DE839716C - Process for the manufacture of flooring - Google Patents

Process for the manufacture of flooring

Info

Publication number
DE839716C
DE839716C DENDAT839716D DE839716DA DE839716C DE 839716 C DE839716 C DE 839716C DE NDAT839716 D DENDAT839716 D DE NDAT839716D DE 839716D A DE839716D A DE 839716DA DE 839716 C DE839716 C DE 839716C
Authority
DE
Germany
Prior art keywords
parts
styrene
flooring
manufacture
butadiene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DENDAT839716D
Other languages
German (de)
Inventor
Marl Dr. Wilhelm Klein (Kr. Recklinghausen) und Dr. Paul Kränzlein, Marl (Kr. Recklinghausen)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Publication date
Application granted granted Critical
Publication of DE839716C publication Critical patent/DE839716C/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/10Copolymers of styrene with conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/10Copolymers of styrene with conjugated dienes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N1/00Linoleum, e.g. linoxyn, polymerised or oxidised resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

COWGBl. S. ITS)COWGBl. S. ITS)

AUSGEGEBEN AM 23. MAI 1952ISSUED MAY 23, 1952

Cio82lVc/-3pbCio82lVc / -3pb

Es wurde gefunden, daß man ein als Fußbodenbelag verwendbares Material mit vorzüglichen Eigenschaften herstellen kann, wenn man mit Alterungsschutzmitteln, wie o-Kresylcamphan oder 1 'henyl-/)'-na|>hthylamin, versetzte Styrol-Butadien-Mischpolymerisate mit überwiegendem Styrolgehalt als Bindemittel für die Füllstoffe verwendet. Geeignete Mischpolymerisate der erwähnten Art enthalten etwa 55 bis 90% Styrol und 45 bis 10% Butadien. Sie können beispielsweise durch Emulsionspolymerisation nach an sich bekanntem Verfahren hergestellt werden und sowohl in Form ihrer wäßrigen Dispersionen als auch im festen Zustand mit den bei der Herstellung von Fußbodenbelag gebräuchlichen Füllstoffen, wie Korkmehl, Holzmehl, Kreide, Farbstoffe usw., vermischt werden.It has been found that one can use a floor covering usable material with excellent properties can be produced if you can use Anti-aging agents such as o-cresylcamphane or 1'henyl - /) '- na |> ethylamine, mixed styrene-butadiene copolymers with a predominant styrene content used as a binder for the fillers. Suitable Copolymers of the type mentioned contain about 55 to 90% styrene and 45 to 10% Butadiene. You can, for example, by emulsion polymerization by methods known per se are produced and both in the form of their aqueous dispersions and in the solid state with the fillers commonly used in the production of floor coverings, such as cork flour, wood flour, Chalk, dyes, etc., can be mixed.

Gewünschtenfalls kann man durch Mitverwendung von Weichmachungsmitteln, z. B. Ester der Phthalsäure, die Oberflächenhärte des Endstoffes in weiten Grenzen abändern. Man erhält Fußbodenbelagstoffe mit guten elastischen Eigenschaften, die gegenüber dem Linoleum den Vorteil aufweisen, daß zu ihrer Herstellung keine Gewebeunterlagen (Jute- oder Papiergeflecht) benötigt werden.If desired, you can by using plasticizers such. B. Esters of phthalic acid, change the surface hardness of the end product within wide limits. Floor coverings are obtained with good elastic properties, which have the advantage over linoleum, that no fabric documents (jute or paper braid) are required for their production.

Beispiel 1example 1

250 Teile eines krümeligen, 0,5 bis 1 °/o eines Alterungsschutzmittels enthaltenden Mischpolymerisates, hergestellt aus 70 Teilen Styrol und 30Teilen Butadien durch Emulsionspolymerisation, werden auf der Mischwalze mit 40 Teilen Dibutylphthalat plastifiziert, worauf ein Gemisch aus 500 Teilen250 parts of a crumbly copolymer containing 0.5 to 1% of an anti-aging agent, produced from 70 parts of styrene and 30 parts of butadiene by emulsion polymerization Plasticized on the mixing roll with 40 parts of dibutyl phthalate, whereupon a mixture of 500 parts

Korkmehl und 200 Teilen Ocker eingewalzt wird. Man zieht die zäh-plastische Masse auf einem Kalander zu einer Bahn aus.Cork flour and 200 parts of ocher is rolled in. One pulls the viscous-plastic mass on one Calender into a web.

Beispiel 2Example 2

250 Teile eines krümeligen, 0,5 bis 1 % eines Alterungsschutzmittels enthaltenden Mischpolymerisates, hergestellt durch Emulsionspolymerisation von 80 Teilen Styrol und 20 Teilen Butadien, werden auf der Mischwalze unter Zusatz von 50 Teilen eines Weichmachungsmittels plastifiziert, worauf eine Mischung aus 250Teilen Korkmehl, 250Teilen Holzmehl und 200 Teilen Ocker eingewalzt wird. Man zieht die erhaltene zäh-plastische Masse auf dem Kalander zu Platten aus.250 parts of a crumbly copolymer containing 0.5 to 1% of an anti-aging agent, prepared by emulsion polymerization of 80 parts of styrene and 20 parts of butadiene Plasticized on the mixing roller with the addition of 50 parts of a plasticizer, whereupon a mixture of 250 parts cork flour, 250 parts wood flour and 200 parts ocher is rolled in. The viscous-plastic mass obtained is drawn out into sheets on the calender.

Beispiel 3Example 3

Alan mischt in einem Kneter 1000 Teile einer 3o°/oigen wäßrigen Dispersion eines 0,5 Ibis 1 °/o eines Alterungsschutzmittels enthaltenden Misch- ao polymerisates, das aus 70 Teilen Styrol und 30 Teilen Butadien erhalten wurde, mit 250 Teilen Korkmehl, 250 Teilen Holzmehl, 200 Teilen Ocker und 40 Teilen eines Weichmachungsmittels. Nach beendeter Mischung trocknet man die erhaltene Masse im geheizten Kneter oder in erwärmter Luft, plastifiziert das Material auf einer jcr heißen Mischwalze und zieht auf einem Kalander zu einer Bahn aus.Alan mixes in a kneader 1000 parts of a 30% aqueous dispersion of a mixed ao polymer containing 0.5 ibis 1% of an anti-aging agent, obtained from 70 parts of styrene and 30 parts of butadiene, with 250 parts of cork flour, 250 parts Wood flour, 200 parts of ocher and 40 parts of a plasticizer. When the mixing is complete, the resulting mass is dried in a heated kneader or in heated air, the material is plasticized on a hot mixing roll and drawn into a sheet on a calender.

Claims (1)

PATENTANSPRUCH:PATENT CLAIM: Verfahren zur Herstellung von Fußbodenbelag, dadurch gekennzeichnet, daß man mit Alterungsschutzmittel versetzte Styrol-Butadien-Mischpolymerisate mit überwiegendem Styrolgehalt als Bindemittel für die Füllstoffe verwendet.Process for the production of floor covering, characterized in that with Styrene-butadiene copolymers mixed with anti-aging agents with a predominant styrene content used as a binder for the fillers. Q 5020 s. Q 5020 s.
DENDAT839716D 1950-01-21 Process for the manufacture of flooring Expired DE839716C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1026694X 1950-01-21

Publications (1)

Publication Number Publication Date
DE839716C true DE839716C (en) 1952-04-10

Family

ID=7715205

Family Applications (1)

Application Number Title Priority Date Filing Date
DENDAT839716D Expired DE839716C (en) 1950-01-21 Process for the manufacture of flooring

Country Status (2)

Country Link
DE (1) DE839716C (en)
FR (1) FR1026694A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1098908B (en) * 1957-07-24 1961-02-09 Semtex Ltd Process for the production of multi-layer sheets such as floor coverings, wall coverings, table tops, etc. like

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1098908B (en) * 1957-07-24 1961-02-09 Semtex Ltd Process for the production of multi-layer sheets such as floor coverings, wall coverings, table tops, etc. like

Also Published As

Publication number Publication date
FR1026694A (en) 1953-04-30

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