DE717938C - Process for the softening of textiles made from cellulose rayon - Google Patents
Process for the softening of textiles made from cellulose rayonInfo
- Publication number
- DE717938C DE717938C DEI38225D DEI0038225D DE717938C DE 717938 C DE717938 C DE 717938C DE I38225 D DEI38225 D DE I38225D DE I0038225 D DEI0038225 D DE I0038225D DE 717938 C DE717938 C DE 717938C
- Authority
- DE
- Germany
- Prior art keywords
- softening
- sulfonic acids
- cellulose rayon
- textiles made
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/04—Protein or carboxylic compound containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2965—Cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zum Weichmachen von Textilgut aus Cellulosekunstseiäe Viele Fasermaterialien, insbesondere Kunstfasern, besitzen eine ihre Verwendbarkeit erschwerende geringe Geschmeidigkeit und Weichheit, und oftmals ist auch bei an sich schon geschmeidigen und weichen Materialien eine Steigerung dieser Eigenschaften erwiinscht.Process for the softening of textiles made from cellulose synthetic silk. Many Fiber materials, in particular synthetic fibers, have something that makes them difficult to use poor suppleness and softness, and often is already pliable in itself and soft materials would like an increase in these properties.
Es wurde nun gefunden, daß man Textilgut aus Cellulosekunstseide eine hervorragende Weichheit und Geschmeidigkeit .erteilen kann, wenn man dieses mit wäßrigen Isösüngen von Salzen von Sulfonsäuren höhermolekularer, d. h. 8 oder mehr C-Atome enthaltender aliphatischer oder höhermolekulare aliphatische Reste enthaltender, gemischt aliphatisch-a.romatischer Verbindungen behandelt.It has now been found that textiles made from cellulose rayon can be used excellent softness and suppleness aqueous Isösüngen of salts of sulfonic acids of higher molecular weight, d. H. 8 or more Aliphatic or higher molecular weight aliphatic radicals containing carbon atoms, mixed aliphatic-a.romatic compounds treated.
Es ist schon vorgeschlagen worden, TürhischrotÜle als geschmeidigmachende Mittel für Faserstoffe zu verwenden. Türkischrotäle sind jedoch keine echten Sulfonsäuren, sondern Schwefelsäureester. Daß gerade die wasserlöslichen Salze von echten Sulfonsäuren aus den genannten organischen Verbindungen den Textilien technisch besonders wertvolle Eigenschaften verleihen würden, war aus dem Schrifttum nicht zu .entnehmen. Ihre Verwendung bietet gegenüber der Verwendung der Tür'kischrotöle den Vorteil, daß Faserstoffe von besonders weichem und glattem Griff erhalten werden. Man hat auch schon beim Naßspinnen von Flachs oder anderen Textilfasern dem zur Anfeuchtung dienenden Wasser geringe Mengeri organischer Sulfonsäuren zugefügt. Hierbei werden die Rohfasern in einen Zustand übergeführt, der sie besonders für den Spinnprozeß geeignet macht. Im vorliegenden Falle handelt es sich jedoch darum, bereits gesponnene Fasermaterialien, d. h. Garne oder Gewebe, aus regenerierter Cellulose mit den Salzen der genannten Stdfonsäuren zu behandeln. Das Textilgut erhält auf diese Weise eine beständige und besonders hohe Weichheit und Geschmeidigkeit.It has already been suggested that TürhischrotÜle be used as emollient To use funds for fibrous materials. However, Turkish reds are not real sulfonic acids, but sulfuric acid ester. That just the water-soluble salts of real sulfonic acids from the organic compounds mentioned, the textiles are technically particularly valuable Would confer properties could not be inferred from the literature. Her Use has the advantage over the use of Tür'kischrotöle that Fibers of a particularly soft and smooth handle can be obtained. One also has even when wet spinning flax or other textile fibers the one used for moistening Small quantities of organic sulfonic acids are added to the water. Here are the raw fibers transferred to a state that makes them particularly suitable for the spinning process. In the present case, however, it is a matter of already spun fiber materials, d. H. Yarns or fabrics, made from regenerated cellulose with the salts of the aforesaid Treat stdfonic acids. In this way, the textile material is given a permanent one and particularly high softness and suppleness.
Es ist weiterhin schon vorgeschlagen worden, Stdfonierungsprodukte aus Ölen oder Fetten oder der Salze dieser zusammen mit den üblichen Imprägnierungsmitteln, wie Paraffinen, ölen oder Fetten, zur Behandlung von Textilien zu verwenden. Hierbei dienen die erwähnten Sulfonierungsproduhte ledig- ]ich dazu, die wasserunlöslichen Im-präbniermittel in Lösung zu bringen. Bei dem vorliegenden Verfahren handelt es sich jedoch im Gegensatz zu der bekannten Arbeitsweise darum, die Sulfonsäuren für sich allein 'zu. verwenden, um den Textilien eine hohe Weichheit und Geschmeidigkeit zu verleihen:-Die Verwendung der gemäß Patent 542 048 hergestellten Sulfonsäuren von mehr als S Kohlenstoffatome enthaltenden aliphatischen Alkoholen wird im vorliegenden Fall nicht beansprucht.It has also been proposed to use stdfunding products from oils or fats or their salts together with the usual impregnating agents, such as paraffins, oils or fats, to be used for treating textiles. Here the sulphonation products mentioned serve only ] I do that to bring water-insoluble impregnating agent into solution. In the present case In contrast to the known procedure, however, it is a matter of the sulfonic acids for yourself 'too. use to give the textiles a high level of softness and suppleness to lend: -The use of sulfonic acids prepared according to patent 542 048 of aliphatic alcohols containing more than 5 carbon atoms is used herein Case not claimed.
Beispiel i .Example i.
In einer Lösung, die auf 11 Wasser = g des Mononatriumsalzes der Sulfopalmitinsä.ure enthält, behandelt man Kunstseide 2o Minuten lang bei 5o bis 6o°, schleudert und trocknet. Die so behandelte Kunstseide besitzt einen sehr weichen und angenehmen Griff. Beispiel @'iscosckunstseidestränge werden üi einer Lbsung, die 5 g des Triäthanolaminsalzes der Palmitovlhenzolsulfonsäure im Liter Wasser enthält, y 2o :Minuten lang bei 5o bis 55- behandelt, hierauf geschleudert und getrocknet. Man erhält so eine Kunstseide von hoher Geschrneidigkeit.In a solution containing 1 g water = 1 contains the monosodium salt of Sulfopalmitinsä.ure, is treated rayon 2o to 6o minutes at 5o °, spun and dried. The artificial silk treated in this way has a very soft and pleasant feel. Example @ 'Iscosckunstseidestränge are üi a solution containing 5 g of the triethanolamine salt of palmitovlhenzenesulfonic acid per liter of water, treated for 20 minutes at 50 to 55 minutes, then spun and dried. In this way, an artificial silk of great dexterity is obtained.
Claims (1)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI38225D DE717938C (en) | 1929-05-30 | 1929-05-30 | Process for the softening of textiles made from cellulose rayon |
NL50842A NL29185C (en) | 1929-05-30 | 1930-03-21 | |
FR693019D FR693019A (en) | 1929-05-30 | 1930-03-29 | Process for improving the qualities of fibrous materials |
BE369053D BE369053A (en) | 1929-05-30 | 1930-03-31 | |
US454515A US1951712A (en) | 1929-05-30 | 1930-05-21 | Process for improving fibrous materials |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI38225D DE717938C (en) | 1929-05-30 | 1929-05-30 | Process for the softening of textiles made from cellulose rayon |
GB2583729A GB339858A (en) | 1929-08-24 | 1929-08-24 | A process for improving fibrous materials |
Publications (1)
Publication Number | Publication Date |
---|---|
DE717938C true DE717938C (en) | 1942-02-26 |
Family
ID=25981579
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEI38225D Expired DE717938C (en) | 1929-05-30 | 1929-05-30 | Process for the softening of textiles made from cellulose rayon |
Country Status (5)
Country | Link |
---|---|
US (1) | US1951712A (en) |
BE (1) | BE369053A (en) |
DE (1) | DE717938C (en) |
FR (1) | FR693019A (en) |
NL (1) | NL29185C (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2528570A (en) * | 1946-07-20 | 1950-11-07 | Celanese Corp | Sizing composition for yarns |
US2725314A (en) * | 1952-01-29 | 1955-11-29 | Leslie E Lancy | In line treatment of toxic carry-over of work pieces |
US3148017A (en) * | 1961-07-14 | 1964-09-08 | Gagliardi Domenick Donald | Treatment and coloring of preformed polyolefin materials |
-
1929
- 1929-05-30 DE DEI38225D patent/DE717938C/en not_active Expired
-
1930
- 1930-03-21 NL NL50842A patent/NL29185C/xx active
- 1930-03-29 FR FR693019D patent/FR693019A/en not_active Expired
- 1930-03-31 BE BE369053D patent/BE369053A/xx unknown
- 1930-05-21 US US454515A patent/US1951712A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
BE369053A (en) | 1930-04-30 |
FR693019A (en) | 1930-11-14 |
US1951712A (en) | 1934-03-20 |
NL29185C (en) | 1933-03-15 |
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