DE69501277D1 - Katalysatorkomponente zur Olefinpolymerisation, erhalten durch Impregnierung eines Prepolymeren mit einer Lösung einer Katalysator komponente und unter Verwendung dieser Katalysatorkomponente erhaltenes Polymer - Google Patents

Katalysatorkomponente zur Olefinpolymerisation, erhalten durch Impregnierung eines Prepolymeren mit einer Lösung einer Katalysator komponente und unter Verwendung dieser Katalysatorkomponente erhaltenes Polymer

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Publication number
DE69501277D1
DE69501277D1 DE69501277T DE69501277T DE69501277D1 DE 69501277 D1 DE69501277 D1 DE 69501277D1 DE 69501277 T DE69501277 T DE 69501277T DE 69501277 T DE69501277 T DE 69501277T DE 69501277 D1 DE69501277 D1 DE 69501277D1
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Germany
Prior art keywords
catalyst component
prepolymer
impregnating
compsn
solution
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Expired - Fee Related
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DE69501277T
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English (en)
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DE69501277T2 (de
Inventor
Jean Malinge
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Arkema France SA
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Elf Atochem SA
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Publication of DE69501277T2 publication Critical patent/DE69501277T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/627—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/629—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69501277T 1994-03-23 1995-03-13 Katalysatorkomponente zur Olefinpolymerisation, erhalten durch Impregnierung eines Prepolymeren mit einer Lösung einer Katalysator komponente und unter Verwendung dieser Katalysatorkomponente erhaltenes Polymer Expired - Fee Related DE69501277T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9403420A FR2717816B1 (fr) 1994-03-23 1994-03-23 Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.

Publications (2)

Publication Number Publication Date
DE69501277D1 true DE69501277D1 (de) 1998-02-05
DE69501277T2 DE69501277T2 (de) 1998-07-16

Family

ID=9461352

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69501277T Expired - Fee Related DE69501277T2 (de) 1994-03-23 1995-03-13 Katalysatorkomponente zur Olefinpolymerisation, erhalten durch Impregnierung eines Prepolymeren mit einer Lösung einer Katalysator komponente und unter Verwendung dieser Katalysatorkomponente erhaltenes Polymer

Country Status (12)

Country Link
US (2) US6551956B1 (de)
EP (1) EP0673950B1 (de)
JP (1) JPH07268016A (de)
KR (1) KR100397861B1 (de)
CN (1) CN1068605C (de)
AT (1) ATE161551T1 (de)
CA (1) CA2144472A1 (de)
DE (1) DE69501277T2 (de)
ES (1) ES2112020T3 (de)
FI (1) FI951347A (de)
FR (1) FR2717816B1 (de)
NO (1) NO951097L (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
KR970015607A (ko) * 1995-09-14 1997-04-28 크리스탄 플뢰미히 다수의 고체 촉매성분을 결합시키는 올레핀 중합을 위한 초기중합체
FR2738829B1 (fr) * 1995-09-19 1997-10-17 Atochem Elf Sa Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides
ES2171640T3 (es) 1996-06-26 2002-09-16 Bp Chem Int Ltd Procedimiento para la polimerizacion de etileno en fase gaseosa.
EP0816394B1 (de) * 1996-06-26 2002-01-30 BP Chemicals S.N.C. Verfahren zur Ethylenpolymerisation in der Gasphase
DE69907785T2 (de) 1998-03-09 2004-02-12 Basell Poliolefine Italia S.P.A. Mehrstufiges Verfahren zur Olefinpolymerisation
US6136747A (en) * 1998-06-19 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst composition for the production of olefin polymers
ITMI991552A1 (it) * 1999-07-14 2001-01-14 Licio Zambon Componenti di catalizzatori per la polimerizzazione di olefine
US7991291B2 (en) * 2007-02-08 2011-08-02 Finisar Corporation WDM PON based on DML
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0745541B2 (ja) 1986-10-02 1995-05-17 チッソ株式会社 ポリオレフイン製造用固体触媒成分の製造法
US4921825A (en) 1986-12-30 1990-05-01 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and processes for its production
US5122583A (en) * 1987-02-02 1992-06-16 Fina Technology, Inc. Efficiency of a pre-polymerized catalyst
US5120696A (en) 1989-12-29 1992-06-09 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
US5266544A (en) 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
MY141000A (en) * 1990-04-18 2010-02-12 Mitsui Chemicals Inc Process for the preparation of an ethylene copolymer and an olefin polymer, and catalysts for olefin polymerization
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
US5804524A (en) * 1993-04-28 1998-09-08 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
BE1007040A3 (fr) 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
IT1269931B (it) 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine

Also Published As

Publication number Publication date
EP0673950B1 (de) 1997-12-29
NO951097D0 (no) 1995-03-22
CN1112131A (zh) 1995-11-22
ES2112020T3 (es) 1998-03-16
US6551956B1 (en) 2003-04-22
FR2717816B1 (fr) 1996-04-26
CA2144472A1 (fr) 1995-09-24
CN1068605C (zh) 2001-07-18
FI951347A (fi) 1995-09-24
US20030171208A1 (en) 2003-09-11
EP0673950A1 (de) 1995-09-27
ATE161551T1 (de) 1998-01-15
US7019090B2 (en) 2006-03-28
KR100397861B1 (ko) 2003-12-18
FI951347A0 (fi) 1995-03-22
FR2717816A1 (fr) 1995-09-29
JPH07268016A (ja) 1995-10-17
KR950032331A (ko) 1995-12-20
NO951097L (no) 1995-09-25
DE69501277T2 (de) 1998-07-16

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8363 Opposition against the patent
8328 Change in the person/name/address of the agent

Representative=s name: PATENTANWAELTE GESTHUYSEN, VON ROHR & EGGERT, 45128

8365 Fully valid after opposition proceedings
8339 Ceased/non-payment of the annual fee