DE897010C - Floor coverings - Google Patents

Floor coverings

Info

Publication number
DE897010C
DE897010C DEC4428A DEC0004428A DE897010C DE 897010 C DE897010 C DE 897010C DE C4428 A DEC4428 A DE C4428A DE C0004428 A DEC0004428 A DE C0004428A DE 897010 C DE897010 C DE 897010C
Authority
DE
Germany
Prior art keywords
parts
styrene
vinyl chloride
floor coverings
fillers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEC4428A
Other languages
German (de)
Inventor
Paul Dr Kraenzlein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE1949815404T priority Critical patent/DE815404C/en
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Priority to DEC4428A priority patent/DE897010C/en
Application granted granted Critical
Publication of DE897010C publication Critical patent/DE897010C/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/065—PVC together with other resins except polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/007—Cork
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Floor Finish (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

(WiGBl. S. 175)(WiGBl. P. 175)

AUSGEGEBEN AM 16. NOVEMBER 1953ISSUED NOVEMBER 16, 1953

C 4428 IVc j 3g bC 4428 IVc j 3g b

FußbodenbelagstoffeFloor coverings

Das Patent 815 404 betrifft die Verwendung von weichgemachten Mischpolymerisaten des Vinylchlorids mit Styrol und Füllstoffen als Fußbodenbelagstoff.The 815,404 patent relates to the use of plasticized copolymers of vinyl chloride with styrene and fillers as flooring material.

Es wurde nun gefunden, daß die Mischungen aus weichgemachten Mischpolymerisaten des Vinylchlorids mit Styrol und Füllstoffen in ihrer Verwendbarkeit als Fußbodenbelagstoff noch weiter verbessert werden können, wenn man zusätzlich Leinölfirnis, Linoxyn bzw. Kondensationsprodukte aus Dicarbonsäuren mit mehrwertigen Alkoholen mitverwendet.It has now been found that the mixtures of plasticized copolymers of vinyl chloride with styrene and fillers their usability as floor covering material can be further improved can, if you also use boiled linseed oil, linoxyn or condensation products from dicarboxylic acids polyhydric alcohols are also used.

Besonders wertvolle Vinylchlorid-Styrol-Mischpolymerisate sind diejenigen, bei denen der Vinylchloridanteil den Styrolanteil übertrifft. Geeignete Kondensationsprodukte aus Dicarbonsäuren und mehrwertigen Alkoholen werden z. B. aus Bernstein-, Glutar-, Adipin- oder Sebazinsäure einerseits und Glycerin, Trimethylolpropan oder Pentaerythrit andererseits erhalten. Das Mengenverhältnis zwischen dem Mischpolymerisat einerseits und dem Leinölfirnis, Linoxyn oder dem Kondensationsprodukt andererseits kann in weiten Grenzen schwanken und richtet sich nach dem gewünschten Ergebnis. Die aus den Massen erhaltenen Bodenbelagstoffe zeichnen sich durch glatte Oberfläche, guten Abrieb, gute Elastizität und Wasser-.festigkeit vor den aus Leinölzement allein hergestellten Fußbodenbelagstoffen aus und besitzen erheblich verkürzte Trockenzeiten.Particularly valuable vinyl chloride-styrene copolymers are those in which the vinyl chloride content exceeds the styrene content. Suitable condensation products from dicarboxylic acids and polyvalent ones Alcohols are z. B. from succinic, glutaric, adipic or sebacic acid on the one hand and glycerol, trimethylolpropane or pentaerythritol on the other hand. The quantitative ratio between the copolymer on the one hand and the linseed oil varnish, linoxyn or the condensation product on the other hand, in vary widely and depends on the desired result. Those obtained from the masses Floor coverings are characterized by a smooth surface, good abrasion, good elasticity and water resistance from floor coverings made from linseed oil cement alone and have considerably shortened Dry seasons.

Beispiel 1example 1

50 Teile eines krümeligen Mischpolymerisates, hergestellt aus 80 Teilen Vinylchlorid und 20 Teilen Styrol, werden mit 33 Teilen Dioctylphthalat und 166 Teilen50 parts of a crumbly copolymer made from 80 parts of vinyl chloride and 20 parts of styrene, are with 33 parts of dioctyl phthalate and 166 parts

Linoxyn auf einer Mischwalze bei 8o° plastifiziert, worauf 460 Teile einer Mischung aus Korkmehl, Holzmehl und Ocker eingewalzt werden. Man zieht die plastische Masse auf einem Kalander zu einer Bahn aus und erhält einen biegsamen Fußbodenbelagstoff, der noch 5 Tage einer Nachtrocknung bei 6o° unterworfen wird.Linoxyn plasticized on a mixing roller at 8o °, whereupon 460 parts of a mixture of cork flour, wood flour and ocher are rolled in. One pulls the plastic mass on a calender into a web and is given a flexible floor covering material, the is subjected to post-drying at 60 ° for another 5 days.

Beispiel 2Example 2

50 Teile eines krümeligen Mischpolymerisates, hergestellt aus 70 Teilen Vinylchlorid und 30 Teilen Styrol, werden mit 33 Teilen Dioctylphthalat und 166 Teilen eines zähplastischen Kondensationsproduktes aus gleichen Teilen Adipinsäure und Trimethylolpropan mit 460 Teilen Füllstoffen auf einer Mischwalze bei 80° vermischt. Nach eingehender Homogenisierung wird die Masse wie üblich zu Bahnen ausgezogen und etwa 5 Tage bei einer Temperatur von 50 bis 6o° getrocknet.50 parts of a crumbly copolymer made from 70 parts of vinyl chloride and 30 parts Styrene, with 33 parts of dioctyl phthalate and 166 parts of a viscous condensation product from equal parts of adipic acid and trimethylolpropane with 460 parts of fillers on one Mixing roller mixed at 80 °. After thorough homogenization, the mass becomes webs as usual drawn out and dried for about 5 days at a temperature of 50 to 60 °.

Beispiel 3Example 3

50 Teile des im Beispiel 1 verwendeten Vinylchlorid-Styrol-Mischpolymerisates werden mit 33 Teilen Dioctylphthalat auf einer Mischwalze bei 80° plastifiziert und mit weiteren 83 Teilen Leinölzement und 83 Teilen eines zähplastischen Kondensationsproduktes aus gleichen Teilen Adipinsäure und Trimethylolpropan sowie 460 Teilen Füllstoffen in einem Mischwalzwerk vermischt. Nach dem Ausziehen der Masse auf einem Kalander mit Jute als Unterlage erhält man einen Bodenbelag.50 parts of the vinyl chloride-styrene copolymer used in Example 1 are plasticized with 33 parts of dioctyl phthalate on a mixing roll at 80 ° and with a further 83 parts of linseed oil cement and 83 parts of a viscoplastic condensation product from equal parts of adipic acid and trimethylolpropane as well as 460 parts of fillers in a mixing mill mixed. After pulling out the mass on a calender with jute as a base, you get one Flooring.

Claims (1)

Patentanspruch:Claim: Die Verwendung von Mischungen aus weichgemachten Mischpolymerisaten des Vinylchlorids mit Styrol, Leinölfirnis, Linoxyn und bzw. oder Kondensationsprodukten von zweiwertigen Carbonsäuren mit mehrwertigen Alkoholen und Füllstoffen als Fußbodenbelagstoffe.The use of mixtures of plasticized copolymers of vinyl chloride with styrene, linseed oil varnish, linoxyn and / or condensation products of dibasic carboxylic acids with polyhydric alcohols and fillers as flooring materials. 1 5543 11.531 5543 11.53
DEC4428A 1951-07-08 1951-07-08 Floor coverings Expired DE897010C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE1949815404T DE815404C (en) 1951-07-08 1949-05-24 Floor covering
DEC4428A DE897010C (en) 1951-07-08 1951-07-08 Floor coverings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC4428A DE897010C (en) 1951-07-08 1951-07-08 Floor coverings

Publications (1)

Publication Number Publication Date
DE897010C true DE897010C (en) 1953-11-16

Family

ID=7013371

Family Applications (2)

Application Number Title Priority Date Filing Date
DE1949815404T Expired DE815404C (en) 1951-07-08 1949-05-24 Floor covering
DEC4428A Expired DE897010C (en) 1951-07-08 1951-07-08 Floor coverings

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE1949815404T Expired DE815404C (en) 1951-07-08 1949-05-24 Floor covering

Country Status (1)

Country Link
DE (2) DE815404C (en)

Also Published As

Publication number Publication date
DE815404C (en) 1951-10-01

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