DE69826477T2 - Flammhemmende zusammensetzungen - Google Patents
Flammhemmende zusammensetzungen Download PDFInfo
- Publication number
- DE69826477T2 DE69826477T2 DE69826477T DE69826477T DE69826477T2 DE 69826477 T2 DE69826477 T2 DE 69826477T2 DE 69826477 T DE69826477 T DE 69826477T DE 69826477 T DE69826477 T DE 69826477T DE 69826477 T2 DE69826477 T2 DE 69826477T2
- Authority
- DE
- Germany
- Prior art keywords
- flame
- flame retardant
- hindered amine
- test
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims description 76
- -1 amine compound Chemical class 0.000 claims description 163
- 239000003063 flame retardant Substances 0.000 claims description 106
- 229920001577 copolymer Polymers 0.000 claims description 61
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 60
- 150000001412 amines Chemical class 0.000 claims description 55
- 125000004432 carbon atom Chemical group C* 0.000 claims description 42
- 125000000217 alkyl group Chemical group 0.000 claims description 35
- 229920000642 polymer Polymers 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 18
- 229920002397 thermoplastic olefin Polymers 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229920000307 polymer substrate Polymers 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 8
- 229920000098 polyolefin Polymers 0.000 claims description 8
- 230000002195 synergetic effect Effects 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000000000 cycloalkoxy group Chemical group 0.000 claims description 6
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 4
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical class CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001463 antimony compounds Chemical class 0.000 claims description 3
- 150000004677 hydrates Chemical class 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 2
- 150000004692 metal hydroxides Chemical class 0.000 claims description 2
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- 239000010703 silicon Substances 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
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- 239000000126 substance Substances 0.000 description 16
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 15
- 239000005977 Ethylene Substances 0.000 description 15
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 15
- 239000006260 foam Substances 0.000 description 13
- 125000002947 alkylene group Chemical group 0.000 description 12
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 12
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- 125000001931 aliphatic group Chemical group 0.000 description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
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- 229910019142 PO4 Inorganic materials 0.000 description 9
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- 125000006309 butyl amino group Chemical group 0.000 description 9
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- 239000012796 inorganic flame retardant Substances 0.000 description 8
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- BHYQWBKCXBXPKM-UHFFFAOYSA-N tris[3-bromo-2,2-bis(bromomethyl)propyl] phosphate Chemical compound BrCC(CBr)(CBr)COP(=O)(OCC(CBr)(CBr)CBr)OCC(CBr)(CBr)CBr BHYQWBKCXBXPKM-UHFFFAOYSA-N 0.000 description 8
- HCUOEKSZWPGJIM-IYNMRSRQSA-N (e,2z)-2-hydroxyimino-6-methoxy-4-methyl-5-nitrohex-3-enamide Chemical compound COCC([N+]([O-])=O)\C(C)=C\C(=N\O)\C(N)=O HCUOEKSZWPGJIM-IYNMRSRQSA-N 0.000 description 7
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 description 7
- 101100162200 Aspergillus parasiticus (strain ATCC 56775 / NRRL 5862 / SRRC 143 / SU-1) aflD gene Proteins 0.000 description 7
- 239000006096 absorbing agent Substances 0.000 description 7
- 125000003710 aryl alkyl group Chemical group 0.000 description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 7
- 150000001993 dienes Chemical class 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
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- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical group C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 5
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 5
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- 229910000410 antimony oxide Inorganic materials 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
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- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 4
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 4
- UZUNCLSDTUBVCN-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-(2-phenylpropan-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound C=1C(C(C)(C)CC(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C(O)C=1C(C)(C)C1=CC=CC=C1 UZUNCLSDTUBVCN-UHFFFAOYSA-N 0.000 description 4
- VVISQEKWYPFFLK-UHFFFAOYSA-N 2-n,2-n,4-n,4-n-tetrabutyl-6-chloro-1,3,5-triazine-2,4-diamine Chemical compound CCCCN(CCCC)C1=NC(Cl)=NC(N(CCCC)CCCC)=N1 VVISQEKWYPFFLK-UHFFFAOYSA-N 0.000 description 4
- YZXTWMQYSSMUFH-UHFFFAOYSA-N 4-[6-(1-amino-2,2,6,6-tetramethylpiperidin-4-yl)hexyl]-2,2,6,6-tetramethylpiperidin-1-amine Chemical compound C1C(C)(C)N(N)C(C)(C)CC1CCCCCCC1CC(C)(C)N(N)C(C)(C)C1 YZXTWMQYSSMUFH-UHFFFAOYSA-N 0.000 description 4
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 4
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
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- 239000001177 diphosphate Substances 0.000 description 4
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 4
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- OKELZJLBUAZSCL-UHFFFAOYSA-N 1-cyclohexyloxy-2,2,6,6-tetramethyl-n-octadecylpiperidin-4-amine Chemical compound CC1(C)CC(NCCCCCCCCCCCCCCCCCC)CC(C)(C)N1OC1CCCCC1 OKELZJLBUAZSCL-UHFFFAOYSA-N 0.000 description 3
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
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- 239000000945 filler Substances 0.000 description 1
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- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229940093920 gynecological arsenic compound Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical class OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- BAQLUVXNKOTTHU-UHFFFAOYSA-N metofenazate Chemical compound COC1=C(OC)C(OC)=CC(C(=O)OCCN2CCN(CCCN3C4=CC(Cl)=CC=C4SC4=CC=CC=C43)CC2)=C1 BAQLUVXNKOTTHU-UHFFFAOYSA-N 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KIWSYRHAAPLJFJ-DNZSEPECSA-N n-[(e,2z)-4-ethyl-2-hydroxyimino-5-nitrohex-3-enyl]pyridine-3-carboxamide Chemical compound [O-][N+](=O)C(C)C(/CC)=C/C(=N/O)/CNC(=O)C1=CC=CN=C1 KIWSYRHAAPLJFJ-DNZSEPECSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical class OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 229920001627 poly(4-methyl styrene) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical group 0.000 description 1
- SPDZFJLQFWSJGA-UHFFFAOYSA-N uredepa Chemical compound C1CN1P(=O)(NC(=O)OCC)N1CC1 SPDZFJLQFWSJGA-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Paper (AREA)
- Printing Methods (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5133197P | 1997-06-30 | 1997-06-30 | |
| US51331P | 1997-06-30 | ||
| PCT/US1998/013469 WO1999000450A1 (en) | 1997-06-30 | 1998-06-25 | Flame retardant compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69826477D1 DE69826477D1 (de) | 2004-10-28 |
| DE69826477T2 true DE69826477T2 (de) | 2005-11-17 |
Family
ID=21970653
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69826477T Expired - Lifetime DE69826477T2 (de) | 1997-06-30 | 1998-06-25 | Flammhemmende zusammensetzungen |
| DE69841728T Expired - Lifetime DE69841728D1 (de) | 1997-06-30 | 1998-06-25 | Verwendung von NOR-HALS Verbindung als flammhemmende Additive in Polymerzusammensetzungen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69841728T Expired - Lifetime DE69841728D1 (de) | 1997-06-30 | 1998-06-25 | Verwendung von NOR-HALS Verbindung als flammhemmende Additive in Polymerzusammensetzungen |
Country Status (12)
| Country | Link |
|---|---|
| EP (2) | EP1462481B1 (enExample) |
| JP (1) | JP4378574B2 (enExample) |
| KR (1) | KR100540156B1 (enExample) |
| CN (1) | CN1178978C (enExample) |
| AU (1) | AU735643B2 (enExample) |
| BR (1) | BR9810957A (enExample) |
| CA (1) | CA2292598C (enExample) |
| DE (2) | DE69826477T2 (enExample) |
| ES (1) | ES2227855T3 (enExample) |
| RU (1) | RU2207352C2 (enExample) |
| TW (1) | TW480276B (enExample) |
| WO (1) | WO1999000450A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2450401A1 (de) | 2008-09-05 | 2012-05-09 | THOR GmbH | Flammschutzzusammensetzung enthaltend ein Phosphonsäurederivat |
Families Citing this family (84)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999054530A1 (en) * | 1998-04-20 | 1999-10-28 | Bba Nonwovens Simpsonville, Inc. | Nonwoven fabric having both uv stability and flame retardancy and related method for its manufacture |
| JP5362938B2 (ja) * | 1999-12-09 | 2013-12-11 | チバ ホールディング インコーポレーテッド | エチレン性不飽和樹脂の保存安定性を向上させる添加組成物 |
| JP2004083913A (ja) * | 2000-04-06 | 2004-03-18 | Mitsubishi Rayon Co Ltd | 難燃性ポリプロピレンフィルム |
| JP3540759B2 (ja) * | 2000-04-06 | 2004-07-07 | 三菱レイヨン株式会社 | 難燃性ポリプロピレン繊維及びその製造方法 |
| JP3822046B2 (ja) * | 2000-10-11 | 2006-09-13 | 大和紡績株式会社 | 繊維およびその繊維組成物 |
| JP2002121333A (ja) * | 2000-10-13 | 2002-04-23 | Daiwabo Co Ltd | ポリオレフィン樹脂成形物及びそれからなるフィルム |
| GB2386901B (en) * | 2000-12-12 | 2004-03-31 | Ciba Sc Holding Ag | Improved weatherability of flame retardant polyolefin |
| TWI273115B (en) * | 2000-12-12 | 2007-02-11 | Ciba Sc Holding Ag | Improved weatherability of flame retardant polyolefin |
| JP2002322322A (ja) † | 2001-02-27 | 2002-11-08 | Bromine Compounds Ltd | 難燃性ポリオレフィン組成物 |
| ATE302814T1 (de) | 2001-03-20 | 2005-09-15 | Ciba Sc Holding Ag | Flammhemmende zusammensetzungen |
| US6465645B1 (en) * | 2001-04-17 | 2002-10-15 | Ciba Specialty Chemicals Corporation | Long chain hindered amines and compositions stabilized therewith |
| JP3679738B2 (ja) * | 2001-07-16 | 2005-08-03 | 三菱レイヨン株式会社 | 難燃性ポリプロピレン繊維及びその製造方法 |
| US6822023B2 (en) * | 2001-12-03 | 2004-11-23 | Kaneka Corporation | Flame retardant polyolefin resin pre-expanded particles and in-mold foamed articles prepared therefrom |
| JP4406869B2 (ja) * | 2001-12-10 | 2010-02-03 | チバ ホールディング インコーポレーテッド | 難燃性組成物 |
| KR101029863B1 (ko) | 2001-12-21 | 2011-04-18 | 시바 홀딩 인코포레이티드 | 신규한 난연제 화합물 |
| JP4091317B2 (ja) * | 2002-02-28 | 2008-05-28 | 萩原工業株式会社 | 光透過性を有するクロスシート |
| JP2003251748A (ja) * | 2002-02-28 | 2003-09-09 | Hagihara Industries Inc | 膜材料ラミネートシート |
| JP2004315544A (ja) * | 2002-02-28 | 2004-11-11 | Hagihara Industries Inc | ポリオレフィンフイルムまたはラミネートシート |
| JP2003251767A (ja) * | 2002-02-28 | 2003-09-09 | Hagihara Industries Inc | 不織布補強用ポリオレフィンクロスシート |
| JP2003251771A (ja) * | 2002-02-28 | 2003-09-09 | Hagihara Industries Inc | ポリオレフィン防炎性ラミネートシート |
| JP4009117B2 (ja) * | 2002-03-06 | 2007-11-14 | 大和紡績株式会社 | オレフィン複合シートおよび強化複合不織布 |
| US7323502B2 (en) * | 2002-03-12 | 2008-01-29 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| JP2004000173A (ja) * | 2002-03-28 | 2004-01-08 | Hagihara Industries Inc | 防草シート |
| JP3895207B2 (ja) * | 2002-03-29 | 2007-03-22 | 大和紡績株式会社 | 難燃性ポリオレフィン繊維およびこれを用いた繊維組成物と繊維積層体 |
| AU2003224035A1 (en) * | 2002-04-10 | 2003-10-20 | Ciba Specialty Chemicals Holding Inc. | Flame retardant coatings |
| ATE420136T1 (de) | 2002-04-17 | 2009-01-15 | Ciba Holding Inc | Flammhemmende polymerzusammensetzung mit hydroxylaminestern |
| JP2003313737A (ja) * | 2002-04-24 | 2003-11-06 | Hagihara Industries Inc | パイル糸 |
| JP2004019074A (ja) * | 2002-06-19 | 2004-01-22 | Hagihara Industries Inc | 防虫網 |
| JP4016123B2 (ja) * | 2002-07-22 | 2007-12-05 | 平岡織染株式会社 | 難燃化ポリプロピレン系樹脂膜材 |
| AU2003270264A1 (en) * | 2002-10-03 | 2004-04-23 | Ciba Specialty Chemicals Holding Inc. | Flame retardant compositions |
| JP2004131869A (ja) * | 2002-10-10 | 2004-04-30 | Mitsubishi Rayon Co Ltd | 難燃性を有するポリプロピレン系熱接着性複合繊維及びその製造方法 |
| CN100352852C (zh) * | 2002-10-17 | 2007-12-05 | 西巴特殊化学品控股有限公司 | 阻燃聚合物电气部件 |
| MY139230A (en) | 2002-10-17 | 2009-08-28 | Ciba Holding Inc | Flame retardant polymeric electrical parts |
| US7109260B2 (en) * | 2002-10-17 | 2006-09-19 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| US7138448B2 (en) * | 2002-11-04 | 2006-11-21 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| JP2004161850A (ja) * | 2002-11-12 | 2004-06-10 | Mitsubishi Rayon Co Ltd | 難燃性シート状物 |
| JP4077745B2 (ja) * | 2003-02-28 | 2008-04-23 | 株式会社ジェイエスピー | ポリオレフィン系樹脂型内発泡成形体 |
| JP4158559B2 (ja) * | 2003-03-07 | 2008-10-01 | 東洋インキ製造株式会社 | 難燃性樹脂組成物およびそれを用いたシート |
| JP3879695B2 (ja) * | 2003-04-25 | 2007-02-14 | チッソ株式会社 | 難燃性ポリオレフィン樹脂組成物 |
| US7235596B2 (en) | 2003-04-25 | 2007-06-26 | Chisso Polypro Fiber Company Limited. | Flame-resistant fiber and fiber molding using the same |
| ATE346883T1 (de) * | 2003-07-18 | 2006-12-15 | Ciba Sc Holding Ag | Flammwidrige polymilchsäure |
| WO2006070859A1 (ja) * | 2004-12-28 | 2006-07-06 | Mitsubishi Rayon Co., Ltd. | ポリプロピレン難燃繊維およびこれを用いた織編物並びに繊維製品 |
| JP2006316168A (ja) * | 2005-05-12 | 2006-11-24 | Marubishi Oil Chem Co Ltd | 難燃剤及びそれを含む合成樹脂組成物 |
| JP4721823B2 (ja) * | 2005-08-23 | 2011-07-13 | 出光ライオンコンポジット株式会社 | 難燃性樹脂組成物及びそれからなる成形体 |
| US20090318592A1 (en) * | 2005-10-11 | 2009-12-24 | Ciba Corporation | Process for the Synthesis of Amine Ethers |
| KR101403753B1 (ko) | 2006-03-16 | 2014-06-03 | 클라리언트 파이넌스 (비브이아이)리미티드 | 개질된 왁스, 이의 제조 방법, 및 이의 용도 |
| CN101405306B (zh) * | 2006-03-16 | 2011-07-27 | 克莱里安特财务(Bvi)有限公司 | 改性蜡、其制备方法及其用途 |
| JP5473613B2 (ja) * | 2007-02-21 | 2014-04-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 難燃性組成物における対称性アゾ化合物 |
| US20120037837A1 (en) * | 2009-04-15 | 2012-02-16 | Kaneka Corporation | Polyolefin-based resin pre-expanded particles and polyolefin-based resin in-mold expansion molded article comprising polyolefin-based resin pre-expanded particles |
| JP2011068717A (ja) * | 2009-09-24 | 2011-04-07 | Yazaki Corp | 難燃性樹脂組成物 |
| US20130059952A1 (en) | 2010-01-15 | 2013-03-07 | Basf Se | Phospho-substituted alkoxyamine compounds |
| RU2012145171A (ru) * | 2010-03-25 | 2014-04-27 | Басф Се | Огнезащитные композиции солей фосфиновых кислот и нитроксильных производных |
| JP5581133B2 (ja) * | 2010-07-02 | 2014-08-27 | 日本ポリエチレン株式会社 | 太陽電池封止材用樹脂組成物、及びそれを用いた太陽電池封止材、その製造方法、ならびに太陽電池モジュール |
| CA2804228A1 (en) | 2010-07-28 | 2012-02-02 | Basf Se | Phosphinic acid hydrazide flame retardant compositions |
| WO2012013565A1 (en) | 2010-07-29 | 2012-02-02 | Basf Se | Phosphinic acid hydrazide flame retardant compositions |
| CN101914217B (zh) * | 2010-07-29 | 2011-12-28 | 济南泰星精细化工有限公司 | 一种替代三氧化二锑的环保阻燃剂 |
| EP2692794B1 (en) * | 2011-03-31 | 2019-12-25 | Toray Industries, Inc. | Carbon-fiber reinforced polypropylene resin composition, molding material, and molded articles |
| WO2013136285A1 (en) * | 2012-03-16 | 2013-09-19 | Basf Se | Nor-hals compounds as flame retardants |
| JP2014062189A (ja) * | 2012-09-21 | 2014-04-10 | Mitsubishi Motors Corp | 車輌用バッテリーケース |
| DE102012022482A1 (de) | 2012-11-19 | 2014-05-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymerzusammensetzung mit verbesserter Langzeitstabilität, hieraus hergestellte Formteile sowie Verwendungszwecke |
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| TW201718742A (zh) * | 2015-07-20 | 2017-06-01 | 巴地斯公司 | 阻燃聚烯烴系統 |
| JP6826846B2 (ja) * | 2016-09-13 | 2021-02-10 | 日本ポリエチレン株式会社 | 難燃性フィルム |
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| EP4365225A1 (en) | 2022-11-04 | 2024-05-08 | Clariant International Ltd | Flame-retardant composition, polymer composition comprising same and use thereof |
| JP2024149247A (ja) * | 2023-04-07 | 2024-10-18 | 出光ファインコンポジット株式会社 | 樹脂組成物 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4978699A (en) * | 1988-10-24 | 1990-12-18 | Atochem North America, Inc. | Light stabilizing flame retardants |
| US5393812A (en) * | 1993-08-31 | 1995-02-28 | Hercules Incorporated | Flame retardant, light stable composition |
| EP0792911A3 (en) * | 1996-02-27 | 1998-01-14 | Fmc Corporation | Flame resistant polyolefin compositions |
-
1998
- 1998-06-25 BR BR9810957-0A patent/BR9810957A/pt not_active IP Right Cessation
- 1998-06-25 CA CA002292598A patent/CA2292598C/en not_active Expired - Lifetime
- 1998-06-25 WO PCT/US1998/013469 patent/WO1999000450A1/en not_active Ceased
- 1998-06-25 KR KR10-1999-7012483A patent/KR100540156B1/ko not_active Expired - Lifetime
- 1998-06-25 JP JP50584099A patent/JP4378574B2/ja not_active Expired - Lifetime
- 1998-06-25 DE DE69826477T patent/DE69826477T2/de not_active Expired - Lifetime
- 1998-06-25 EP EP04013753A patent/EP1462481B1/en not_active Expired - Lifetime
- 1998-06-25 RU RU2000102671/04A patent/RU2207352C2/ru active
- 1998-06-25 AU AU81749/98A patent/AU735643B2/en not_active Expired
- 1998-06-25 DE DE69841728T patent/DE69841728D1/de not_active Expired - Lifetime
- 1998-06-25 ES ES98931701T patent/ES2227855T3/es not_active Expired - Lifetime
- 1998-06-25 CN CNB988067269A patent/CN1178978C/zh not_active Expired - Lifetime
- 1998-06-25 EP EP98931701A patent/EP0996669B1/en not_active Expired - Lifetime
- 1998-08-29 TW TW087114386A patent/TW480276B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2450401A1 (de) | 2008-09-05 | 2012-05-09 | THOR GmbH | Flammschutzzusammensetzung enthaltend ein Phosphonsäurederivat |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4378574B2 (ja) | 2009-12-09 |
| DE69826477D1 (de) | 2004-10-28 |
| BR9810957A (pt) | 2000-09-26 |
| KR20010014333A (ko) | 2001-02-26 |
| KR100540156B1 (ko) | 2005-12-29 |
| EP0996669A1 (en) | 2000-05-03 |
| TW480276B (en) | 2002-03-21 |
| AU8174998A (en) | 1999-01-19 |
| CA2292598C (en) | 2008-03-18 |
| WO1999000450A1 (en) | 1999-01-07 |
| RU2207352C2 (ru) | 2003-06-27 |
| DE69841728D1 (de) | 2010-07-29 |
| EP1462481A3 (en) | 2004-10-13 |
| EP1462481A2 (en) | 2004-09-29 |
| AU735643B2 (en) | 2001-07-12 |
| ES2227855T3 (es) | 2005-04-01 |
| EP1462481B1 (en) | 2010-06-16 |
| JP2002507238A (ja) | 2002-03-05 |
| CN1178978C (zh) | 2004-12-08 |
| EP0996669B1 (en) | 2004-09-22 |
| CA2292598A1 (en) | 1999-01-07 |
| CN1261904A (zh) | 2000-08-02 |
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