DE748122C - Magnetic core (earth core) pressed from powdery magnetic material and a binding and insulating agent - Google Patents

Magnetic core (earth core) pressed from powdery magnetic material and a binding and insulating agent

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Publication number
DE748122C
DE748122C DE1937748122D DE748122DD DE748122C DE 748122 C DE748122 C DE 748122C DE 1937748122 D DE1937748122 D DE 1937748122D DE 748122D D DE748122D D DE 748122DD DE 748122 C DE748122 C DE 748122C
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Germany
Prior art keywords
core
binding
cores
magnetic
pressed
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Expired
Application number
DE1937748122D
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German (de)
Inventor
Walter Schulze
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/20Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/22Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
    • H01F1/24Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated
    • H01F1/26Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated by macromolecular organic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Materials For Medical Uses (AREA)
  • Organic Insulating Materials (AREA)
  • Inorganic Insulating Materials (AREA)

Description

Aus pulverförmigem magnetischem Material und einem Binde- und Isoliermittel gepreßter Magnetkern (Massekerri) Die Erfindung bezieht sich auf Magnetkerne für elektrische Einrichtungen, beispielsweise Pupinspulen oder Hochfrequenzspulen für elektrische Schwingungskreise u. dgl. Die Erfindung betrifft diejenige Art von Magnetkernen, bei denen das magnetische Material in fein verteilter Form mit einem Isolier- und/oder Bindemittel gemischt und zusammen mit dem Bindemittel in die gewünschte Form gepreßt 'wird. An die Eigenschaften des Bindemittels müssen erhebliche Anforderungen gestellt werden, wenn die 'Kerne brauchbar sein sollen. Das Binde-- oder Isoliermittel muß einmal die Eisenteilchen gut umschließen, so daß benachbarte Eisenteilchen nicht in metallische Berührung treten und so zu Wirbelstromverlusten Anlaß geben können. Die Druck- und Haftfestigkeit des Isoliermittels muß so groß sein, daß ein Hindurchdrücken der Eisenteilchen durch die Isolierschicht vermieden wird. Für Zwecke der Mehrfachisolation soll das Isoliermittel auch durch einfache Verfahren, z. B. Erhitzen, in eine unlösliche Form überführt werden können. Schließlich mul) (las Bindemittel so beschaffen sein, daß der fertige Kern eine genügende Härte und Formfestigkeit aufweist.Made of powdery magnetic material and a binding and insulating agent Pressed magnetic core (Massekerri) The invention relates to magnetic cores for electrical devices, such as Pupin coils or high frequency coils for electrical oscillating circuits and the like. The invention relates to that type of magnetic cores, in which the magnetic material is finely divided with an insulating and / or Binder mixed and pressed together with the binder into the desired shape 'will. Considerable demands must be made on the properties of the binder if the 'kernels are to be usable. The binding or isolating agent must be used once the iron particles enclose well so that neighboring iron particles do not come into metallic contact and thus give rise to eddy current losses. The compressive strength and adhesive strength of the insulating agent must be so great that it can be pushed through the iron particles is avoided by the insulating layer. For purposes of multiple isolation should the isolating agent also by simple methods, e.g. B. heating, into an insoluble Form can be converted. Finally mul) (read binders are of such a nature, that the finished core has sufficient hardness and dimensional stability.

Gerade die Festigkeit der Massekerne läßt aber sehr zu wünschen übrig. Die meisten der bisher bekannten Massekerne sind derart spröde, daß sie beim Auffallen auf harten Boden zerbrechen oder von Hand mit Leichtigkeit in Stücke gebrochen «erden können. Dies gilt für Massekerne mit Isolier- und Bindemitteln der verschiedensten Art, insbesondere auch für Kerne, bei denen das Bindemittel aus einem Pbenolforinaldehydkondensatiotisprodukt (Bakelit) oder aus Polvnierisationsprodukten von Derivaten der _@crvlsiittre oder deren Homologen bestellt.However, it is precisely the strength of the mass cores that leaves a lot to be desired. Most of the previously known mass cores are so brittle that they are noticed when they are noticed break on hard ground or "earth" easily broken into pieces by hand can. This applies to mass cores with a wide variety of insulating and binding agents Kind, in particular also for cores where the binder is made a benzene foraldehyde condensation product (Bakelite) or polvnierization products of derivatives of the _ @ crvlsiittre or their homologues.

Es sind auch schon Masseherne 1>el;ziiitit- geworden, deren Isolier- und Bindemittel einer Mischung von Polvmerisationspro teil von Acrvlsätireverbindttngen mit stvrol oder aus Polvstyrol allein besfeht: Diese Kerne unterscheiden sich in bezug aüf,@ die Festigkeit nicht von den übrigen vorbekannten Massehernen.There are already mass stars 1>el; ziiitit- become their insulating and binding agents a mixture of polymerisation pro part of acrvlsätireverbindungen with stvrol or from polvstyrene alone: these cores do not differ in terms of their strength from the other previously known mass cores.

Die bekannten Masseherne «-eisen noch Nachteile anderer Art auf. Beispielsweise haben die Untersuchungen an Kernen mit einem Bindemittel aus Polyacrylaten gezeigt, dafi die Kerne bei der thermischen Nachbehandlung eine gewisse Ausdehnung erfahren. Dieses tVachsen der Kerne wird besonders unangenehm da empfunden, wo die Kerne genau maßhaltig sein müssen, also beispielsweise bei den sogenannten Schraubkernen der flochlrequenztechnik. Umgekehrt weisen Kerne mit einer Isolation aus Pbenolformaldelivdkondensationsprodukten ein Schwindma13 auf, d. 1i. sie verkleinern ihr Volumen lief einer thermischen Nachbehandlung.The well-known mass iron still have disadvantages of another kind. For example the investigations on cores with a binding agent made of polyacrylates have shown that the cores experience a certain expansion during the thermal aftertreatment. This growth of the kernels is felt to be particularly uncomfortable where the kernels are located Must be true to size, for example with the so-called screw cores of the floch frequency technology. Conversely, cores with an insulation of pbenolformaldelivdcondensation products show a shrinkage13, d. 1i. they reduce their volume and underwent a thermal aftertreatment.

Gegenstand der Erfindung ist nun ein Hassehern, der voll den obengenannten @Tacliteilen frei ist. Erfindungsgemäß bestellt das Isolier- und Bindemittel des Kernes aus Polymerisationsprodukten von Derivaten der Acrvlsäure oder deren Homologen, denen 2o bis ,#o°/o eines härtbaren Kondensationsproduktes, insbesondere eines Pheilolforinaldeliv dkondensationsproduktes, zugesetzt sind. Zur Herstellung dieses Gemisches werden die entsprechenden Anteile der einzelnen Stoffe in einem geeigneten Lösungsmittel, beispielsweise Aceton, gelöst, wobei sich das Phenolformaldehydkondensationsprodukt in einem noch nicht gehärteten Zustande befinden muß. Das so gelöste Isolier- und Bindemittel wird sodann dem zu isolierenden Eisenpulver in bekannter Weise beigegeben und nach Austreibung des Lösungsmittels unter hohem Druck zti "-Massehernen beliebiger Form gepreßt. Als besonders zweckmäßig hat sich eine Mischung erwiesen, welche 6o11/, des Kondensationsproduktes und q.o°io des Polynierisationsproduktes enthält. Das letztere ist zweckmäßig ein --Misebpolymerisat aus Act-ylsäurenitril und Acrylsä ureäthylester. Die so leergestellten Kerne zeichnen sich vor allen bisher bekannten Kernen durch eine ungewöhnlich große Festigkeit aus. Vergleicht man beispielsweise Kerne in H-Form, die nach sollst gleichem Verfahren hergestellt, aper verschiedene an sich bekannte Bindemittel aufweisen. so findet man, daß nian sie alle Weil leichten Druck auf die Kernschenkel @i-echen kann. Ein Kern mit einem Binde- @ix tel gemäß der Erfindung, der itii übrigen 'ach dem gleichen Verfahren hergestellt ist, weist dagegen eine so große Festigkeit auf, daß er durch Fingerdruck auf die Schenkel nicht mehr zerstört werden kann. Es tritt soinit die überraschende Wirkung ein, daß ein Bindemittel, welches aus PlietioIrorinaldeliydkondensationsprodukten und Polyacrylaten gelnisclit ist, einen Kern finit z-ielf.tcli'liölierer Festigkeit liefert, als wenn inan eines der eben genannten Bindemittel allein benutzt.The subject of the invention is now a hatred, who is completely free of the above @Tacli parts. According to the invention, the insulating and binding agent of the core is made up of polymerization products of derivatives of acrylic acid or their homologues to which 20 to .o.% of a curable condensation product, in particular a Pheilolforinaldeliv dcondensation product, are added. To produce this mixture, the appropriate proportions of the individual substances are dissolved in a suitable solvent, for example acetone, the phenol-formaldehyde condensation product must be in a not yet hardened state. The insulating and binding agent dissolved in this way is then added to the iron powder to be isolated in a known manner and, after the solvent has been expelled under high pressure, it is pressed into any shape The latter is expediently a -misebpolymerisate of actyl acid nitrile and acrylic acid ethyl ester. The cores vacated in this way are distinguished from all cores known hitherto by an unusually high strength should be produced by the same process, but have different binders known per se, so it is found that none of them are used Because light pressure on the core limbs @ i-echen can. A core with a connective @ix tel according to the invention, the rest of itii 'After the same process is produced, on the other hand, has such a high strength that it can no longer be destroyed by finger pressure on the legs. There is thus the surprising effect that a binder which is composed of plietiorinaldelium condensation products and polyacrylates provides a core that is finitely more stable than when one of the binders just mentioned is used alone.

Die Kerne gemäß der Erfindung haben den weiteren Vorteil, daß sie bei einer tlierinischen. Nachbehandlung ihre äußeren Allmessungen nicht oder nicht merklich veränderte, weil das Schwinden des Kondeisationsproduktes durch das Wachsen des Polymerisationsproduktes kompensiert wird.The cores according to the invention have the further advantage that they at a Tlierinian. Post-treatment her external universal measurements either not or not changed noticeably because the shrinkage of the condensation product was caused by the growth of the polymerization product is compensated.

Claims (3)

PATENTANSPRÜCHE,: t. Alts pulverförinigein magnetischem Material und einem Binde- und Isoliermittel geprellter Magnetkern (Massehern), insbesondere zur Verwendung in Hochlrequenzspulen, bei dem das Binde- und Isoliermittel aus einer Mischung von Polvmerisationsprodukten von Derivaten der Acrylsäure oder deren Homologen mit einem anderen organischen Isolierstoff bestellt, dadurch gekennzeichnet, claß den Polynierisationsprodukten voll Derivaten der Acrvlsäure oder deren Hotnologetl 20 bis 8o11/0 eines härtbaren Kondensationsproduktes, insbesondere eines Plienolformaldehydkondensationsproduktes, beigegeben sind. PATENT CLAIMS: t. Alts powdery in magnetic material and a binding and insulating material bruised magnetic core (earthers), in particular for Use in high-frequency coils, where the binding and insulating material consists of one Mixture of polymerization products of derivatives of acrylic acid or their homologues ordered with another organic insulating material, characterized in that class the polymerization products full of derivatives of acrylic acid or its hotnology 20 to 8o11 / 0 of a curable condensation product, in particular a plienol-formaldehyde condensation product, are included. 2. Massehern nach Anspruch i, dadurch gekennzeichnet, daß das Bindemittel aus 000f,, eines Plienolforinaldeliy<lk(3,ndensationsproduktes und aus .Io°j" _ eines 1lisclipolvinerisates voll _lcrylsätireiiiti-il und -lcrvlsäureiitlivlester bestellt. 2. Massehern according to claim i, characterized in that the binder from 000f ,, a Plienolforinaldeliy <lk (3, change product and from .Io ° j " _ of a 1lisclipolvinerisates full of _lcrylsätireiiiti-il and -lcrvl acidiitlivester ordered. 3. Verwendung der 1lassekerne nach Anspruch i oder 2 als Schraubkerne für die: Hochfrequenztechnik.3. Use of the 1-class cores according to claim i or 2 as screw cores for: high frequency technology.
DE1937748122D 1937-05-29 1937-05-29 Magnetic core (earth core) pressed from powdery magnetic material and a binding and insulating agent Expired DE748122C (en)

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Application Number Priority Date Filing Date Title
DE748122T 1937-05-29

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DE748122C true DE748122C (en) 1944-10-26

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966314C (en) * 1949-08-26 1957-07-25 Standard Elek K Ag Process for the production of mass cores from magnetizable powder particles raised with an insulating material of high softening temperature
DE975863C (en) * 1949-02-02 1962-11-08 Siemens Ag Process for the production of homogeneous magnetizable cores from powder particles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE975863C (en) * 1949-02-02 1962-11-08 Siemens Ag Process for the production of homogeneous magnetizable cores from powder particles
DE966314C (en) * 1949-08-26 1957-07-25 Standard Elek K Ag Process for the production of mass cores from magnetizable powder particles raised with an insulating material of high softening temperature

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