DE2930061A1 - SOFT SOFTENER - Google Patents

SOFT SOFTENER

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Publication number
DE2930061A1
DE2930061A1 DE19792930061 DE2930061A DE2930061A1 DE 2930061 A1 DE2930061 A1 DE 2930061A1 DE 19792930061 DE19792930061 DE 19792930061 DE 2930061 A DE2930061 A DE 2930061A DE 2930061 A1 DE2930061 A1 DE 2930061A1
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Germany
Prior art keywords
methyl
alkyl
carbon atoms
cation
iii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19792930061
Other languages
German (de)
Inventor
Hans-Walter Dr Buecking
Adolf Dr May
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to DE19792930061 priority Critical patent/DE2930061A1/en
Priority to AT80104269T priority patent/ATE5662T1/en
Priority to EP80104269A priority patent/EP0023334B1/en
Priority to DE8080104269T priority patent/DE3065943D1/en
Priority to JP10064180A priority patent/JPS5620677A/en
Priority to BR8004626A priority patent/BR8004626A/en
Priority to CA000356977A priority patent/CA1153510A/en
Publication of DE2930061A1 publication Critical patent/DE2930061A1/en
Withdrawn legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Detergent Compositions (AREA)

Abstract

1. Fabric softeners in the form of an aqueous solution or dispersion, which contain from 1 to 15% by weight of one or several compounds of formulae I to III see diagramm : EP0023334,P5,F1 see diagramm : EP0023334,P5,F2 see diagramm : EP0023334,P5,F3 in which R1 is alkyl or alkenyl of from 10 to 30 carbon atoms, preferably from 8 to 14 carbon atoms, R2 is alkyl of from 1 to 4 carbon atoms, preferably methyl, R3 is methyl or hydrogen, m is a number of from 1 to 15, preferably 1, and A is an anion, such as Cl (cation) , Br (cation) , R2 OSO3 (cation) or R2 OPO3 (cation) , and from 0.01 to 4, preferably from 0.5 to 2.5%, by weight of a fatty acid ethanolamine polyglycol ether of formula IV see diagramm : EP0023334,P5,F4 in which R4 is C4 -C20 -alkyl, preferably C8 -C16 -alkyl, n is a number of from 2 to 20, preferably from 2 to 6, x and y represent hydrogen or methyl, but are not methyl at the same time and additionally water and auxiliaries and substances usual in fabric softeners in an amount to complete 100% with the proviso that these auxiliaries and substances do not constitute surfactants.

Description

Es ist bekannt, daß gewaschene Textilien, besonders solche aus Cellulosefaser^, nach dem Trocknen eine unangenehme Verhärtung aufweisen. Dies tritt insbesondere dann ein, wenn die Wäsche im Waschautomaten erfolgt. Diese unerwünschte Griffverhärtung kann man dadurch beseitigen, daß man die Textilien nach der Wäsche in einem Spülbad mit kationischen Substanzen behandelt, die mindestens zwei langkettige aliphatische Reste im Molekül enthalten. In der Praxis haben sich für diesen Zweck besonders die in Wasser dispergierbaren Dialkyldimethylammoniumsalze eingeführt. Diese Produkte haben jedoch den Nachteil, daß bei Überdosierung das behandelte Gewebe hydrophob und dadurch die Wiederbenetzbarkeit verzögert wird.It is known that washed textiles, especially those made of cellulose fibers, are uncomfortable after drying Show induration. This occurs especially when the laundry is done in the washing machine. This undesirable Hardening of the handle can be eliminated by rinsing the textiles with cationic ones after washing Treats substances that contain at least two long-chain aliphatic residues in the molecule. In practice The water-dispersible dialkyldimethylammonium salts have been introduced for this purpose. These However, products have the disadvantage that, in the event of an overdose, the treated tissue is hydrophobic and therefore rewettable is delayed.

Es wurde nun gefunden, daß man diese Schwierigkeiten beseitigen kann, wenn man die als Waseheweichspulmittel dienenden quaternären Ammoniumverbindungen mit einem Fettsäureethanoiamidpolyglykolether kombiniert. Gegenstand der Erfindung sind somit Wäscheweiehspülmittel in Form einer wäßrigen Lösung oder Dispersion, die 1 bis 15, vorzugsweise 2 bis 16 Gew.-i einer oder mehrerer Verbindungen der Formeln I bis IIIIt has now been found that these difficulties can be eliminated by using those used as wash softeners quaternary ammonium compounds with a fatty acid ethanoiamide polyglycol ether combined. The invention thus relates to laundry detergents in the form of a aqueous solution or dispersion containing 1 to 15, preferably 2 to 16% by weight of one or more compounds of the formulas I to III

R.R.

.R,.R,

IIII

130008/0110130008/0110

R2 R 2

CH2-CH-OHCH 2 -CH-OH

IIIIII

wobei R1 Alkyl oder Alkenyl mit 10 - 30 Kohlenstoffatomen, vorzugsweise 8-14 Kohlenstoffatomen, R? Alkyl mit 1 - 4 Kohlenstoffatomen, vorzugsweise Methyl, Methyl oder Wasserstoff und A ein Anion wie z.B. Cl , Br*-\ R20S0o(~^ oder R2OPO3*"* bedeutet, 0,01 - 4, vorzugsweise 0,5 - 2,5 Gew.-$ eines Fettsäureethanolamidpolyglykolethers der Formel IVwhere R 1 is alkyl or alkenyl with 10-30 carbon atoms, preferably 8-14 carbon atoms, R ? Alkyl with 1 - 4 carbon atoms, preferably methyl, methyl or hydrogen and A is an anion such as Cl, Br * - \ R 2 0S0o ( ~ ^ or R 2 OPO 3 * "* means 0.01-4, preferably 0, 5-2.5% by weight of a fatty acid ethanolamide polyglycol ether of the formula IV

R11-CO-NH-(CH-CHO)nH IVR 11 -CO-NH- (CH-CHO) n H IV

χ yχ y

wobei Ru Ci.-C20-Alkyl, vorzugsweise Cg-C^-Alkyl, η eine Zahl von 2 bis 20, vorzugsweise 2 bis 6, χ und y Wasserstoff oder Methyl bedeuten, wobei χ und y jedoch nicht gleichzeitig Methyl bedeuten.where Ru C i -C 20 -alkyl, preferably Cg-C ^ -alkyl, η is a number from 2 to 20, preferably 2 to 6, χ and y are hydrogen or methyl, but χ and y are not simultaneously methyl.

Diese Kombination der Verbindungen I, II und III mit einer Verbindung der Formel IV verleiht beliebigen Textilmaterialien, besonders solchen aus natürlicher oder regenerierter Cellulose, Wolle, Cellulose-acetat, -triacetat, Polyamid, Polyacrylnitril, Polyester, Polypropylen einen angenehmen und weichen Griff. Besonders vorteilhaft ist der Einsatz als Wäschenachbehandlungsmittel für Frottee- und Leibwäsche aus Baumwolle. Die Herstellung dieser Wäscheweichspülmittel erfolgt durch einfaches Vermischen oder Dispergieren der Einzelkomponenten in Wasser. Diese Wäscheweichspülmittel gemäß der Erfindung können entweder nur jeweils eine Verbindung der Formeln I bis III enthalten oder aber sie enthalten ein Gemisch aus zwei oder mehr Verbindungen dieser Formeln I bis III innerhalb der angegebenen Grenzen. Liegt ein Gemisch aus zwei oder mehr Verbindungen der Formeln IThis combination of compounds I, II and III with a compound of formula IV confers any Textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, -triacetate, polyamide, polyacrylonitrile, polyester, polypropylene a pleasant and soft grip. Particularly Its use as a laundry aftertreatment agent for terrycloth and underwear made of cotton is advantageous. The production This fabric softener is made by simply mixing or dispersing the individual components in water. This fabric softener according to the invention can either only one connection each Formulas I to III contain or they contain a mixture of two or more compounds of these formulas I. to III within the specified limits. If there is a mixture of two or more compounds of the formulas I.

130008/0110130008/0110

-ϊ-s-ϊ-s

bis III vor, so ist deren Mischungsverhältnis untereinander völlig unkritisch und kann jeden beliebigen Wert annehmen.to III before, their mixing ratio is among each other completely uncritical and can assume any value.

Darüberhinaus können die erfindungsgemäßen Wäscheweichspülmittel noch weitere Substanzen und Hilfsmittel enthalten, die entweder schon im Konzentrat des Wäscheweichspülmittels zugemischt oder dem gebrauchsfertigen, verdünnten Wäscheweichspülmittel gesondert zugesetzt werden. Hierbei handelt es sich um Substanzen oder Hilfsmittel, die man bereits in Wäscheweichspülmitteln eingesetzt hat, wie z.B. kationische oder nichtionische oberflächenaktive Substanzen, Elektrolyse, Absäuerungsmittel, organische Komplexbildner, optische Aufhellungsmittel oder Lösungsvermittler sowie Färb- und Duftstoffe. Sie dienen zur zusätzlichen Beeinflussung des Warengriffs oder sonstiger Eigenschaften der zu behandelnden Textilien oder zur Viskositätseinstellung, zur pH-Regulierung oder zur Erhöhung der Kältestabilität.In addition, the fabric softeners according to the invention contain other substances and auxiliaries that are either already in the concentrate of the fabric softener mixed in or added separately to the ready-to-use, diluted fabric softener will. These are substances or auxiliaries that are already in fabric softeners has used, such as cationic or nonionic surface-active substances, electrolysis, acidulants, organic complexing agents, optical brighteners or solubilizers as well as dyes and fragrances. They serve to additionally influence the handle of the goods or other properties of the items to be treated Textiles or for viscosity adjustment, for pH regulation or to increase cold stability.

Die Anwendung dieser Wäscheweichspülmittel erfolgt wie üblich, indem man sie im Anschluß an die Textilwäsche in das letzte Spülwasser gibt. Das so behandelte Textilmaterial wird dann getrocknet, wobei die Wiederbenetzbarkeit des Textilmaterial wesentlich verbessert ist im Vergleich zu handelsüblichen Mitteln.These fabric softeners are used as usual, by adding them to the laundry after washing the last rinse water is there. The textile material treated in this way is then dried, whereby the rewettability of the textile material is significantly improved compared to commercially available means.

In den folgenden Beispielen sind einige erfindungsgemäße Wäscheweichspülmittel beschrieben. Prozentangaben sind in allen Fällen Gewichtsprozente. Die Herstellung dieser Wäscheweichspülmittel erfolgt in allen Fällen durch einfaches Verrühren in der Kälte von wässrigen Lösungen der einzelnen Komponenten.In the following examples some are according to the invention Laundry softener described. Percentages are in all cases percentages by weight. The making of this In all cases, fabric softener is made by simply stirring aqueous solutions in the cold of the individual components.

Beispiel 1example 1

Distearyldimethylammoniumchlorid 4 % Distearyldimethylammonium chloride 4 %

Cocos-Fettsäureethanolamid + 5 Ethylenoxid 2 % Coconut fatty acid ethanolamide + 5 ethylene oxide 2 %

13 0 0 0 8/0110 CPV3!NAL 'N^13 0 0 0 8/0110 CPV3! NAL 'N ^

Farbstoff, Parfüm, Rest Wasser ad 100 % Beispiel 2 Dye, perfume, remainder water ad 100 % Example 2

Ditalgfettalkyldimethylammoniumchlorid 5,3 % Cocs-Fettsäureethanolamid + 5 Ethylenoxid 2 % Farbstoff, Parfüm und Rest Wasser ad 100 % Ditallow fat alkyl dimethyl ammonium chloride 5.3 % cocs fatty acid ethanolamide + 5 ethylene oxide 2 % dye, perfume and the rest water ad 100 %

Beispiel 3 Example 3

Dialkylimidazolinderivat der Formel HR= C10-Cl8-Alkenyl, R3=CH3, A=CH3OSO3* 5,3 % Cocos-Fettsäureethanolamid + 5 Ethylenoxid 2 % Farbstoff, Parfüm und Rest Wasser ad 100 % Dialkylimidazoline derivative of the formula HR = C 10 -C 18 -alkenyl, R 3 = CH 3 , A = CH 3 OSO 3 * 5.3 % coconut fatty acid ethanolamide + 5 ethylene oxide 2 % dye, perfume and the remainder water ad 100 %

Beispiel 4Example 4

VergleichsformulierungComparative formulation

Distearyldimethylammoniumchlorid 6 % nichtionisches Tensid NonylphenoloxethylatDistearyldimethylammonium chloride 6 % nonionic surfactant nonylphenol oxyethylate

+ 10 Ethylenoxid 1 % + 10 ethylene oxide 1 %

Farbstoff, Parfüm und Rest Wasser ad 100 % Dye, perfume and remainder water up to 100 %

Diese Wäscheweichspülmittel wurden auf ihren Einfluß auf die Wiederbenetzbarkeit nach der Steighöhenmethode (DIN 53 924) geprüft.These fabric softeners were based on their influence the rewettability was tested according to the rising height method (DIN 53 924).

Dabei werden glatte Baumwollgewebe mit den erfindungsgemäßen Mischungen behandelt. Zum Vergleich wurde ein handelsüblicher Weichmacher hinzugezogen (Beispiel 4). Nach dieser Prüfmethode wurden für die Mischungen der Beispiele 1 - 4 die in der nachfolgenden Tabelle aufgeführten Ergebnisse erhalten. Die Steighöhe nicht ausgerüsteter Gewebe wird dabei mit 100 % bezeichnet.Smooth cotton fabrics are treated with the mixtures according to the invention. A commercially available plasticizer was used for comparison (Example 4). According to this test method, the results listed in the table below were obtained for the mixtures of Examples 1-4. The height of rise of unfinished tissue is designated as 100 % .

130008/0110130008/0110

-Jg--Jg-

Steighöhe in % 1 g WS/kg StoffHeight of rise in % 1 g WS / kg fabric

Beispiel 1 73 % Example 1 73 %

Beispiel 2 70 % Example 2 70 %

Beispiel 3 71 % Example 3 71 %

Beispiel 4 (Vergleichsform.) 50 % Example 4 (comparative form.) 50 %

Die Ergebnisse zeigen, daß die erfindungsgemäßen Wäscheweichspülmittelkombinationen im Vergleich mit einem handelsüblichen Produkt ein verbessertes Saugvermögen aufweisen.The results show that the fabric softener combinations according to the invention have an improved pumping speed compared to a commercially available product.

130008/01 10130008/01 10

Claims (2)

HOE 79/F 203 Patentansprüche:HOE 79 / F 203 claims: 1. Wäscheweichspülmittel in Form einer wässrigen Lösung oder Dispersion, die 1 bis 15 Gew.-? einer oder mehrerer Verbindungen der Formeln I bis III1. Fabric softener in the form of an aqueous solution or dispersion that is 1 to 15 wt. one or more compounds of the formulas I to III R.R. N CH2 N CH 2 "R,"R, ■CH.■ CH. flfl R2 CH2-CH2-NH-C-R1 R 2 CH 2 -CH 2 -NH-CR 1 R.R. CH2-CH-OHCH 2 -CH-OH IIIIII wobei R1 Alkyl oder Alkenyl mit 10 - 30 Kohlenstoffatomen, wobei χ und y jedoch nicht gleichzeitig Methyl, R2 mit 1 - 4 Kohlenstoffatomen, vorzugsweise Methyl, R, Methyl oder Wasserstoff und A ein An-where R 1 is alkyl or alkenyl with 10-30 carbon atoms, but χ and y are not simultaneously methyl, R 2 with 1-4 carbon atoms, preferably methyl, R, methyl or hydrogen and A is an ion wie z.B. Cl , Brv , R2OSO, oder R2OPO5 bedeutet, 0,01 - 4 Gew.-% eines Fettsäureethanolamidpolyglykolethers der Formel IVion such as Cl, Br v , R 2 OSO, or R 2 OPO 5 means 0.01-4% by weight of a fatty acid ethanolamide polyglycol ether of the formula IV R4-CONH-(CH-CHO)nHR 4 -CONH- (CH-CHO) n H χ yχ y IVIV wobei R4 Cij-C20-Alkyl, η eine Zahl von 2 bis 20, χ und y Wasserstoff oder Methyl bedeuten, wobei χ und y jedoch nicht gleichzeitig Methyl bedeuten und weitere übliche Hilfs- und Zusatzstoffe enthalten.where R 4 C i jC 20 alkyl, η is a number from 2 to 20, χ and y are hydrogen or methyl, but χ and y are not simultaneously methyl and contain other customary auxiliaries and additives. 130008/0110130008/0110 ■-e-■ -e- 2. Wäscheweichspülmittel nach Anspruch 1 enthaltend 8 bis 6 Gew.-? einer oder mehrerer Verbindungen der Formel I, II oder III und 0,5 bis 2,5 Gew.-% eines Fettsäureethanolämid-polyglykolethers der Formel IV.2. Fabric softener according to claim 1 containing 8 to 6 wt.? one or more compounds of the Formula I, II or III and 0.5 to 2.5% by weight of a fatty acid ethanol amide polyglycol ether of the formula IV. 130008/0110130008/0110
DE19792930061 1979-07-25 1979-07-25 SOFT SOFTENER Withdrawn DE2930061A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE19792930061 DE2930061A1 (en) 1979-07-25 1979-07-25 SOFT SOFTENER
AT80104269T ATE5662T1 (en) 1979-07-25 1980-07-19 LAUNDRY SOFTENER.
EP80104269A EP0023334B1 (en) 1979-07-25 1980-07-19 Fabric softener
DE8080104269T DE3065943D1 (en) 1979-07-25 1980-07-19 Fabric softener
JP10064180A JPS5620677A (en) 1979-07-25 1980-07-24 Fabric softening agent
BR8004626A BR8004626A (en) 1979-07-25 1980-07-24 SOFTENING RINSE COMPOSITION OF CLOTHING
CA000356977A CA1153510A (en) 1979-07-25 1980-07-24 Fabric softeners

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19792930061 DE2930061A1 (en) 1979-07-25 1979-07-25 SOFT SOFTENER

Publications (1)

Publication Number Publication Date
DE2930061A1 true DE2930061A1 (en) 1981-02-19

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DE19792930061 Withdrawn DE2930061A1 (en) 1979-07-25 1979-07-25 SOFT SOFTENER
DE8080104269T Expired DE3065943D1 (en) 1979-07-25 1980-07-19 Fabric softener

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE8080104269T Expired DE3065943D1 (en) 1979-07-25 1980-07-19 Fabric softener

Country Status (6)

Country Link
EP (1) EP0023334B1 (en)
JP (1) JPS5620677A (en)
AT (1) ATE5662T1 (en)
BR (1) BR8004626A (en)
CA (1) CA1153510A (en)
DE (2) DE2930061A1 (en)

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Publication number Priority date Publication date Assignee Title
US4439335A (en) * 1981-11-17 1984-03-27 The Procter & Gamble Company Concentrated fabric softening compositions
DE3150178A1 (en) * 1981-12-18 1983-06-30 Hoechst Ag, 6230 Frankfurt "CONCENTRATED SOFT SOFT DETERGENT"
DE3150179A1 (en) * 1981-12-18 1983-06-23 Hoechst Ag, 6230 Frankfurt CONCENTRATED PRE-MIXTURES OF SOFT SOFTENER
JPS58144175A (en) * 1982-02-23 1983-08-27 ライオン株式会社 Article for treating fiber product
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
GB8410319D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous fabric softening composition
GB8410320D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous fabric softening composition
GB8410321D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
GB8430301D0 (en) * 1984-11-30 1985-01-09 Swan Thomas & Co Ltd Compositions of matter for fabric softeners
EP1445303A3 (en) * 1994-10-14 2004-10-20 Kao Corporation Liquid softener composition
GB2319180B (en) * 1996-11-12 2001-01-17 Reckitt & Colman Inc Mycobacterial compositions
DE19651447C1 (en) * 1996-12-11 1997-10-02 Henkel Kgaa Textile or hair conditioners having improved performance
DE19708133C1 (en) * 1997-02-28 1997-12-11 Henkel Kgaa Conditioner for textile and keratin fibres useful as e.g. laundry or hair conditioner
US6635607B2 (en) * 2001-05-15 2003-10-21 Ici Americas Inc. Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants
JP7415563B2 (en) 2020-01-07 2024-01-17 富士フイルムビジネスイノベーション株式会社 Information processing device and program

Family Cites Families (3)

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Publication number Priority date Publication date Assignee Title
BE545267A (en) *
US3451927A (en) * 1964-07-08 1969-06-24 Lever Brothers Ltd Fabric conditioner
DE2605502A1 (en) * 1976-02-12 1977-08-18 Exquisit Kosmetik Gmbh Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester

Also Published As

Publication number Publication date
EP0023334A1 (en) 1981-02-04
EP0023334B1 (en) 1983-12-21
JPS6338470B2 (en) 1988-07-29
CA1153510A (en) 1983-09-13
BR8004626A (en) 1981-02-03
ATE5662T1 (en) 1984-01-15
JPS5620677A (en) 1981-02-26
DE3065943D1 (en) 1984-01-26

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