DE717938C - Process for the softening of textiles made from cellulose rayon - Google Patents

Process for the softening of textiles made from cellulose rayon

Info

Publication number
DE717938C
DE717938C DEI38225D DEI0038225D DE717938C DE 717938 C DE717938 C DE 717938C DE I38225 D DEI38225 D DE I38225D DE I0038225 D DEI0038225 D DE I0038225D DE 717938 C DE717938 C DE 717938C
Authority
DE
Germany
Prior art keywords
softening
sulfonic acids
cellulose rayon
textiles made
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI38225D
Other languages
German (de)
Inventor
Dr Conrad Schoeller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI38225D priority Critical patent/DE717938C/en
Priority claimed from GB2583729A external-priority patent/GB339858A/en
Priority to NL50842A priority patent/NL29185C/xx
Priority to FR693019D priority patent/FR693019A/en
Priority to BE369053D priority patent/BE369053A/xx
Priority to US454515A priority patent/US1951712A/en
Application granted granted Critical
Publication of DE717938C publication Critical patent/DE717938C/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03Organic sulfoxy compound containing
    • Y10S516/04Protein or carboxylic compound containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2938Coating on discrete and individual rods, strands or filaments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2964Artificial fiber or filament
    • Y10T428/2965Cellulosic

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Verfahren zum Weichmachen von Textilgut aus Cellulosekunstseiäe Viele Fasermaterialien, insbesondere Kunstfasern, besitzen eine ihre Verwendbarkeit erschwerende geringe Geschmeidigkeit und Weichheit, und oftmals ist auch bei an sich schon geschmeidigen und weichen Materialien eine Steigerung dieser Eigenschaften erwiinscht.Process for the softening of textiles made from cellulose synthetic silk. Many Fiber materials, in particular synthetic fibers, have something that makes them difficult to use poor suppleness and softness, and often is already pliable in itself and soft materials would like an increase in these properties.

Es wurde nun gefunden, daß man Textilgut aus Cellulosekunstseide eine hervorragende Weichheit und Geschmeidigkeit .erteilen kann, wenn man dieses mit wäßrigen Isösüngen von Salzen von Sulfonsäuren höhermolekularer, d. h. 8 oder mehr C-Atome enthaltender aliphatischer oder höhermolekulare aliphatische Reste enthaltender, gemischt aliphatisch-a.romatischer Verbindungen behandelt.It has now been found that textiles made from cellulose rayon can be used excellent softness and suppleness aqueous Isösüngen of salts of sulfonic acids of higher molecular weight, d. H. 8 or more Aliphatic or higher molecular weight aliphatic radicals containing carbon atoms, mixed aliphatic-a.romatic compounds treated.

Es ist schon vorgeschlagen worden, TürhischrotÜle als geschmeidigmachende Mittel für Faserstoffe zu verwenden. Türkischrotäle sind jedoch keine echten Sulfonsäuren, sondern Schwefelsäureester. Daß gerade die wasserlöslichen Salze von echten Sulfonsäuren aus den genannten organischen Verbindungen den Textilien technisch besonders wertvolle Eigenschaften verleihen würden, war aus dem Schrifttum nicht zu .entnehmen. Ihre Verwendung bietet gegenüber der Verwendung der Tür'kischrotöle den Vorteil, daß Faserstoffe von besonders weichem und glattem Griff erhalten werden. Man hat auch schon beim Naßspinnen von Flachs oder anderen Textilfasern dem zur Anfeuchtung dienenden Wasser geringe Mengeri organischer Sulfonsäuren zugefügt. Hierbei werden die Rohfasern in einen Zustand übergeführt, der sie besonders für den Spinnprozeß geeignet macht. Im vorliegenden Falle handelt es sich jedoch darum, bereits gesponnene Fasermaterialien, d. h. Garne oder Gewebe, aus regenerierter Cellulose mit den Salzen der genannten Stdfonsäuren zu behandeln. Das Textilgut erhält auf diese Weise eine beständige und besonders hohe Weichheit und Geschmeidigkeit.It has already been suggested that TürhischrotÜle be used as emollient To use funds for fibrous materials. However, Turkish reds are not real sulfonic acids, but sulfuric acid ester. That just the water-soluble salts of real sulfonic acids from the organic compounds mentioned, the textiles are technically particularly valuable Would confer properties could not be inferred from the literature. Her Use has the advantage over the use of Tür'kischrotöle that Fibers of a particularly soft and smooth handle can be obtained. One also has even when wet spinning flax or other textile fibers the one used for moistening Small quantities of organic sulfonic acids are added to the water. Here are the raw fibers transferred to a state that makes them particularly suitable for the spinning process. In the present case, however, it is a matter of already spun fiber materials, d. H. Yarns or fabrics, made from regenerated cellulose with the salts of the aforesaid Treat stdfonic acids. In this way, the textile material is given a permanent one and particularly high softness and suppleness.

Es ist weiterhin schon vorgeschlagen worden, Stdfonierungsprodukte aus Ölen oder Fetten oder der Salze dieser zusammen mit den üblichen Imprägnierungsmitteln, wie Paraffinen, ölen oder Fetten, zur Behandlung von Textilien zu verwenden. Hierbei dienen die erwähnten Sulfonierungsproduhte ledig- ]ich dazu, die wasserunlöslichen Im-präbniermittel in Lösung zu bringen. Bei dem vorliegenden Verfahren handelt es sich jedoch im Gegensatz zu der bekannten Arbeitsweise darum, die Sulfonsäuren für sich allein 'zu. verwenden, um den Textilien eine hohe Weichheit und Geschmeidigkeit zu verleihen:-Die Verwendung der gemäß Patent 542 048 hergestellten Sulfonsäuren von mehr als S Kohlenstoffatome enthaltenden aliphatischen Alkoholen wird im vorliegenden Fall nicht beansprucht.It has also been proposed to use stdfunding products from oils or fats or their salts together with the usual impregnating agents, such as paraffins, oils or fats, to be used for treating textiles. Here the sulphonation products mentioned serve only ] I do that to bring water-insoluble impregnating agent into solution. In the present case In contrast to the known procedure, however, it is a matter of the sulfonic acids for yourself 'too. use to give the textiles a high level of softness and suppleness to lend: -The use of sulfonic acids prepared according to patent 542 048 of aliphatic alcohols containing more than 5 carbon atoms is used herein Case not claimed.

Beispiel i .Example i.

In einer Lösung, die auf 11 Wasser = g des Mononatriumsalzes der Sulfopalmitinsä.ure enthält, behandelt man Kunstseide 2o Minuten lang bei 5o bis 6o°, schleudert und trocknet. Die so behandelte Kunstseide besitzt einen sehr weichen und angenehmen Griff. Beispiel @'iscosckunstseidestränge werden üi einer Lbsung, die 5 g des Triäthanolaminsalzes der Palmitovlhenzolsulfonsäure im Liter Wasser enthält, y 2o :Minuten lang bei 5o bis 55- behandelt, hierauf geschleudert und getrocknet. Man erhält so eine Kunstseide von hoher Geschrneidigkeit.In a solution containing 1 g water = 1 contains the monosodium salt of Sulfopalmitinsä.ure, is treated rayon 2o to 6o minutes at 5o °, spun and dried. The artificial silk treated in this way has a very soft and pleasant feel. Example @ 'Iscosckunstseidestränge are üi a solution containing 5 g of the triethanolamine salt of palmitovlhenzenesulfonic acid per liter of water, treated for 20 minutes at 50 to 55 minutes, then spun and dried. In this way, an artificial silk of great dexterity is obtained.

Claims (1)

PATEXTANSPPUCH: Verfahren zum Wcichmachen %-on Te1-tilgut aus Cellulosekunstseide. dadurch gekennzeichnet, daß man dieses mit wärrigen Lösungen von Salzen von Sulfon-Säuren höhermolekularer aliphatischer oder höhermolekulare aliphatische Reste enthaltender, gemischt aliphatisch-aromatischer Verhindungen mit Ausnahme der gemäß Patent 5.12 048 erhältlichen Salze von Sulfonsäuren behandelt.PATEXT APPLICATION: Method for making up% -on part of cellulose rayon. characterized in that this is done with aqueous solutions of salts of sulfonic acids higher molecular weight aliphatic or containing higher molecular weight aliphatic radicals, mixed aliphatic-aromatic compounds with the exception of those according to patent 5.12 048 available salts of sulfonic acids treated.
DEI38225D 1929-05-30 1929-05-30 Process for the softening of textiles made from cellulose rayon Expired DE717938C (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DEI38225D DE717938C (en) 1929-05-30 1929-05-30 Process for the softening of textiles made from cellulose rayon
NL50842A NL29185C (en) 1929-05-30 1930-03-21
FR693019D FR693019A (en) 1929-05-30 1930-03-29 Process for improving the qualities of fibrous materials
BE369053D BE369053A (en) 1929-05-30 1930-03-31
US454515A US1951712A (en) 1929-05-30 1930-05-21 Process for improving fibrous materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEI38225D DE717938C (en) 1929-05-30 1929-05-30 Process for the softening of textiles made from cellulose rayon
GB2583729A GB339858A (en) 1929-08-24 1929-08-24 A process for improving fibrous materials

Publications (1)

Publication Number Publication Date
DE717938C true DE717938C (en) 1942-02-26

Family

ID=25981579

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI38225D Expired DE717938C (en) 1929-05-30 1929-05-30 Process for the softening of textiles made from cellulose rayon

Country Status (5)

Country Link
US (1) US1951712A (en)
BE (1) BE369053A (en)
DE (1) DE717938C (en)
FR (1) FR693019A (en)
NL (1) NL29185C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2528570A (en) * 1946-07-20 1950-11-07 Celanese Corp Sizing composition for yarns
US2725314A (en) * 1952-01-29 1955-11-29 Leslie E Lancy In line treatment of toxic carry-over of work pieces
US3148017A (en) * 1961-07-14 1964-09-08 Gagliardi Domenick Donald Treatment and coloring of preformed polyolefin materials

Also Published As

Publication number Publication date
NL29185C (en) 1933-03-15
BE369053A (en) 1930-04-30
US1951712A (en) 1934-03-20
FR693019A (en) 1930-11-14

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