DE69701169T2 - Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzung - Google Patents

Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzung

Info

Publication number
DE69701169T2
DE69701169T2 DE69701169T DE69701169T DE69701169T2 DE 69701169 T2 DE69701169 T2 DE 69701169T2 DE 69701169 T DE69701169 T DE 69701169T DE 69701169 T DE69701169 T DE 69701169T DE 69701169 T2 DE69701169 T2 DE 69701169T2
Authority
DE
Germany
Prior art keywords
hydrogenation
conjugated diene
catalyst composition
diene polymers
composition usable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69701169T
Other languages
English (en)
Other versions
DE69701169D1 (de
Inventor
Boer Eric Johannes Maria De
Bart Hessen
Der Huizen Adriaan Albert Van
Jong Wouter De
Der Linden Adrianus Johann Van
Bart Johan Ruisch
Lodewijk Schoon
Smet Heleen Johanna Augusta De
Der Steen Frederik Hendrik Van
Strien Hubertus Cornelis T Van
Alan Villena
Judith Johanna Berendin Walhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of DE69701169D1 publication Critical patent/DE69701169D1/de
Publication of DE69701169T2 publication Critical patent/DE69701169T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0245—Nitrogen containing compounds being derivatives of carboxylic or carbonic acids
    • B01J31/0247—Imides, amides or imidates (R-C=NR(OR))
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0225—Complexes comprising pentahapto-cyclopentadienyl analogues
    • B01J2531/023—Phospholyl ligands, i.e. [CnP(5-n)Rn]- in which n is 0-4 and R is H or hydrocarbyl, or analogous condensed ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69701169T 1996-05-29 1997-05-28 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzung Expired - Fee Related DE69701169T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96303815 1996-05-29

Publications (2)

Publication Number Publication Date
DE69701169D1 DE69701169D1 (de) 2000-02-24
DE69701169T2 true DE69701169T2 (de) 2000-07-13

Family

ID=8224956

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69701169T Expired - Fee Related DE69701169T2 (de) 1996-05-29 1997-05-28 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzung

Country Status (6)

Country Link
US (1) US5886107A (de)
EP (1) EP0810231B1 (de)
JP (1) JPH1053614A (de)
DE (1) DE69701169T2 (de)
ES (1) ES2140944T3 (de)
TW (1) TW422849B (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
JP3777810B2 (ja) 1998-07-24 2006-05-24 Ｊｓｒ株式会社 オレフイン性不飽和化合物の水素添加触媒および水素添加方法
KR100267080B1 (ko) 1998-08-03 2000-10-02 박찬구 공액디엔 중합체의 수소화 방법
KR100287961B1 (ko) * 1998-09-30 2001-05-02 박찬구 공역디엔을 포함하는 고분자의 수소첨가 방법
TW583027B (en) 1998-10-30 2004-04-11 Shell Int Research A method for preparing a hydrogenation catalyst system
KR100295601B1 (ko) * 1999-01-18 2001-07-03 박찬구 공액디엔 중합체의 수소화 방법
US6313230B1 (en) * 1999-09-21 2001-11-06 Industrial Technology Research Institute Catalyst composition for hydrogenation of conjugated diene based synthetic rubbers
KR100348761B1 (ko) * 1999-11-26 2002-08-13 금호석유화학 주식회사 공액디엔을 포함하는 중합체의 선택적 수소화 방법
KR100356533B1 (ko) * 2000-02-09 2002-10-18 금호석유화학 주식회사 공액디엔 중합체의 선택적 수소화 방법
AU2002233185A1 (en) 2000-07-28 2002-05-06 Kraton Polymers Research B.V. Process for preparing partially hydrogenated butadiene polymers
CN1239626C (zh) 2000-12-01 2006-02-01 克拉通聚合物研究有限公司 具有降低胶凝倾向的沥青组合物
US7166679B2 (en) * 2003-09-24 2007-01-23 Kraton Polymers Llc Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same
KR101550120B1 (ko) 2011-02-18 2015-09-03 크레이튼 폴리머즈 유.에스. 엘엘씨 케이블 충전용 경화성 중합체 조성물
CN113368903A (zh) * 2021-07-09 2021-09-10 浙江众立合成材料科技股份有限公司 一种用于制备氢化聚合物的三组分复合催化剂

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE737574A (de) * 1968-09-05 1970-02-02
US4501857A (en) * 1983-01-20 1985-02-26 Asahi Kasei Kogyo Kabushiki Kaisha Method for hydrogenation of polymer
JPS60220147A (ja) * 1984-04-18 1985-11-02 Asahi Chem Ind Co Ltd オレフイン水添触媒および該触媒を用いた重合体の水添方法
JP2969771B2 (ja) * 1989-12-22 1999-11-02 ジェイエスアール株式会社 オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物
US5039755A (en) * 1990-05-29 1991-08-13 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5206307A (en) * 1991-09-09 1993-04-27 Shell Oil Company Process for selective hydrogenation of conjugated diolefin polymers
US5270274A (en) * 1991-11-28 1993-12-14 Japan Synthetic Rubber Co., Ltd. Catalyst composition for hydrogenating olefinically unsaturated polymers
ES2053363B1 (es) * 1991-12-05 1995-02-16 Repsol Quimica Sa Procedimiento de hidrogenacion de olefinas.
US5173537A (en) * 1991-12-20 1992-12-22 Shell Oil Company Selective hydrogenation of conjugated diolefin poylmers
WO1995025136A1 (en) * 1992-03-05 1995-09-21 Exxon Research And Engineering Co. Sulfonated unhydrogenated copolymers of styrene and butadiene
US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
US5242986A (en) * 1992-08-10 1993-09-07 Shell Oil Company Selective partial hydrogenation of conjugated diolefin polymers
ES2050620B1 (es) * 1992-11-03 1994-12-16 Repsol Quimica Sa Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido.
BE1007262A3 (nl) * 1993-07-09 1995-05-02 Dsm Nv Katalysatorsamenstelling en werkwijze voor de polymerisatie van een olefine.
EP0638593A1 (de) * 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Katalysatorzusammensetzungen
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes

Also Published As

Publication number Publication date
EP0810231B1 (de) 2000-01-19
ES2140944T3 (es) 2000-03-01
EP0810231A1 (de) 1997-12-03
TW422849B (en) 2001-02-21
DE69701169D1 (de) 2000-02-24
US5886107A (en) 1999-03-23
JPH1053614A (ja) 1998-02-24

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