DE69906893D1 - Verfahren zur Hydrierung von Dinitrotoluol zu Toluenediamin mittels eines monolithischen Katalysators - Google Patents
Verfahren zur Hydrierung von Dinitrotoluol zu Toluenediamin mittels eines monolithischen KatalysatorsInfo
- Publication number
- DE69906893D1 DE69906893D1 DE69906893T DE69906893T DE69906893D1 DE 69906893 D1 DE69906893 D1 DE 69906893D1 DE 69906893 T DE69906893 T DE 69906893T DE 69906893 T DE69906893 T DE 69906893T DE 69906893 D1 DE69906893 D1 DE 69906893D1
- Authority
- DE
- Germany
- Prior art keywords
- dinitrotoluene
- toluenediamine
- hydrogenation
- monolithic catalyst
- monolithic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
- B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/2485—Monolithic reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/322—Basic shape of the elements
- B01J2219/32296—Honeycombs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/324—Composition or microstructure of the elements
- B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/130,936 US6005143A (en) | 1998-08-07 | 1998-08-07 | Use of a monolith catalyst for the hydrogenation of dinitrotoluene to toluenediamine |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69906893D1 true DE69906893D1 (de) | 2003-05-22 |
DE69906893T2 DE69906893T2 (de) | 2003-11-06 |
Family
ID=22447073
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69906893T Expired - Lifetime DE69906893T2 (de) | 1998-08-07 | 1999-08-04 | Verfahren zur Hydrierung von Dinitrotoluol zu Toluenediamin mittels eines monolithischen Katalysators |
Country Status (7)
Country | Link |
---|---|
US (1) | US6005143A (de) |
EP (1) | EP0978505B1 (de) |
JP (1) | JP2000080061A (de) |
KR (1) | KR100339285B1 (de) |
CN (1) | CN1192012C (de) |
BR (1) | BR9903380A (de) |
DE (1) | DE69906893T2 (de) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0212321D0 (en) * | 2002-05-29 | 2002-07-10 | Johnson Matthey Plc | Catalyst composition |
EP1121976A1 (de) * | 2000-02-03 | 2001-08-08 | Engelhard Corporation | Chemisches Verfahren in Reaktor mit strukturiertem Katalysator |
US6506361B1 (en) * | 2000-05-18 | 2003-01-14 | Air Products And Chemicals, Inc. | Gas-liquid reaction process including ejector and monolith catalyst |
WO2002051778A1 (en) | 2000-12-27 | 2002-07-04 | Corning Incorporated | Flow control in a three-phase monolithic catalyst reactor |
US20020085975A1 (en) * | 2001-01-04 | 2002-07-04 | Wambaugh James Allen | Method to equalize heat distribution in reactor tube |
US6632414B2 (en) * | 2001-03-30 | 2003-10-14 | Corning Incorporated | Mini-structured catalyst beds for three-phase chemical processing |
US6716339B2 (en) | 2001-03-30 | 2004-04-06 | Corning Incorporated | Hydrotreating process with monolithic catalyst |
US6479704B1 (en) | 2001-04-20 | 2002-11-12 | Air Products And Chemicals, Inc. | Hydrogenation with monolith reactor under conditions of immiscible liquid phases |
EP1518602A1 (de) * | 2001-04-20 | 2005-03-30 | Air Products And Chemicals, Inc. | Beschichtetes monolithisches Substrat und Katalysatoren enthaltend dieses Substrat als Träger |
US20030050510A1 (en) * | 2001-08-30 | 2003-03-13 | Welp Keith Allen | Monolith catalytic reactor coupled to static mixer |
US7109378B2 (en) * | 2001-08-30 | 2006-09-19 | Air Products And Chemicals, Inc. | Monolith catalytic reactor coupled to static mixer |
US6521791B1 (en) | 2001-11-09 | 2003-02-18 | Air Products And Chemicals, Inc. | Process for regenerating a monolith hydrogenation catalytic reactor |
US6762324B2 (en) * | 2002-05-01 | 2004-07-13 | Air Products And Chemicals, Inc. | Metal modified Pd/Ni catalysts |
US20040004031A1 (en) * | 2002-06-26 | 2004-01-08 | Boger Thorsten R. | System and process for pyrolysis gasoline hydrotreatment |
US7771156B2 (en) * | 2003-09-25 | 2010-08-10 | Corning Incorporated | Method and apparatus for reactor monolith loading |
US20050070740A1 (en) * | 2003-09-29 | 2005-03-31 | Rode Chandrashekhar Vasant | Nickel catalyst, process for the preparation thereof, process for hydrogenation of m-dinitro benzene to m-phenylene diamine |
DE10347439A1 (de) * | 2003-10-13 | 2005-05-04 | Bayer Materialscience Ag | Verfahren zur Herstellung von aromatischen Aminen durch heterogen katalysierte Hydrierung |
WO2005056147A2 (en) * | 2003-11-24 | 2005-06-23 | Corning Incorporated | Diesel filter plugging process |
US7045107B2 (en) * | 2004-09-20 | 2006-05-16 | Air Products And Chemicals, Inc. | Process for the production of nitrogen trifluoride |
DE102005008613A1 (de) | 2005-02-23 | 2006-08-31 | Basf Ag | Vefahren zur Herstellung von aromatischen Aminen oder aliphatischen Aminoalkoholen |
DE102006060572A1 (de) * | 2006-12-19 | 2008-06-26 | Bayer Materialscience Ag | Verfahren zur Herstellung von Toluylendiaminen durch katalytische Hydrierung von Dinitrotoluolen |
KR101371842B1 (ko) * | 2007-05-29 | 2014-03-07 | 에보니크 데구사 게엠베하 | 활성화된 베이스 금속 촉매 |
WO2008145181A1 (en) * | 2007-05-29 | 2008-12-04 | Evonik Degussa Gmbh | Activated base metal catalysts |
BRPI0721717A2 (pt) * | 2007-05-29 | 2013-02-13 | Evonik Degussa Gmbh | hidrogenaÇço de compostos nitro, hidrogenaÇço de aromÁticos nitrados, hidrogenaÇço contÍnua de aromÁticos nitrados e catalisadores de ni ativado |
US20080312480A1 (en) * | 2007-06-15 | 2008-12-18 | E. I. Du Pont De Nemours And Company | Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks |
DE102007045125A1 (de) * | 2007-09-20 | 2009-04-02 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von aromatischen Aminen |
BRPI0722161A2 (pt) * | 2007-10-15 | 2014-03-18 | Evonik Degussa Gmbh | Misturas catalíticas em pó de filtragem rápida |
US8298499B2 (en) * | 2007-11-02 | 2012-10-30 | University Of Connecticut | Process intensification in microreactors |
EP2058050A1 (de) * | 2007-11-07 | 2009-05-13 | Centre National De La Recherche Scientifique (Cnrs) | Einstufige katalytische Herstellung von Para-Aminophenol |
US7524995B1 (en) | 2008-06-12 | 2009-04-28 | E.I. Du Pont De Nemours And Company | Continuous process to produce hexafluoroisopropanol |
DE102008063991A1 (de) | 2008-12-19 | 2010-06-24 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
DE102008064281A1 (de) * | 2008-12-20 | 2010-06-24 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Diamintoluol durch vielstufig adiabate Hydrierung |
DE102008063308B4 (de) * | 2008-12-29 | 2013-03-07 | Basf Se | Verfahren zur Herstellung von Toluylendiamin durch Hydrierung von Dinitrotoluol |
US8865608B2 (en) * | 2009-02-27 | 2014-10-21 | Uop Llc | Turndown thermocompressor design for continuous catalyst recovery |
US10792647B2 (en) * | 2009-04-21 | 2020-10-06 | Johnson Matthey Public Limited Company | Base metal catalysts for the oxidation of carbon monoxide and volatile organic compounds |
CN101733169B (zh) * | 2009-12-14 | 2012-07-04 | 江苏圣奥化学科技有限公司 | 一种用于制备对苯二胺类防老剂的铜系催化剂的预处理工艺 |
EP2757088B1 (de) * | 2013-01-22 | 2016-08-03 | Covestro Deutschland AG | Verfahren zur Herstellung von aromatischen Aminen |
KR20160067158A (ko) * | 2013-10-08 | 2016-06-13 | 코베스트로 도이칠란트 아게 | 디아미노톨루엔의 제조 방법 |
CN106349081A (zh) * | 2016-08-29 | 2017-01-25 | 江苏天嘉宜化工有限公司 | 3,4‑二氨基甲苯的合成方法 |
KR102500508B1 (ko) * | 2017-12-28 | 2023-02-16 | 한화솔루션 주식회사 | 사이클로도데센의 제조 방법 및 이의 합성 장치 |
CN114289034B (zh) * | 2021-12-27 | 2024-02-02 | 万华化学集团股份有限公司 | 一种贵金属催化剂和制备方法及其在催化二硝基甲苯加氢制备甲苯二胺应用 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3356728A (en) * | 1964-03-12 | 1967-12-05 | Olin Mathieson | Process of preparing aromatic polyamines by catalytic hydrogenation of aromatic polynitro compounds |
DE2044657A1 (en) * | 1970-09-09 | 1972-03-23 | Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen | Toluylene diamine prepn - using solid ni or ru - contg catalyst |
US4520124A (en) * | 1981-03-19 | 1985-05-28 | Sakai Chemical Industry Co., Ltd. | Method for producing a catalytic structure for the reduction of nitrogen oxides |
US4400538A (en) * | 1981-06-11 | 1983-08-23 | Mobay Chemical Corporation | Fixed bed catalyst for MNB and DNT hydrogenation |
US4513149A (en) * | 1982-04-05 | 1985-04-23 | Olin Corporation | Raney nickel alloy expanded mesh hydrogenation catalysts |
US4743577A (en) * | 1986-10-14 | 1988-05-10 | Amoco Corporation | Catalyst composition |
US5250490A (en) * | 1991-12-24 | 1993-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Noble metal supported on a base metal catalyst |
DE4428018A1 (de) * | 1994-08-08 | 1996-02-15 | Bayer Ag | Verfahren zur Herstellung von aromatischen Aminen |
DE19521587A1 (de) * | 1995-06-14 | 1996-12-19 | Bayer Ag | Verfahren und Katalysator zur Herstellung von aromatischen Aminen durch Gasphasenhydrierung |
FR2741877B1 (fr) * | 1995-12-01 | 1998-02-13 | Rhone Poulenc Chimie | Procede d'hydrogenation de composes nitres aromatiques |
DE19651688A1 (de) * | 1996-12-12 | 1998-06-18 | Bayer Ag | Verfahren zur Herstellung von aromatischen Aminen durch Gasphasenhydrierung |
-
1998
- 1998-08-07 US US09/130,936 patent/US6005143A/en not_active Expired - Lifetime
-
1999
- 1999-08-03 KR KR1019990031780A patent/KR100339285B1/ko not_active IP Right Cessation
- 1999-08-04 BR BR9903380-1A patent/BR9903380A/pt not_active IP Right Cessation
- 1999-08-04 EP EP99115409A patent/EP0978505B1/de not_active Expired - Lifetime
- 1999-08-04 DE DE69906893T patent/DE69906893T2/de not_active Expired - Lifetime
- 1999-08-06 CN CNB991175131A patent/CN1192012C/zh not_active Expired - Fee Related
- 1999-08-06 JP JP11223566A patent/JP2000080061A/ja not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CN1192012C (zh) | 2005-03-09 |
KR100339285B1 (ko) | 2002-06-03 |
KR20000017021A (ko) | 2000-03-25 |
EP0978505A3 (de) | 2000-11-02 |
BR9903380A (pt) | 2000-10-17 |
US6005143A (en) | 1999-12-21 |
JP2000080061A (ja) | 2000-03-21 |
EP0978505A2 (de) | 2000-02-09 |
CN1245163A (zh) | 2000-02-23 |
DE69906893T2 (de) | 2003-11-06 |
EP0978505B1 (de) | 2003-04-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |