DE938723C - Process for the production of a modified plastic dispersion for the finishing of textiles - Google Patents
Process for the production of a modified plastic dispersion for the finishing of textilesInfo
- Publication number
- DE938723C DE938723C DEP8444A DEP0008444A DE938723C DE 938723 C DE938723 C DE 938723C DE P8444 A DEP8444 A DE P8444A DE P0008444 A DEP0008444 A DE P0008444A DE 938723 C DE938723 C DE 938723C
- Authority
- DE
- Germany
- Prior art keywords
- textiles
- dispersion
- plastic
- production
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/238—Tannins, e.g. gallotannic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Es ist zur Herstellung· von· Appreturen auf Textilien bekannt, wäßrige KunststO'ffdispersionen im Gemisch mit wasserunlöslichen Weichmachern!, gegebenenfalls Netzmittel», Borax und. Pigmenten, zu verwenden. Diese Appreturen werden auch durch öfteres Waschen aus den .Geweben nicht ausgewaschen und verleihen ihnen einen vollen Griff sowie Elastizität oder jeden gewünschten Steifheitsgrad. It is used to produce · finishes · on textiles known, aqueous KunststO'ffdispersionen mixed with water-insoluble plasticizers !, if appropriate Wetting agents », borax and. Pigments, to use. These finishes are too the fabrics are not washed out by repeated washing and give them a full grip as well as elasticity or any desired degree of stiffness.
Ferner ist es altbekannt, Textilien, insbesondere Leib-, Bett- und Tischwäsche, durch Aufbewahren, zusammen) mit Duftträgerm, wie L&vendßlkissen oder wohlriechenden Seifen, eine vorteilhafte Geruchsnoite zu verleihen, doch verliert sich dieselbe meist schon bed der Benutzung·, spätestens aber bei der nächsten Wäsche.It is also well known to store textiles, in particular body, bed and table linen, together) with fragrance carriers, such as pillow cases or fragrant soaps to impart a beneficial olfactory note, but the same is lost usually already used, but at the latest with the next wash.
Darüber hinaus- wäre es aber zu begrüßen1, wenn man nicht nur Wäsche, sondern auch andere Textilien des täglichen Gebrauchs, z. B. Kragen, Blusen und Kleider, ebenso wie Draperien für Innenräume, z,. B. Vorhänge und Sofakissen, und ferner Hüte, Kunstblumen, Kopftücher u. dgl. mit einer dauerhaften· Duftnote versehen könnte.In addition, it would be welcomed 1 if you not only use laundry, but also other textiles for everyday use, e.g. B. collars, blouses and dresses, as well as draperies for interiors, z. B. curtains and sofa cushions, and also hats, artificial flowers, headscarves and the like.
Es wurde nun gefunden, daß man Textilien gleichzeitig1 mit einer dauerhaften Appretur und einem dauerhaften Duft versehen kann, wenn· einer wäßrigen Dispersion von Kunststoff wasserunlösliche Weichmacher, die ätherische Öle als Duftstoffe gelöst enthalten, eingearbeitet werden, wobei diese Behandlung so lange fortgesetzt wird, bis das System Weichmacher—ätherisches öl in die Kunststöffteilchen aufgenommen ist.It has now been found that textiles can simultaneously 1 provided with a durable finish and a durable fragrance when included solved · an aqueous dispersion of plastic water softeners, the essential oils as perfumes, are incorporated, and this treatment is continued, until the plasticizer-essential oil system is absorbed into the plastic particles.
Als für das Verfahren nach der ErfindungAs for the method according to the invention
geeignete wäßrige Kumststoffdiispersiomen lassen sich besonders solche von, Polyvinylestern und!leave suitable aqueous Kumststoffdiispersiomen especially those of, polyvinyl esters and!
-äthern sowie vom Polyacrylsaurees'tern und Mischpolymerisaten der vorgenannten sowie Latioes aus NaiturkaiUtsohuk und synthetischen Polymerisaten und· Mischpolymerisaten des Butadiens und·. Isobutylens verwenden. Als Polyvinylester sei vor allem Polyvinylacetat geeigneter Polymerisatioms,-gnade genannt.ethers and polyacrylic acid esters and copolymers of the aforementioned as well as latioes from NaiturkaiUtsohuk and synthetic polymers and · copolymers of butadiene and ·. Isobutylene use. Polyvinyl acetate is particularly suitable as a polyvinyl ester called.
In diese, in üblicher Weise hergestellten wäßrigen Kunststoffdispersiiomem, die gegebenenfalls mit Appretorzusätzen üblicher Art, wie Netzmitteln, Pigmenten, und Borax verseihen werden, werden er-1-5 findungsgemäß wasserunlösliche Weichmacher eingearbeitet, in denen als Duftstoffe ätherische Öle gelöst sind.In these aqueous plastic dispersions prepared in the usual way, which may optionally be mixed with Conventional finish additives, such as wetting agents, pigments, and borax, will be er-1-5 Water-insoluble plasticizers are incorporated according to the invention, in which essential oils are used as fragrances are resolved.
Als wasserunlösliche Weichmacher, die natürlich keinen Eigengeruch aufweisen dürfen, lassen siich u. a. Ester der Phthalsäure und' der Phosphorsäure, z. B. Dibutylphthalat, Benzylbutylphthalat, Dimethylglykolphthalat und weitere Phthalsäureester aliphaitiischer Alkohole, T'rikresylphosphat und Tribuitylphosp-hjat, verwenden.As water-insoluble plasticizers, which of course must not have any inherent odor, can be used i.a. Esters of phthalic acid and phosphoric acid, e.g. B. dibutyl phthalate, benzyl butyl phthalate, dimethyl glycol phthalate and other phthalic acid esters of aliphatic alcohols, tricresyl phosphate and tribuityl phosphate, use.
Als in diesen Weichmachern zu. lösende ätherische öle dienern z. B-. Blüten- und'Fruchtöle und die daraus, hergestelltem Koimpositliomen.Than in these plasticizers too. dissolving ethereal oils serve z. B-. Flower and fruit oils and those made from them, produced Koimpositliomen.
D as· Einarbeiten des Systems Weichmacher—ätherisches, öli in die: Kunststoffdispersionen, geschieht nach üblicher Dispergiertechnik mittels· geeigneter Vorrichtungen durch starkes Rühren und bzw. ader . Homogenisieren. Dieses Dispergieren muß so lange fortgesetzt werden, bis die Lösung vollständig von den feinidispersen Kunststoffteilchen aufgenommen worden ist.The incorporation of the plasticizer system - essential, Öli in die: plastic dispersions, happens according to the usual dispersion technique by means of suitable devices by vigorous stirring and / or vein . Homogenize. This dispersing must be continued until the solution is completely from the finely dispersed plastic particles has been absorbed.
In die soi erhaltenen duf tstoffhaltigen Kunststoffdispersiomem kann man gegebenenfalls zur Erleichterung der Appretierwirkung, noch natürliche oder synthetische wasserlösliche Kolloide einarbeiten, wie z·. B. Stärke, Leim oder Casein.In the thus obtained fragrance-containing plastic dispersions You can optionally to facilitate the finishing effect, natural or incorporate synthetic water-soluble colloids, such as z. B. starch, glue or casein.
Die Appretur der Textilien mit den erfindungsgemäß hergestellten duftstoffhaltigen Dispersionen, geschiehti in der Weise, daß die letzteren mit einer beliebigen Menge Wasser verdünnt werden, worauf man die Textilien in die milchige Flüssigkeit "einträgt und dann kurz, trocknet und bügelt oder kalamdriiert. Zur Erhaltung des Duftstoffs im Gewebe sollte nur bei mäßigen Temperaturen gearbeitet werden.The finishing of the textiles with the inventive manufactured fragrance-containing dispersions, happens in such a way that the latter are diluted with any amount of water, whereupon the textiles are introduced into the milky liquid and then briefly dried and ironed or calamated. To preserve the fragrance in the fabric, work should only be done at moderate temperatures will.
Die mittels der erfindungsgemäß modifizierten KunststoffdlLspersiooen hergestelltem Appreturen auf Textilien lassem sich auch durch viele Waschen nicht auswaschen und behalten gleicherweise ihre Duf'twiirkung.The finishes produced by means of the plastic materials modified according to the invention Textiles cannot be washed out even after being washed too many times and they also keep theirs Fragrance effect.
100 Gewichtsteile einer 50°/oigen wäßrigen Dispersiom vom Polyvinylacetat niedrigen Polymerisartiomsgrades werden unter starkem Rühren mittels eines Turboriihrers mit einer Lösung vom 2 Gewi chtsteilen Lavendelöl in 12Gewichtsteileni Dibwtylphthakit versetzt, worauf das starke Rühren noch 6 Stunden fortgesetzt wird1. Hierauf wird die Dispersion; 3 Tage bei Zimmertemperatur stehengelassem und damm zum Abschluß d[er Behandlung durch einen Homo'geniisator geschickt. Danach ist, wie der mikroskopische Befund ergibt, die Weichmacherlösung vollkommen von den Kunststoffteilchen aufgenommen worden. Der Dispersion, werden noch 0,5 Gewichtsteile eines Netzmittels, 5 Gewichtsteile Titamdioxyd und 100 Gewachtsteile Reisstärke zugeführt.A solution of 2 parts by weight of lavender oil in 12 parts by weight of dibutylphthakite is added to 100 parts by weight of a 50% aqueous dispersion of polyvinyl acetate with a low degree of polymerisation while stirring vigorously using a turbo mixer, after which vigorous stirring is continued for a further 6 hours 1 . Then the dispersion; Left to stand for 3 days at room temperature and then sent through a homogenizer to complete the treatment. Then, as the microscopic findings show, the plasticizer solution has been completely absorbed by the plastic particles. 0.5 parts by weight of a wetting agent, 5 parts by weight of titanium dioxide and 100 parts by weight of rice starch are added to the dispersion.
In die so erhaltene, mit 2000 Gewichtsteilen Wasser verdünnte Dispersion wird Weißwäsche eingelegt, die damm bei mäßiger Hitze kurz getrackmet und kalandert wird. Die Appretur läßt sich auch durch eine Reihe vom Wäschen nicht auswaschen und behält ihrem Lavendelgeruch,.The resulting dispersion, diluted with 2000 parts by weight of water, is washed white inserted, the dam briefly tracked in moderate heat and is calendered. The finish cannot be washed out even by a series of washes and retains its lavender scent.
100 Gewichtsteile der im -Beispiel 1 verwendeten Polyvinylacetatdiispersioin werden unter starkem Rühren mit einer Lösung von 10 Gewichtsteilen synthetischem Rosenöl in 18 Gewichtsteilen Dibutylphthalat versetzt, worauf 8 Stunden nachgerührt wird. Die Dispersion wird dann 4 Tage sich selbst überlassen und schließlich durch eine Homogenisiervorrichtung geschickt. Unter dem Mikroskop läßt sich nun mit Hilfe eines Anfärbemittels feststellen, daß die Lösung vollständig von den Kunststoffteilchen aufgenommen worden ist. Dies ist der Fall, wenn die dispergierten Teilchen gleichmäßig gefärbt erscheinen. Es werden darauf noch 0,5 Gewichtsteile eines üblichen Netzmittels zugerührt. In diese Dispersion werden nach Verdünnung mit 5000 Gewichtsteilen Wasser Sofakissenbezüge getaucht, dann bei mäßiger Hitze kurz getrocknet und gebügelt. Sie behalten jahrelang ihren Rosenduft.100 parts by weight of that used in Example 1 Polyvinyl acetate diispersion are mixed with a solution of 10 parts by weight with vigorous stirring synthetic rose oil in 18 parts by weight of dibutyl phthalate, followed by stirring for 8 hours will. The dispersion is then left to its own devices for 4 days and finally through a Sent homogenizer. Under the microscope it can now be done with the help of a stain determine that the solution has been completely absorbed by the plastic particles. This is the case when the dispersed particles appear uniformly colored. It will be on it 0.5 parts by weight of a customary wetting agent were also added. Be in this dispersion after dilution with 5000 parts by weight of water, dipped sofa cushion covers, then at moderate Heat briefly dried and ironed. They keep their rose scent for years.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP8444A DE938723C (en) | 1952-09-30 | 1952-09-30 | Process for the production of a modified plastic dispersion for the finishing of textiles |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP8444A DE938723C (en) | 1952-09-30 | 1952-09-30 | Process for the production of a modified plastic dispersion for the finishing of textiles |
| GB2979053A GB735684A (en) | 1953-10-28 | 1953-10-28 | Method of imparting a permanent fragrance to fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE938723C true DE938723C (en) | 1956-02-09 |
Family
ID=25989728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEP8444A Expired DE938723C (en) | 1952-09-30 | 1952-09-30 | Process for the production of a modified plastic dispersion for the finishing of textiles |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE938723C (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE557001C (en) * | 1931-03-17 | 1932-08-17 | Lueneburger Wachsbleiche J Boe | Method for treating socks with stocking wax |
| FR981831A (en) * | 1949-02-28 | 1951-05-30 | Scented plastics |
-
1952
- 1952-09-30 DE DEP8444A patent/DE938723C/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE557001C (en) * | 1931-03-17 | 1932-08-17 | Lueneburger Wachsbleiche J Boe | Method for treating socks with stocking wax |
| FR981831A (en) * | 1949-02-28 | 1951-05-30 | Scented plastics |
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