DE69611420T2 - Hochfeste poröse Folie und Herstellungsverfahren - Google Patents

Hochfeste poröse Folie und Herstellungsverfahren

Info

Publication number
DE69611420T2
DE69611420T2 DE69611420T DE69611420T DE69611420T2 DE 69611420 T2 DE69611420 T2 DE 69611420T2 DE 69611420 T DE69611420 T DE 69611420T DE 69611420 T DE69611420 T DE 69611420T DE 69611420 T2 DE69611420 T2 DE 69611420T2
Authority
DE
Germany
Prior art keywords
manufacturing process
high strength
porous film
strength porous
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69611420T
Other languages
English (en)
Other versions
DE69611420D1 (de
Inventor
Toshio Fujii
Tatsuya Mochizuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Publication of DE69611420D1 publication Critical patent/DE69611420D1/de
Application granted granted Critical
Publication of DE69611420T2 publication Critical patent/DE69611420T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/26—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/26—Polyalkenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/26—Polyalkenes
    • B01D71/261—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05—Filamentary, e.g. strands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
    • B29C48/83—Heating or cooling the cylinders
    • B29C48/832—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/86—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the nozzle zone
    • B29C48/865—Heating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/417—Polyolefins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/491—Porosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/046—Elimination of a polymeric phase
    • C08J2201/0462—Elimination of a polymeric phase using organic solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/054—Precipitating the polymer by adding a non-solvent or a different solvent
    • C08J2201/0542—Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition
    • C08J2201/0543—Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition the non-solvent being organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/054—Precipitating the polymer by adding a non-solvent or a different solvent
    • C08J2201/0545—Precipitating the polymer by adding a non-solvent or a different solvent from an aqueous solvent-based polymer composition
    • C08J2201/0546—Precipitating the polymer by adding a non-solvent or a different solvent from an aqueous solvent-based polymer composition the non-solvent being organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249978—Voids specified as micro
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/261—In terms of molecular thickness or light wave length
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Cell Separators (AREA)
DE69611420T 1995-10-05 1996-10-02 Hochfeste poröse Folie und Herstellungsverfahren Expired - Lifetime DE69611420T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25861295 1995-10-05

Publications (2)

Publication Number Publication Date
DE69611420D1 DE69611420D1 (de) 2001-02-08
DE69611420T2 true DE69611420T2 (de) 2001-06-07

Family

ID=17322698

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69611420T Expired - Lifetime DE69611420T2 (de) 1995-10-05 1996-10-02 Hochfeste poröse Folie und Herstellungsverfahren

Country Status (3)

Country Link
US (1) US5759678A (de)
EP (1) EP0767200B1 (de)
DE (1) DE69611420T2 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69626194T2 (de) * 1995-03-03 2003-11-27 Asahi Chemical Ind Mikroporöser polyethylenfilm und verfahren zu dessen herstellung
JPH107832A (ja) * 1996-04-26 1998-01-13 Mitsui Petrochem Ind Ltd 高強度ポリプロピレン多孔フィルム及びその製造方法
US6096213A (en) * 1998-08-14 2000-08-01 3M Innovative Properties Company Puncture-resistant polyolefin membranes
DE60035656T3 (de) * 1999-02-19 2013-12-12 Toray Battery Separator Film Co., Ltd. Mikroporöse Polyolefinfolie und Verfahren zu deren Herstellung
US6602593B1 (en) * 1999-08-30 2003-08-05 Celgard Inc. Battery separators with reduced splitting propensity
JP4152049B2 (ja) * 1999-12-22 2008-09-17 花王株式会社 粒子堆積体の製造方法
KR100917838B1 (ko) * 2001-03-03 2009-09-18 다이오세이시가부시끼가이샤 일회용 기저귀
US6692867B2 (en) * 2001-10-12 2004-02-17 Celgard Inc. Battery separator-pin removal
JP4833486B2 (ja) * 2002-05-28 2011-12-07 住友化学株式会社 ミクロフィルター用濾材の製造方法およびミクロフィルター用濾材
DE102004001324A1 (de) * 2003-07-25 2005-02-10 Degussa Ag Pulverförmige Komposition von Polymer und ammoniumpolyphosphathaltigem Flammschutzmittel, Verfahren zu dessen Herstellung und Formkörper, hergestellt aus diesem Pulver
WO2005113657A1 (ja) * 2004-05-20 2005-12-01 Asahi Kasei Chemicals Corporation ポリオレフィン製微多孔膜
US7332531B2 (en) * 2004-06-11 2008-02-19 Sk Corporation Microporous high density polyethylene film
KR100683845B1 (ko) 2004-06-11 2007-02-15 에스케이 주식회사 고밀도폴리에틸렌 미세다공막 및 그 제조방법
US7435761B2 (en) * 2004-07-06 2008-10-14 Sk Energy Co., Ltd. Microporous polyethylene film and method of producing the same
US20060008636A1 (en) * 2004-07-06 2006-01-12 Lee Young K Microporous polyethylene film and method of producing the same
KR100943697B1 (ko) * 2005-04-06 2010-02-23 에스케이에너지 주식회사 물성, 생산성 및 품질 균일도가 우수한 폴리에틸렌 미세다공막 및 그 제조방법
KR101288803B1 (ko) 2007-09-12 2013-07-23 에스케이이노베이션 주식회사 고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막
DE102012203755A1 (de) * 2012-03-09 2013-09-12 Evonik Litarion Gmbh Perforierte Polymerfolien mit verbesserter Toleranz gegen Zugspannung
CN104262674B (zh) * 2014-08-26 2018-02-13 东莞新能源科技有限公司 多孔复合隔离膜的制备方法

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US4237083A (en) * 1979-02-13 1980-12-02 Evans Products Company Process of manufacturing a microporous sheet material
JPS56159128A (en) * 1980-05-15 1981-12-08 Asahi Chem Ind Co Ltd Thermoplastic resin porous film and production thereof
JPS5859072A (ja) * 1981-10-05 1983-04-07 Asahi Chem Ind Co Ltd 熱可塑性樹脂多孔膜の製造方法
JPS59227420A (ja) * 1983-06-10 1984-12-20 Mitsui Petrochem Ind Ltd 超高分子量ポリオレフイン二軸延伸フイルム及びその製造方法
JPS60242035A (ja) * 1984-04-27 1985-12-02 Toa Nenryo Kogyo Kk ポリエチレン微多孔膜の製造方法
US4828772A (en) * 1984-10-09 1989-05-09 Millipore Corporation Microporous membranes of ultrahigh molecular weight polyethylene
US4778601A (en) * 1984-10-09 1988-10-18 Millipore Corporation Microporous membranes of ultrahigh molecular weight polyethylene
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JPH0655433B2 (ja) * 1985-08-12 1994-07-27 三井石油化学工業株式会社 インフレ−シヨンフイルム、その製法と装置
JPH0790153B2 (ja) * 1986-04-28 1995-10-04 三菱化学株式会社 ポリオレフイン製透過膜及びその製造方法
US4833172A (en) * 1987-04-24 1989-05-23 Ppg Industries, Inc. Stretched microporous material
JPS63273651A (ja) * 1987-04-30 1988-11-10 Toa Nenryo Kogyo Kk 超高分子量ポリエチレン微多孔膜の製造方法
JP2580270B2 (ja) * 1988-07-20 1997-02-12 三井石油化学工業株式会社 超高分子量ポリエチレン二軸延伸フィルムおよびその製造方法
JP2794179B2 (ja) * 1988-09-30 1998-09-03 旭化成工業株式会社 ポリエチレン微多孔膜及びリチウム電池セパレーター
JPH02251545A (ja) * 1988-12-23 1990-10-09 Nitto Denko Corp 超高分子量ポリエチレン多孔質フィルムおよびその製造法
JP2520310B2 (ja) * 1989-09-19 1996-07-31 東燃株式会社 リチウム電池用セパレ―タの製造方法
JPH059332A (ja) * 1991-07-05 1993-01-19 Asahi Chem Ind Co Ltd 均質な超高分子量ポリエチレン製微多孔膜及びその製造方法
EP0547237B1 (de) * 1991-07-05 1996-06-12 Asahi Kasei Kogyo Kabushiki Kaisha Seperator einer Batterie in der ein organischer Elektrolyt benutzt wird und dessen Herstellung
JPH05117440A (ja) * 1991-10-31 1993-05-14 Mitsubishi Kasei Corp 多孔化ポリオレフインフイルムの製造方法
US5240655A (en) * 1991-12-20 1993-08-31 W. R. Grace & Co.-Conn. Process of making a battery separator
JPH05310989A (ja) * 1992-04-30 1993-11-22 Mitsubishi Kasei Corp ポリエチレン多孔膜
DE69320927T2 (de) * 1992-12-21 1999-02-18 Mitsubishi Chem Corp Poröse(r) Film oder Folie, Batterie-Separator und Lithium-Batterie
JP3252016B2 (ja) * 1993-05-28 2002-01-28 旭化成株式会社 ポリオレフィン微孔性多孔膜の製造方法
JPH0785907B2 (ja) * 1993-06-28 1995-09-20 三井石油化学工業株式会社 超高分子量ポリオレフィン二軸延伸フィルム及びその製造方法
JPH07228718A (ja) * 1994-02-16 1995-08-29 Tonen Chem Corp ポリオレフィン微多孔膜

Also Published As

Publication number Publication date
EP0767200A3 (de) 1998-01-07
DE69611420D1 (de) 2001-02-08
EP0767200A2 (de) 1997-04-09
US5759678A (en) 1998-06-02
EP0767200B1 (de) 2001-01-03

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