DE69514384T2 - Verfahren zur hemmung frühzeitiger polymerisierung von vinyl-aromatischen monomeren - Google Patents
Verfahren zur hemmung frühzeitiger polymerisierung von vinyl-aromatischen monomerenInfo
- Publication number
- DE69514384T2 DE69514384T2 DE69514384T DE69514384T DE69514384T2 DE 69514384 T2 DE69514384 T2 DE 69514384T2 DE 69514384 T DE69514384 T DE 69514384T DE 69514384 T DE69514384 T DE 69514384T DE 69514384 T2 DE69514384 T2 DE 69514384T2
- Authority
- DE
- Germany
- Prior art keywords
- vinyl aromatic
- aromatic monomers
- early polymerization
- inhibiting early
- inhibiting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/04—Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Polymerisation Methods In General (AREA)
- Hydrogenated Pyridines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34509794A | 1994-11-28 | 1994-11-28 | |
US08383279 US5545786C1 (en) | 1994-11-28 | 1995-02-03 | Method for inhibiting premature polymerization of vinyl aromatic monomers |
PCT/EP1995/004501 WO1996016921A1 (en) | 1994-11-28 | 1995-11-16 | A method for inhibiting premature polymerization of vinyl aromatic monomers |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69514384D1 DE69514384D1 (de) | 2000-02-10 |
DE69514384T2 true DE69514384T2 (de) | 2000-08-10 |
Family
ID=26994252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69514384T Revoked DE69514384T2 (de) | 1994-11-28 | 1995-11-16 | Verfahren zur hemmung frühzeitiger polymerisierung von vinyl-aromatischen monomeren |
Country Status (10)
Country | Link |
---|---|
US (2) | US5545786C1 (de) |
EP (2) | EP0959059A3 (de) |
JP (1) | JP2818977B2 (de) |
KR (1) | KR100248534B1 (de) |
CN (1) | CN1046493C (de) |
AU (1) | AU4172396A (de) |
BR (1) | BR9509777A (de) |
CA (1) | CA2203397C (de) |
DE (1) | DE69514384T2 (de) |
WO (1) | WO1996016921A1 (de) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6409887B1 (en) | 1996-07-15 | 2002-06-25 | Aah Marks And Company Limited | Polymerization inhibitor |
WO1998014416A1 (en) * | 1996-10-04 | 1998-04-09 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
DE69710163T2 (de) * | 1996-12-02 | 2002-10-02 | Ondeo Nalco Energy Serv Lp | Hemmung der Polymerisation von vinylaromatischen Monomeren |
DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
ID20069A (id) * | 1997-03-20 | 1998-09-24 | Ciba Sc Holding Ag | Proses inhibitor polimerisasi |
US5928558A (en) * | 1997-06-13 | 1999-07-27 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
DE19725519A1 (de) | 1997-06-17 | 1998-12-24 | Basf Ag | Stoffmischung, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US6024894A (en) * | 1998-03-25 | 2000-02-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
US5907071A (en) * | 1998-04-21 | 1999-05-25 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
US5910232A (en) * | 1998-06-10 | 1999-06-08 | Nalco/Exxon Energy Chemicals, L.P. | Method for inhibiting polymer formation in styrene processing |
WO2000003965A1 (en) | 1998-07-14 | 2000-01-27 | Ciba Specialty Chemicals Holding Inc. | Derivatives of 1-oxyl-4-hydroxy- or 4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
CA2342945A1 (en) * | 1998-09-09 | 2000-03-16 | Muslim Shahid | Styrene monomer polymerization inhibition using substituted dihydroxyarenes and nitroxides |
WO2000036052A1 (en) * | 1998-12-17 | 2000-06-22 | Nalco/Exxon Energy Chemicals, L.P. | Inhibiting polymerization of vinyl aromatic monomers using synergistic mixtures containing nitroxide stabilizers |
US20040019247A1 (en) * | 1999-02-26 | 2004-01-29 | Basf Aktiengesellschaft | Continuous recovery of styrene from a styrene-containing mixture |
DE19926758A1 (de) * | 1999-06-11 | 2000-12-14 | Basf Ag | Verfahren zur Verhinderung unerwünschter Polymerisation in einem ethylenisch ungesättigte Verbindungen enthaltenden Stoffgemisch |
US6300533B1 (en) | 1999-08-16 | 2001-10-09 | Uniroyal Chemical Company, Inc. | Inhibition of polymerization of ethylenically unsaturated monomers |
FR2801306B1 (fr) * | 1999-11-24 | 2001-12-28 | Atofina | Procede de purification des monomeres (meth) acryliques par distillation |
CA2392055C (en) | 1999-12-02 | 2010-06-22 | Crompton Corporation | Inhibition of polymerization of unsaturated monomers |
AR029410A1 (es) | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
MXPA02005502A (es) * | 1999-12-03 | 2002-09-02 | Uniroyal Chem Co Inc | Composicion y metodo para inhibir polimerizacion y crecimiento de polimero. |
US20050192384A1 (en) * | 1999-12-09 | 2005-09-01 | Tunja Jung | Additive composition for increasing the storage stability of ethylenically unsaturated resins |
US20110071232A1 (en) * | 1999-12-09 | 2011-03-24 | Tunja Jung | Additive composition for increasing the storage stability of ethylenically unsaturated resins |
US6403850B1 (en) | 2000-01-18 | 2002-06-11 | Uniroyal Chemical Company, Inc. | Inhibition of polymerization of unsaturated monomers |
US6344560B1 (en) | 2000-05-03 | 2002-02-05 | Uniroyal Chemical Company, Inc. | Nitroaromatic solubilizer for nitroxyls in aromatic solvents |
US6376728B1 (en) | 2000-06-20 | 2002-04-23 | Hercules Incorporated | Method, composition and mixture for inhibiting monomer polymerization |
ATE356105T1 (de) * | 2000-08-02 | 2007-03-15 | Uniroyal Chem Co Inc | Wiedergewinnung von nitroxyl-enthaltenden strömen bei niedriger temperatur |
CA2422655A1 (en) | 2000-10-16 | 2002-04-25 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors |
US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
DE60335783D1 (en) * | 2002-02-15 | 2011-03-03 | Chemtura Corp | Nitrosophenole und c-nitrosoaniline als polymerisationsinhibitoren |
US7691952B2 (en) * | 2004-09-28 | 2010-04-06 | Chemtura Corporation | Sulfonated nitrophenols as polymerization inhibitors |
US20060069219A1 (en) * | 2004-09-28 | 2006-03-30 | Vilan Kosover | Sulfonated phenols with nitrophenols as polymerization inhibitors |
US7696290B2 (en) * | 2004-12-03 | 2010-04-13 | Crompton Corporation | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors |
CN101115699B (zh) | 2005-02-04 | 2011-09-14 | 科聚亚公司 | 控制苯乙烯类单体与磺酸的放热反应的手段 |
US7553896B2 (en) * | 2005-06-17 | 2009-06-30 | Chemtura Corporation | Ortho-nitrosophenols as polymerization inhibitors |
CN101351449A (zh) | 2005-12-27 | 2009-01-21 | 株式会社Adeka | 硝酰基化合物以及使用其的聚合抑制剂和聚合抑制剂组合物 |
JP5105762B2 (ja) * | 2006-04-12 | 2012-12-26 | 日本合成化学工業株式会社 | カルボン酸ビニルの重合抑制方法 |
DE102007023515A1 (de) * | 2006-07-05 | 2008-01-10 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Dienen durch Hydrodimerisierung |
US7968001B2 (en) | 2007-12-19 | 2011-06-28 | Air Products And Chemicals, Inc. | Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor |
EP2072485B1 (de) * | 2007-12-19 | 2012-06-20 | Air Products and Chemicals, Inc. | Stabilisierungsmittel zur Stabilisierung einer ungesättigten, auf Kohlenwasserstoff basierenden Vorläuferverbindung |
US8440099B2 (en) | 2007-12-19 | 2013-05-14 | Air Products And Chemicals, Inc. | Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor |
EP2292688B1 (de) | 2008-06-09 | 2016-05-11 | Adeka Corporation | Verfahren zur verfestigung von phosphorsäureester-flammschutzmitteln |
WO2012082482A1 (en) * | 2010-12-17 | 2012-06-21 | Dow Global Technologies Llc | Process for preparing divinylarene oxides |
CN103946186B (zh) * | 2011-11-29 | 2016-12-28 | 多尔夫凯塔尔化学制品(I)私人有限公司 | 用于控制及抑制苯乙烯的聚合的基于胺的添加剂组合物及其使用方法 |
KR101728269B1 (ko) * | 2013-03-15 | 2017-04-18 | 보오슈 앤드 롬 인코포레이팃드 | 중합을 지연시키는 방법 및 장치 |
JP6176420B2 (ja) * | 2015-07-01 | 2017-08-09 | Dic株式会社 | 安定剤化合物、液晶組成物および表示素子 |
WO2018165382A1 (en) * | 2017-03-09 | 2018-09-13 | Ecolab USA, Inc. | Polymerization inhibitor compositions |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3163677A (en) * | 1961-08-07 | 1964-12-29 | American Cyanamid Co | Process for preparing n, n, o-trisubstituted hydroxyl amines and n, n-disubstituted nitroxides and products |
GB983134A (en) * | 1962-06-13 | 1965-02-10 | American Cyanamid Co | Cyclic nitroxides and process for preparing same |
GB1218456A (en) * | 1968-09-06 | 1971-01-06 | Bp Chem Int Ltd | Process for the stabilisation of butadiene |
US3733326A (en) * | 1971-03-10 | 1973-05-15 | Sankyo Co | Inhibition of the polymerization of vinyl monomers |
US3988212A (en) * | 1975-03-21 | 1976-10-26 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
SU1027150A1 (ru) * | 1981-10-21 | 1983-07-07 | Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского | Способ стабилизации стирола или метилметакрилата |
US4466904A (en) * | 1983-01-10 | 1984-08-21 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
US4468343A (en) * | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
SU1139722A1 (ru) * | 1983-04-12 | 1985-02-15 | Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" | Способ ингибировани полимеризации стирола |
SU1558888A1 (ru) * | 1987-12-11 | 1990-04-23 | Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ | Способ ингибировани полимеризации стирола |
JPH01165534A (ja) * | 1987-12-22 | 1989-06-29 | Mitsubishi Petrochem Co Ltd | スチレン類の重合防止剤 |
US5254760A (en) * | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
US5488192A (en) * | 1993-07-23 | 1996-01-30 | Kourbatov | Method for inhibiting the polymerization of styrene |
-
1995
- 1995-02-03 US US08383279 patent/US5545786C1/en not_active Expired - Fee Related
- 1995-05-17 US US08443051 patent/US5545782C1/en not_active Expired - Fee Related
- 1995-11-16 JP JP8518128A patent/JP2818977B2/ja not_active Expired - Fee Related
- 1995-11-16 CA CA002203397A patent/CA2203397C/en not_active Expired - Fee Related
- 1995-11-16 WO PCT/EP1995/004501 patent/WO1996016921A1/en not_active Application Discontinuation
- 1995-11-16 KR KR1019970703616A patent/KR100248534B1/ko not_active IP Right Cessation
- 1995-11-16 EP EP99112035A patent/EP0959059A3/de not_active Withdrawn
- 1995-11-16 DE DE69514384T patent/DE69514384T2/de not_active Revoked
- 1995-11-16 BR BR9509777A patent/BR9509777A/pt not_active Application Discontinuation
- 1995-11-16 EP EP95940182A patent/EP0794933B1/de not_active Revoked
- 1995-11-16 AU AU41723/96A patent/AU4172396A/en not_active Abandoned
- 1995-11-16 CN CN95196481A patent/CN1046493C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AU4172396A (en) | 1996-06-19 |
CA2203397C (en) | 2002-01-22 |
MX9703906A (es) | 1998-05-31 |
EP0959059A2 (de) | 1999-11-24 |
DE69514384D1 (de) | 2000-02-10 |
BR9509777A (pt) | 1997-09-30 |
US5545786C1 (en) | 2001-10-16 |
EP0794933A1 (de) | 1997-09-17 |
KR100248534B1 (ko) | 2000-03-15 |
US5545782A (en) | 1996-08-13 |
CN1166820A (zh) | 1997-12-03 |
EP0794933B1 (de) | 2000-01-05 |
CA2203397A1 (en) | 1996-06-06 |
US5545786A (en) | 1996-08-13 |
JP2818977B2 (ja) | 1998-10-30 |
EP0959059A3 (de) | 1999-12-01 |
CN1046493C (zh) | 1999-11-17 |
WO1996016921A1 (en) | 1996-06-06 |
JPH10504317A (ja) | 1998-04-28 |
US5545782C1 (en) | 2001-05-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69514384T2 (de) | Verfahren zur hemmung frühzeitiger polymerisierung von vinyl-aromatischen monomeren | |
DE59707512D1 (de) | Verfahren zur anionischen polymerisation | |
DE69701997T2 (de) | Verfahren zur bromierung von styrolpolymeren | |
DE69937681D1 (de) | Verfahren zur radikalischen polymerisation | |
DE69808622D1 (de) | Verfahren zur herstellung von blockcopolymeren durch kontrollierte radikalische polymerisation | |
ATE230767T1 (de) | Verfahren zur olefinpolymerisation | |
DE69423653D1 (de) | Verfahren zur radikalischen polymerisation | |
DE69907459D1 (de) | Verbessertes verfahren zur polymerisation von epoxiden | |
DE69416589D1 (de) | Verfahren zur herstellung von copolymeren aromatischer vinylverbindungen | |
DE69705526D1 (de) | Verfahren zur polymerisation von monomeren mit olefingruppe | |
DE69515241D1 (de) | Verfahren zur Emulsions-Polymerisation | |
DE59908107D1 (de) | Verfahren zur retardierten anionischen polymerisation | |
DE69707055D1 (de) | Verfahren zur Herstellung von Malonat enthaltenden Acrylatmonomeren | |
DE59905188D1 (de) | Verfahren zur retardierten anionischen polymerisation | |
DE69624494D1 (de) | Verfahren zur polymerisation von tetrafluorethylen | |
DE69717478T2 (de) | Verfahren zur polymerisierung von fluorierten olefinmonomeren | |
DE69601092D1 (de) | Verfahren zur Herstellung von Isopren-enthaltenden Block-Copolymeren | |
ATE234328T1 (de) | Verfahren zum starten der polymerisation | |
ATE257847T1 (de) | Verfahren zum starten der polymerisation | |
DE59701956D1 (de) | Verfahren zur polymerisation vinylischer monomere | |
DE69525614D1 (de) | Verfahren zur kontrolle des molekulargewichtes von styrolpolymeren | |
DE69604616D1 (de) | Verfahren zur Polymerisierungshemmung | |
DE69628797D1 (de) | Verfahren zur verhinderung von harzablagerungen | |
DE68911300D1 (de) | Verfahren zur polymerisationsinhibierung von säuremonomeren. | |
DE69716419D1 (de) | Methode zur inhibierung der polymerisation von ethylenische ungesattigten monomeren |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8327 | Change in the person/name/address of the patent owner |
Owner name: NALCO/EXXON ENERGY CHEMICALS L.P., SUGAR LAND, TEX |
|
8363 | Opposition against the patent | ||
8331 | Complete revocation | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: ONDEO NALCO ENERGY SERVICES,L.P.(N.D.GES.D.STAATES |