DE69824550T2 - Modifizierte polyester - Google Patents
Modifizierte polyester Download PDFInfo
- Publication number
- DE69824550T2 DE69824550T2 DE69824550T DE69824550T DE69824550T2 DE 69824550 T2 DE69824550 T2 DE 69824550T2 DE 69824550 T DE69824550 T DE 69824550T DE 69824550 T DE69824550 T DE 69824550T DE 69824550 T2 DE69824550 T2 DE 69824550T2
- Authority
- DE
- Germany
- Prior art keywords
- polyester
- polyhydric alcohol
- polyfunctional
- pet
- precursor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 140
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 66
- 150000008065 acid anhydrides Chemical class 0.000 claims abstract description 44
- 239000002243 precursor Substances 0.000 claims abstract description 39
- 229920002959 polymer blend Polymers 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 40
- 239000000654 additive Substances 0.000 claims description 33
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 claims description 31
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 23
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 22
- 150000008064 anhydrides Chemical class 0.000 claims description 21
- 239000000155 melt Substances 0.000 claims description 21
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 19
- -1 polyethylene terephthalate Polymers 0.000 claims description 19
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 19
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 15
- 238000006068 polycondensation reaction Methods 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 11
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical group O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000009833 condensation Methods 0.000 claims description 8
- 230000005494 condensation Effects 0.000 claims description 8
- 238000010168 coupling process Methods 0.000 claims description 8
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 8
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 7
- 230000008878 coupling Effects 0.000 claims description 7
- 238000005859 coupling reaction Methods 0.000 claims description 7
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 7
- 229920001225 polyester resin Polymers 0.000 claims description 7
- 239000004645 polyester resin Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 229920013730 reactive polymer Polymers 0.000 claims description 7
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000012963 UV stabilizer Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 3
- 229920000106 Liquid crystal polymer Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 30
- 230000000694 effects Effects 0.000 description 26
- 238000012986 modification Methods 0.000 description 26
- 230000004048 modification Effects 0.000 description 26
- 230000008569 process Effects 0.000 description 17
- 238000000518 rheometry Methods 0.000 description 15
- 238000012545 processing Methods 0.000 description 12
- 230000006872 improvement Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 10
- 150000002148 esters Chemical class 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 230000000996 additive effect Effects 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 8
- 230000008025 crystallization Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 7
- 238000001746 injection moulding Methods 0.000 description 7
- 239000004594 Masterbatch (MB) Substances 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 239000003607 modifier Substances 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- QQGYZOYWNCKGEK-UHFFFAOYSA-N 5-[(1,3-dioxo-2-benzofuran-5-yl)oxy]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(OC=2C=C3C(=O)OC(C3=CC=2)=O)=C1 QQGYZOYWNCKGEK-UHFFFAOYSA-N 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000003856 thermoforming Methods 0.000 description 5
- 238000005809 transesterification reaction Methods 0.000 description 5
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 241000233805 Phoenix Species 0.000 description 4
- 238000000071 blow moulding Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JASHGAIOBWYPBI-UHFFFAOYSA-N 3a,4a,7a,7b-tetrahydrodifuro[5,4-a:5',4'-d]furan-1,3,5,7-tetrone Chemical compound O=C1OC(=O)C2C1C1C(=O)OC(=O)C1O2 JASHGAIOBWYPBI-UHFFFAOYSA-N 0.000 description 2
- POLIXZIAIMAECK-UHFFFAOYSA-N 4-[2-(2,6-dioxomorpholin-4-yl)ethyl]morpholine-2,6-dione Chemical compound C1C(=O)OC(=O)CN1CCN1CC(=O)OC(=O)C1 POLIXZIAIMAECK-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- BJXXCOMGRRCAGN-CLFAGFIQSA-N [2,2-bis(hydroxymethyl)-3-[(z)-octadec-9-enoyl]oxypropyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CO)(CO)COC(=O)CCCCCCC\C=C/CCCCCCCC BJXXCOMGRRCAGN-CLFAGFIQSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 239000006085 branching agent Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- WOSVXXBNNCUXMT-UHFFFAOYSA-N cyclopentane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1CC(C(O)=O)C(C(O)=O)C1C(O)=O WOSVXXBNNCUXMT-UHFFFAOYSA-N 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 1
- MNUHUVIZSPCLFF-UHFFFAOYSA-N 1-methylhept-6-ene-1,2,4,5-tetracarboxylic acid Chemical compound OC(=O)C(C)C(C(O)=O)CC(C(O)=O)C(C=C)C(O)=O MNUHUVIZSPCLFF-UHFFFAOYSA-N 0.000 description 1
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
- GDGUCRQNTDPGSD-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)CO.OCC(CO)(CO)CO GDGUCRQNTDPGSD-UHFFFAOYSA-N 0.000 description 1
- SQQCWHCJRWYRLB-UHFFFAOYSA-N 2,3,4,5,6-pentahydroxy-1-[4-[4-[(2,3,4,5,6-pentahydroxy-1-sulfohexyl)amino]phenyl]sulfonylanilino]hexane-1-sulfonic acid Chemical compound C1=CC(NC(C(O)C(O)C(O)C(O)CO)S(O)(=O)=O)=CC=C1S(=O)(=O)C1=CC=C(NC(C(O)C(O)C(O)C(O)CO)S(O)(=O)=O)C=C1 SQQCWHCJRWYRLB-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- GWHLJVMSZRKEAQ-UHFFFAOYSA-N 3-(2,3-dicarboxyphenyl)phthalic acid Chemical compound OC(=O)C1=CC=CC(C=2C(=C(C(O)=O)C=CC=2)C(O)=O)=C1C(O)=O GWHLJVMSZRKEAQ-UHFFFAOYSA-N 0.000 description 1
- SQNMHJHUPDEXMS-UHFFFAOYSA-N 4-(1,2-dicarboxyethyl)-1,2,3,4-tetrahydronaphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=C2C(C(CC(=O)O)C(O)=O)CC(C(O)=O)C(C(O)=O)C2=C1 SQNMHJHUPDEXMS-UHFFFAOYSA-N 0.000 description 1
- VILWHDNLOJCHNJ-UHFFFAOYSA-N 4-(3,4-dicarboxyphenyl)sulfanylphthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1SC1=CC=C(C(O)=O)C(C(O)=O)=C1 VILWHDNLOJCHNJ-UHFFFAOYSA-N 0.000 description 1
- AVCOFPOLGHKJQB-UHFFFAOYSA-N 4-(3,4-dicarboxyphenyl)sulfonylphthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1S(=O)(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 AVCOFPOLGHKJQB-UHFFFAOYSA-N 0.000 description 1
- APXJLYIVOFARRM-UHFFFAOYSA-N 4-[2-(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(C(O)=O)C(C(O)=O)=C1 APXJLYIVOFARRM-UHFFFAOYSA-N 0.000 description 1
- GEYAGBVEAJGCFB-UHFFFAOYSA-N 4-[2-(3,4-dicarboxyphenyl)propan-2-yl]phthalic acid Chemical compound C=1C=C(C(O)=O)C(C(O)=O)=CC=1C(C)(C)C1=CC=C(C(O)=O)C(C(O)=O)=C1 GEYAGBVEAJGCFB-UHFFFAOYSA-N 0.000 description 1
- HOOIIRHGHALACD-UHFFFAOYSA-N 5-(2,5-dioxooxolan-3-yl)-3-methylcyclohex-3-ene-1,2-dicarboxylic acid Chemical compound C1C(C(O)=O)C(C(O)=O)C(C)=CC1C1C(=O)OC(=O)C1 HOOIIRHGHALACD-UHFFFAOYSA-N 0.000 description 1
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241001295925 Gegenes Species 0.000 description 1
- HIZCTWCPHWUPFU-UHFFFAOYSA-N Glycerol tribenzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(OC(=O)C=1C=CC=CC=1)COC(=O)C1=CC=CC=C1 HIZCTWCPHWUPFU-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229920001054 Poly(ethylene‐co‐vinyl acetate) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- NIDZWWNRMZPMLN-UHFFFAOYSA-N [1,4,4-tris(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCC(CO)(CO)CC1 NIDZWWNRMZPMLN-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WKDNYTOXBCRNPV-UHFFFAOYSA-N bpda Chemical compound C1=C2C(=O)OC(=O)C2=CC(C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 WKDNYTOXBCRNPV-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000012024 dehydrating agents Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000006159 dianhydride group Chemical group 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000012632 extractable Substances 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010096 film blowing Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000010103 injection stretch blow moulding Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000013365 molecular weight analysis method Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- OBKARQMATMRWQZ-UHFFFAOYSA-N naphthalene-1,2,5,6-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 OBKARQMATMRWQZ-UHFFFAOYSA-N 0.000 description 1
- DOBFTMLCEYUAQC-UHFFFAOYSA-N naphthalene-2,3,6,7-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C=C2C=C(C(O)=O)C(C(=O)O)=CC2=C1 DOBFTMLCEYUAQC-UHFFFAOYSA-N 0.000 description 1
- MNZMMCVIXORAQL-UHFFFAOYSA-N naphthalene-2,6-diol Chemical compound C1=C(O)C=CC2=CC(O)=CC=C21 MNZMMCVIXORAQL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- FVDOBFPYBSDRKH-UHFFFAOYSA-N perylene-3,4,9,10-tetracarboxylic acid Chemical compound C=12C3=CC=C(C(O)=O)C2=C(C(O)=O)C=CC=1C1=CC=C(C(O)=O)C2=C1C3=CC=C2C(=O)O FVDOBFPYBSDRKH-UHFFFAOYSA-N 0.000 description 1
- 229920001713 poly(ethylene-co-vinyl alcohol) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002338 polyhydroxyethylmethacrylate Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000417 polynaphthalene Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 125000006160 pyromellitic dianhydride group Chemical group 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/916—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
- C08G63/86—Germanium, antimony, or compounds thereof
- C08G63/866—Antimony or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPO488797 | 1997-01-31 | ||
| AUPO4887A AUPO488797A0 (en) | 1997-01-31 | 1997-01-31 | Modified polyesters |
| AUPO662797 | 1997-05-06 | ||
| AUPO6627A AUPO662797A0 (en) | 1997-05-06 | 1997-05-06 | Modified polyesters |
| PCT/AU1998/000051 WO1998033837A1 (en) | 1997-01-31 | 1998-01-30 | Modified polyesters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69824550D1 DE69824550D1 (de) | 2004-07-22 |
| DE69824550T2 true DE69824550T2 (de) | 2005-08-25 |
Family
ID=25645354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69824550T Expired - Fee Related DE69824550T2 (de) | 1997-01-31 | 1998-01-30 | Modifizierte polyester |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6350822B1 (OSRAM) |
| EP (1) | EP0956313B1 (OSRAM) |
| JP (1) | JP2001509197A (OSRAM) |
| KR (1) | KR100567089B1 (OSRAM) |
| CN (1) | CN1109056C (OSRAM) |
| AT (1) | ATE269370T1 (OSRAM) |
| CA (1) | CA2278800C (OSRAM) |
| DE (1) | DE69824550T2 (OSRAM) |
| DK (1) | DK0956313T3 (OSRAM) |
| ES (1) | ES2223117T3 (OSRAM) |
| ID (1) | ID22418A (OSRAM) |
| IL (1) | IL131170A (OSRAM) |
| MY (1) | MY120019A (OSRAM) |
| NZ (1) | NZ336961A (OSRAM) |
| PT (1) | PT956313E (OSRAM) |
| WO (1) | WO1998033837A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102020216002A1 (de) | 2020-12-16 | 2022-06-23 | Robert Bosch Gesellschaft mit beschränkter Haftung | Dichtmaterial zur Abdichtung einer Bipolarplatte |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPP610798A0 (en) * | 1998-09-23 | 1998-10-15 | Swig Pty Ltd | Improved polymers |
| EP1054031B1 (de) * | 1999-05-21 | 2005-08-24 | Ciba SC Holding AG | Molekulargewichtsaufbau und Modifizierung von Polykondensaten |
| DK1470175T3 (da) * | 2002-02-01 | 2007-05-21 | Clariant Int Ltd | Oligomere kædeforlængere til behandling, efterbehandling og recirkulering af kondensationspolymerer, syntese, sammensætninger og anvendelser |
| KR100531934B1 (ko) * | 2002-06-25 | 2005-11-28 | 주식회사 삼양사 | 필름용 폴리에스테르계 수지 조성물 및 그 제조방법 |
| US20040147678A1 (en) * | 2003-01-29 | 2004-07-29 | Clariant International, Ltd. | Solid concentrate composition for polymeric chain extension |
| KR100553883B1 (ko) * | 2003-02-26 | 2006-02-24 | 삼성전자주식회사 | 저온 정착 토너 |
| JP2006528991A (ja) * | 2003-05-19 | 2006-12-28 | ポリマーズ オーストラリア プロプライアタリー リミティド | ポリエステルマスターバッチ組成物 |
| US20100234501A1 (en) * | 2006-03-01 | 2010-09-16 | Invista North America S.A.R.L. | Polymer composition with enhanced gas barrier, articles and methods |
| CA2659123C (en) * | 2006-07-28 | 2015-05-26 | Biograde (Hong Kong) Pty Ltd | Biodegradable polymer composition and masterbatch |
| US8080191B2 (en) | 2006-10-20 | 2011-12-20 | Pepsico, Inc. | Extrudable polyethylene terephthalate blend |
| US9095997B2 (en) * | 2007-03-22 | 2015-08-04 | Toyo Seikan Kaisha, Ltd. | Multi-layer polyester container and method of producing the same |
| JP5305610B2 (ja) * | 2007-04-05 | 2013-10-02 | 東洋製罐株式会社 | 耐圧性ポリエステル容器及びその製造方法 |
| FR2919874B1 (fr) * | 2007-08-07 | 2011-02-18 | Setup Performance | Procede de modification des caracteristiques physiques, rheologiques et thermomecaniques d'un polymere thermoplastique polaire |
| FR2919873B1 (fr) * | 2007-08-07 | 2009-11-20 | Setup Performance | Matiere thermoplastique postreticulable apres transformation et articles moules stables a tres haute temperature obtenus apres transformation |
| US8404755B2 (en) | 2008-04-18 | 2013-03-26 | Pepsico, Inc. | Polyester composition and method for preparing articles by extrusion blow molding |
| US8110265B2 (en) * | 2008-12-09 | 2012-02-07 | The Coca-Cola Company | Pet container and compositions having enhanced mechanical properties and gas barrier properties |
| US20100143546A1 (en) * | 2008-12-09 | 2010-06-10 | The Coca-Cola Company | Container and composition for enhanced gas barrier properties |
| TW201100622A (en) * | 2009-06-16 | 2011-01-01 | Nien Made Entpr Co Ltd | Curtain manufacture and its manufacturing method |
| WO2012120148A1 (en) | 2011-03-10 | 2012-09-13 | Nexam Chemical Ab | Compositions for improving polyesters |
| US8623969B2 (en) * | 2011-12-08 | 2014-01-07 | Surfatech Corporation | Terminal silicone capped regiospecific glycerin polyesters |
| WO2015006547A1 (en) * | 2013-07-12 | 2015-01-15 | Polyone Corporation | Polyester compounds having enhanced hydrophobic surface properties |
| CN104497284B (zh) * | 2015-01-17 | 2016-06-01 | 上海青品新材料科技有限公司 | 改性聚酯及其制备方法 |
| TWI608031B (zh) | 2015-11-04 | 2017-12-11 | 財團法人工業技術研究院 | 聚酯及其製造方法 |
| EP3246349A1 (en) | 2017-05-24 | 2017-11-22 | Nexam Chemical AB | Process for increasing the melt strength of a thermoplastic polymer |
| EP3802663A1 (en) * | 2018-06-01 | 2021-04-14 | Elantas Pdg, Inc. | Continous process for producing polyol modified polyalkenylene terephthalate |
| KR102734010B1 (ko) | 2018-11-21 | 2024-11-25 | 삼성전자주식회사 | 액정 고분자, 복합체 조성물, 성형품, 전지 케이스, 및 전지 |
| US11637365B2 (en) | 2019-08-21 | 2023-04-25 | Ticona Llc | Polymer composition for use in an antenna system |
| US11258184B2 (en) | 2019-08-21 | 2022-02-22 | Ticona Llc | Antenna system including a polymer composition having a low dissipation factor |
| US11555113B2 (en) | 2019-09-10 | 2023-01-17 | Ticona Llc | Liquid crystalline polymer composition |
| US12294185B2 (en) | 2019-09-10 | 2025-05-06 | Ticona Llc | Electrical connector formed from a polymer composition having a low dielectric constant and dissipation factor |
| US11912817B2 (en) | 2019-09-10 | 2024-02-27 | Ticona Llc | Polymer composition for laser direct structuring |
| US12209164B2 (en) | 2019-09-10 | 2025-01-28 | Ticona Llc | Polymer composition and film for use in 5G applications |
| US12142820B2 (en) | 2019-09-10 | 2024-11-12 | Ticona Llc | 5G system containing a polymer composition |
| US11646760B2 (en) | 2019-09-23 | 2023-05-09 | Ticona Llc | RF filter for use at 5G frequencies |
| US11917753B2 (en) | 2019-09-23 | 2024-02-27 | Ticona Llc | Circuit board for use at 5G frequencies |
| US11721888B2 (en) | 2019-11-11 | 2023-08-08 | Ticona Llc | Antenna cover including a polymer composition having a low dielectric constant and dissipation factor |
| KR102548758B1 (ko) * | 2020-11-30 | 2023-06-28 | 피아이첨단소재 주식회사 | Lcp 분말을 포함하는 폴리이미드 복합 분말 및 이의 제조방법 |
| CN115975354B (zh) * | 2022-12-28 | 2025-04-29 | 金发科技股份有限公司 | 一种pbt复合材料及其制备方法和应用 |
| CN116496476B (zh) * | 2023-04-28 | 2025-04-25 | 苏州何洛清洁能源科技研究院有限公司 | 高抗蠕变性pet聚酯材料的制备方法 |
| CN119753881B (zh) * | 2024-12-30 | 2025-09-26 | 常熟涤纶有限公司 | 一种具有高效阻燃特性的有色阻燃聚酯纤维及其制备方法 |
| CN121699355A (zh) * | 2026-02-24 | 2026-03-20 | 烟台南山学院 | 一种酯化交联型热塑性弹性体及其制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61124684A (ja) * | 1984-11-16 | 1986-06-12 | 日本合成化学工業株式会社 | 繊維用糊剤 |
| CH678184A5 (OSRAM) | 1989-03-09 | 1991-08-15 | Tisslan S A | |
| WO1993013152A1 (fr) * | 1991-12-20 | 1993-07-08 | Showa Highpolymer Co., Ltd. | Procede d'elaboration d'un polyester aliphatique a forte structure moleculaire et film realise a partir de ce polyester |
| US5229432A (en) | 1992-11-24 | 1993-07-20 | E. I. Du Pont De Nemours And Company | High melt strength pet polymers for foam applications and methods relating thereto |
| JPH07179736A (ja) * | 1993-12-24 | 1995-07-18 | Kanegafuchi Chem Ind Co Ltd | 高溶融粘弾性発現性樹脂組成物およびそれを用いた芳香族ポリエステル系樹脂発泡体の製造法 |
-
1998
- 1998-01-30 ID IDW990789A patent/ID22418A/id unknown
- 1998-01-30 EP EP98901250A patent/EP0956313B1/en not_active Expired - Lifetime
- 1998-01-30 PT PT98901250T patent/PT956313E/pt unknown
- 1998-01-30 DK DK98901250T patent/DK0956313T3/da active
- 1998-01-30 JP JP53238998A patent/JP2001509197A/ja active Pending
- 1998-01-30 IL IL13117098A patent/IL131170A/en not_active IP Right Cessation
- 1998-01-30 NZ NZ336961A patent/NZ336961A/xx not_active IP Right Cessation
- 1998-01-30 CA CA002278800A patent/CA2278800C/en not_active Expired - Fee Related
- 1998-01-30 DE DE69824550T patent/DE69824550T2/de not_active Expired - Fee Related
- 1998-01-30 WO PCT/AU1998/000051 patent/WO1998033837A1/en not_active Ceased
- 1998-01-30 US US09/355,540 patent/US6350822B1/en not_active Expired - Fee Related
- 1998-01-30 ES ES98901250T patent/ES2223117T3/es not_active Expired - Lifetime
- 1998-01-30 AT AT98901250T patent/ATE269370T1/de not_active IP Right Cessation
- 1998-01-30 KR KR1019997006903A patent/KR100567089B1/ko not_active Expired - Fee Related
- 1998-01-30 CN CN98802201A patent/CN1109056C/zh not_active Expired - Fee Related
- 1998-02-03 MY MYPI98000411A patent/MY120019A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102020216002A1 (de) | 2020-12-16 | 2022-06-23 | Robert Bosch Gesellschaft mit beschränkter Haftung | Dichtmaterial zur Abdichtung einer Bipolarplatte |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998033837A1 (en) | 1998-08-06 |
| IL131170A0 (en) | 2001-01-28 |
| ATE269370T1 (de) | 2004-07-15 |
| MY120019A (en) | 2005-08-30 |
| NZ336961A (en) | 2001-02-23 |
| ES2223117T3 (es) | 2005-02-16 |
| PT956313E (pt) | 2004-10-29 |
| CA2278800C (en) | 2007-04-03 |
| CN1246129A (zh) | 2000-03-01 |
| EP0956313A1 (en) | 1999-11-17 |
| IL131170A (en) | 2004-09-27 |
| ID22418A (id) | 1999-10-14 |
| KR20000070654A (ko) | 2000-11-25 |
| CA2278800A1 (en) | 1998-08-06 |
| DK0956313T3 (da) | 2004-08-30 |
| US6350822B1 (en) | 2002-02-26 |
| EP0956313A4 (en) | 2001-05-02 |
| JP2001509197A (ja) | 2001-07-10 |
| KR100567089B1 (ko) | 2006-03-31 |
| EP0956313B1 (en) | 2004-06-16 |
| CN1109056C (zh) | 2003-05-21 |
| DE69824550D1 (de) | 2004-07-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6350822B1 (en) | Modified polyesters | |
| DE69412843T2 (de) | Poylesterzusammensetzungen und verfahren zu ihrer herstellung | |
| EP2350162B1 (de) | Aliphatische polyester | |
| DE69417482T2 (de) | Erhöhter durchsatz beim schäumen und anderen schmelzverfahren von polyester | |
| EP2331603B1 (de) | Aliphatisch-aromatischer polyester | |
| EP2499189B1 (de) | Verfahren zur herstellung von schrumpffolien | |
| DE69430197T2 (de) | Verfahren zur herstellung von bioabbaubaren, verformbaren und modifizierten stärkeprodukten und filmen | |
| DE60317238T2 (de) | Mischungen von polyester und polycarbonat für extrusionsblasverfahren | |
| US11560450B2 (en) | Aliphatic-aromatic polyester having elevated whiteness index | |
| EP0697428B1 (de) | Verfahren zur Herstellung von linearen, w-Hydroxycarbonsäureeinheiten enthaltenden Copolyestern | |
| DE69617545T2 (de) | Polyester mit verbesserten rheologischen Eigenschaften | |
| EP1204700B1 (de) | Biologisch abbaubare schaumstoffpartikel | |
| DE69914939T2 (de) | Erhöhung der schmelzviskosität von polyester | |
| KR20000076394A (ko) | 디블록 폴리에스테르 공중합체 및 그 제조방법 | |
| JP4503215B2 (ja) | 乳酸系樹脂組成物、過酸化物変性乳酸系樹脂組成物、並びに、それらの成形体 | |
| EP3891208B1 (de) | Verfahren zur herstellung eines (co)polyesters | |
| EP4103644B1 (en) | Flame retardant copolyester compositions | |
| DE10000712A1 (de) | Verfahren zur Herstellung eines modifizierten thermoplastischen Polyesterharzes und seiner geschäumten Form | |
| CN102942687A (zh) | 一种阻燃脂肪-芳香族共聚酯及其制备方法 | |
| DE2622858C2 (de) | Polyesterformmasssen | |
| DE69326633T2 (de) | Polyesterharzzusammensetzung | |
| AU730757C (en) | Modified polyesters | |
| US4833217A (en) | Polycarbonate resin composition | |
| KR20230128679A (ko) | 폴리에스테르-락타이드계 블록공중합체를 포함하는 생분해성 고분자 조성물 | |
| US20090152761A1 (en) | Process for preparation of modified poly |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |