DE887890C - Pest control - Google Patents

Pest control

Info

Publication number
DE887890C
DE887890C DED4171D DED0004171D DE887890C DE 887890 C DE887890 C DE 887890C DE D4171 D DED4171 D DE D4171D DE D0004171 D DED0004171 D DE D0004171D DE 887890 C DE887890 C DE 887890C
Authority
DE
Germany
Prior art keywords
water
soluble salts
carbon atoms
pest control
sulfur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DED4171D
Other languages
German (de)
Inventor
Winfried Dr Hentrich
Christoph Dr Grundmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deutsche Hydrierwerke AG
Original Assignee
Deutsche Hydrierwerke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Hydrierwerke AG filed Critical Deutsche Hydrierwerke AG
Priority to DED4171D priority Critical patent/DE887890C/en
Application granted granted Critical
Publication of DE887890C publication Critical patent/DE887890C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

Schädlingsbekämpfung Gegenstand des Patents 879 181 ist die Verwendung von Gemischen aus schwefelhaltigen Abkömmlingen der Kohlensäure und wasserlöslichen Salzen aus Äthercarbonsäuren als Schädlingsbekämpfungsmittel, insbesondere für tierische und menschliche Parasiten, wie z. B. Läuse. Es wurde nun gefunden, daß sich für diesen Zweck nicht nur wasserlösliche Salze aus Äthercarbonsäuren eignen, sondern daß dafür ganz allgemein wasserlösliche Salze von Verbindungen verwendet werden können, die neben einem oder mehreren aliphatischen oder cycloaliphatischen Resten von q. bis 9 Kohlenstoffatomen saure salzbildende Gruppen enthalten.Pest control The subject of patent 879 181 is the use of mixtures of sulfur-containing derivatives of carbonic acid and water-soluble ones Salts from ether carboxylic acids as pesticides, especially for animal and human parasites such as B. Lice. It has now been found that Not only water-soluble salts of ether carboxylic acids are suitable for this purpose, but that for this very generally water-soluble salts of compounds are used can, in addition to one or more aliphatic or cycloaliphatic radicals from q. up to 9 carbon atoms contain acidic salt-forming groups.

Es kommen hierfür in erster Linie die wasserlöslichen Salze von Carbonsäuren, Sulfocarbonsäuren, Schwefelsäureester, Sulfonsäuren, Phosphorsäureester u. dgl. in Betracht. Die Kohlenwasserstoffreste dieser Verbindungen sollen aliphatischen oder cycloaliphatischen Charakter und eine Kohlenstoffatomzahl von q. bis 9, insbesondere von 7 bis 9 besitzen. Sie können daneben durch Schwefel, Stickstoff, Carbonyl-, Sulfon-, Ester- oder Säureamidgruppen u. dgl. unterbrochen sein oder auch Substituenten enthalten, wie Halogen, Hydroxylgruppen usw. Produkte dieser und der vorerwähnten Art sind in der Technik seit langem bekannt und vielfach beschrieben.There are primarily the water-soluble salts of carboxylic acids, Sulfocarboxylic acids, sulfuric acid esters, sulfonic acids, phosphoric acid esters and the like. into consideration. The hydrocarbon radicals of these compounds are said to be aliphatic or cycloaliphatic character and a number of carbon atoms of q. to 9, in particular from 7 to 9 own. You can also use sulfur, nitrogen, carbonyl, Sulfonic, ester or acid amide groups and the like may be interrupted or substituents contain, such as halogen, hydroxyl groups, etc., products of these and the aforementioned Art have long been known in the art and have been described many times.

Besonderes Interesse beanspruchen die wasserlöslichen Salze solcher Verbindungen, die unmittelbar oder mittelbar aus Abfallfettstoffen gewonnen werden. Hierfür sind z. B. zu nennen Abfallfettsäuren aus natürlichen Fettstoffen mit q. bis 9 Kohlenstoffatomen im Molekül, Abfallfettsäuren entsprechender Kohlenstoffatomzahl aus der Paraffinoxydation, Sulfonate der Alkohole, die aus den vorgenannten Fettsäuregruppen durch Reduktion erhalten werden, Sulfonate niedermolekularer Alkohole aus der Paraffinoxydation oder höherer Alkohole der Methanolsynthese sowie Fettsäuren, die aus diesen Alkoholen, beispielsweise durch Alkalischmelze, erhalten werden, ferner Sulfonate von Alkoholen, die durch Anlagerung von Kohlenoxyd und Wasserstoff an niedermolekulare Olefine erhalten werden, u. dgl. In ähnlicher Weise lassen sich auch wasserlösliche Salze entsprechender Naphthensäuren verwenden.The water-soluble salts thereof are of particular interest Compounds that are obtained directly or indirectly from waste fatty substances. For this are z. B. to name waste fatty acids from natural fatty substances with q. up to 9 carbon atoms in the molecule, waste fatty acids corresponding to the number of carbon atoms the end the oxidation of paraffin, sulfonates of alcohols from the aforementioned fatty acid groups obtained by reduction, sulfonates of low molecular weight alcohols from paraffin oxidation or higher alcohols of the methanol synthesis as well as fatty acids, which from these alcohols, for example by alkali melt, also sulfonates of alcohols, those caused by the addition of carbon monoxide and hydrogen to low molecular weight olefins and the like. Similarly, water-soluble salts can also be obtained use appropriate naphthenic acids.

Die wasserlöslichen Salze, insbesondere Alkalisalze, dieser saure salzbildende Gruppen enthaltenden Verbindungen sind geeignet, die wasserlöslichen Salze von Äthercarbonsäuren in den Schädlingsbekämpfungsmitteln des Patents 879 r8r, welche als wirksames Prinzip schwefelhaltige Derivate der Kohlensäure enthalten, zu vertreten. Sie sind geeignet, die dort genannten schwefelhaltigen Derivate der Kohlensäure, z. B. das Sulfocarboxy-äthyl-disulfid, in wäßrige Lösung bzw. Dispersion zu bringen und ihre feine Verteilung auf Trägerstoffen und Substraten, z. B. Textilmaterialien, zu gewährleisten. Diese Mittel sind zudem leicht zugänglich und stehen als Abfallstoffe in unbegrenzten Mengen zur Verfügung.The water-soluble salts, in particular alkali salts, of these compounds containing acidic salt-forming groups are suitable to represent the water-soluble salts of ether carboxylic acids in the pesticides of patent 879 r8r, which contain sulfur-containing derivatives of carbonic acid as an effective principle. They are suitable for the sulfur-containing derivatives of carbonic acid mentioned there, e.g. B. to bring the sulfocarboxy-ethyl disulfide, in aqueous solution or dispersion and their fine distribution on carriers and substrates, eg. B. textile materials to ensure. These funds are also easily accessible and are available in unlimited quantities as waste materials.

Beispiel z 2 Gewichtsteile Sulfocarboxy-butyl-disulfid werden mit 2o Gewichtsteilen eines Gemisches der Natriumsalze von Fettsäuren-mit 7 bis 9 Kohlenstoffatomen, wie sie bei der Oxydation von Paraffin anfallen, unter allmählichem Zusatz von ro Gewichtsteilen Wasser in der Wärme emulgiert. Die entstehende schmierseifenartige Paste kann mit Vorteil zur Reinigung von verlausten Kleidungsstücken Verwendung finden. Beispiel 2 2 Gewichtsteile Tetra-äthyl-thiuramdisulfid werden in zo Gewichtsteilen einer 65°/oigen wäßrigen Paste von Natriumsalzen der sauren Schwefelsäureester aus aliphatischen Alkoholen mit einer mittleren Länge der Kohlenstoffkette von 7 Kohlenstoffatomen unter Erwärmen gelöst. Beim Verdünnen des Gemisches mit Wasser entsteht eine haltbare Emulsion, die zum Imprägnieren von Wäsche Verwendung finden kann. Die so behandelten Kleidungsstücke werden von Kleiderläusen gemieden.Example z 2 parts by weight of sulfocarboxy-butyl disulfide are added 2o parts by weight of a mixture of the sodium salts of fatty acids with 7 to 9 carbon atoms, as they occur in the oxidation of paraffin, with the gradual addition of ro Parts by weight of water emulsified in the heat. The resulting soap-like Paste can be used to advantage to clean lousy clothing Find. Example 2 2 parts by weight of tetra-ethyl-thiuram disulfide are used in zo parts by weight a 65% aqueous paste of sodium salts of acid sulfuric acid esters aliphatic alcohols with an average carbon chain length of 7 carbon atoms dissolved with warming. When the mixture is diluted with water, a durable one is created Emulsion that can be used to impregnate laundry. Those treated like that Clothes lice avoid clothes.

Claims (1)

PATENTANSPRUCH: Abänderung des Gegenstandes gemäß Patent 879 i8r, gekennzeichnet durch die Verwendung von Gemischen aus schwefelhaltigen Abkömmlingen der Kohlensäure und wasserlöslichen Salzen aliphatischer oder cycloaliphatischer Verbindungen, die saure salzbildende Gruppen und q. bis 9 Kohlenstoffatome im Molekül enthalten, als Schädlingsbekämpfungsmittel, mit Ausnahme der wasserlöslichen Salze von Äthercarbonsäuren.PATENT CLAIM: Modification of the subject matter according to patent 879 i8r, characterized by the use of mixtures of sulfur-containing derivatives the carbonic acid and water-soluble salts of aliphatic or cycloaliphatic Compounds containing acidic salt-forming groups and q. up to 9 carbon atoms in the molecule contain, as pesticides, with the exception of the water-soluble salts of ether carboxylic acids.
DED4171D 1942-10-04 1942-10-04 Pest control Expired DE887890C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DED4171D DE887890C (en) 1942-10-04 1942-10-04 Pest control

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED4171D DE887890C (en) 1942-10-04 1942-10-04 Pest control

Publications (1)

Publication Number Publication Date
DE887890C true DE887890C (en) 1953-08-27

Family

ID=7030866

Family Applications (1)

Application Number Title Priority Date Filing Date
DED4171D Expired DE887890C (en) 1942-10-04 1942-10-04 Pest control

Country Status (1)

Country Link
DE (1) DE887890C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1021626B (en) * 1956-01-04 1957-12-27 Bayer Ag Pest repellants

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1021626B (en) * 1956-01-04 1957-12-27 Bayer Ag Pest repellants

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