DE719167C - Soap-free detergents - Google Patents

Soap-free detergents

Info

Publication number
DE719167C
DE719167C DEK152808D DEK0152808D DE719167C DE 719167 C DE719167 C DE 719167C DE K152808 D DEK152808 D DE K152808D DE K0152808 D DEK0152808 D DE K0152808D DE 719167 C DE719167 C DE 719167C
Authority
DE
Germany
Prior art keywords
soap
detergents
sodium
cellulose
acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEK152808D
Other languages
German (de)
Inventor
Dr Kurt Sponsel
Dr Julius Voss
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kalle GmbH and Co KG
Original Assignee
Kalle GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kalle GmbH and Co KG filed Critical Kalle GmbH and Co KG
Priority to DEK152808D priority Critical patent/DE719167C/en
Application granted granted Critical
Publication of DE719167C publication Critical patent/DE719167C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Seifenfreie Waschmittel Es wurde gefunden, daß Mischungen aus wasserlöslichen Celluloseallkyläthern, die im Alklrest eine endständige Carboxylgruppe enthalten, und Alkalisalzen von Naphthalinsulfonsäuren ausgezeichnete Waschmittel darstellen. MUlan verwendet die carboxylgruppenhaltigen Cellulosealkyläther vorteilhaft in Form ihrer Alkalisalze. Besonders gut sind die Alkalisalze von Celluloseglykolsäuren geeignet. Es können auch Mischäther der Celliulose verwendet werden, die neben den carboxylgruppenhaltigen Alkylresten noch unsubstituierbe Alkylreste enthalten. Ein ges Produkt ist die Methvlcelluloseglykolsaure.Soap-free detergents It has been found that mixtures of water-soluble Cellulose alkyl ethers which contain a terminal carboxyl group in the alkyl residue, and alkali salts of naphthalenesulfonic acids are excellent detergents. MUlan uses the carboxyl group-containing cellulose alkyl ethers advantageously in the form their alkali salts. The alkali salts of cellulose glycolic acids are particularly good suitable. Mixed ethers of cellulose can also be used, which in addition to the carboxyl-containing alkyl radicals still contain unsubstituted alkyl radicals. A The product is methylcellulose glycolic acid.

Als Naplhthalinsulfonsäuren eignen sich insbesondere Alkylnaphthalinsulfonsäuren. Geeignete Produkte sind beispielsweise dimethylnaphtlialinsulfonsaures Natrium, dibutylnaplithalinsulfonsaures Natrium oder dinonylnaphthalinsulfonsaures Natrium. Auch aralkylnaphthalinsulfonsaure Salze können benutzt werden.Particularly suitable naphthalenesulfonic acids are alkylnaphthalenesulfonic acids. Suitable products are, for example, sodium dimethylnaphthalenesulfonic acid, sodium dibutylnaplithalinsulfonic acid or sodium dinonylnaphthalenesulfonic acid. Aralkylnaphthalenesulfonic acid salts can also be used.

Die Waschmittel gemäß der Erfindung besitzen eine gute Schaum- und Reinigungskraft. Die neuen Waschmittel können infolge ihrer Neutralität bei den verschiedensten Waschvorgängen verwendet werden. Sauerstoffabgebende Salze können ihnen ohne die Gefahr eines Zerfalls zugesetzt werden. Außerdem kann man sie im Gemisch mit anderen üblichen Waschmittelzusätzen verwuenden. Die neuen Waschmittel eignen sich besonders gut für die Baumwollwäsche.The detergents according to the invention have a good foam and Cleaning person. The new detergents can be due to their neutrality with the various washing processes can be used. Oxygen-releasing salts can can be added to them without the risk of disintegration. You can also use them in Use a mixture with other common detergent additives. The new detergents are particularly suitable for cotton laundry.

Waschmittel, die neben Alkalisalzeri von Alkylnaphthalinsulfonsäuren Methylcellulose enthalten, sind bekannt. Die Waschmittel gemäß der Erfindung sind aber wirksamer als die bekannten Waschmittel, insbesondere dann, wenn mit heißen Flotten gewaschen wird.Detergents that contain alkali salts of alkylnaphthalenesulfonic acids Containing methyl cellulose are known. The detergents according to the invention are but more effective than the known detergents, especially when using hot Liquors are washed.

Bei spiele I. Durch Vermischen von 3 Teilen celluloseglykolsaurem Natrium, das auf I Mol Cellulose (C6H1o05) o,8 Mol Glykolsäure gebunden enthält, mit 2 Teilen dibutylnaphthalinsulfonsaurem Natrium und 3 Teilen Soda erhält man ein vorzügliches Waschmittel.Examples I. By mixing 3 parts of celluloseglycolic acid Sodium, which contains 0.8 moles of glycolic acid bound to 1 mole of cellulose (C6H1o05), with 2 parts of sodium dibutylnaphthalenesulfonate and 3 parts of soda are obtained an excellent detergent.

Man verfährt gemäß "Beispiel z, verwendet aber ein celluloseglykolsaures Natrium, das nur 0,5 Mol Glykolsäure auf i Mol Cellulose gebunden eüthält. 3. Eia gutes Waschmittel wird erhalten, indem man I Teil methylcelluloseglykolsaures i Natrium (hergestellt durch Einwirkung ri. 0,4 MOI lblethylchlorid und I Mol chl e$s g.- saurem Natrium auf I Mol Cellulose in Gegenwart von Alkali) mit I Teil dibutylnaphthalinsulfonsaurem Natrium, 2 Teilen Soda und 2 Teilen Natriummetaphosphat vermischt.The procedure is as in "Example z, but a cellulose glycolic acid sodium is used which only contains 0.5 mol of glycolic acid bound to 1 mol of cellulose Sodium (produced by action ri. 0.4 MOI methyl chloride and 1 mol chl e $ s g.- acidic sodium to 1 mole of cellulose in the presence of alkali) mixed with 1 part of sodium dibutylnaphthalenesulfonate, 2 parts of soda and 2 parts of sodium metaphosphate.

Claims (1)

PATENTANSPRUCH: Verwendung von Mischungen aus wasserlöslichen Cellulosealkyläthern, die im Alkylrest eine endständige Carboxylgruppe enthalten, Alkalisalzen von Naphthalinsulfonsäuren, insbesondere von Alkylnaphthalinsulfonsäureln, und gegebenenfalls üblichen Waschmittelzusätzen als seifenfreie Waschmittel.PATENT CLAIM: Use of mixtures of water-soluble cellulose alkyl ethers, which contain a terminal carboxyl group in the alkyl radical, alkali salts of naphthalenesulfonic acids, in particular of alkylnaphthalenesulfonic acids, and optionally customary detergent additives as a soap-free detergent.
DEK152808D 1936-04-25 1936-04-25 Soap-free detergents Expired DE719167C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEK152808D DE719167C (en) 1936-04-25 1936-04-25 Soap-free detergents

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEK152808D DE719167C (en) 1936-04-25 1936-04-25 Soap-free detergents

Publications (1)

Publication Number Publication Date
DE719167C true DE719167C (en) 1942-03-31

Family

ID=7252682

Family Applications (1)

Application Number Title Priority Date Filing Date
DEK152808D Expired DE719167C (en) 1936-04-25 1936-04-25 Soap-free detergents

Country Status (1)

Country Link
DE (1) DE719167C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966725C (en) * 1942-12-12 1957-09-05 Boehme Fettchemie Gmbh Skin cleanser
DE969822C (en) * 1951-08-01 1958-07-24 Kurt Lindner Dr Detergents, wetting agents and dispersants

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966725C (en) * 1942-12-12 1957-09-05 Boehme Fettchemie Gmbh Skin cleanser
DE969822C (en) * 1951-08-01 1958-07-24 Kurt Lindner Dr Detergents, wetting agents and dispersants

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