DE851845C - Process for the production of foam rubber - Google Patents

Process for the production of foam rubber

Info

Publication number
DE851845C
DE851845C DEM9816A DEM0009816A DE851845C DE 851845 C DE851845 C DE 851845C DE M9816 A DEM9816 A DE M9816A DE M0009816 A DEM0009816 A DE M0009816A DE 851845 C DE851845 C DE 851845C
Authority
DE
Germany
Prior art keywords
agents
foam rubber
production
vulcanization
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEM9816A
Other languages
German (de)
Inventor
Heinz Vieweg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Metzeler Gummiwerke AG
Original Assignee
Metzeler Gummiwerke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metzeler Gummiwerke AG filed Critical Metzeler Gummiwerke AG
Priority to DEM9816A priority Critical patent/DE851845C/en
Application granted granted Critical
Publication of DE851845C publication Critical patent/DE851845C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/30Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers
    • C08J2321/02Latex

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Description

Verfahren zur Herstellung von Schaumkautschuk Es ist bekannt, mit Luftblasen durchsetzten Kautschuk, sogenannten Schaumkautschuk, dadurch Herzustellen, daß eine Kautschukdispersion zu Schaum gesehlagen und dieser Schaum verfestigt, vulkanisiert und getrocknet wird.Process for the production of foam rubber It is known with Air bubbles permeated rubber, so-called foam rubber, thereby producing that a rubber dispersion formed into foam and this foam solidified, vulcanized and dried.

Derartiger Schaumkautschuk und die aus solchem hergestellten Sitze, Rückenlehnen und Matratzen haben jedoch den :Machteil, daß die darin enthaltenen Poren im allgemeinen geschlossen sind bzw. nicht miteinander in Verbindung stehen und -daß daher das Material nicht oder nur höchst ungenügend luft-und wasserdampfdurchlässig und damit auch seine Weichheit entsprechend begrenzt ist.Such foam rubber and seats made from it, However, backrests and mattresses have the disadvantage that they contain Pores are generally closed or not in communication with one another and that therefore the material is not or only extremely inadequately permeable to air and water vapor and thus its softness is limited accordingly.

Man hat daher auch schon vorgeschlagen, die Weichheit des Materials durch Steigerung der Porengröße zu @-erhessern, und zwar dadurch, daß man dem Ausgangsmaterial Blähmittel, wie z. B. Diazoaminobenzol, zusetzt, welche nach Einleitung 1>z«-. während der Vulkanisation zur Wirkung komtnen und dabei die Schaumblasen bzw. Poren mehr oder minder ausweiten. Der Erfolg einer solchen Steigerung der Porengröße ist jedoch ein nur sehr bedingter, da auch 'hierbei die Poren im allgemeinen geschlossen bleiben und so auch die Durchlässigkeit des Materials nicht verbessert wird.It has therefore already been suggested that the material should be soft by increasing the pore size to @ -erhessern, namely by the fact that the starting material Blowing agents such. B. diazoaminobenzene, which after introduction 1> z «-. while the vulcanization come into effect and thereby the foam bubbles or pores more or expand less. However, the success of such an increase in pore size is only a very limited one, since here too the pores generally remain closed and so the permeability of the material is not improved either.

Es ist nun möglich, die Poren von Schaumkautschuk durch mechanische Mittel teilweise zu öffnen und damit das Material durchlässig zu machen, z. B. dadurch, daß man das Material durch ein eng gestelltes Walzenpaar hindurchführt. Ein solches Vorgehen erfordert jedoch nicht nur einen zusätzlichen Arbeitsgang, sondern ist auch nicht in allen Fällen mit durchgängig gleichem Erfolg durchführbar, insbesondere dann nicht, wenn es sich um Erzeugnisse ungleichmäßiger Stärke handelt.It is now possible to open the pores of foam rubber by mechanical means To partially open means and thus to make the material permeable, z. B. by that the material is passed through a pair of rollers set close together. One such However, the procedure not only requires an additional operation, it is also not feasible in all cases with consistently the same success, in particular then not when it comes to products of uneven thickness.

-Mit Hilfe des erfindungsgemäßen Verfahrens gelingt es nun, ohne einen zusätzlichen Arbeitsgang auszukommen und auch hei ungleichmäßigen Gestaltungsformeni zu in sich einheitlichen Erzeugnissen von hoher Durchlässigkeit zu gelangen.-With the help of the method according to the invention it is now possible without one to get along with additional work and also called uneven Design forms i to achieve uniform products with a high level of permeability.

Dieses erfindungsgemäße Verfahren stimmt mit dem bekannten Verfahren darin überein, daß dabei eine natürliche oder künstliche Kautschukdispersion, welche die üblichen Zusätze, wie Schwefel, Zinkoxyd, Vulkanisationsbeschleuniger, Alterungsschutzmittel und Seife, sowie Blähmittel enthält, in üblicher Weise mit einem Rührer schaumig geschlagen oder auf sonstige Weise schaumig gemacht wird, und daß vor dem. Gießen ein oder mehrere Geliermittel, wie z. B. Natriumsilicofluorid, zugegeben wird.This method according to the invention agrees with the known method agree that this is a natural or artificial rubber dispersion, which the usual additives such as sulfur, zinc oxide, vulcanization accelerators, anti-aging agents and soap, as well as blowing agent containing, in the usual way with a stirrer foamy whipped or otherwise made frothy, and that before. to water one or more gelling agents, such as. B. sodium silicofluoride is added.

In Abweichung von dem bekannten Vorgehen werden jedoch bei dem erfindungsgemäßen Verfahren die Vulkanisationsmittel und die Vulkanisationsführung derart gesteuert, daß die Vulkanisation erst dann einsetzt, nachdem das oder die Blähmittel zu einer Zertrümmerung der urfiter dem Einfluß des oder der Geliermittel verfestigten Zellwände geführt hat.In deviation from the known procedure, however, in the case of the invention Process the vulcanizing agents and the vulcanization process are controlled in such a way that that the vulcanization begins only after the blowing agent or agents to a Shattering of the cell walls solidified by the influence of the gelling agent or agents has led.

Im Rahmen des erfindungsgemäßen Verfahrens wird also im Gegensatz zu dem vorerwähnten, ebenfalls mit Blähmitteln arbeitenden Verfahren .durch die Blähmittel an der durch die anfängliche Schaumstruktur gegebenen Porengröße als solcher nichts Wesentliches geändert. Die Blähmittel kommen vielmehr schon dann zur Wirkung, bevor die Vulkanisation eingesetzt hat, und führen so zu einer öffnung und Verbindung der Zellen untereinander, die sich dann im Endprodukt in einer entsprechenden Durchlässigkeit und Weichheit desselben auswirkt.In the context of the method according to the invention, in contrast to the aforementioned, also working with blowing agents method .by the Blowing agent at the pore size given by the initial foam structure as such nothing substantial changed. Rather, the blowing agents come already then take effect before vulcanization has started and thus lead to an opening and connection of the cells with one another, which is then in the end product in a corresponding Permeability and softness of the same.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung von Schaumkautschuk aus schaumigen, Geliermittel und Blähmittel enthaltenden Kautschukdispersionen, dadurch gekennzeichnet, daß die Vulkanisationsmittel und die Vulkanisationsführung derart gesteuert werden, daß die Vulkanisation erst dann einsetzt, nachdem das oder die Blähmittel zu einer Zertrümmerung der unter dem Einfluß des oder der Geliermittel verfestigten Zellwände geführt hat.PATENT CLAIM: Process for the production of foam rubber from foamy rubber dispersions containing gelling agents and blowing agents, thereby characterized in that the vulcanizing agent and the vulcanization guide such be controlled that the vulcanization starts only after that or the Blowing agents to a disintegration under the influence of the gelling agent or agents solidified cell walls.
DEM9816A 1951-06-09 1951-06-09 Process for the production of foam rubber Expired DE851845C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEM9816A DE851845C (en) 1951-06-09 1951-06-09 Process for the production of foam rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM9816A DE851845C (en) 1951-06-09 1951-06-09 Process for the production of foam rubber

Publications (1)

Publication Number Publication Date
DE851845C true DE851845C (en) 1952-10-09

Family

ID=7294861

Family Applications (1)

Application Number Title Priority Date Filing Date
DEM9816A Expired DE851845C (en) 1951-06-09 1951-06-09 Process for the production of foam rubber

Country Status (1)

Country Link
DE (1) DE851845C (en)

Similar Documents

Publication Publication Date Title
DE851845C (en) Process for the production of foam rubber
DE563165C (en) Process for the production of cellular rubber
DE421777C (en) Process for the production of porous building materials
DE714434C (en) Process for the production of homogeneous cellulose solutions in mineral acids or their mixtures for the production of rayon, films, tapes and similar products
DE923390C (en) Process for the production of cellular rubber molded articles
DE1769127A1 (en) Process for the production of plasticized foams from polyvinyl chloride and copolymers of vinyl chloride
CH528285A (en) Figures of elastic material - based on (co)pvc blends with slow tensile recovery, for toys and advertising
DE841358C (en) Process for the production of storable, moldable and vulcanizable porous rubber products
DE570894C (en) Process for the production of molded synthetic masses by coagulating viscose
DE2029284C3 (en) Process for the production of polyether urethane foams
DE1219378B (en) Process for the production of insulating bodies consisting essentially of inorganic fibers
DE854572C (en) Process for the production of microporous vulcanizates
DE1020788B (en) Process for the production of flexible, crack-free cell bodies
DE722673C (en) Process for the production of porous moldings
DE655722C (en) Process for the production of cellular or porous rubber from rubber milk
DE668980C (en) Process for the production of medical aids for foot treatment and foot care from sponge rubber
DE892514C (en) Process for the production of sponge rubber
DE707443C (en) Process for the production of plastics from proteins or synthetic resins
AT153348B (en) Process for the production of cellular or sponge rubber.
DE1248286B (en) Process for the production of open-cell, flexible foams from polyurethanes
DE900016C (en) Process for the production of a fiber material reinforced with rubber for upholstery purposes
AT145811B (en) Process for the production of homogeneous solutions of cellulose in sulfuric acid or in other acids or mixtures of acids and of rayon threads, films, ribbons and similar artificial products from these solutions.
DE883342C (en) Process for the production of foam rubber
DE585447C (en) Process for the production of threads, fibers and pipes from aqueous rubber dispersions
DE686891C (en) Method for processing animal hide material, sausage casings