DK0596437T3 - Biodegradable polymer blend - Google Patents
Biodegradable polymer blendInfo
- Publication number
- DK0596437T3 DK0596437T3 DK93117666.3T DK93117666T DK0596437T3 DK 0596437 T3 DK0596437 T3 DK 0596437T3 DK 93117666 T DK93117666 T DK 93117666T DK 0596437 T3 DK0596437 T3 DK 0596437T3
- Authority
- DK
- Denmark
- Prior art keywords
- starch
- mixture
- biodegradable polymer
- hydrophobic polymer
- essentially
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F9/00—Fertilisers from household or town refuse
- C05F9/04—Biological compost
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/14—Mixed esters, e.g. cellulose acetate-butyrate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
A biodegradable polymer mixture is proposed which essentially comprises starch and at least one hydrophobic polymer. The hydrophobic polymer should be at least substantially biodegradable and thermoplastically processible, and the mixture with the starch should contain a polymeric phase promoter or a macromolecular dispersant, so that the starch is present in the mixture as the disperse phase with the hydrophobic polymer as the continuous phase, and the phase promoter or the dispersant is responsible for the molecular coupling of the two phases. The starch used is preferably thermoplastic starch prepared by means of sorbitol or glycerol essentially in the absence of water. The preparation of the biodegradable polymer mixture should likewise take place essentially in the absence of water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4237535A DE4237535C2 (en) | 1992-11-06 | 1992-11-06 | Biodegradable polymer blend, process and film |
Publications (2)
Publication Number | Publication Date |
---|---|
DK0596437T3 true DK0596437T3 (en) | 1998-05-25 |
DK0596437T4 DK0596437T4 (en) | 2002-03-11 |
Family
ID=6472292
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK93117666T DK0596437T4 (en) | 1992-11-06 | 1993-11-02 | Biodegradable polymer blend |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0596437B2 (en) |
CN (1) | CN1044002C (en) |
AT (1) | ATE158805T1 (en) |
BR (1) | BR9304477A (en) |
DE (3) | DE4237535C2 (en) |
DK (1) | DK0596437T4 (en) |
ES (1) | ES2107600T5 (en) |
GR (1) | GR3025086T3 (en) |
HK (1) | HK1014016A1 (en) |
SG (1) | SG72624A1 (en) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2149296T3 (en) | 1994-08-25 | 2000-11-01 | Topac Multimediaprint Gmbh | CASE FOR A DISC SHAPED RECORD STAND. |
DE19519495A1 (en) * | 1995-05-27 | 1996-11-28 | Reynolds Tobacco Gmbh | Biodegradable thermoplastic materials for packaging cigarettes etc. |
AU700005B2 (en) | 1994-12-22 | 1998-12-17 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Technical and non-technical textile products and packaging materials |
US5498650A (en) * | 1995-02-24 | 1996-03-12 | Ecological Chemical Products | Poly(lactic acid) composition having improved physical properties |
DE19513237A1 (en) * | 1995-04-07 | 1996-12-05 | Biotec Biolog Naturverpack | Bio-degradable polymer mixt. for adhesive, hygiene articles etc. |
CA2217541A1 (en) * | 1995-04-07 | 1996-10-10 | Biotec Biologische Naturverpackungen Gmbh | Biologically degradable polymer mixture |
DE19516361A1 (en) * | 1995-05-04 | 1996-11-07 | Buna Sow Leuna Olefinverb Gmbh | Biodegradable packaging material |
DE19520093A1 (en) * | 1995-06-01 | 1996-12-05 | Bayer Ag | Polymer blends containing starch and polyurethanes |
DE19624641A1 (en) * | 1996-06-20 | 1998-01-08 | Biotec Biolog Naturverpack | Biodegradable material consisting essentially of or based on thermoplastic starch |
CA2263122C (en) * | 1996-08-09 | 2005-02-15 | Biotec Biologische Naturverpackungen Gmbh | Thermoplastic processable starch or starch derivative polymer mixtures |
EP0947559B1 (en) * | 1996-11-05 | 2004-10-27 | NOVAMONT S.p.A. | Biodegradable polymeric compositions comprising starch and a thermoplastic polymer |
ATE237656T1 (en) * | 1997-06-20 | 2003-05-15 | Biotec Biolog Naturverpack | WEAR ARTICLES IN THE DEFENSE OR PYROTECHNOLOGY AS WELL AS FOLDING ROADS, DRIVING AND WALKING AIDS MADE OF BIODEGRADABLE MATERIALS |
IT1303553B1 (en) | 1998-09-01 | 2000-11-14 | Novamont Spa | BIODEGRADABLE COMPOSITIONS INCLUDING STARCH AND CELLULOSE ESTERS. |
AU1070900A (en) * | 1998-12-23 | 2000-07-31 | Bayer Aktiengesellschaft | Biodegradable polymer materials or ternary polymer mixtures on a polysaccharide or polysaccharide derivative basis |
DE29905603U1 (en) | 1999-03-26 | 1999-09-09 | Tscheuschler, Ulrich, Dipl.-Ing., 79539 Lörrach | Containers for sex attractants made from compostable (biodegradable) polymers |
DE10010826A1 (en) * | 2000-03-08 | 2001-09-13 | Basf Ag | Use of starch and cellulose as phase mediators in the production of polymer compositions containing beeswax and/or montan ester wax, especially for making water vapor impermeable films or coatings |
DE10027905A1 (en) * | 2000-06-06 | 2001-12-13 | Bayer Ag | Biodegradable molding composition, useful for the production of plant covers, disposable cutlery, casings or packaging, comprises a biodegradable polymer and a mineral and/or a renewable material, |
DE10208858A1 (en) | 2002-03-01 | 2003-09-11 | Kalle Gmbh & Co Kg | Smoke and water vapor permeable food casing made of a thermoplastic mixture |
KR20020029050A (en) * | 2002-03-29 | 2002-04-17 | 주식회사 나선하이테크 | Disasemble resin and the manufacturing method for thereof |
DE10258227A1 (en) | 2002-12-09 | 2004-07-15 | Biop Biopolymer Technologies Ag | Biodegradable multilayer film |
CN1230466C (en) * | 2003-02-25 | 2005-12-07 | 丁少忠 | Fully bio-degradable plastic master batch and preparing process thereof |
DE10336387A1 (en) * | 2003-08-06 | 2005-03-03 | Basf Ag | Biodegradable polyester blend |
DE202007018690U1 (en) | 2006-04-14 | 2009-02-19 | Bio-Tec Biologische Naturverpackungen Gmbh & Co.Kg | Multilayer film |
DE102007026719B4 (en) | 2007-06-06 | 2014-05-15 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Shaped body produced by blown film extrusion of a biodegradable polymeric composition, use of the molding and method for producing the molding |
DE102007050770A1 (en) * | 2007-10-22 | 2009-04-23 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Polymeric material and process for its preparation |
DE102007050769A1 (en) | 2007-10-22 | 2009-04-23 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Polymeric material and process for its preparation |
DE202008017653U1 (en) | 2008-05-23 | 2010-06-10 | Schliewe, Jörg | Hygiene product with fully biodegradable materials and their use |
DE102009055688A1 (en) | 2009-11-25 | 2011-06-09 | Schliewe, Jörg | Method for manufacturing of hygiene products for receiving human excretions body, involves providing individual components of biological degradable materials, where biodegradable materials are assembled with mounting process |
DE102010012386A1 (en) | 2010-03-22 | 2011-09-22 | Jörg Beckmann | Preparing polymeric plastic, comprises adding hardener containing many components, and mixing in a close temporal connection, preferably immediately prior to processing |
DE202010004546U1 (en) | 2010-04-01 | 2010-07-22 | Rother, Sabine | Biodegradable packaging material |
TWI445755B (en) | 2012-06-27 | 2014-07-21 | Ind Tech Res Inst | Flame-retardant thermoplastic starch material, bio-composite and manufacturing method thereof |
DE202012103846U1 (en) | 2012-10-08 | 2012-10-25 | Heimbach Gmbh & Co. Kg | The paper machine belt |
CN103122083A (en) * | 2013-03-11 | 2013-05-29 | 太仓协乐高分子材料有限公司 | Preparation method of potato starch biodegradable plastic |
DE102013017024A1 (en) | 2013-10-15 | 2015-04-16 | Bio-Tec Biologische Naturverpackungen Gmbh & Co.Kg | polymer composition |
DE102013103614A1 (en) | 2013-04-10 | 2014-10-16 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | polymer composition |
CN103624989B (en) * | 2013-11-08 | 2016-05-04 | 苏州万图明电子软件有限公司 | A kind of modification compound film material preparation method for material |
DE102014019214A1 (en) | 2014-12-23 | 2016-06-23 | Bio-Tec Biologische Naturverpackungen Gmbh & Co.Kg | Process for the production of molded parts |
DE202016008627U1 (en) * | 2016-06-08 | 2018-10-15 | Martin Schwemmer | Material mixture for the production of water-soluble, biodegradable substances and water-soluble, biodegradable packaging |
CN107793591B (en) * | 2016-09-06 | 2020-10-16 | 中国石油化工股份有限公司 | Biodegradable polyester toughened thermoplastic polysaccharide blend and preparation method and film thereof |
DE102017126340A1 (en) | 2017-11-10 | 2019-05-16 | Innovent E.V. | SURFACE COATING COMPOSITION, PROCESS FOR THEIR PREPARATION AND THEIR USE |
CN109519887A (en) * | 2018-12-16 | 2019-03-26 | 李斌 | Anti-dazzle light device and lighting apparatus |
EP3674059A1 (en) * | 2018-12-28 | 2020-07-01 | Agrana Stärke GmbH | Compound or film containing thermoplastic starch and a thermoplastic polymer |
DE102020115765A1 (en) | 2020-06-15 | 2021-12-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Expandable granulate based on a renewable raw material and a process for its production |
DE102021101538A1 (en) | 2021-01-25 | 2022-07-28 | Bio-Tec Biologische Naturverpackungen Gmbh & Co.Kg | Polymer composition containing pea starch |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3485777A (en) * | 1966-03-28 | 1969-12-23 | Us Plywood Champ Papers Inc | Compatibilization of polymers by adding graft copolymers |
US3850863A (en) * | 1972-07-28 | 1974-11-26 | Union Carbide Corp | Blends of a biodegradable thermoplastic oxyalkanoyl polymer and a naturally occurring biodegradable product |
ZA815185B (en) * | 1980-08-06 | 1982-09-29 | Coloroll Ltd | Plastics based composition |
US4712460A (en) * | 1985-11-18 | 1987-12-15 | Biotrack, Inc. | Integrated drug dosage form and metering system |
CH672066A5 (en) * | 1987-02-20 | 1989-10-31 | Modima Sa | |
GB2214920A (en) * | 1988-02-03 | 1989-09-13 | Warner Lambert Co | Polymeric material made from destructurized starch and zein |
US5095054A (en) * | 1988-02-03 | 1992-03-10 | Warner-Lambert Company | Polymer compositions containing destructurized starch |
HUT54719A (en) * | 1988-07-20 | 1991-03-28 | Ivan Tomka | Process for improving hydrophyl solvent-proof character of hydrophyl polymeres |
DE3939721C2 (en) * | 1988-12-05 | 2002-08-01 | Nippon Synthetic Chem Ind | Polyvinyl alcohol-starch film |
IL93620A0 (en) | 1989-03-09 | 1990-12-23 | Butterfly Srl | Biodegradable articles based on starch and process for producing them |
DE3917324A1 (en) * | 1989-05-27 | 1990-11-29 | Basf Ag | THERMOPLASTIC MOLDING MATERIALS BASED ON POLYAMIDES AND POLYPHENYLENE ETHERS |
IT1233599B (en) | 1989-05-30 | 1992-04-06 | Butterfly Srl | POLYMERIC COMPOSITIONS FOR THE PRODUCTION OF BIODEGRADABLE PLASTIC ITEMS AND PROCEDURES FOR THEIR PREPARATION |
JPH0725941B2 (en) * | 1989-07-18 | 1995-03-22 | ワーナー・ランバート・カンパニー | Polymer-based blend composition containing modified starch |
US5206087A (en) * | 1990-02-28 | 1993-04-27 | Director-General Of Agency Of Industrial Science And Technology | Biodecomposable or biodisintegrable moldable material |
US5108807A (en) * | 1990-03-14 | 1992-04-28 | First Brands Corporation | Degradable multilayer thermoplastic articles |
CH680590A5 (en) * | 1990-04-26 | 1992-09-30 | Biotec Biolog Naturverpack | |
IT1242722B (en) * | 1990-08-09 | 1994-05-17 | Butterfly Srl | LAYERED STARCH FILM AND LOW PERMEABILITY AND PROCEDURE FOR ITS PRODUCTION. |
JPH04299131A (en) * | 1991-03-28 | 1992-10-22 | Dainippon Printing Co Ltd | Vessel for food |
EP0539541B1 (en) † | 1991-05-03 | 1997-07-09 | NOVAMONT S.p.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
DE4116404A1 (en) * | 1991-05-18 | 1992-11-19 | Tomka Ivan | POLYMERMISCHUNG FOR THE MANUFACTURE OF FOILS |
SG47625A1 (en) * | 1991-11-14 | 1998-04-17 | Bio Tech Biolog Naturverparkun | Biodegradable mould material |
-
1992
- 1992-11-06 DE DE4237535A patent/DE4237535C2/en not_active Revoked
-
1993
- 1993-11-02 ES ES93117666T patent/ES2107600T5/en not_active Expired - Lifetime
- 1993-11-02 SG SG9603242A patent/SG72624A1/en unknown
- 1993-11-02 DK DK93117666T patent/DK0596437T4/en active
- 1993-11-02 AT AT93117666T patent/ATE158805T1/en active
- 1993-11-02 DE DE9321391U patent/DE9321391U1/en not_active Expired - Lifetime
- 1993-11-02 DE DE59307460T patent/DE59307460D1/en not_active Expired - Lifetime
- 1993-11-02 EP EP93117666A patent/EP0596437B2/en not_active Expired - Lifetime
- 1993-11-06 CN CN93112699A patent/CN1044002C/en not_active Expired - Lifetime
- 1993-11-08 BR BR9304477A patent/BR9304477A/en not_active Application Discontinuation
-
1997
- 1997-10-17 GR GR970402727T patent/GR3025086T3/en unknown
-
1998
- 1998-12-17 HK HK98113956A patent/HK1014016A1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
SG72624A1 (en) | 2002-04-16 |
DE9321391U1 (en) | 1997-09-25 |
ES2107600T3 (en) | 1997-12-01 |
EP0596437A3 (en) | 1995-02-22 |
BR9304477A (en) | 1994-07-26 |
EP0596437B1 (en) | 1997-10-01 |
CN1088226A (en) | 1994-06-22 |
ATE158805T1 (en) | 1997-10-15 |
DE59307460D1 (en) | 1997-11-06 |
ES2107600T5 (en) | 2002-09-01 |
DE4237535C2 (en) | 2000-05-25 |
DE4237535A1 (en) | 1994-05-11 |
EP0596437B2 (en) | 2002-01-30 |
DK0596437T4 (en) | 2002-03-11 |
EP0596437A2 (en) | 1994-05-11 |
GR3025086T3 (en) | 1998-01-30 |
HK1014016A1 (en) | 1999-09-17 |
CN1044002C (en) | 1999-07-07 |
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