DK2601159T3 - Fremgangsmåde til fremstilling af olefiner af isobutanol - Google Patents

Fremgangsmåde til fremstilling af olefiner af isobutanol Download PDF

Info

Publication number
DK2601159T3
DK2601159T3 DK11730958.3T DK11730958T DK2601159T3 DK 2601159 T3 DK2601159 T3 DK 2601159T3 DK 11730958 T DK11730958 T DK 11730958T DK 2601159 T3 DK2601159 T3 DK 2601159T3
Authority
DK
Denmark
Prior art keywords
isobutanol
catalyst
reactor
process according
propylene
Prior art date
Application number
DK11730958.3T
Other languages
English (en)
Inventor
Cindy Adam
Delphine Minoux
Nikolai Nesterenko
Donk Sander Van
Jean-Pierre Dath
Original Assignee
Total Res & Technology Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Res & Technology Feluy filed Critical Total Res & Technology Feluy
Application granted granted Critical
Publication of DK2601159T3 publication Critical patent/DK2601159T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/026—Unsaturated compounds, i.e. alkenes, alkynes or allenes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/16—Butanols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Claims (14)

  1. Fremgangsmåde til fremstilling af olefiner af isobutanol
    1. Fremgangsmåde til omdannelse af en alkoholblanding (A) omfattende 20 vægt-% til 100 % isobutanol for primært at fremstille propylen, hvilken fremgangsmåde omfatter: a) tilføring til en reaktor (A) af en strøm omfattende blandingen (A), eventuelt vand, eventuelt en inert komponent, b) etablering af kontakt mellem strømmen og en katalysator (A1) ved en temperatur over 450 °C i reaktoren (A) under forhold, der kan dehydrere mindst en del af isobutanolen og andre, eventuelle, alkoholer, og fremstille en cracking, c) genvinding fra reaktoren (A) af en effluent, der omfatter: ethylen, propylen, vand, eventuelt ikke-omdannede alkoler fra blandingen (A), diverse carbonhydrider og den eventuelle inertekomponent fra trin a), d) fraktionering af effluenten fra trin c) for at fremstille mindst en ethylenstrøm, en propylenstrøm, en fraktion, der primært består af carbonhydrider med 4 carbonatomer eller flere, vand og den eventuelle inerte komponent fra trin a), eventuel tilbageføring af ethylen i hele eller i en del af indgangen til reaktoren (A), eventuel tilbageføring fra fraktionen, der primært består af carbonhydrider med 4 carbonatomer eller flere ved indgangen af reaktoren (A), hvor alkoholernes partialtryk i trin a) og b) er lavere end 0,4 MPa.
  2. 2. Fremgangsmåde ifølge krav 1 hvor, inden tilbageføring af carbonhydriderne med 4 carbonatomer eller flere ved indgangen til reaktoren (A), carbonhydriderne med 4 carbonatomer eller flere sendes til en anden fraktionator til udrensning af tunge forbindelser.
  3. 3. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor alkoholtilførslen oprenses for at reducere indholdet i metalionerne, navnlig i Na, Fe, K, Ca og Al.
  4. 4. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor temperaturen i reaktoren i trin a) og b) ligger inden for intervallet fra 450° til 650 °C, fortrinsvis fra 500° til 650 °C, mere fortrinsvis fra 520° til 600 °C, og endnu mere fortrinsvis fra 540 °C til 590 °C.
  5. 5. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor alkoholblandingen (A) omfatter 40 til 100 vægt-% isobutanol, fortrinsvis 60 til 100 vægt-% isobutanol, mere fortrinsvis 80 til 100 vægt-% isobutanol.
  6. 6. Fremgangsmåde ifølge krav 5 hvor alkoholblandingen (A) primært omfatter isobutanol.
  7. 7. Fremgangsmåde ifølge et hvilket som helst af de foregående krav hvor katalysatoren (A1) er et krystallinsk silicat, der mindst omfatter én 10-leddet ring i strukturen.
  8. 8. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 6, hvor katalysatoren (A1) er en P-modificeret zeolit.
  9. 9. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvilken fremgangsmåde endvidere omfatter et yderligere trin, hvor ethylen omsættes med 2-buten fra fraktionen, der i alt væsentligt består af carbonhydrider med 4 carbonatomer eller flere, der er genvundet i trin d), for at producere propylen.
  10. 10. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 8, hvilken fremgangsmåde omfatter et yderligere trin, hvor n-butenerne fra fraktionen, der i alt væsentligt består af carbonhydrider med 4 carbonatomer eller flere, der er genvundet i trin d), omsættes i en automethathese for at fremstille propylen og pentener.
  11. 11. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor isobutanol opnås ved fermentering af carbohydrater, der stammer fra biomassen, eller fra syntesegasvejen eller fra den basekatalyserede Guerbet-kondensation.
  12. 12. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 10, hvor isobutanol fremstilles ved den direkte 2-ketosyrebane af carbohydrater, der er isoleret fra biomassen.
  13. 13. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor ethylen polymeriseres yderligere eventuelt med én eller flere comonomerer.
  14. 14. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 12, hvor propylen polymeriseres yderligere eventuelt med én eller flere comonomerer.
DK11730958.3T 2010-08-03 2011-07-08 Fremgangsmåde til fremstilling af olefiner af isobutanol DK2601159T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10171672 2010-08-03
PCT/EP2011/061583 WO2012016787A1 (en) 2010-08-03 2011-07-08 Process to make olefins from isobutanol

Publications (1)

Publication Number Publication Date
DK2601159T3 true DK2601159T3 (da) 2016-08-15

Family

ID=43355523

Family Applications (1)

Application Number Title Priority Date Filing Date
DK11730958.3T DK2601159T3 (da) 2010-08-03 2011-07-08 Fremgangsmåde til fremstilling af olefiner af isobutanol

Country Status (8)

Country Link
US (3) US9056807B2 (da)
EP (1) EP2601159B1 (da)
CN (1) CN103153920B (da)
BR (1) BR112013002359B1 (da)
DK (1) DK2601159T3 (da)
ES (1) ES2582592T3 (da)
PL (1) PL2601159T3 (da)
WO (1) WO2012016787A1 (da)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140100404A1 (en) 2011-06-15 2014-04-10 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbons
US9434658B2 (en) 2013-03-06 2016-09-06 Ut-Battelle, Llc Catalytic conversion of alcohols to hydrocarbons with low benzene content
CN105377795A (zh) 2013-07-02 2016-03-02 Ut巴特勒有限公司 具有至少三个碳原子的醇到烃混合原料的催化转化
EP3390336A1 (en) * 2015-12-14 2018-10-24 Total Research & Technology Feluy Process for converting butanol into propylene
US10696606B2 (en) 2016-06-09 2020-06-30 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbon fractions with reduced gaseous hydrocarbon content
US9919983B2 (en) * 2016-06-22 2018-03-20 Uop Llc Processes and apparatuses for production of polypropylene
IT201600105178A1 (it) * 2016-10-19 2018-04-19 Versalis Spa Procedimento per la produzione di dieni
CN110753575A (zh) * 2017-06-07 2020-02-04 日本碍子株式会社 脱水方法及脱水装置
FR3090393B1 (fr) * 2018-12-20 2021-04-23 Ifp Energies Now Procédé de traitement d’une charge alcool pour la production d’oléfines
CN112209791B (zh) * 2019-07-12 2023-08-04 中国石油化工股份有限公司 一种叔丁醇转化生产丙烯的方法
CN112321378B (zh) * 2019-08-05 2022-06-28 中国石油化工股份有限公司 环氧丙烷的共氧化法联产工艺废液的再利用方法
CN111530444B (zh) * 2020-06-01 2023-10-27 四川泸天化股份有限公司 一种合成长链α-烯烃的催化剂及其制备方法和应用

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3529033A (en) * 1963-05-20 1970-09-15 Mobil Oil Corp Catalytic conversion
US3658927A (en) 1969-09-02 1972-04-25 Phillips Petroleum Co Olefin conversion and catalysts therefor
US3911041A (en) 1974-09-23 1975-10-07 Mobil Oil Corp Conversion of methanol and dimethyl ether
US3979472A (en) * 1975-03-28 1976-09-07 Mobil Oil Corporation Process for manufacturing hydrocarbons
US4568788A (en) 1980-11-17 1986-02-04 Phillips Petroleum Company Olefin disproportionation and catalyst therefor
EP0150832B1 (en) 1984-01-27 1988-11-02 Sumitomo Chemical Company, Limited A method for producing compounds having a double bond at the terminal
US4695560A (en) 1985-10-01 1987-09-22 Uop Inc. Catalyst for the selective hydrogenation of diolefinic hydrocarbons
US4698452A (en) 1986-10-02 1987-10-06 Institut Nationale De La Recherche Scientifique Ethylene light olefins from ethanol
US5026936A (en) * 1989-10-02 1991-06-25 Arco Chemical Technology, Inc. Enhanced production of propylene from higher hydrocarbons
US5171921A (en) * 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
EP0568913A3 (en) 1992-05-03 1995-03-22 Dalian Chemical Physics Inst Process for the conversion of methanol into light olefins and catalyst used therefor.
US6222087B1 (en) * 1999-07-12 2001-04-24 Mobil Oil Corporation Catalytic production of light olefins rich in propylene
US6797851B2 (en) 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US6768037B2 (en) 2002-10-30 2004-07-27 Chevron U.S.A. Inc. Process to upgrade fischer-tropsch products and form light olefins
US7288689B2 (en) * 2003-11-19 2007-10-30 Exxonmobil Chemical Patents Inc. Methanol and fuel alcohol production for an oxygenate to olefin reaction system
US20100029994A1 (en) 2006-12-01 2010-02-04 E. I. Du Pont De Nemours And Company Production of butenes and derivatives therefrom from dry ethanol
US20080132730A1 (en) * 2006-12-01 2008-06-05 Leo Ernest Manzer Process for making butenes from dry 2-butanol
US7910342B2 (en) 2007-04-18 2011-03-22 Butamax(Tm) Advanced Biofuels Llc Fermentive production of isobutanol using highly active ketol-acid reductoisomerase enzymes
EP2070896A1 (en) 2007-12-12 2009-06-17 BP p.l.c. A process for the conversion of n-butanol to di-isobutene and propene
EP2082801A1 (en) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining modified molecular sieves
EP2082802A1 (en) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
CN104761427A (zh) 2008-02-07 2015-07-08 道达尔研究技术弗吕公司 醇在结晶硅酸盐上的脱水
US8704010B2 (en) * 2010-05-07 2014-04-22 Celanese International Corporation Alcohol production process with impurity removal

Also Published As

Publication number Publication date
US9056807B2 (en) 2015-06-16
BR112013002359A2 (pt) 2016-05-24
ES2582592T3 (es) 2016-09-13
US20150225311A1 (en) 2015-08-13
PL2601159T3 (pl) 2016-11-30
US9522853B2 (en) 2016-12-20
CN103153920A (zh) 2013-06-12
EP2601159B1 (en) 2016-04-27
WO2012016787A1 (en) 2012-02-09
US20140148630A1 (en) 2014-05-29
BR112013002359B1 (pt) 2019-10-08
EP2601159A1 (en) 2013-06-12
US9162941B2 (en) 2015-10-20
US20160002122A1 (en) 2016-01-07
CN103153920B (zh) 2015-04-15

Similar Documents

Publication Publication Date Title
DK2601159T3 (da) Fremgangsmåde til fremstilling af olefiner af isobutanol
US9334202B2 (en) Process to make propylene from isobutanol by dehydration and subsequent cracking
DK2547638T3 (da) Samtidig dehydrering og skeletisomerisering af isobutanol på syrekatalysatorer
DK2547639T3 (da) FREMSTILLING AF PROPYLEN VIA SAMTIDIG DEHYDRERING og SKELETISOMERISERING AF ISOBUTANOL PÅ SYREKATALYSATORER EFTERFULGT AF METATESE
EP2231321A1 (en) Process for the preparation of an olefinic product
WO2012016788A1 (en) Process to make olefins from methanol and isobutanol
US9227885B2 (en) Process to make olefins from isobutanol
EP2374781A1 (en) Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
EP2366682A1 (en) Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts