DK2340295T3 - Fremgangsmåde til omdannelse af biomasse - Google Patents

Fremgangsmåde til omdannelse af biomasse Download PDF

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Publication number
DK2340295T3
DK2340295T3 DK09829596.7T DK09829596T DK2340295T3 DK 2340295 T3 DK2340295 T3 DK 2340295T3 DK 09829596 T DK09829596 T DK 09829596T DK 2340295 T3 DK2340295 T3 DK 2340295T3
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Denmark
Prior art keywords
biomass
catalyst
product
riser
particles
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DK09829596.7T
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English (en)
Inventor
Robert Bartek
Steve Yanik
Paul O'connor
Dennis Stamires
Michael Brady
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Kior Inc
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Publication of DK2340295T3 publication Critical patent/DK2340295T3/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/02—Multi-step carbonising or coking processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/57—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds according to the fluidised bed technique
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)

Claims (17)

1. Fremgangsmåde til omdannelse af fast biomasse til carbonhydrider, omfattende: a. at bringe den faste biomasse i kontakt med en katalysator i et første stig-rør, der har en temperatur i området fra 50 °C til 200 °C, så der derved frembringes en første biomasse-katalysator-blanding og et første produkt omfattende carbonhydrider; b. at separere det første produkt fra den første biomasse-katalysator-blanding; c. at fylde den første biomasse-katalysator-blanding i et andet stigrør, der har en temperatur i området fra 200 °C til 400 °C, så der derved frembringes en anden biomasse-katalysator-blanding og et andet produkt omfattende carbonhydrider; d. at separere det andet produkt fra den anden biomasse-katalysator-blanding; e. at fylde den anden biomasse-katalysator-blanding i et tredje stigrør, der har en temperatur, der er højere end 450 °C, så der derved frembringes anvendt katalysator og et tredje produkt omfattende carbonhydrider; og f. at separere det tredje udstrømmende materiale fra den anvendte katalysator.
2. Fremgangsmåde ifølge krav 1, hvor det første stigrør har en temperatur i området fra 100 til 150 °C, og det andet stigrør har en temperatur i området fra 200 til 350 °C.
3. Fremgangsmåde ifølge krav 1, hvor det første produkt, det andet produkt og det tredje produkt blandes sammen til dannelse af et endeligt produkt omfattende bestanddele udvalgt fra gruppen bestående af ethan, propan, butan og carbonhydrider, der koger i området for naphtha, flybrændstof, diesel, fyringsolie og kombinationer deraf.
4. Fremgangsmåde ifølge krav 1, hvor den faste biomasse bringes i kontakt med katalysatoren ved omrøring i en gasstrøm, hvilket medfører tæt kontakt mellem den faste biomasse og katalysatoren.
5. Fremgangsmåde ifølge krav 1, hvor katalysatoren er udvalgt fra gruppen bestående af et katalytisk metal, en refraktær oxid, ler, hydrotalcit, krystallinsk aluminiumsilicat, lagdelt hydroxylsalt og kombinationer deraf.
6. Fremgangsmåde ifølge krav 1, hvor en tung fraktion af det andet produkt separeres fra det andet produkt og fyldes sammen med den anden biomas-se-katalysator-blanding i det tredje stigror til omdannelse til lettere carbonhy-drider.
7. Fremgangsmåde ifølge krav 1, hvor en tung fraktion af det tredje produkt separeres fra det tredje produkt og recirkuleres til det tredje stigror til omdannelse til lettere carbonhydrider.
8. Fremgangsmåde ifølge krav 1, hvor den anvendte katalysator fyldes i en regenerator, hvor koks afbrændes fra den anvendte katalysator og danner regenereret katalysator, og hvor dele af den regenererede katalysator recirkuleres til det andet stigror og det tredje stigror med eller uden mellemkøling.
9. Fremgangsmåde ifølge krav 8, hvor en del af den regenererede katalysator recirkuleres til det første stigror med eller uden mellemkøling.
10. Fremgangsmåde ifølge krav 1, hvor den anden biomasse-katalysator-blanding omfatter flydende biomasse-råmateriale, der er et resultat af omdannelsen af mindst en del af den faste biomasse, der er indeholdt i den første bi o m asse- katal ysato r- bl and i n g.
11. Fremgangsmåde ifølge krav 1, hvor den faste biomasse omfatter he-micellulose, cellulose og lignin.
12. Fremgangsmåde ifølge krav 11, hvor mindst en del af hemicellulosen omdannes til carbonhydrider i det første stigror.
13. Fremgangsmåde ifølge krav 11, hvor mindst en del af cellulosen omdannes til carbonhydrider i det andet stigror.
14. Fremgangsmåde ifølge krav 11, hvor mindst en del af ligninen omdannes til carbonhydrider i det tredje stigror.
15. Fremgangsmåde ifølge krav 1, hvor trin e) udføres i nærvær af damp.
16. Fremgangsmåde ifølge krav 1, hvor den faste biomasse mindst delvist tørres under trin a).
17. Fremgangsmåde ifølge krav 1, hvor petroleumråmateriale fyldes i det tredje stigror sammen med den anden biomasse-katalysator-blanding.
DK09829596.7T 2008-10-27 2009-10-27 Fremgangsmåde til omdannelse af biomasse DK2340295T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10865708P 2008-10-27 2008-10-27
PCT/US2009/062241 WO2010062611A2 (en) 2008-10-27 2009-10-27 Biomass conversion process

Publications (1)

Publication Number Publication Date
DK2340295T3 true DK2340295T3 (da) 2017-05-15

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US (1) US8003835B2 (da)
EP (1) EP2340295B1 (da)
CN (1) CN102197113B (da)
BR (1) BRPI0917976A2 (da)
CA (1) CA2733095C (da)
DK (1) DK2340295T3 (da)
WO (1) WO2010062611A2 (da)

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WO2010062611A3 (en) 2010-08-12
WO2010062611A2 (en) 2010-06-03
CA2733095A1 (en) 2010-06-03
CN102197113B (zh) 2014-12-10
CN102197113A (zh) 2011-09-21
EP2340295A4 (en) 2016-01-27
US8003835B2 (en) 2011-08-23
BRPI0917976A2 (pt) 2015-11-17
US20100105970A1 (en) 2010-04-29

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