DE716473C - Process for the production of mass cores - Google Patents

Process for the production of mass cores

Info

Publication number
DE716473C
DE716473C DEI57775D DEI0057775D DE716473C DE 716473 C DE716473 C DE 716473C DE I57775 D DEI57775 D DE I57775D DE I0057775 D DEI0057775 D DE I0057775D DE 716473 C DE716473 C DE 716473C
Authority
DE
Germany
Prior art keywords
sugar
cores
production
mass
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI57775D
Other languages
German (de)
Inventor
Dr Friedrich Bergmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI57775D priority Critical patent/DE716473C/en
Application granted granted Critical
Publication of DE716473C publication Critical patent/DE716473C/en
Expired legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/20Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/22Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
    • H01F1/24Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated
    • H01F1/26Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated by macromolecular organic substances

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

. Verfahren -zur Herstellung von Massekernen Bekanntlich werden Massekerne, wie sie für Magnetkerne, Pupinspulen, Hochfrequenzeisenkerne u. dgl. Verwendung finden, aus magnetisierbaren Metallpulvern in der Weise hergestellt, daß man- die Pulverteilchen mit Isoliermitteln umgibt und das Pulver dann in die gewünschte Form preßt. Als Isoliermittel hat man u. a. Natur- und Kunstharze, z. B. Schellack, Phenol-Formaldehyd- oder Harnstaff-Formaldelhyd-Kondensationsprodukte, ferner Celluloseabkömmlinge, Wachse und asphaltartige Massen vo..7geschlagen. Ferner hat man empfohlen, als Isoliermittel Wasserglas und Zucker entweder für sich oder gemeinsam zu verwenden. Auch hat man Harzpulver mit Hilfe von Zuckerlösung als Bindemittel auf die Ehenpulverteilchen aufjebracht.. Process - for the production of mass cores It is well known that mass cores, as they are used for magnetic cores, Pupin coils, high-frequency iron cores and the like find, made of magnetizable metal powders in such a way that one- the Powder particles are surrounded with isolating agents and the powder is then given the desired shape presses. As an isolating agent one has inter alia. Natural and synthetic resins, e.g. B. shellac, phenol-formaldehyde or Harnstaff formaldehyde condensation products, also cellulose derivatives, Waxes and asphalt-like masses were beaten. It has also been recommended as an isolating agent Use water glass and sugar either alone or together. One also has Resin powder with the help of a sugar solution as a binding agent on the marriage powder particles upset.

Insbesondere bei Magnetkernen, die für die Verwendung bei hohen Frequenzen, wie z. B. Radiofrequenzen, bestimmt sind,.._igt,mu.._.er.", streben, da13 die im Kern auftretenden Verluste möglichst gering sind. Da bei diesen hohen Frequenzen den Hauptanteil der Gesamtverluste des Massekernes die mit dem Quadrat der Frequenz ansteigenden Wirb.elstromverluste verursachen, kann man erwarten, eine Bestwirkung dann zu erhalten, wenn es gelingt, die einzelnen Magnetpulverteilchen voneinander so vollständig elekt:isch zu isolieren, daß der Kern als Ganzes praktisch keine elektrische Leitfähigkeit zeigt und Wrbelstromverluste iiur im einzelnen Magnetpulverteilchen auftreten. Ein möglichst hoher Isolationswiderstand der Massekerne bei ihrer Verwendung als Induktionsspulenkerne für Hochfrequenz ist überdies auch deswegen er-@vünscht, geil, zumal bei geschlossenen Keinformen, die Spulenwicklung oder ihre Zuführungen mit dem Magnetkern häufig in Berühruug*.:;komtneu und dann bei geringem Isolationswiderstand des Keines leicht.tlie Dämpfung der Induktionsspule erheblich erhöht wird.Especially with magnetic cores that are designed for use at high frequencies, such as B. radio frequencies are determined, .._ igt, must .._. He. ", Strive that the im Core losses are as low as possible. Because at these high frequencies the main part of the total losses of the mass core those with the square of the frequency cause increasing eddy current losses, one can expect an optimal effect to be obtained if it is possible to separate the individual magnetic powder particles from one another so completely electrical to insulate that the core as a whole is practically nonexistent shows electrical conductivity and eddy current losses only in individual magnetic powder particles appear. The highest possible insulation resistance of the earth cores when they are used as induction coil cores for high frequency it is also desirable cool, especially with closed Keinformen, the coil winding or its feeders often in contact with the magnetic core *.:; Comes new and then with low insulation resistance of No easy.tlie attenuation of the induction coil is increased considerably.

Es wurde nun gefunden, daß sich bei V9 X, «-endung von Zucker mit Kunst- oder '1 atis=: , harzen als . Isoliermittel Massekerne stellen lassen, die bei niedrigen Hochfre% quenzverlusten einen hohen Isolationswiderstand aufweisen, wenn man Zucker und Harze beide in gelöster Form mit dem magnetisierbaren Pulver verarbeitet.It has now been found that in V9 X , "-end of sugar with artificial or '1 atis =:, resin as. Let isolating agents put mass cores that have a high insulation resistance at low high frequency losses if sugar and resins are both processed in dissolved form with the magnetizable powder.

Als Zucker kann man die verschiedensten Zuckerarten verwenden, wie z. B. Rohrzucker, Fruchtzucker, Malzzucker, Milchzucker oder Dextrin, auch in nicht kristallinem Zustand. Als Harte eis nen sich u. a. h ärtbare Phenol- bnv. Kresol - Formaldehyd -Kondensationsprodukt:e, Harnstoff - Formaldehyd - Kondensationsprodukte, Polystyrol, Schellack. Durch thermische Zersetzung von Metallcarbonylen hergestellte magnetisierbare Metallpulver sind besonders gut zur Verarbeitung auf \lasse@@erne nach dein vorliegenden Verfahren geeignet. Zweckmäßig bringt man die Zuckerisolation vor der Harzisolation auf die Pulverteilchen auf. Die Formung der Kerne kann man je nach der Beschaffenheit des verwendeten Harzes z. E. nach dem Preß- oder Spritzverfahren ausführen. Auch kann die Pressung in Gegenwart von Löse- oder Quellmitt:eln vorgenammen werden, um größer;. Festigkeit der gepreßten Kerne zu erzielen.The most varied types of sugar can be used as sugar, such as z. B. cane sugar, fructose, malt sugar, milk sugar or dextrin, not even in crystalline state. As hard iron nen, inter alia. hardenable phenol bnv. Cresol - formaldehyde condensation product: e, urea - formaldehyde - condensation products, Polystyrene, shellac. Produced by thermal decomposition of metal carbonyls Magnetizable metal powders are particularly good for processing on \ lasse @@ erne suitable according to your present method. It is useful to bring the sugar isolation on the powder particles before the resin insulation. The formation of the cores can be done depending on the nature of the resin used, e.g. E. after the pressing or spraying process carry out. The pressing can also be carried out in the presence of solvents or swelling agents get to get bigger. To achieve strength of the pressed cores.

Beispiel i oo Gewichtsteile eines durch thermisch;. Zersetzung von Eisencarbonyl hergestellten Eisenpulvers wurden mit 2 Gewichtsteilen Rohrzucker, der in einer Mischung aus gleichen Teilen Wasser und Alkohol gelöst war. in einer Knetmaschine durch Kneten und `jläteres Austreiben des Lösemittels durch R"'ärine isoliert. Anschließend hieran wurde c;,ie «>eitere Isolation., bestehend aus 3 G:-wichtsteilen eines in Alkohol gelösten, hzrtbaren Kresol-Formaldeh3-d-Kond:enca.ionspr"-duktes in der gleichen Weise aufgebracht. Das so, mit den zwei Isolationen versehene Eisenpulver wurde mit einem Druck von etwa 3oool>gicm° zu Hochfrequenzknrnen gepreP.r. Die Kerne wurden i6 Stunden lang hei i io'-im Ofen gehärtet. Die Kerne zeigten einen Isolationswiderstand von 30000o 0hm!cm ".Example i oo parts by weight of a by thermal ;. Decomposition of Iron powder produced by iron carbonyl was mixed with 2 parts by weight of cane sugar, which was dissolved in a mixture of equal parts of water and alcohol. in a Kneading machine by kneading and later expelling the solvent by R "" arine isolated. Then c;, ie «> purulent insulation., Consisting of 3 G: weight parts a heatable cresol-formaldehyde3-d-cond: enca.ionspr "-duktes dissolved in alcohol applied in the same way. The iron powder with the two insulations was tested at a pressure of about 3oool> gicm ° to high-frequency knobs. The cores were cured in the oven for 16 hours. The cores showed insulation resistance of 30000 ohms! cm ".

Zum Vergleich wurden ioo Gewichtsteile des gleichen Eisenpulvers ohne Zuckerisolation mit 7 Gewichtsteilen des in Alkohol gelösten, härtbaren Kresol-Formal,dehyd-ison -densationsDroduktes isoliert und die hernc in der gleichen Weise gepreßt und behandelt. Ihr Isolations«-iderstand hetru-- nur-600o Ohm!cm .For comparison, 100 parts by weight of the same iron powder were used without Sugar isolation with 7 parts by weight of the hardenable cresol-formal, dehyd-ison, dissolved in alcohol -densationsDroduktes isolated and the hernc pressed and treated in the same way. Your insulation resistance is only 600 ohms! Cm.

Claims (1)

PA-rEN T AN SPR tiCH Verfahren zur Herstellung von Massf- lcernen für Magnetkerne, Pupinsn _@lei2, Hochfrequenzeisenkern,e u.dgl. aus ma-- gnetisierbaren, insbesondere durch ther- mische Zersetzung von lt1.etallcarbonylei@ gewonnenen Metallpulvern unter Zusatz von Zucker und Harzen, dadurch gekenn- zeichnet, daß Zucker und Natur- oder Kunstharze, beide in gelöster Form, ver- wendet werden.
PA-REN T ASK Process for the production of learning for magnetic cores, Pupinsn _ @ lei2, High-frequency iron core, e and the like from ma gnetisable, in particular by thermal mixed decomposition of lt1.etallcarbonylei @ obtained metal powders with additive of sugar and resins, thus identifiable draws that sugar and natural or Synthetic resins, both in dissolved form, be turned.
DEI57775D 1937-04-22 1937-04-22 Process for the production of mass cores Expired DE716473C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI57775D DE716473C (en) 1937-04-22 1937-04-22 Process for the production of mass cores

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEI57775D DE716473C (en) 1937-04-22 1937-04-22 Process for the production of mass cores

Publications (1)

Publication Number Publication Date
DE716473C true DE716473C (en) 1942-01-21

Family

ID=7194640

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI57775D Expired DE716473C (en) 1937-04-22 1937-04-22 Process for the production of mass cores

Country Status (1)

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DE (1) DE716473C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE964895C (en) * 1952-02-14 1957-05-29 Siemens Ag Magnetic shunt for the current iron of an induction counter to improve the error curve
DE976118C (en) * 1944-08-29 1963-03-07 Int Standard Electric Corp Process for the production of magnetic powder cores

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE976118C (en) * 1944-08-29 1963-03-07 Int Standard Electric Corp Process for the production of magnetic powder cores
DE964895C (en) * 1952-02-14 1957-05-29 Siemens Ag Magnetic shunt for the current iron of an induction counter to improve the error curve

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