JPS6338470B2 - - Google Patents

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Publication number
JPS6338470B2
JPS6338470B2 JP55100641A JP10064180A JPS6338470B2 JP S6338470 B2 JPS6338470 B2 JP S6338470B2 JP 55100641 A JP55100641 A JP 55100641A JP 10064180 A JP10064180 A JP 10064180A JP S6338470 B2 JPS6338470 B2 JP S6338470B2
Authority
JP
Japan
Prior art keywords
alkyl
methyl
carbon atoms
cation
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55100641A
Other languages
Japanese (ja)
Other versions
JPS5620677A (en
Inventor
Mai Adorufu
Uaruteru Byutsukingu Hansu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of JPS5620677A publication Critical patent/JPS5620677A/en
Publication of JPS6338470B2 publication Critical patent/JPS6338470B2/ja
Granted legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

1. Fabric softeners in the form of an aqueous solution or dispersion, which contain from 1 to 15% by weight of one or several compounds of formulae I to III see diagramm : EP0023334,P5,F1 see diagramm : EP0023334,P5,F2 see diagramm : EP0023334,P5,F3 in which R1 is alkyl or alkenyl of from 10 to 30 carbon atoms, preferably from 8 to 14 carbon atoms, R2 is alkyl of from 1 to 4 carbon atoms, preferably methyl, R3 is methyl or hydrogen, m is a number of from 1 to 15, preferably 1, and A is an anion, such as Cl (cation) , Br (cation) , R2 OSO3 (cation) or R2 OPO3 (cation) , and from 0.01 to 4, preferably from 0.5 to 2.5%, by weight of a fatty acid ethanolamine polyglycol ether of formula IV see diagramm : EP0023334,P5,F4 in which R4 is C4 -C20 -alkyl, preferably C8 -C16 -alkyl, n is a number of from 2 to 20, preferably from 2 to 6, x and y represent hydrogen or methyl, but are not methyl at the same time and additionally water and auxiliaries and substances usual in fabric softeners in an amount to complete 100% with the proviso that these auxiliaries and substances do not constitute surfactants.

Description

【発明の詳細な説明】 洗浄した繊維材料殊にセルロース繊維からなる
該繊維材料は乾燥後不快なかたさを示すことが知
られている。これは特に洗浄を自動洗浄機で行わ
れるときに生ずる。この望ましくない硬い手ざわ
りは、織物を洗浄後すゝぎ浴中で、分子中に少く
とも２個の長鎖脂肪族残基を含有する陽イオン物
質で処理することにより取り除くことができる。
実際この目的には殊に水に分散し得るジアルキル
ジメチルアンモニウム塩が採用されている。併し
この生成物は過剰に配量すると処理した織物を疎
水性にしそしてこれにより再湿潤性を妨げる欠点
を有する。DETAILED DESCRIPTION OF THE INVENTION It is known that washed fibrous materials, especially those consisting of cellulose fibers, exhibit an unpleasant stiffness after drying. This occurs especially when cleaning is carried out in automatic washers. This undesirable hard texture can be removed by treating the fabric in a rinse bath after washing with a cationic substance containing at least two long-chain aliphatic residues in the molecule.
In practice, particularly water-dispersible dialkyldimethylammonium salts are employed for this purpose. However, this product has the disadvantage that, when dosed in excess, it renders the treated fabric hydrophobic and thus impedes rewetting.

本発明者は、繊維柔軟剤として使用される第４
級アンモニウム化合物を脂肪酸エタノールアミド
ポリグリコールエーテルと組合せれば上記困難を
取り除くことができることを見出した。それ故本
発明の対象は、式乃至 （式中R1は14−30個の炭素原子好ましくは14
−20個の炭素原子を有するアルキル又はアルケニ
ルを、R2は１−４個の炭素原子を有するアルキ
ル好ましくはメチルを、R3はメチル又は水素を、
ｍは１乃至15好ましくは１の数をそしてＡは陰イ
オン好ましくはCl(-)、Br(-)、R2OSO3 (-)又は
R2OPO3 (-)を意味する）の、一又は多数個の化合
物１乃至15好ましくは２乃至16重量％及び式 （式中R4はC4−C20−アルキル好ましくはC8−
C16−アルキルを、ｎは２乃至20好ましくは２乃
至６の数を、ｘ及びｙは水素又はメチルを意味
し、但しその際ｘ及びｙは同時にはメチルを意味
しない）の脂肪酸エタノールアミドポリグリコー
ルエーテル0.01−４好ましくは0.5−2.5重量％を
含有する水溶液又は分散液の形態の繊維柔軟剤で
ある。 The inventor has discovered that the fourth
It has been found that the above-mentioned difficulties can be overcome by combining grade ammonium compounds with fatty acid ethanolamide polyglycol ethers. The object of the invention is therefore the formula (wherein R 1 is 14-30 carbon atoms, preferably 14
- alkyl or alkenyl having 20 carbon atoms; R 2 is alkyl having 1-4 carbon atoms, preferably methyl; R 3 is methyl or hydrogen;
m is a number from 1 to 15, preferably 1, and A is an anion, preferably Cl (-) , Br (-) , R 2 OSO 3 (-) or
1 to 15 preferably 2 to 16% by weight of one or more compounds of the formula R 2 OPO 3 (-) and the formula (In the formula, R 4 is C 4 -C 20 -alkyl, preferably C 8 -
C 16 -alkyl, n is a number from 2 to 20, preferably 2 to 6, x and y are hydrogen or methyl, with the proviso that x and y do not simultaneously mean methyl). A fiber softener in the form of an aqueous solution or dispersion containing 0.01-4%, preferably 0.5-2.5% by weight of glycol ether.

化合物、及びと式の化合物とのこの組
合せは任意の繊維材料殊に天然又は再生セルロー
ス、羊毛、セルロース−アセテート、−トリアセ
テート、ポリアミド、ポリアクリルニトリル、ポ
リエステル、ポリプロピレンからなる繊維材料に
気持ちがよくそして柔かい手ざわりを与える。殊
に有利なのは木綿からなるテリー織物及びアンダ
ー・ウエアへの後処理剤としての使用である。こ
の織物柔軟剤の製造は、個別的成分の水への簡単
な混合又は分散により行われる。本発明によるこ
の繊維柔軟剤は式乃至の化合物を一つのみ含
有するか又は上記の範囲内で式乃至の二又は
多数の化合物からなる混合物を含有することがで
きる。式乃至の、二又は多数の化合物からな
る混合物が存在すれば、その混合比は相互に完全
に臨界的でなくそして任意の値を有することがで
きる。 This combination of compounds and compounds of the formula is pleasant on any textile material, especially textile materials consisting of natural or regenerated cellulose, wool, cellulose-acetate, -triacetate, polyamide, polyacrylonitrile, polyester, polypropylene. Gives a soft texture. Particularly advantageous is the use as after-treatment agent for cotton terry fabrics and underwear. The fabric softeners are produced by simple mixing or dispersion of the individual components in water. The fabric softener according to the invention can contain only one compound of the formula or a mixture of two or more compounds of the formula within the ranges mentioned above. If mixtures of two or more compounds of the formula are present, the mixing ratios are not completely critical to each other and can have arbitrary values.

更に本発明による繊維柔軟剤はなお別の、繊維
柔軟剤の濃縮体中に既に混入されるか又はすぐ使
える、稀釈した繊維柔軟剤に別個に添加される、
物質及び助剤を含有することができる。これらは
繊維柔軟剤に既に使用されている物質又は助剤例
えば陽イオン又は非イオン表面活性物質、電解
質、中和剤、有機錯化合物形成剤、螢光増白剤又
は可溶化剤並びに染料及び香料である。これら
は、処理さるべき繊維材料の手ざわり又はその他
の性質の追加的影響に又は粘度調整又はPH−調整
又は低温安定性の向上に使用される。 Furthermore, the fabric softener according to the invention is added separately to a further diluted fabric softener, either already mixed into a concentrate of fabric softener or ready for use.
It may contain substances and auxiliaries. These are substances or auxiliaries already used in textile softeners, such as cationic or nonionic surface-active substances, electrolytes, neutralizing agents, organic complex formers, fluorescent brighteners or solubilizers, as well as dyes and fragrances. It is. These are used to additionally influence the hand or other properties of the fiber material to be treated or to adjust the viscosity or adjust the pH or improve the low-temperature stability.

この繊維柔軟剤の使用は、これらを繊維洗浄に
続いて最後のすゝぎ水に加えることによつて常法
の如く行われる。この様に処理した繊維材料を次
に乾燥する。その際繊維材料の再湿潤性が市販の
剤と比軟して著しく改善される。 The use of the fabric softeners is carried out in a conventional manner by adding them to the final rinse water following fabric washing. The fiber material treated in this way is then dried. In this case, the rewetting properties of the fiber material are significantly improved compared to commercially available agents.

次の例に於ては若干の本発明による繊維柔軟剤
が記載されている。百分率の記載は全ての場合重
量パーセントである。この繊維柔軟剤の製造は全
ての場合冷温下個別的成分の水性溶液を簡単に混
合して行われる。 In the following examples some fabric softeners according to the invention are described. All percentages are percentages by weight. The preparation of the fabric softeners is carried out in all cases by simply mixing aqueous solutions of the individual components in the cold.

例 １ ジステアリルジメチルアンモニウムクロリド
４％ やし油脂肪酸エタノールアミド＋５エチレンオ
キシド ２％ 染料、香料、残り 水 合計100％ 例 ２ ジ獣脂脂肪アルキルジメチルアンモニウムクロ
リド 5.3％ やし油脂肪酸エタノールアミド＋５エチレンオ
キシド ２％ 染料、香料及び残り 水 合計100％ 例 ３ R1＝C10−C18−アルケニル、R2＝CH3、Ａ＝
CH3OSO3の式のジアルキルイミダゾリン
誘導体 5.3％ やし油脂肪酸エタノールアミド＋５エチレンオ
キシド ２％ 染料、香料及び残り 水 合計100％ 例 ４ 比較配合物 ジステアリルジメチルアンモニウムクロリド
６％ 非イオン表面活性剤ノニルフエノールオキシエ
チレート＋10エチレンオキシド １％ 染料、香料及び残り 水 合計100％ この繊維柔軟剤を毛管上昇法（GIN第53924
号）により再湿潤性へのその影響に関して試験す
る。Example 1 Distearyldimethylammonium chloride
4% Coconut oil fatty acid ethanolamide + 5 ethylene oxide 2% Dye, fragrance, remainder Water Total 100% Example 2 Ditallow fatty alkyldimethylammonium chloride 5.3% Coconut oil fatty acid ethanolamide + 5 ethylene oxide 2% Dye, fragrance, remainder Water Total 100 % Example 3 R 1 = C 10 -C 18 -alkenyl, R 2 = CH 3 , A=
Dialkyl imidazoline derivative of the formula CH 3 OSO 3 5.3% Coconut oil fatty acid ethanolamide + 5 ethylene oxide 2% Dyes, fragrances and balance Water Total 100% Example 4 Comparative formulation distearyldimethylammonium chloride
6% Nonionic surfactant nonyl phenol oxyethylate + 10 ethylene oxide 1% Dyes, fragrances and remainder Water Total 100%
No. 1) to test for its effect on rewetting properties.

この場合平織りの木綿織物を本発明による混合
物で処理する。比軟のため市販の柔軟剤を使用す
る（例４）。この試験法により例１−４の混合物
に就て次表に於て示した結果が得られる。この場
合仕上げ処理していない繊維の毛管上昇は100％
と定められている。 In this case plain-woven cotton fabrics are treated with the mixture according to the invention. A commercially available softener is used for specific softness (Example 4). This test method gives the results shown in the following table for the mixtures of Examples 1-4. In this case, the capillary rise of unfinished fibers is 100%.
It is stipulated that

繊維柔軟剤１ｇ／織物Kg に於ける毛管上昇（％） 例１ 73％ 例２ 70％ 例３ 71％ 例４（比較配合物） 50％ 成果は、本発明による繊維柔軟剤の組合せは市
販の生成物と比較して改善された吸収能を有する
ことを示している。 Capillary rise (%) in 1g of fabric softener/Kg of fabric Example 1 73% Example 2 70% Example 3 71% Example 4 (comparative formulation) 50% The results show that the fabric softener combination according to the invention has an improved absorption capacity compared to commercial products. It shows.

Claims (1)

【特許請求の範囲】 １ 式乃至 （式中R1は14−30個の炭素原子好ましくは14
−20個の炭素原子を有するアルキル又はアルケニ
ルを、R2は１−４個の炭素原子を有するアルキ
ル好ましくはメチルを、R3はメチル又は水素を、
ｍは１乃至15好ましくは１の数を、そしてＡは陰
イオン、好ましくはCl(-)、Br(-)、R2OSO3 (-)又は
R2OPO3 (-)を意味する） で示される一又は多数個の化合物１乃至15重量％
及び式 （式中R4はC4〜C20−アルキル好ましくはC8〜
C16−アルキルを、ｎは２乃至20好ましくは２乃
至６の数を、ｘ及びｙは水素又はメチルを意味
し、但しその際ｘ及びｙは同時にはメチルを意味
しない） で示される脂肪酸エタノールアミドポリグリコー
ルエーテル0.01−４重量％、好ましくは0.5−2.5
重量％を含有する水溶液又は分散液の形態の繊維
柔軟剤。[Claims] 1 formula to (wherein R 1 is 14-30 carbon atoms, preferably 14
- alkyl or alkenyl having 20 carbon atoms; R 2 is alkyl having 1-4 carbon atoms, preferably methyl; R 3 is methyl or hydrogen;
m is a number from 1 to 15, preferably 1, and A is an anion, preferably Cl (-) , Br (-) , R 2 OSO 3 (-) or
1 to 15% by weight of one or more compounds represented by R 2 OPO 3 (-)
and expression (In the formula, R 4 is C 4 -C 20 -alkyl, preferably C 8 -
C 16 -alkyl, n is a number from 2 to 20, preferably 2 to 6, x and y are hydrogen or methyl, provided that x and y do not mean methyl at the same time) Amido polyglycol ether 0.01-4% by weight, preferably 0.5-2.5
% by weight in the form of an aqueous solution or dispersion.
JP10064180A 1979-07-25 1980-07-24 Fabric softening agent Granted JPS5620677A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19792930061 DE2930061A1 (en) 1979-07-25 1979-07-25 SOFT SOFTENER

Publications (2)

Publication Number Publication Date
JPS5620677A JPS5620677A (en) 1981-02-26
JPS6338470B2 true JPS6338470B2 (en) 1988-07-29

Family

ID=6076677

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10064180A Granted JPS5620677A (en) 1979-07-25 1980-07-24 Fabric softening agent

Country Status (6)

Country Link
EP (1) EP0023334B1 (en)
JP (1) JPS5620677A (en)
AT (1) ATE5662T1 (en)
BR (1) BR8004626A (en)
CA (1) CA1153510A (en)
DE (2) DE2930061A1 (en)

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US11146701B2 (en) 2020-01-07 2021-10-12 Fujifilm Business Innovation Corp. Information processing apparatus and non-transitory computer readable medium

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Publication number Priority date Publication date Assignee Title
US4439335A (en) * 1981-11-17 1984-03-27 The Procter & Gamble Company Concentrated fabric softening compositions
DE3150179A1 (en) * 1981-12-18 1983-06-23 Hoechst Ag, 6230 Frankfurt CONCENTRATED PRE-MIXTURES OF SOFT SOFTENER
DE3150178A1 (en) * 1981-12-18 1983-06-30 Hoechst Ag, 6230 Frankfurt "CONCENTRATED SOFT SOFT DETERGENT"
JPS58144175A (en) * 1982-02-23 1983-08-27 ライオン株式会社 Article for treating fiber product
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
GB8410319D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous fabric softening composition
GB8410321D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
GB8410320D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous fabric softening composition
GB8430301D0 (en) * 1984-11-30 1985-01-09 Swan Thomas & Co Ltd Compositions of matter for fabric softeners
EP1445303A3 (en) * 1994-10-14 2004-10-20 Kao Corporation Liquid softener composition
GB2319180B (en) * 1996-11-12 2001-01-17 Reckitt & Colman Inc Mycobacterial compositions
DE19651447C1 (en) * 1996-12-11 1997-10-02 Henkel Kgaa Textile or hair conditioners having improved performance
DE19708133C1 (en) * 1997-02-28 1997-12-11 Henkel Kgaa Conditioner for textile and keratin fibres useful as e.g. laundry or hair conditioner
US6635607B2 (en) 2001-05-15 2003-10-21 Ici Americas Inc. Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants

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Publication number Priority date Publication date Assignee Title
BE545267A (en) *
US3451927A (en) * 1964-07-08 1969-06-24 Lever Brothers Ltd Fabric conditioner
DE2605502A1 (en) * 1976-02-12 1977-08-18 Exquisit Kosmetik Gmbh Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester

Cited By (1)

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Publication number Priority date Publication date Assignee Title
US11146701B2 (en) 2020-01-07 2021-10-12 Fujifilm Business Innovation Corp. Information processing apparatus and non-transitory computer readable medium

Also Published As

Publication number Publication date
ATE5662T1 (en) 1984-01-15
EP0023334B1 (en) 1983-12-21
DE2930061A1 (en) 1981-02-19
CA1153510A (en) 1983-09-13
JPS5620677A (en) 1981-02-26
EP0023334A1 (en) 1981-02-04
BR8004626A (en) 1981-02-03
DE3065943D1 (en) 1984-01-26

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