DE69620871T2 - Geträgerter katalysatoraktivator - Google Patents

Geträgerter katalysatoraktivator

Info

Publication number
DE69620871T2
DE69620871T2 DE69620871T DE69620871T DE69620871T2 DE 69620871 T2 DE69620871 T2 DE 69620871T2 DE 69620871 T DE69620871 T DE 69620871T DE 69620871 T DE69620871 T DE 69620871T DE 69620871 T2 DE69620871 T2 DE 69620871T2
Authority
DE
Germany
Prior art keywords
supported catalyst
catalyst activator
activator
supported
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69620871T
Other languages
English (en)
Other versions
DE69620871D1 (de
Inventor
George Ward
Malott Carnahan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
WR Grace and Co
Original Assignee
WR Grace and Co Conn
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co Conn, WR Grace and Co filed Critical WR Grace and Co Conn
Publication of DE69620871D1 publication Critical patent/DE69620871D1/de
Application granted granted Critical
Publication of DE69620871T2 publication Critical patent/DE69620871T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69620871T 1995-01-25 1996-01-02 Geträgerter katalysatoraktivator Expired - Lifetime DE69620871T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US37820295A 1995-01-25 1995-01-25
US08/544,051 US5939347A (en) 1995-01-25 1995-10-17 Supported catalytic activator
PCT/US1996/000644 WO1996023005A1 (en) 1995-01-25 1996-01-02 A supported catalytic activator

Publications (2)

Publication Number Publication Date
DE69620871D1 DE69620871D1 (de) 2002-05-29
DE69620871T2 true DE69620871T2 (de) 2002-12-12

Family

ID=27008110

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69620871T Expired - Lifetime DE69620871T2 (de) 1995-01-25 1996-01-02 Geträgerter katalysatoraktivator

Country Status (5)

Country Link
US (1) US5939347A (de)
EP (1) EP0805824B1 (de)
AU (1) AU4701796A (de)
DE (1) DE69620871T2 (de)
WO (1) WO1996023005A1 (de)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
US7153909B2 (en) 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
CZ162698A3 (cs) * 1995-11-27 1998-08-12 The Dow Chemical Company Nosičový materiál, nanesený katalyzátor obsahující volně poutaný aktivátor tvořící kation a způsob adiční polymerace za použití tohoto katalyzátoru
ATE234870T1 (de) * 1996-03-27 2003-04-15 Dow Global Technologies Inc Lösungspolymerisationsverfahren mit dispergierten katalysator-aktivierer
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
EP0824113B2 (de) * 1996-08-13 2012-06-27 Basell Polyolefine GmbH Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE59712644D1 (de) 1996-08-13 2006-06-14 Basell Polyolefine Gmbh Geträgerte chemische Verbindung
US6262200B1 (en) * 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) * 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
WO1998028342A1 (fr) * 1996-12-20 1998-07-02 Sumitomo Chemical Company, Limited Polymere d'olefine, pellicules ou feuilles de ce materiau, et procede de fabrication dudit polymere
EP0931099A1 (de) * 1997-03-07 1999-07-28 Basell Polyolefine GmbH Verfahren zur herstellung von olefinpolymerisaten mit erhöhtem schmelzpunkt
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6426313B2 (en) * 1997-06-05 2002-07-30 Exxon Mobil Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
FR2769245B1 (fr) 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
DE19757540A1 (de) * 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
ES2216586T3 (es) 1998-06-12 2004-10-16 Univation Technologies Llc Procedimiento de polimerizacion de olefinas que usa complejos activados de acido-base de lewis.
ATE355308T1 (de) 1998-07-16 2006-03-15 Univation Tech Llc Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
KR100592621B1 (ko) 1998-08-26 2006-06-23 엑손모빌 케미칼 패턴츠 인코포레이티드 고활성의 지지된 촉매 조성물
WO2000015671A1 (en) * 1998-09-16 2000-03-23 The Dow Chemical Company Slurry polymerization process and polymer compositions
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
US6239060B1 (en) * 1998-12-31 2001-05-29 Phillips Petroleum Company Supported metallocene catalyst system and method for polymerizing olefins
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
DE19917985A1 (de) * 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
ATE366757T1 (de) * 1999-07-15 2007-08-15 Dow Global Technologies Inc Polyethylen mit hoher dichte und mischungen davon
US6475946B1 (en) * 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
EP1237957B1 (de) * 1999-11-19 2006-08-23 ExxonMobil Chemical Patents Inc. Vorbereitung eines geträgerten katalysatorsystems zur polymerisation von olefinen
US6395847B2 (en) * 1999-11-19 2002-05-28 Exxonmobil Chemical Patents Inc. Supported organometallic catalysts and their use in olefin polymerization
US6822057B2 (en) * 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
MXPA02006197A (es) * 1999-12-20 2002-12-09 Exxon Chemical Patents Inc Procesos para la preparacion de resinas de poliolefinas usando catalizadores ionicos soportados.
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
SG83828A1 (en) * 1999-12-27 2001-10-16 Sumitomo Chemical Co Catalyst for addition polymerization, and process for producing addition polymer with the same
US6495484B1 (en) * 2000-08-28 2002-12-17 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US20050176578A1 (en) * 2000-09-26 2005-08-11 Neithamer David R. Supported catalyst systems
US6632770B2 (en) 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
JP2005538245A (ja) 2002-07-15 2005-12-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 担体を有する触媒組成物の製造方法
AU2003253004A1 (en) * 2002-08-20 2004-03-11 Bp Chemicals Limited Supported polymerisation catalysts
US20050209096A1 (en) * 2002-08-20 2005-09-22 Jacobsen Grant B Supported polymerisation catalysts
CA2405241C (en) * 2002-09-24 2011-07-26 Nova Chemicals Corporation Olefin polymerization catalyst system
CN100528914C (zh) 2003-12-23 2009-08-19 巴塞尔聚烯烃股份有限公司 负载型助催化剂的制备
US7217676B2 (en) * 2004-01-16 2007-05-15 Exxon Mobil Chemical Patents Inc. Hydrophobization and silica for supported catalyst
US7847038B2 (en) * 2007-07-13 2010-12-07 Exxonmobil Chemical Patents Inc. Preparation of supported silyl-capped silica-bound anion activators and associated catalysts

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
WO1991009882A1 (en) * 1990-01-02 1991-07-11 Exxon Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
US5079205A (en) * 1990-07-13 1992-01-07 Exxon Chemical Patents Inc. Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization
ES2085000T3 (es) * 1990-12-27 1996-05-16 Exxon Chemical Patents Inc Un compuesto de amido-metal de transicion y un sistema catalitico para la produccion de polipropileno isotactico.
CA2124187C (en) * 1991-11-25 2001-08-07 Howard William Turner Polyonic transition metal catalyst composition
DE69331112T2 (de) * 1992-08-05 2002-06-20 Exxonmobil Chem Patents Inc Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation
ES2148204T3 (es) * 1992-09-04 2000-10-16 Bp Chem Int Ltd Composiciones cataliticas y procedimiento para la preparacion de poliolefinas.
US5276199A (en) * 1993-02-11 1994-01-04 Ethyl Corporation Process for preparing cyclopentenones
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
DE69523764T2 (de) * 1994-08-03 2002-08-01 Exxonmobil Chem Patents Inc Ionische katalysatorzusammensetzung auf träger
ES2188751T3 (es) * 1995-03-10 2003-07-01 Dow Global Technologies Inc Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion.

Also Published As

Publication number Publication date
EP0805824B1 (de) 2002-04-24
WO1996023005A1 (en) 1996-08-01
DE69620871D1 (de) 2002-05-29
EP0805824A1 (de) 1997-11-12
US5939347A (en) 1999-08-17
AU4701796A (en) 1996-08-14

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Legal Events

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