DE870989C - Process for the production of supple, breathable artificial leather - Google Patents

Process for the production of supple, breathable artificial leather

Info

Publication number
DE870989C
DE870989C DEE535A DEE0000535A DE870989C DE 870989 C DE870989 C DE 870989C DE E535 A DEE535 A DE E535A DE E0000535 A DEE0000535 A DE E0000535A DE 870989 C DE870989 C DE 870989C
Authority
DE
Germany
Prior art keywords
artificial leather
supple
textile web
production
organic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEE535A
Other languages
German (de)
Inventor
Hans Dr Eberle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DEE535A priority Critical patent/DE870989C/en
Application granted granted Critical
Publication of DE870989C publication Critical patent/DE870989C/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0025Rubber threads; Elastomeric fibres; Stretchable, bulked or crimped fibres; Retractable, crimpable fibres; Shrinking or stretching of fibres during manufacture; Obliquely threaded fabrics
    • D06N3/0029Stretchable fibres; Stretching of fibres during manufacture

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Description

Verfahren zur Herstellung von geschmeidigem, luftdurchlässigem Kunstleder Die Erfindung betrifft ein Verfahren zur Herstellung von geschmeidigem und porösem Kunstleder oder kunstlederartigem Produkt, das aus einer Textilgrundlage auf Gewebe- oder Gewirkebasis besteht, die mit einer elastischen Schicht hierzu geeigneten organischen Materials versehen ist.Process for the production of supple, breathable synthetic leather The invention relates to a method for making pliable and porous Imitation leather or imitation leather-like product that consists of a textile base on fabric or a knitted fabric base, the organic material suitable for this purpose with an elastic layer Material is provided.

Bisher wurde bei der Herstellung von Gewebe-oder Gewirkekunstledern besonders darauf geachtet, daß die Beschichtung mit elastischem Material nur oberflächlich erfolgte. Hierbei wurde also bewußt ein Verkleben der Fadenkreuzungsstellen und der Fasern der einzelnen Fäden vermieden, weil sonst der geschmeidige Griff der Ware verlorengeht. Es wurde nun gefunden, daß man, ausgehend von einem Flächengebilde auf Gewebe- oder Gewirkebasis, das mit einer elastischen Schicht hierzu geeigneten organischen Materials beschichtet ist, selbst unter Verwendung einer mit hierzu geeignetem Material, insbesondere Natur- oder Kunstharzen, imprägnierten und gegebenenfalls damit beschichteter Textilbahn zu einem porösen und ge- schmeidigen Kunstleder oder kunstlederähnlichem Produkt gelangen kann, wenn man während der anschließenden Trocknung oder Plastifizierung das Flächengebilde in derLängs-und/oderQuerrichtung bei erhöhter Temperatur und vorteilhaft unter sich allmählich steigernder Spannung einer Streckung unterwirft. Hierdurch erfolgt eine Wiederauflockerung des Gefüges. des imprägnierten bzw. beschichteten Flächengebildes, insbesondere auch seiner Fadenkreuzungsstellen, wodurch das Kunstleder geschmeidig und besonders porös wird.So far, in the manufacture of woven or knitted artificial leather, particular care has been taken to ensure that the elastic material is only coated on the surface. In this case, the thread crossing points and the fibers of the individual threads were deliberately avoided from sticking together, because otherwise the smooth grip of the goods would be lost. It has now been found that, starting from a fabric-based or knitted fabric, coated with an elastic layer of organic material suitable for this purpose, even using a material which is suitable for this purpose, in particular natural or synthetic resins, is impregnated and optionally coated with it textile web can pass into a porous and overall schmeidigen synthetic leather or artificial leather-like product when it is advantageous during the subsequent drying, or plasticizing the sheet in derLängs and / or transverse direction at elevated temperature and subjected under gradually-increasing voltage of an extension. This loosens the structure again. of the impregnated or coated sheet-like structure, in particular its crosshairs, which makes the artificial leather supple and particularly porous.

Das Verfahren wird an Hand des anliegenden . Beispiels erläutert: Ein Rundstuhlgewirke 24 grob Zellwolle mit 7o % Streichgarn Nm io, plattiert mit Zellwolle Kammgarn INTm 4o/I-9@, wird auf der Lackiermaschine mit einem i mm dicken Film der nachfolgend beschriebenen Dispersion belegt,, wobei die Kunstharzdispersion zum größten Teil in das Gewirke eindringt. Die angewandte Dispersion besteht aus 6o Teilen Polyvinylchlorid, q.o Teilen Diocthylphthalat, 5: Teilen Farbpigment, 2o Teilen Lösungsmittelgemisch aus Trichlorät'hylen und B.utanol.The procedure is based on the attached. Example explained: A round chair knit 24 coarse viscose wool with 7o% carded yarn Nm io, clad with Viscose wool worsted INTm 4o / I-9 @, is thick on the varnishing machine with an i mm Film covered the dispersion described below, being the synthetic resin dispersion for the most part penetrates into the knitted fabric. The applied dispersion consists of 6o parts of polyvinyl chloride, q.o parts of dioctyl phthalate, 5: parts of color pigment, 2o parts solvent mixture of trichlorethylene and B.utanol.

Hierauf wird -das imprägnierte Gewirke, anschließend an das Verdampfen des Lösungsmittels der Dispersion, einer Trocknung bzw. Plastifizierung und dabei einer allmählich zunehmenden Spannung in Längs- und in Querrichtung unterworfen,: indem man das vorbeih.andelte Gewirke über ein auseinanderlaufendes Nadelkettenpaar führt, von deren Nadeln das Textilband an seinen Seitenleisten erfaßt und auf diese Weise in Querrichtung unter zunehmender Spannung gehalten wird. Die Spannung in der Längsrichtung wird dadurch erzeugt, daß die Abzugsgeschwindigkeit des Nadelkettenpaares etwas größer ist als diejenige des von der Lackiermaschine kommenden imprägnierten Textilbandes. Die Luftdurchlässigkeit eines auf diese Weise behandelten Kunstleders beträgt gemessen in'i Bergmannapparat nach Stather f > so, gegenüber f < 2o: ohne Anwendung des Streckungsverfahrens. Der Griff der Ware durch diese Behandlung ist wesentlich weicher und geschmeidiger geworden. -Then the impregnated knitted fabric is then evaporated the solvent of the dispersion, a drying or plasticizing and thereby subjected to a gradually increasing tension in the longitudinal and transverse direction: by passing the knitted fabric over a diverging pair of needle chains leads, the needles of the textile tape captured on its side strips and on this Way is held in the transverse direction under increasing tension. The tension in the longitudinal direction is generated by the withdrawal speed of the pair of needle chains is slightly larger than that of the impregnated material coming from the painting machine Textile tape. The air permeability of artificial leather treated in this way measured in'i Bergmannapparat according to Stather f> so, compared to f <2o: without using the stretching process. The handle of the goods through this treatment has become much softer and more supple. -

Claims (1)

PATENTANSPRÜCHE: i. Verfahren zur Herstellung von geschmeidigem, luftdurchlässigem Kunstleder öder kunstlederähnlichen Produkten unter Verwendung einer Textilgründläge auf Gewe#- qder-_.Gewirkeba is mit einer elastischen Schicht hierzu geeigneten organischen Materials versehen ist, dadurch gekennzeichnet, daß man die so vorbehan eltlee_Textilbabn während-.dex .aii: schlne en@den__Trocknung und .-gegebenenfalls PlastiEzierung bei erhöhter Temperatur in der Län-s- und/oder ru_e_rxichtung, vorteilhaft unter sich allma Ich steigernder _ Spannung, @e_ iner Strecküng@ünterwirft.K_ ,@ z.-Verfahren nach Anspruch i, dadurch -gekennzeichnet, daß man eine Textilbahn verwendet, die mit hierzu geeignetem organischem Material, insbesondere mit Natur- oder Kunstharzen, imprägniert und gegebenenfalls auch damit beschichtet ist. 3. Verfahren nach Anspruch .i und 2, dadurch gekennzeichnet, daß man die so vorbehandelte Textilbahi. über ein äuseinanderlaufendes Nadelkettenpaar führt, von deren Nadeln die Textilbahn an ihren Seitenleisten erfaßt wird, wobei die Abzugsgeschwindigkeit der Nadelketten wenig größer ist als diejenige der Textilbahn. PATENT CLAIMS: i. Process for the production of supple, air-permeable artificial leather or products similar to artificial leather using a textile base on Gewe # - qder -_. Gewirkeba is provided with an elastic layer of organic material suitable for this purpose, characterized in that the so pre-treated eltlee_Textilbabn while-.dex .aii: Schlne en @ den__Drocknung and.-if necessary plastiEzierung at elevated temperature in the Län-s- and / or ru_e_rxichtung, advantageous under allma ich increasing _ tension, @e_ iner Strecküng@ünterwirft.K_, @ z.-procedure Claim i, characterized in that a textile web is used which is impregnated with organic material suitable for this purpose, in particular with natural or synthetic resins, and optionally also coated therewith. 3. The method according to claim .i and 2, characterized in that the so pretreated Textilbahi. over a pair of juxtaposed needle chains, the needles of which grasp the textile web at its side strips, the withdrawal speed of the needle chains being slightly greater than that of the textile web.
DEE535A 1950-01-20 1950-01-20 Process for the production of supple, breathable artificial leather Expired DE870989C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEE535A DE870989C (en) 1950-01-20 1950-01-20 Process for the production of supple, breathable artificial leather

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEE535A DE870989C (en) 1950-01-20 1950-01-20 Process for the production of supple, breathable artificial leather

Publications (1)

Publication Number Publication Date
DE870989C true DE870989C (en) 1953-03-19

Family

ID=7064817

Family Applications (1)

Application Number Title Priority Date Filing Date
DEE535A Expired DE870989C (en) 1950-01-20 1950-01-20 Process for the production of supple, breathable artificial leather

Country Status (1)

Country Link
DE (1) DE870989C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1026273B (en) * 1955-07-12 1958-03-20 Konrad Hornschuch A G Process for the production of artificial leather
DE1063112B (en) * 1953-08-14 1959-08-13 Dualoy Company Process for the production of artificial leather
DE1101345B (en) * 1955-07-27 1961-03-09 Du Pont Artificial leather of a soft, suede-like texture and process for its manufacture
DE1143477B (en) * 1956-11-05 1963-02-14 Du Pont Water vapor permeable, abrasion-resistant, flexible synthetic leather
DE1175425B (en) * 1952-04-18 1964-08-06 Dr Adolf Becker Process for manufacturing drive belts
DE1261656B (en) * 1954-11-23 1968-02-22 Frederick Horace Bentley Process for the production of a reinforced molding material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1175425B (en) * 1952-04-18 1964-08-06 Dr Adolf Becker Process for manufacturing drive belts
DE1063112B (en) * 1953-08-14 1959-08-13 Dualoy Company Process for the production of artificial leather
DE1261656B (en) * 1954-11-23 1968-02-22 Frederick Horace Bentley Process for the production of a reinforced molding material
DE1026273B (en) * 1955-07-12 1958-03-20 Konrad Hornschuch A G Process for the production of artificial leather
DE1101345B (en) * 1955-07-27 1961-03-09 Du Pont Artificial leather of a soft, suede-like texture and process for its manufacture
DE1143477B (en) * 1956-11-05 1963-02-14 Du Pont Water vapor permeable, abrasion-resistant, flexible synthetic leather

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