DE69916455D1 - Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler - Google Patents

Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler

Info

Publication number
DE69916455D1
DE69916455D1 DE69916455T DE69916455T DE69916455D1 DE 69916455 D1 DE69916455 D1 DE 69916455D1 DE 69916455 T DE69916455 T DE 69916455T DE 69916455 T DE69916455 T DE 69916455T DE 69916455 D1 DE69916455 D1 DE 69916455D1
Authority
DE
Germany
Prior art keywords
open chain
polymerization regulator
alkoxyamine compounds
chain alkoxyamine
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69916455T
Other languages
English (en)
Other versions
DE69916455T2 (de
Inventor
Peter Nesvadba
Andreas Kramer
Marie-Odile Zink
Dario Lazzari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of DE69916455D1 publication Critical patent/DE69916455D1/de
Application granted granted Critical
Publication of DE69916455T2 publication Critical patent/DE69916455T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/06—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/14—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having at least one of the hydroxy groups esterified by a carboxylic acid having the esterifying carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C237/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C237/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/24—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C07C239/12—Hydroxylamino compounds or their ethers or esters having nitrogen atoms of hydroxylamino groups further bound to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C07C239/18—Hydroxylamino compounds or their ethers or esters having nitrogen atoms of hydroxylamino groups further bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C07C239/20—Hydroxylamino compounds or their ethers or esters having oxygen atoms of hydroxylamino groups etherified
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/16—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound oxygen atoms bound to the same carbon atom of an acyclic carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/45—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C255/46—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of non-condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C291/00—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00
    • C07C291/02—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00 containing nitrogen-oxide bonds
    • C07C291/04—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00 containing nitrogen-oxide bonds containing amino-oxide bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/08—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D309/10—Oxygen atoms
    • C07D309/12—Oxygen atoms only hydrogen atoms and one oxygen atom directly attached to ring carbon atoms, e.g. tetrahydropyranyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
DE69916455T 1998-07-31 1999-07-27 Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler Expired - Lifetime DE69916455T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98810741 1998-07-31
EP98810741 1998-07-31
PCT/EP1999/005377 WO2000007981A1 (en) 1998-07-31 1999-07-27 Open chain alkoxyamine compounds and their use as polymerization regulators

Publications (2)

Publication Number Publication Date
DE69916455D1 true DE69916455D1 (de) 2004-05-19
DE69916455T2 DE69916455T2 (de) 2004-09-09

Family

ID=8236227

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69916455T Expired - Lifetime DE69916455T2 (de) 1998-07-31 1999-07-27 Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler

Country Status (7)

Country Link
US (2) US6518326B1 (de)
EP (1) EP1100772B1 (de)
JP (1) JP2002522415A (de)
AU (1) AU759817B2 (de)
CA (1) CA2337482A1 (de)
DE (1) DE69916455T2 (de)
WO (1) WO2000007981A1 (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7843300A (en) * 1999-09-30 2001-04-30 Noveon Ip Holdings Corp. Polymerization compositions and methods
US7030196B2 (en) 2000-05-19 2006-04-18 Ciba Specialty Chemicals Corporation Process for reducing the molecular weight of polypropylene
WO2001090113A1 (en) * 2000-05-19 2001-11-29 Ciba Specialty Chemicals Holding Inc. Hydroxylamine esters as polymerization initiators
TWI225492B (en) * 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
TW574236B (en) * 2000-09-25 2004-02-01 Ciba Sc Holding Ag Process for controlled radical polymerization in aqueous dispersion
DE60305299T2 (de) * 2002-03-05 2007-05-10 Ciba Speciality Chemicals Holding Inc. Offenkettige alkoxyamine und deren entsprechende nitroxyde für kontrollierte niedrige temperatur- polymerisation
EP1615962A2 (de) * 2003-02-10 2006-01-18 Ciba SC Holding AG Kammpolymere mit definierten seitenketten und verfahren zu deren herstellung
EP1786860B1 (de) * 2004-09-03 2008-03-26 Ciba Specialty Chemicals Holding Inc. In-can stabilisatoren
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
US20100311920A1 (en) 2005-08-26 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
JP5068765B2 (ja) * 2005-12-14 2012-11-07 ノバルティス アーゲー シリコーンヒドロゲルの製造方法
US20100311849A1 (en) 2006-08-23 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
US20090171049A1 (en) * 2007-12-27 2009-07-02 Linhardt Jeffrey G Segmented reactive block copolymers
WO2009085754A1 (en) * 2007-12-27 2009-07-09 Bausch & Lomb Incorporated Segmented interactive block copolymers
EP2385937A1 (de) * 2009-01-08 2011-11-16 Basf Se Polymerisationsinitiator
MX2011007229A (es) * 2009-01-14 2011-08-03 Basf Se Mezcla de fotoiniciador liquido.
RU2559874C2 (ru) * 2009-05-07 2015-08-20 Басф Се Соединения о-имино-изомочевины и их полимеризуемые композиции
EP2588520B1 (de) 2010-06-29 2014-06-25 Basf Se Verfahren zur Verbesserung der Strömungseigenschaften von Polymerschmelzen und Verwendung von Block- oder Blockkammpolymeren
US9000107B2 (en) 2011-01-31 2015-04-07 Bridgestone Corporation Process for producing polydienes
US20140298591A1 (en) 2011-10-25 2014-10-09 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
CN104937011B (zh) 2013-01-18 2020-12-29 巴斯夫欧洲公司 具有聚二甲基硅氧烷嵌段的嵌段共聚物
WO2014154508A1 (en) 2013-03-27 2014-10-02 Basf Se Block copolymers as soil release agents in laundry processes
EP4251665A1 (de) 2020-11-30 2023-10-04 Basf Se Verfahren zur herstellung von polymerdispersionen
EP4314155A1 (de) 2021-03-26 2024-02-07 Basf Se Polymerzusammensetzung mit polyacrylblockcopolymer und polyalkylenoxid auf aromatischer basis als dispergiermittel

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3253015A (en) * 1962-06-13 1966-05-24 American Cyanamid Co N, n-disubstituted nitroxides and process for preparing same
FR1357477A (fr) * 1963-05-27 1964-04-03 American Cyanamid Co Nitroxydes n.n-disubstitués et leur procédé de préparation
DE3486145T2 (de) * 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
AU571240B2 (en) 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
US5412047A (en) * 1994-05-13 1995-05-02 Xerox Corporation Homoacrylate polymerization processes with oxonitroxides
US6258911B1 (en) * 1994-08-18 2001-07-10 Xerox Corporation Bifunctional macromolecules and toner compositions therefrom
US6320007B1 (en) * 1994-11-18 2001-11-20 Xerox Corporation Process for producing thermoplastic resin polymers
US5449724A (en) * 1994-12-14 1995-09-12 Xerox Corporation Stable free radical polymerization process and thermoplastic materials produced therefrom
US5530079A (en) * 1995-01-03 1996-06-25 Xerox Corporation Polymerization processes
US5498679A (en) * 1995-03-30 1996-03-12 Xerox Corporation Process for producing telechelic, branched and star thermoplastic resin polymers
US5608023A (en) 1995-03-30 1997-03-04 Xerox Corporation Rate enhanced polymerization processes
US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators
US5552502A (en) * 1995-11-16 1996-09-03 Xerox Corporation Polymerization process and compositions thereof
US5723511A (en) * 1996-06-17 1998-03-03 Xerox Corporation Processes for preparing telechelic, branched and star thermoplastic resin polymers
US5910549A (en) * 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
WO1998030601A2 (en) * 1997-01-10 1998-07-16 E.I. Du Pont De Nemours And Company Method of controlling polymer molecular weight and structure
JP2001510208A (ja) * 1997-07-15 2001-07-31 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド ニトロソ化合物又はニトロン化合物から誘導されたアルコキシアミン化合物を含む重合可能な組成物
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
DE50015539D1 (de) * 1999-09-07 2009-03-19 Bayer Materialscience Ag Oligomere und polymere Telechelen
FR2807439B1 (fr) * 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
EP1375457A1 (de) * 2002-06-25 2004-01-02 Bayer Aktiengesellschaft Ein-Topf-Verfahren zur Herstellung von funktionalisierten Alkoxyaminen
EP1375476A1 (de) * 2002-06-25 2004-01-02 Bayer Aktiengesellschaft Neuer Prozess zur Synthese von Alkoxyaminen, die in der kontrollierten radikalischen Polymerisation aktiv sind

Also Published As

Publication number Publication date
US6518326B1 (en) 2003-02-11
US20030125489A1 (en) 2003-07-03
CA2337482A1 (en) 2000-02-17
AU5371999A (en) 2000-02-28
WO2000007981A1 (en) 2000-02-17
JP2002522415A (ja) 2002-07-23
EP1100772B1 (de) 2004-04-14
AU759817B2 (en) 2003-05-01
US6841703B2 (en) 2005-01-11
DE69916455T2 (de) 2004-09-09
EP1100772A1 (de) 2001-05-23

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Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

8327 Change in the person/name/address of the patent owner

Owner name: CIBA HOLDING INC., BASEL, CH

8328 Change in the person/name/address of the agent

Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC