DE82982C - - Google Patents
Info
- Publication number
- DE82982C DE82982C DENDAT82982D DE82982DC DE82982C DE 82982 C DE82982 C DE 82982C DE NDAT82982 D DENDAT82982 D DE NDAT82982D DE 82982D C DE82982D C DE 82982DC DE 82982 C DE82982 C DE 82982C
- Authority
- DE
- Germany
- Prior art keywords
- superoxide
- alkali
- calcium
- magnesia
- lime
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 150000004677 hydrates Chemical class 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 159000000009 barium salts Chemical class 0.000 claims description 2
- 159000000007 calcium salts Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 159000000008 strontium salts Chemical class 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 2
- 239000006286 aqueous extract Substances 0.000 claims 1
- 239000000292 calcium oxide Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 5
- 235000015450 Tilia cordata Nutrition 0.000 description 5
- 235000011941 Tilia x europaea Nutrition 0.000 description 5
- 239000004571 lime Substances 0.000 description 5
- FGIUAXJPYTZDNR-UHFFFAOYSA-N Potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001737 promoting Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
KAISERLICHESIMPERIAL
PATENTAMT.^PATENT OFFICE. ^
Die salpetersauren Alkalien sind zur Herstellung von Alkalisuperoxyd bis jetzt noch nicht benutzt worden, weil es noch nicht gelang, Schmelzgefäfse herzustellen, welche der Einwirkung der Hitze und des gebildeten Alkalioxyds widerstehen. Zwar kann man die Zersetzung durch Zumischung von Kupferblech, Braunstein und anderen Metalloxyden fördern, jedoch ist das entstandene Alkalioxyd infolge seiner Mischung mit Metalloxyden (Ozonide) nicht zu dem technisch wichtigen Superoxyd oxydirbar.The nitric acid alkalis are still used in the production of alkali peroxide until now has not been used because it has not yet been possible to manufacture melting vessels which the Resist exposure to heat and the alkali oxide formed. Although you can see the decomposition promote by adding copper sheet, brownstone and other metal oxides, but the resulting alkali oxide is a result its mixture with metal oxides (ozonides) does not result in the technically important superoxide oxidizable.
Angestellte Versuche zeigten noch, dafs die Oxyde der Erdalkalien und des Magnesiums den Zweck erreichen lassen, indem sie die Zersetzung der Alkalinitrate befördern und die Oxydation zu Superoxyd nicht hindern. Sie bilden ein Aufnahmemedium für den geschmolzenen Salpeter und das daraus entstehende feuerflüssige Alkalioxyd, geben der zersetzten Masse eine poröse, zur Oxydation geeignete Beschaffenheit und erlauben die Superoxydbildung durch Behandlung mit gereinigter Luft.Experiments carried out showed that the oxides of alkaline earths and magnesium let achieve the purpose by promoting the decomposition of the alkali nitrates and the Do not prevent oxidation to superoxide. They form a recording medium for the melted Saltpetre and the resulting molten alkali oxide give the decomposed mass a porous, oxidizing surface suitable consistency and allow superoxide formation by treatment with purified Air.
Die Alkalinitrate werden mit den hier technisch in Betracht kommenden Oxyden, Kalk oder Magnesia gemicht, indem man auf 100 Th. Salpeter etwa 70 bis 90 Th. Magnesia bezvv. Kalk nimmt. In feuerfesten Gefäfsen steigender Hitze ausgesetzt, beginnt die Masse bei Dunkelrothglut nitrose Gase zu entwickeln, die schliefslich bei Rothglut allmälig durch Sauerstoff und Stickstoff verdrängt werden. Bei heller Rothglut ist die Zersetzung vollendet. Die erhaltene graue, poröse Masse wird bei einer zwischen 300 und 5000 C. liegenden Temperatur mit trockener und kohlensä'urefreier Luft behandelt, wobei das Alkalioxyd in Superoxyd übergeht. Trägt man nun die gepulverte Masse unter Rühren in kaltes Wasser ein, so erhält man nach Entfernung des unlöslichen Kalks oder der Magnesia eine Superoxydlösung, die direct zum Bleichen verwendet werden kann. Läfst man die Superoxydlösung mit dem Kalk- oder Magnesianiederschlage unter beständigem Rühren zusammen, so setzt sie sich mit dem Kalk vollständig und mit der Magnesia unvollständig zu Alkalihydrat und Calcium- bezw. Magnesiumsuperoxyd um. Es kann jedoch auch die klare Superoxydlösung mit löslichen Calcium-, Strontium- oder Bariumsalzen oder deren Hydraten versetzt werden, wodurch die Erdalkalisuperoxydhydrate unlöslich ausfallen.The alkali nitrates are mixed with the oxides, lime or magnesia which are technically possible here, by adding about 70 to 90 th. Magnesia to 100 th. Saltpeter. Lime takes. When exposed to increasing heat in refractory vessels, the mass begins to develop nitrous gases when it is red-hot, which is gradually displaced by oxygen and nitrogen when it is red-hot. When the glow is bright red, the decomposition is complete. The gray, porous mass obtained is treated at a temperature between 300 and 500 0 C. temperature with dry air and kohlensä'urefreier, wherein the alkali oxide turns into peroxide. If the powdered mass is then introduced into cold water with stirring, a superoxide solution is obtained after the insoluble lime or magnesia has been removed, which can be used directly for bleaching. If the superoxide solution is allowed to combine with the lime or magnesia precipitate with constant stirring, it is completely combined with the lime and incompletely with the magnesia to form alkali hydrate and calcium or calcium. Magnesium superoxide around. However, soluble calcium, strontium or barium salts or their hydrates can also be added to the clear superoxide solution, as a result of which the alkaline earth superoxide hydrates are insoluble.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE82982C true DE82982C (en) |
Family
ID=355348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT82982D Active DE82982C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE82982C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7445518B2 (en) | 2006-05-05 | 2008-11-04 | Schneider Nee Hild Anja | Pressure contact |
-
0
- DE DENDAT82982D patent/DE82982C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7445518B2 (en) | 2006-05-05 | 2008-11-04 | Schneider Nee Hild Anja | Pressure contact |
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