærer udsættes for en temperaturstigningsrampe på mellem 0,5 og 5 °C/min for at opnå en temperatur på mellem 300 og 450 °C, idet bærerens opholdstid i kalcineringstrinet, efter opnåelse af kalcineringstemperaturen, er på mellem 5 og 120 min.
DK13305441.1T 2012-05-30 2013-04-05 Fremgangsmåde til fremstilling af en katalysator under anvendelse af mindst ét trin til hurtigtørring, hvilken katalysator kan anvendes til Fischer-Tropsch-syntese DK2669007T3 (da)

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FR1201542A FR2991198B1 (fr) 2012-05-30 2012-05-30 Procede de preparation d'un catalyseur mettant en oeuvre au moins une etape de sechage rapide et au moins une etape de sechage en lit fluidise et son utilisation pour la synthese fischer-tropsch

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JP (1) JP6220558B2 (da)
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US9333496B2 (en) * 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
FR3018702B1 (fr) * 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR3039432B1 (fr) 2015-07-31 2017-08-04 Ifp Energies Now Procede de preparation d'un catalyseur destine a etre mis en œuvre dans une reaction fischer-tropsch.
FR3041270A1 (fr) * 2015-09-17 2017-03-24 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib, de bore et d'un support contenant du phosphore introduit sous forme d'un sel
JP6599223B2 (ja) * 2015-12-16 2019-10-30 岩谷産業株式会社 炭化水素合成触媒の製造方法、炭化水素製造方法
CN108722411B (zh) * 2017-04-25 2021-03-09 天津大学 α-三氧化二铝负载四氧化三铁的催化剂及其制备方法
WO2020121076A1 (en) * 2018-12-10 2020-06-18 Sasol South Africa Limited Process for preparing a cobalt-containing catalyst precursor and process for hydrocarbon synthesis
CN114713282B (zh) * 2021-01-05 2023-08-04 中国石油化工股份有限公司 一种甲醇制烯烃催化剂的改性方法

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FR2718145B1 (fr) * 1994-04-01 1996-05-31 Inst Francais Du Petrole Procédé de traitement avec hydroisomérisation de charges issues du procédé fischer-tropsch.
ATE243561T1 (de) * 1998-10-05 2003-07-15 Sasol Tech Pty Ltd Tränkungsverfahren für katalysatoren
WO2001039882A1 (en) 1999-12-01 2001-06-07 Sasol Technology (Proprietary) Limited Cobalt catalysts
ATE339484T1 (de) * 2001-07-27 2006-10-15 Sasol Tech Pty Ltd Verfahren zur herstellung von fischer-tropsch- wachsen
US7341976B2 (en) 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
FR2879478B1 (fr) 2004-12-17 2007-10-26 Inst Francais Du Petrole Catalyseur a base de cobalt pour la synthese fisher-tropsch
US8394864B2 (en) * 2008-04-15 2013-03-12 Sasol Technology (Proprietary) Limited Catalysts
US20100022388A1 (en) * 2008-07-25 2010-01-28 Soled Stuart L Preparation of high activity cobalt catalysts, the catalysts and their use
FR2962664B1 (fr) * 2010-07-16 2014-03-14 IFP Energies Nouvelles Catalyseur a base de cobalt sur support silice-alumine pour la synthese fischer-tropsch
EP2603316B1 (en) * 2010-08-09 2017-04-19 Gtl. F1 Ag Fischer-tropsch catalysts

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US9259713B2 (en) 2016-02-16
FR2991198B1 (fr) 2015-05-15
EP2669007B1 (fr) 2018-06-13
JP6220558B2 (ja) 2017-10-25
CA2818058A1 (fr) 2013-11-30
US20130324624A1 (en) 2013-12-05
JP2013248609A (ja) 2013-12-12
CN103447040B (zh) 2017-03-01
FR2991198A1 (fr) 2013-12-06
CN103447040A (zh) 2013-12-18

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